CN102911439B - Fire-resistant control cable material for ships and method for preparing same - Google Patents
Fire-resistant control cable material for ships and method for preparing same Download PDFInfo
- Publication number
- CN102911439B CN102911439B CN201210346183.3A CN201210346183A CN102911439B CN 102911439 B CN102911439 B CN 102911439B CN 201210346183 A CN201210346183 A CN 201210346183A CN 102911439 B CN102911439 B CN 102911439B
- Authority
- CN
- China
- Prior art keywords
- parts
- compound
- control cable
- cable material
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention discloses a fire-resistant control cable material for ships and a method for preparing the fire-resistant control cable material. The fire-resistant control cable material comprises the following raw materials by weight: a mixture A and a mixture B; the mixture A comprises 10-20 parts of polyolefin elastomer, 20-30 parts of ethylene-propylene-diene monomer rubber, 20-30 parts of high-density polyethylene resin, 10-20 parts of chlorinated polyethylene, 1-3 parts of semi-reinforcing carbon black, 40-60 parts of modified sepiolite powder, 1-3 parts of magnesium oxide, 1.5-2.5 parts of a promoting agent which is the DTDM, 1-3 parts of zinc stearate, 3-4 parts of ethylene bis-stearamide, and 1-3 parts of dibutyl phthalate; and the mixture B comprises 10-20 parts of polyolefin elastomer, 20-30 parts of nitrile rubber, 20-30 parts of PVC resin powder, 10-20 parts of acrylate rubber, 1-3 parts of 2-mercaptobenzothiazole, 2-3 parts of DCP (dicumyl peroxide), 1-3 parts of antioxidant 1010, 1-3 parts of talc powder and 1-3 parts of zinc borate. The method for preparing the fire-resistant control cable material is simple, the fire-resistant control cable material has excellent electrical properties, the formula of the raw materials is reasonable, and the prepared cable material is environmentally friendly and has hot oil resistance, fire resistance and thermal oxidative aging properties.
Description
Technical field
The present invention relates to a kind of fireproof control cable material peculiar to vessel and preparation method thereof, belong to CABLE MATERIALS technical field.
Background technology
Along with developing rapidly of economy, electric wire is at industry-by-industry, in field, be all widely used, along with the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually, when cable fire, discharge a large amount of smog and poisonous, corrosive gas is Hazard Factor in fire, people's safe escape and fire-fighting work in fire, are hindered, make lives and properties suffer heavy losses, simultaneously along with communication career, the development of automotive industry and computer industry, particularly wire peculiar to vessel, line for cars, high temperature instrument cable, many occasions such as oil drilling platform cable, certain fireproof control cable material peculiar to vessel is also absolutely necessary.
Summary of the invention
The object of this invention is to provide a kind of fireproof control cable material peculiar to vessel and preparation method thereof, preparation method of the present invention is simple, electrical property excellence, and constitutive material formula is reasonable, not only environmental protection of the CABLE MATERIALS making, has the performances such as well heat-resisting, resistivity against fire and thermo oxidative aging.
The following technical scheme of employing of the present invention for achieving the above object:
Fireproof control cable material peculiar to vessel, the weight part of its constitutive material is:
Compound A: polyolefin elastomer 10-20, terpolymer EP rubber 20-30, high-density polyethylene resin 20-30, chlorinatedpolyethylene 10-20, semi-reinforcing hydrocarbon black 1-3, modified meerschaum powder 40-60, magnesium oxide 1-3, vulkacit D TDM 1.5-2.5, Zinic stearas 1-3, the two hard esteramides 3-4 of ethylene group and dibutyl phthalate 1-3;
Compound B: polyolefin elastomer 10-20, paracril 20-30, polyvinyl chloride resin powder 20-30, acrylic elastomer 10-20,2-thiol group benzimidazolyl 1-3, dicumyl peroxide DCP 2-3, antioxidant 1010 1-3, talcum powder 30-40 and zinc borate 1-3.
