CN103509295A - Environment-friendly heat-proof composite elastic cable material for cables and cords - Google Patents
Environment-friendly heat-proof composite elastic cable material for cables and cords Download PDFInfo
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- CN103509295A CN103509295A CN201310473892.2A CN201310473892A CN103509295A CN 103509295 A CN103509295 A CN 103509295A CN 201310473892 A CN201310473892 A CN 201310473892A CN 103509295 A CN103509295 A CN 103509295A
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- 239000000463 material Substances 0.000 title claims abstract description 40
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000000945 filler Substances 0.000 claims abstract description 16
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 9
- 239000012188 paraffin wax Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052580 B4C Inorganic materials 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 6
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004927 clay Substances 0.000 claims abstract description 6
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 6
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 6
- 239000010445 mica Substances 0.000 claims abstract description 6
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 6
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 6
- 239000003549 soybean oil Substances 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000004113 Sepiolite Substances 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims description 10
- 235000019355 sepiolite Nutrition 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 7
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 5
- 241000143437 Aciculosporium take Species 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 5
- 235000005747 Carum carvi Nutrition 0.000 claims description 5
- 240000000467 Carum carvi Species 0.000 claims description 5
- 229940037003 alum Drugs 0.000 claims description 5
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 239000011021 lapis lazuli Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- -1 phosphorous acid ester Chemical class 0.000 claims description 5
- 229920005559 polyacrylic rubber Polymers 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 239000000341 volatile oil Substances 0.000 claims description 5
- 239000001993 wax Substances 0.000 claims description 5
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 claims description 5
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 claims description 3
- 102100024304 Protachykinin-1 Human genes 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- RWPICVVBGZBXNA-BGYRXZFFSA-N Bis(2-ethylhexyl) terephthalate Natural products CCCC[C@H](CC)COC(=O)C1=CC=C(C(=O)OC[C@H](CC)CCCC)C=C1 RWPICVVBGZBXNA-BGYRXZFFSA-N 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- RWPICVVBGZBXNA-UHFFFAOYSA-N bis(2-ethylhexyl) benzene-1,4-dicarboxylate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C=C1 RWPICVVBGZBXNA-UHFFFAOYSA-N 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 150000008301 phosphite esters Chemical class 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 239000004945 silicone rubber Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an environment-friendly heat-proof composite elastic cable material for cables and cords. The environment-friendly heat-proof composite elastic cable material is prepared from the following raw materials in parts by weight: 30 to 40 parts of polyvinyl chloride resin, 20 to 30 parts of silicone rubber, 20 to 30 parts of polyacrylate rubber, 5 to 8 parts of soybean oil, 10 to 15 parts of bis(2-ethylhexyl) terephthalate, 6 to 8 parts of trioctyl trimellitate, 8 to 10 parts of tributyl citrate, 1 to 2 parts of a crosslinking agent TAC, 12 to 15 parts of ground calcium carbonate, 12 to 14 parts of mica powder, 10 to 12 parts of clay powder, 8 to 10 parts of carbon black powder, 6 to 8 parts of bentonite, 8 to 10 parts of aluminium hydroxide, 2 to 4 parts of talc powder, 1 to 2 parts of nano boron carbide, 1 to 3 parts of phosphoguanidine, 6 to 8 parts of zinc borate, 1 to 2 parts of stearic acid, 2 to 4 parts of high-melting-point paraffin, 1 to 2 parts of semi-refined paraffin wax, 5 to 8 parts of hydrotalcite, 3 to 4 parts of phosphite ester and 5 to 8 parts of modified filler. A cable processed with the cable material provided by the invention can resist high temperature, and the temperature resisting grade is 125 DEG C; the cable material has the advantages of environment-friendliness, good mechanical material performance and the like.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of environment-friendly heatproof composite elastic cable material for wires and cables.
Background technology
Electric wire is important materials indispensable in industrial and agricultural production and the modern life, China is that the electric wire of whole world maximum is produced country, wires and cables industry occupies very important status in the national economy of China, but, at present, CABLE MATERIALS on market exists non-refractory, not ageing-resistant, and after weathering test, the phenomenon that becomes fragile of turning to be yellow appears in material.Electric wire fire aging and that cause is also more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free smokeless environment-friendly heatproof composite elastic cable material for wires and cables is increasing, the production of halide-free smokeless environment-friendly heatproof composite elastic cable material for wires and cables is in polyolefin substrate, to add a large amount of Shawinigan blacks or Shawinigan black to reach flame retardant effect mostly at present, yet, adding of a large amount of inorganic materials, physical and mechanical properties and the processing of CABLE MATERIALS have been affected.Fire-retardant, low cigarette, environmental protection, high temperature resistant, CABLE MATERIALS becomes the direction of CABLE MATERIALS development cheaply.
Summary of the invention
The invention provides a kind of environment-friendly heatproof composite elastic cable material for wires and cables and preparation method thereof.The cable being processed into by CABLE MATERIALS of the present invention has high temperature resistant, and temperature resistant grade is 125 ℃, has the advantages such as environmental protection, mechanical material performance be good.
