CN105374439B - A kind of ship high-toughness wear-resistant damping cable - Google Patents

A kind of ship high-toughness wear-resistant damping cable Download PDF

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CN105374439B
CN105374439B CN201510836501.8A CN201510836501A CN105374439B CN 105374439 B CN105374439 B CN 105374439B CN 201510836501 A CN201510836501 A CN 201510836501A CN 105374439 B CN105374439 B CN 105374439B
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parts
oversheath
proof quality
gel
raw material
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CN105374439A (en
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朱成颍
叶明高
张平
陆长文
汪金飞
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Anhui Nanyang New Material Technology Co Ltd
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Anhui Nanyang New Material Technology Co Ltd
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Abstract

The invention discloses a kind of ship high-toughness wear-resistant damping cable, including conductor, insulating barrier, packed layer, screen layer, armor and oversheath;The raw material of oversheath includes by weight:50 60 parts of butadiene rubber, 20 25 parts of ethylene propylene diene rubber, 15 18 parts of haloflex 140B, 8 12 parts of the high heat-proof quality gel of high tenacity, 1 1.5 parts of Cosan, 1.4 1.7 parts of altax, 2.1 2.4 parts of TM monex TM, 57 parts of trioctyl trimellitate (TOTM), 2 3.5 parts of ATBC, 25 28 parts of blanc fixe, 17 20 parts of high wear-resistant carbon black, 12 15 parts of nano-calcium carbonate, 7 10 parts of superfine talcum powder, 69 parts of hard (china) clay, 58 parts of kaolin, 24 parts of red phosphorus, 0.3 0.6 parts of NOBS, 0.5 1 parts of anti-aging agent RD, 2.5 4 parts of anti-aging agent RD.

Description

A kind of ship high-toughness wear-resistant damping cable
Technical field
The present invention relates to field of cable technology, more particularly to a kind of ship high-toughness wear-resistant damping cable.
Background technology
The elastomeric material used in shipbuilding plays vital effect in terms of maintenance ship normally operation, and electric Cable is particularly important as the important component for ensureing marine vessel power supply and driving safety, because ship use environment is severe, At present, for safety, the replacing to cable is more frequent, while considerably increasing operation costs, also restricts for many ships The execution of long-term marine task, therefore in the application, the toughness of cable, wear-resisting and damping performance need to be strengthened.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of ship high-toughness wear-resistant damping cable, The characteristics of with high intensity, high tenacity, while heat-proof quality is excellent.
A kind of ship proposed by the present invention high-toughness wear-resistant damping cable, includes insulating barrier, the bag of conductor, coating conductor The packed layer of insulating layer coating, the screen layer for coating packed layer, the armor for coating screen layer and the oversheath for coating armor;
The raw material of wherein oversheath includes by weight:50-60 parts of butadiene rubber, 20-25 parts of ethylene propylene diene rubber, chlorination 15-18 parts of polyethylene 140B, 8-12 parts of high tenacity high heat-proof quality gel, 1-1.5 parts of Cosan, altax 1.4-1.7 Part, 2.1-2.4 parts of TM monex TM, 5-7 parts of trioctyl trimellitate (TOTM), 2-3.5 parts of ATBC, blanc fixe 25-28 Part, 17-20 parts of high wear-resistant carbon black, 12-15 parts of nano-calcium carbonate, 7-10 parts of superfine talcum powder, 6-9 parts of hard (china) clay, kaolin 5-8 parts, 2-4 parts of red phosphorus, 0.3-0.6 parts of NOBS, 0.5-1 parts of anti-aging agent RD, 2.5-4 parts of anti-aging agent RD.
Preferably, in the raw material of oversheath, butadiene rubber is high-cis butadiene rubber.
Preferably, in the raw material of oversheath, butadiene rubber, ethylene propylene diene rubber, haloflex 140B, high tenacity it is high every The weight ratio of hot property gel is 53-56:21-24:16-17:9-11.