Fireproof control cable material peculiar to vessel, the weight part of its constitutive material is:
Compound A: polyolefin elastomer 15, terpolymer EP rubber 25, high-density polyethylene resin 25, chlorinatedpolyethylene 15, semi-reinforcing hydrocarbon black 2, modified meerschaum powder 50, magnesium oxide 2, vulkacit D TDM 2, Zinic stearas 2, the two hard esteramides 3.5 of ethylene group and dibutyl phthalate 2;
Compound B: polyolefin elastomer 15, paracril 25, polyvinyl chloride resin powder 25, acrylic elastomer 15,2-thiol group benzimidazolyl 2, dicumyl peroxide DCP 2.5, antioxidant 1010 2, talcum powder 35-40 and zinc borate 2.
The preparation method of fireproof control cable material peculiar to vessel, comprises the following steps:
(1) first take respectively all raw materials of compound A, B by the weight part of constitutive material; By the raw material of compound A, B respectively at temperature 100-120 ℃ after banburying 5-7 minute, mixing 25-35 minute at temperature 170-190 ℃ again after banburying, obtains respectively compound A and compound B;
(2) mix compound A and compound B, mixing 10-15 minute at temperature 170-190 ℃, then carries out high-energy radiation, is respectively cross-linking radiation under 10-12KW, 8-9Mev electron beam at power and energy, and irradiation dose is 180-230Gy, extrudes and makes material.
Described polyolefin elastomer is POE7467, injection grade, and du pont company manufactures.
Described modified meerschaum powder, preparation method thereof, for first using 15-20% salt acid soak sepiolite 1-2 hour, leaves standstill, clarification, centrifugal, solid washes with water to neutrality, after oven dry, add that to be equivalent to the vinyltriethoxysilane agitating of solid weight 3-5% even, dry, be ground into powder.
Advantage of the present invention:
Preparation method of the present invention is simple, electrical property excellence, and constitutive material formula is reasonable, and not only environmental protection of the CABLE MATERIALS making has the performances such as well heat-resisting, resistivity against fire and thermo oxidative aging.
Embodiment
embodiment 1:fireproof control cable material peculiar to vessel, the weight part of its constitutive material is:
Compound A: polyolefin elastomer 15, terpolymer EP rubber 25, high-density polyethylene resin 25, chlorinatedpolyethylene 15, semi-reinforcing hydrocarbon black 2, modified meerschaum powder 50, magnesium oxide 2, vulkacit D TDM 2, Zinic stearas 2, the two hard esteramides 3.5 of ethylene group and dibutyl phthalate 2;
Compound B: polyolefin elastomer 15, paracril 25, polyvinyl chloride resin powder 25, acrylic elastomer 15,2-thiol group benzimidazolyl 2, dicumyl peroxide DCP 2.5, antioxidant 1010 2, talcum powder 35 and zinc borate 2.
The preparation method of fireproof control cable material peculiar to vessel, comprises the following steps:
(1) first take respectively all raw materials of compound A, B by the weight part of constitutive material; By the raw material of compound A, B respectively at temperature 100-120 ℃ after banburying 5-7 minute, mixing 25-35 minute at temperature 170-190 ℃ again after banburying, obtains respectively compound A and compound B;
(2) mix compound A and compound B, mixing 10-15 minute at temperature 170-190 ℃, then carries out high-energy radiation, is respectively cross-linking radiation under 10-12KW, 8-9Mev electron beam at power and energy, and irradiation dose is 180-230Gy, extrudes and makes material.
Described polyolefin elastomer is POE7467, injection grade, and du pont company manufactures; Described modified meerschaum powder, preparation method thereof, for first using 15-20% salt acid soak sepiolite 1-2 hour, leaves standstill, clarification, centrifugal, solid washes with water to neutrality, after oven dry, add that to be equivalent to the vinyltriethoxysilane agitating of solid weight 3-5% even, dry, be ground into powder.
the fireproof control cable material property energy peculiar to vessel that the present invention makes:
Use temperature 170-190 ℃, 220 ℃ of maximum operation (service) temperatures, stretching strength retentivity 75-78%, conservation rate 73-75% is stretched out in fracture, changes in hardness+23,185 ℃ of bendings are qualified.Tensile strength is 15.3-18Mpa, oxygen index 30-38.5%, and smoke density is 69-75, testing vertical flammability is by UL-94V0 level, volume specific resistance 7.4 × 10
14ohm. centimetre, the heat ageing test of 136 ℃ × 168 hours can be passed through.