The technical solution used in the present invention is:
A kind of environment-friendly heatproof composite elastic cable material for wires and cables, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 30-40, silicon rubber 20-30, polyacrylic rubber 20-30, soybean oil 5-8, dioctyl terephthalate 10-15, trioctyl trimellitate 6-8, tributyl citrate 8-10, linking agent TAC1-2, water-ground limestone 12-15, mica powder 12-14, potter's clay powder 10-12, carbon powder 8-10, wilkinite 6-8, aluminium hydroxide 8-10, talcum powder 2-4, nano boron carbide 1-2, phosphoguanidine 1-3, zinc borate 6-8, stearic acid 1-2, inspissated wax 2-4, SEMI-REFINED PARAFFIN WAX 1-2, hydrotalcite 5-8, phosphorous acid ester 3-4, modified filler 5-8,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
Described environment-friendly heatproof composite elastic cable material for wires and cables, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 35, silicon rubber 25, polyacrylic rubber 25, soybean oil 7, dioctyl terephthalate 12, trioctyl trimellitate 8, tributyl citrate 9, linking agent TAC1, water-ground limestone 13, mica powder 13, potter's clay powder 11, carbon powder 9, wilkinite 7, aluminium hydroxide 9, talcum powder 3, nano boron carbide 1, phosphoguanidine 1, zinc borate 7, stearic acid 1, inspissated wax 3, SEMI-REFINED PARAFFIN WAX 2, hydrotalcite 6, phosphorous acid ester 3, modified filler 7,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 200, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
The preparation method of CABLE MATERIALS of the present invention:
By formula rate, take each constitutive material, constitutive material is dropped into homogenizer mixing 5-6miu, blowing, the material mixing is put in twin screw extruder, extruding pelletization, then after entering and being dried in hot air dryer, obtain environment-friendly heatproof composite elastic cable material for wires and cables, while extruding, twin screw extruder temperature setting is set to: 114 ℃ of feeding sections, 175 ℃ of melt zones, melt conveying zone 175-182 ℃, 190 ℃ of mixing sections, 185 ℃ of homogenizing zones, 185 ℃ of head metering zones.
Beneficial effect
The present invention compared with prior art, it is main foundation material that polyvinyl chloride (PVC) RESINS, high-polymerization degree polyacrylate resin, PVC-NBR blend, PVC/PU blend are take in the present invention, add softening agent, stopping composition and other auxiliary agent, finally obtain environment-friendly heatproof composite elastic cable material for wires and cables finished product pellet, carry out in material sulfuration situation not needing, greatly improved the resistance to elevated temperatures of traditional thermoplastic polyvinyl chloride's material, temperature resistant grade is 125 ℃, has the advantages such as environmental protection, mechanical material performance be good.
Embodiment
, by the component raw material preparation of following weight (kg), obtained:
Polyvinyl chloride (PVC) RESINS 35, silicon rubber 25, polyacrylic rubber 25, soybean oil 7, dioctyl terephthalate 12, trioctyl trimellitate 8, tributyl citrate 9, linking agent TAC1, water-ground limestone 13, mica powder 13, potter's clay powder 11, carbon powder 9, wilkinite 7, aluminium hydroxide 9, talcum powder 3, nano boron carbide 1, phosphoguanidine 1, zinc borate 7, stearic acid 1, inspissated wax 3, SEMI-REFINED PARAFFIN WAX 2, hydrotalcite 6, phosphorous acid ester 3, modified filler 7
Wherein, modified filler is to be prepared and obtained by following method:
A. take off the raw material of row weight part: kaolin 200, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
The preparation method of environment-friendly heatproof composite elastic cable material for wires and cables:
By formula rate, take each constitutive material, constitutive material is dropped into homogenizer mixing 5-6miu, blowing, the material mixing is put in twin screw extruder, extruding pelletization, then after entering and being dried in hot air dryer, obtain environment-friendly heatproof composite elastic cable material for wires and cables, while extruding, twin screw extruder temperature setting is set to: 114 ℃ of feeding sections, 175 ℃ of melt zones, melt conveying zone 175-182 ℃, 190 ℃ of mixing sections, 185 ℃ of homogenizing zones, 185 ℃ of head metering zones.