Preferably, the raw material of oversheath includes by weight:53-56 parts of butadiene rubber, 21-24 parts of ethylene propylene diene rubber, 16-17 parts of haloflex 140B, 9-11 parts of high tenacity high heat-proof quality gel, 1.2-1.4 parts of Cosan, altax 1.5-1.6 parts, 2.2-2.3 parts of TM monex TM, 5.5-6 parts of trioctyl trimellitate (TOTM), 2.6-3.2 parts of ATBC, weight 26-27 parts of spar powder, 18-19 parts of high wear-resistant carbon black, 13-14 parts of nano-calcium carbonate, 8-9 parts of superfine talcum powder, hard (china) clay 7-8 Part, 6-7 parts of kaolin, 2.5-3 parts of red phosphorus, 0.4-0.5 parts of NOBS, 0.6-0.7 parts of anti-aging agent RD, anti-aging agent RD 2.8-3.4 Part.
Preferably, the high heat-proof quality gel process for preparing of high tenacity in oversheath raw material is as follows:
S1, polyparaphenylene's Benzo-dioxazole fiber put into the first preformed solution, after immersion, dried, it is broken to obtain thing Expect A;After material A, silane coupler KH-560 are stirred, carry out oxygen plasma processing and obtain being modified polyparaphenylene's benzo Er oxazole fibers;
S2, titanium dioxide, modified polyparaphenylene's Benzo-dioxazole fiber, tetraethyl orthosilicate, absolute ethyl alcohol are mixed after, enter Row is ultrasonically treated to obtain material B;After the pH value for adjusting material B, heat up, insulation;Ammoniacal liquor is subsequently added into, stands and is coagulated after stirring Glue;
S3, by gel put into the second prefabricated cleaning solution in, after immersion, continuously add after hexamethylene, standing, filter, dry Obtain the high heat-proof quality gel of high tenacity.
Preferably, the high heat-proof quality gel process for preparing of high tenacity in oversheath raw material is as follows:
S1, by polyparaphenylene's Benzo-dioxazole fiber put into the first preformed solution in, immersion 12-14h after, dry, crush Obtain material A;After material A, silane coupler KH-560 are stirred, carry out oxygen plasma processing and obtain modified poly- to benzene Benzo-dioxazole fiber is supportted, the pressure of oxygen plasma processing is 36-39Pa, and the power of oxygen plasma processing is 230- 250W, the time of oxygen plasma processing is 10-13min;
S2, titanium dioxide, modified polyparaphenylene's Benzo-dioxazole fiber, tetraethyl orthosilicate, absolute ethyl alcohol are mixed after, enter Row is ultrasonically treated to obtain material B, and ultrasonically treated power is 300-330W, and ultrasonically treated power is at 60-65kHz, ultrasound The time of reason is 30-33min;Material B pH value is adjusted to after 3.5-3.8,57-60 DEG C is warming up to, is incubated 22-25min;Then The ammoniacal liquor that concentration is 8-10mol/L is added, 50-60min is stood after stirring and obtains gel;
S3, gel put into the second prefabricated cleaning solution, after immersion 24-26h, continuously adds hexamethylene, stand after 2-3h, Filtering, is dried to obtain the high heat-proof quality gel of high tenacity.
Preferably, the high heat-proof quality gel process for preparing of high tenacity in oversheath raw material is as follows:
S1,4-7 parts of polyparaphenylene's Benzo-dioxazole fibers are put into 10-13 the first preformed solutions of part by weight, soaked Steep after 12-14h, dry, it is broken to obtain material A;After material A, 5-7 parts of silane coupler KH-560 are stirred, oxygen is carried out Gas plasma treatment obtains being modified polyparaphenylene's Benzo-dioxazole fiber, and the pressure of oxygen plasma processing is 36-39Pa, oxygen The power of plasma treatment is 230-250W, and the time of oxygen plasma processing is 10-13min;
S2, by molar part by 0.4-0.7 parts of titanium dioxide, 0.4-0.7 parts of modified polyparaphenylene's Benzo-dioxazole fibers, 4- After 6 parts of tetraethyl orthosilicates, 15-18 parts of absolute ethyl alcohol mixing, progress is ultrasonically treated to obtain material B, and ultrasonically treated power is 300-330W, ultrasonically treated power is 60-65kHz, and the ultrasonically treated time is 30-33min;Adjust material B pH value to After 3.5-3.8,57-60 DEG C is warming up to, 22-25min is incubated;The ammoniacal liquor that 0.4-0.7 parts of concentration are 8-10mol/L is subsequently added into, 50-60min is stood after stirring and obtains gel;
S3,5-7 parts of gels are put into 10-15 the second prefabricated cleaning solutions of part by weight, after immersion 24-26h, continue to add Enter 10-13 parts of hexamethylenes, stand after 2-3h, filtering is dried to obtain the high heat-proof quality gel of high tenacity.