Claims (4)
1. a fireproof control cable material peculiar to vessel, is characterized in that the weight part of its constitutive material is:
Compound A: polyolefin elastomer 10-20, terpolymer EP rubber 20-30, high-density polyethylene resin 20-30, chlorinatedpolyethylene 10-20, semi-reinforcing hydrocarbon black 1-3, modified meerschaum powder 40-60, magnesium oxide 1-3, vulkacit D TDM 1.5-2.5, Zinic stearas 1-3, the two hard esteramides 3-4 of ethylene group and dibutyl phthalate 1-3;
Compound B: polyolefin elastomer 10-20, paracril 20-30, polyvinyl chloride resin powder 20-30, acrylic elastomer 10-20,2 mercapto benzimidazole 1-3, dicumyl peroxide DCP 2-3, antioxidant 1010 1-3, talcum powder 30-40 and zinc borate 1-3;
Described modified meerschaum powder, preparation method thereof, for first using 15-20% salt acid soak sepiolite 1-2 hour, leaves standstill, clarification, centrifugal, solid washes with water to neutrality, after oven dry, add that to be equivalent to the vinyltriethoxysilane agitating of solid weight 3-5% even, dry, be ground into powder.
2. fireproof control cable material peculiar to vessel according to claim 1, is characterized in that the weight part of its constitutive material is:
Compound A: polyolefin elastomer 15, terpolymer EP rubber 25, high-density polyethylene resin 25, chlorinatedpolyethylene 15, semi-reinforcing hydrocarbon black 2, modified meerschaum powder 50, magnesium oxide 2, vulkacit D TDM 2, Zinic stearas 2, the two hard esteramides 3.5 of ethylene group and dibutyl phthalate 2;
Compound B: polyolefin elastomer 15, paracril 25, polyvinyl chloride resin powder 25, acrylic elastomer 15,2 mercapto benzimidazole 2, dicumyl peroxide DCP 2.5, antioxidant 1010 2, talcum powder 35 and zinc borate 2.
3. a preparation method for fireproof control cable material peculiar to vessel as claimed in claim 1 or 2, is characterized in that comprising the following steps:
(1) first take respectively all raw materials of compound A, B by the weight part of constitutive material; By the raw material of compound A, B, respectively at temperature 100-120 ℃ of banburying 5-7 minute, mixing 25-35 minute at temperature 170-190 ℃ again after banburying, obtains respectively compound A and compound B;
(2) mix compound A and compound B, mixing 10-15 minute at temperature 170-190 ℃, then carries out high-energy radiation, is respectively cross-linking radiation under 10-12KW, 8-9Mev electron beam at power and energy, and irradiation dose is 180-230Gy, extrudes and makes material.
4. fireproof control cable material peculiar to vessel according to claim 1 and 2, is characterized in that: described polyolefin elastomer is POE7467, injection grade, and du pont company manufactures.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210346183.3A CN102911439B (en) | 2012-09-18 | 2012-09-18 | Fire-resistant control cable material for ships and method for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210346183.3A CN102911439B (en) | 2012-09-18 | 2012-09-18 | Fire-resistant control cable material for ships and method for preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102911439A CN102911439A (en) | 2013-02-06 |
| CN102911439B true CN102911439B (en) | 2014-06-18 |
Family
ID=47610032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210346183.3A Expired - Fee Related CN102911439B (en) | 2012-09-18 | 2012-09-18 | Fire-resistant control cable material for ships and method for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102911439B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103205033A (en) * | 2013-03-16 | 2013-07-17 | 安徽华津电缆集团有限公司 | Butyronitrile-PVC (polyvinyl chloride) compound elastomer flame-retardant sheath material for wires and cables and manufacturing method of butyronitrile-PVC compound elastomer flame-retardant sheath |
| CN103351537B (en) * | 2013-06-25 | 2016-04-13 | 绿宝电缆（集团）有限公司 | A kind of elastic CABLE MATERIALS |
| CN103396624B (en) * | 2013-07-15 | 2015-08-05 | 胡本巨 | A kind of antistatic PVC and preparation method thereof |
| CN103509257A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof |
| CN103509295B (en) * | 2013-10-12 | 2016-03-02 | 绿宝电缆（集团）有限公司 | A kind of environment-friendly heatproof composite elastic cable material for wires and cables |
| CN103554638A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | High-heat-resistant oil-resistant ethylene-acrylate rubber cable material |