The performance test results of the CABLE MATERIALS that the present embodiment makes is as following table:
Claims (2)
1. an environment-friendly heatproof composite elastic cable material for wires and cables, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 30-40, silicon rubber 20-30, polyacrylic rubber 20-30, soybean oil 5-8, dioctyl terephthalate 10-15, trioctyl trimellitate 6-8, tributyl citrate 8-10, linking agent TAC 1-2, water-ground limestone 12-15, mica powder 12-14, potter's clay powder 10-12, carbon powder 8-10, wilkinite 6-8, aluminium hydroxide 8-10, talcum powder 2-4, nano boron carbide 1-2, phosphoguanidine 1-3, zinc borate 6-8, stearic acid 1-2, inspissated wax 2-4, SEMI-REFINED PARAFFIN WAX 1-2, hydrotalcite 5-8, phosphorous acid ester 3-4, modified filler 5-8,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
2. environment-friendly heatproof composite elastic cable material for wires and cables according to claim 1, is characterized in that, by the component raw material preparation of following weight part and obtain: polyvinyl chloride (PVC) RESINS 35, silicon rubber 25, polyacrylic rubber 25, soybean oil 7,
dioctyl terephthalate 12,trioctyl trimellitate 8, tributyl citrate 9, linking agent TAC1, water-ground limestone 13, mica powder 13, potter's clay powder 11, carbon powder 9, wilkinite 7, aluminium hydroxide 9, talcum powder 3, nano boron carbide 1, phosphoguanidine 1, zinc borate 7, stearic acid 1, inspissated wax 3, SEMI-REFINED PARAFFIN WAX 2, hydrotalcite 6, phosphorous acid ester 3, modified filler 7
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 200, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310473892.2A CN103509295B (en) | 2013-10-12 | 2013-10-12 | A kind of environment-friendly heatproof composite elastic cable material for wires and cables |
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| CN201310473892.2A CN103509295B (en) | 2013-10-12 | 2013-10-12 | A kind of environment-friendly heatproof composite elastic cable material for wires and cables |
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| CN103509295A true CN103509295A (en) | 2014-01-15 |
| CN103509295B CN103509295B (en) | 2016-03-02 |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN109161207A (en) * | 2018-07-13 | 2019-01-08 | 安徽华菱电缆集团有限公司 | A kind of cable low-smoke non-halogen flame-retardant silastic material and preparation method thereof |
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| US11359071B2 (en) * | 2015-02-12 | 2022-06-14 | Lg Chem, Ltd. | Plasticizer composition and resin composition, and preparation method thereof |
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| CN103756225B (en) * | 2014-01-23 | 2015-08-05 | 宜昌华润红旗电缆有限公司 | A kind of high flame retardant stopping composition and preparation method and the mining high flame retardant flexible cable be made up of it |
| CN104194219A (en) * | 2014-09-01 | 2014-12-10 | 安徽太平洋电缆股份有限公司 | Low-smoke low-halogen flame-retardant PVC cable material and preparation method thereof |
| CN104312066A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Cable material with strong stability as well as preparation method thereof |
| US11359071B2 (en) * | 2015-02-12 | 2022-06-14 | Lg Chem, Ltd. | Plasticizer composition and resin composition, and preparation method thereof |
| CN104927008A (en) * | 2015-07-07 | 2015-09-23 | 姚雳 | Modified insulation cable material |
| CN106349589A (en) * | 2015-07-13 | 2017-01-25 | 日立金属株式会社 | Pvc composition as well as electric wire and cable using the same |
| CN106349590A (en) * | 2015-07-13 | 2017-01-25 | 日立金属株式会社 | Vinyl chloride resin composition as well as electric wire and cable using same |
| CN106349588A (en) * | 2015-07-13 | 2017-01-25 | 日立金属株式会社 | Pvc composition as well as electric wire and cable using the same |
| CN106349590B (en) * | 2015-07-13 | 2019-11-26 | 日立金属株式会社 | Vinyl chloride resin composition and the electric wire and cable for using it |
| CN106349588B (en) * | 2015-07-13 | 2020-02-21 | 日立金属株式会社 | Vinyl chloride resin composition, and electric wire and cable using same |
| CN106349589B (en) * | 2015-07-13 | 2019-12-10 | 日立金属株式会社 | Vinyl chloride resin composition, and electric wire and cable using same |
| CN105374439A (en) * | 2015-11-24 | 2016-03-02 | 安徽南洋新材料科技股份有限公司 | High-toughness abrasion-resistant damping cable used for ships |
| CN105374439B (en) * | 2015-11-24 | 2017-09-15 | 安徽南洋新材料科技股份有限公司 | A kind of ship high-toughness wear-resistant damping cable |
| CN106189002A (en) * | 2016-08-08 | 2016-12-07 | 安徽埃克森科技集团有限公司 | A kind of petrochemical industry fluoroplastics oil resistant cable sheath |
| CN106349601A (en) * | 2016-08-26 | 2017-01-25 | 桐城市中汇塑业有限公司 | PP-PVC blended plastic composite material |
| CN106519512A (en) * | 2016-11-25 | 2017-03-22 | 安徽美翔塑业有限公司 | Rubber material and preparation method thereof |
| CN106700369A (en) * | 2016-12-05 | 2017-05-24 | 钦州市钦南区生产力促进中心 | High-voltage cable and preparation method thereof |
| CN109161207A (en) * | 2018-07-13 | 2019-01-08 | 安徽华菱电缆集团有限公司 | A kind of cable low-smoke non-halogen flame-retardant silastic material and preparation method thereof |
| CN110105690A (en) * | 2019-05-17 | 2019-08-09 | 天长市富达电子有限公司 | A kind of high tenacity cold-resistant electric wire protective materials and preparation method thereof |
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