Preferably, in the S1 of the high heat-proof quality gel process for preparing of high tenacity in oversheath raw material, the first preformed solution It is 3-5 by volume by acetone, absolute ethyl alcohol to be:What 1-3 was mixed.
Preferably, in the S1 of the high heat-proof quality gel process for preparing of high tenacity in oversheath raw material, the length of material A is 3-5mm。
Preferably, in the S3 of the high heat-proof quality gel process for preparing of high tenacity in oversheath raw material, the second preformed solution It is 2-3 by volume by tetraethyl orthosilicate, absolute ethyl alcohol to be:What 7-8 was mixed.
Oversheath of the present invention coordinates ethylene propylene diene rubber, chlorinated polyethylene in preparation process using high-cis butadiene rubber The high heat-proof quality gel of alkene 140B, high tenacity makes the present invention possess excellent toughness, anti-wear performance and damping heat-insulated as major ingredient Performance;Wherein, in the preparation process of the high heat-proof quality gel of high tenacity, the use of polyparaphenylene's Benzo-dioxazole fiber is significantly carried High toughness, intensity, modulus and the resistance to elevated temperatures of the present invention, by polyparaphenylene's Benzo-dioxazole fiber input by designated volume Soaked in the first preformed solution being mixed than acetone and absolute ethyl alcohol, polyparaphenylene's Benzo-dioxazole fiber table can be removed The sizing material and pollutant in face, improve the degree of purity of the high heat-proof quality gel of high tenacity, then with silane coupler KH-560 infiltrations And plasma treatment is carried out with oxygen, a large amount of hole shape patterns can be etched in polyparaphenylene's Benzo-dioxazole fiber surface, are made Its surface irregularity, incorporates in gel so as to be conducive to being modified polyparaphenylene's Benzo-dioxazole fiber, formed it is fire-retardant, heat-insulated, The high heat-proof quality gel of high tenacity of high-modulus;And in the preparation of gel, anhydrous second is mingled in using tetraethyl orthosilicate as major ingredient In alcohol, and carry out it is ultrasonically treated, be conducive to titanium dioxide, modified polyparaphenylene's Benzo-dioxazole fiber, tetraethyl orthosilicate it is equal Even distribution, accelerates the precipitation of gel, while also making Si-O-Si groups in gel interconnect the nano-porous structure constituted more It is firm, and the titanium dioxide added is used as opacifier, caused by can avoiding the present invention in use due to illumination Gel fails;Then the ammoniacal liquor added promotes polycondensation reaction as the use of base catalyst, has further speeded up solidifying The formation of glue;Gelinite is then put into the solution being made up of special ratios tetraethyl orthosilicate and absolute ethyl alcohol to soak, makes gel Network skeleton further solidify;And the hexamethylene added can play solvent substitution, make the drying process then carried out In, solvent volatilization is complete in gel voids, it is ensured that obtain the high heat-proof quality gel of high tenacity of high-quality;With Cosan, promote The vulcanizing system that agent DM, TM monex TM three are constituted has curingprocess rate fast, and the characteristics of compressed shape variability is low can send out this The major ingredient of bright oversheath quickly forms " space three-dimensional structure " with rock-steady structure, enhance oversheath of the present invention toughness and Damping performance;And blanc fixe, high wear-resistant carbon black, nano-calcium carbonate, superfine talcum powder, hard (china) clay, kaolin etc. are different thin The addition of reinforcing filler is spent, oversheath molecular gap of the present invention can be further reduced, so that it is outer further to improve the present invention The anti-wear performance and damping performance of sheath;The ATBC and trioctyl trimellitate (TOTM) of addition are aided in, above-mentioned benefit is improved Strong solubility and dispersiveness of the filler in major ingredient;NOBS addition, can coordinate ATBC and tri trimellitate Monooctyl ester, improves the intermolecular joint power of oversheath major ingredient of the present invention, thus improve the hardness of oversheath of the present invention, tensile strength, Tearing strength;The addition of red phosphorus, reduces the flammable performance of oversheath of the present invention, it is ensured that of the invention uses safety;And it is anti-old Agent RD, anti-aging agent RD coordinate, then further increase the anti-aging and oxidation resistent susceptibility of oversheath of the present invention, extend the present invention Service life.