| CN104672624B (en) * | 2014-10-11 | 2017-02-15 | 台州市百花胶带有限公司 | Rubber composition, V belt wrapper glue with adoption of rubber composition and preparation method of V belt wrapper glue |
| CN104558864A (en) * | 2015-01-15 | 2015-04-29 | 无为县华祥电缆材料有限公司 | Modified ethylene propylene diene monomer insulating cable material |
| US9879121B2 (en) | 2015-09-28 | 2018-01-30 | International Business Machines Corporation | Flame-retardant, cross-linked EPDM rubber |
| CN109553815A (en) * | 2018-12-24 | 2019-04-02 | 宁国市日格美橡塑制品有限公司 | A kind of high tear, lifting lug of vent pipe of highly anti-fatigue and preparation method thereof |
| CN110016190A (en) * | 2019-04-26 | 2019-07-16 | 惠州市福橡新材料科技有限公司 | A kind of radiation core rubber |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1151200C (en) * | 2001-05-15 | 2004-05-26 | 南开大学 | Modified polyolefine elastomer and its preparing process |
| CN101486815A (en) * | 2009-02-20 | 2009-07-22 | 石明东 | Thermoplastic low-smoke halogen-free polyolefin material and preparation thereof |
-
2012
- 2012-09-18 CN CN201210346183.3A patent/CN102911439B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN102911439A (en) | 2013-02-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102911439B (en) | Fire-resistant control cable material for ships and method for preparing same | |
| CN102977605B (en) | A kind of silicone rubber crosslinking fire-resistant cable material and preparation method thereof | |
| CN102977585B (en) | A kind of polyurethane flame-proof environment-friendly cable material and preparation method thereof | |
| CN102911504B (en) | Environment-friendly waterproof and double-shielding control cable material and preparation method thereof | |
| CN102977466B (en) | A kind of flame-proof environmental protection safety type polyolefin jacket material and preparation method thereof | |
| CN103102596B (en) | A kind of cable for nuclear power station jacket insulation material and preparation method thereof | |
| CN102977614B (en) | A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof | |
| CN102911409B (en) | Environment-friendly tensile high-temperature-resistant control cable material and preparation method thereof | |
| CN102977609B (en) | A kind of oil resistant low temperature resistant fireproofing cable material without halide peculiar to vessel and preparation method thereof | |
| CN102977611B (en) | A kind of computer halide-free low-smoke fireproof cable material and preparation method thereof | |
| CN102911467B (en) | Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material | |
| CN102977610B (en) | A kind of cross-linking low smoke halogen-free flame retardant CABLE MATERIALS used for rolling stock and preparation method thereof | |
| CN101649083B (en) | IE-grade KI -type cable insulation material for nuclear power and preparation technology thereof | |
| CN102911441B (en) | High-temperature-resistant moisture-proof mould-proof environment-friendly cable material and preparation method thereof | |
| CN103214749B (en) | A kind of thermoplastic polyurethane elastomer cable material and preparation method thereof | |
| CN102746546A (en) | Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method | |
| CN102757588B (en) | A kind of Polyvinyl chloride flame-retardant fireproof power cable material and preparation method thereof | |
| CN104327366A (en) | Weather-proof type halogen-free flame-retardation cable sheath material formula used for locomotive and preparation method thereof | |
| CN103102544A (en) | Low-smoke zero-halogen flame-retardant cable material and preparation method thereof | |
| CN103102541A (en) | Low-smoke flame retardant cable material for locomotive and preparation method thereof | |
| CN103980619A (en) | Low-smoke halogen-free flame-retardation insulation material for class 1E category K1 cables of nuclear power station | |
| CN102746585A (en) | Polypropylene insulation cable material and its preparation method | |
| CN104183317A (en) | Irradiation-resistant halogen-free high-flame-retardant EVA electric wire and manufacturing method thereof | |
| CN103992567A (en) | Flame retardant high insulation cable material with radiation resistance for nuclear power plant | |
| CN103214774A (en) | Polyvinylchloride insulating electric power cable material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140618 Termination date: 20150918 |
|
| EXPY | Termination of patent right or utility model |