Brief description of the drawings
Fig. 1 is a kind of radial section structural representation of ship high-toughness wear-resistant damping cable proposed by the present invention.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
As shown in figure 1, Fig. 1 is a kind of radial section structure of ship high-toughness wear-resistant damping cable proposed by the present invention Schematic diagram.
Reference picture 1, a kind of ship proposed by the present invention high-toughness wear-resistant damping cable, including conductor 1, coating conductor 1 Insulating barrier 2, coated insulation layer 2 packed layer 3, coat packed layer 3 screen layer 4, coat screen layer 4 armor 5 and bag Cover the oversheath 6 of armor 5;
The raw material of wherein oversheath 6 includes by weight:60 parts of high-cis butadiene rubber, 20 parts of ethylene propylene diene rubber, chlorine Change 18 parts of polyethylene 140B, 8 parts of the high heat-proof quality gel of high tenacity, 1.5 parts of Cosan, 1.4 parts of altax, accelerator TMTM2.4 parts, 5 parts of trioctyl trimellitate (TOTM), 3.5 parts of ATBC, 25 parts of blanc fixe, 20 parts of high wear-resistant carbon black is received 12 parts of calcium carbonate of rice, 10 parts of superfine talcum powder, 6 parts of hard (china) clay, 8 parts of kaolin, 2 parts of red phosphorus, 0.6 part of NOBS, anti-aging agent RD 0.5 part, 4 parts of anti-aging agent RD;
The above-mentioned high heat-proof quality gel process for preparing of high tenacity is as follows:
S1,4 parts of polyparaphenylene's Benzo-dioxazole fibers are put into 13 part of first preformed solution by weight, first is prefabricated It is 5 by volume by acetone, absolute ethyl alcohol that solution, which is,:1 is mixed, and after immersion 12h, dries, and the broken length that obtains is 5mm Material A;After material A, 7 parts of silane coupler KH-560 are stirred, carry out oxygen plasma processing and obtain modified poly- pair Penylene Benzo-dioxazole fiber, the pressure of oxygen plasma processing is 36Pa, and the power of oxygen plasma processing is 250W, oxygen The time of plasma treatment is 10min;
S2, by molar part by 0.4 part of titanium dioxide, 0.7 part of modified polyparaphenylene's Benzo-dioxazole fiber, 4 parts of positive silicic acid After ethyl ester, 18 parts of absolute ethyl alcohol mixing, progress is ultrasonically treated to obtain material B, and ultrasonically treated power is 300W, ultrasonically treated Power is 65kHz, and the ultrasonically treated time is 30min;Material B pH value is adjusted to after 3.8,57 DEG C, insulation are warming up to 25min;The ammoniacal liquor that 0.4 part of concentration is 10mol/L is subsequently added into, 50min is stood after stirring and obtains gel;
S3,7 parts of gels are put into 10 part of second prefabricated cleaning solution by weight, the second preformed solution is by positive silicic acid second Ester, absolute ethyl alcohol are 1 by volume:4 are mixed, and after immersion 26h, continuously add 10 parts of hexamethylenes, stand after 3h, mistake Filter, is dried to obtain the high heat-proof quality gel of high tenacity.
Embodiment 2
A kind of ship proposed by the present invention high-toughness wear-resistant damping cable, including conductor 1, the insulating barrier of coating conductor 1 2nd, the packed layer 3 of coated insulation layer 2, the screen layer 4 for coating packed layer 3, the armor 5 of cladding screen layer 4 and cladding armor 5 Oversheath 6;
The raw material of wherein oversheath 6 includes by weight:50 parts of high-cis butadiene rubber, 25 parts of ethylene propylene diene rubber, chlorine Change 15 parts of polyethylene 140B, 12 parts of the high heat-proof quality gel of high tenacity, 1 part of Cosan, 11.7 parts of altax, accelerator 2.1 parts of TMTM, 7 parts of trioctyl trimellitate (TOTM), 2 parts of ATBC, 28 parts of blanc fixe, 17 parts of high wear-resistant carbon black, nanometer 15 parts of calcium carbonate, 7 parts of superfine talcum powder, 9 parts of hard (china) clay, 5 parts of kaolin, 4 parts of red phosphorus, 0.3 part of NOBS, anti-aging agent RD 1 Part, 2.5 parts of anti-aging agent RD;
The above-mentioned high heat-proof quality gel process for preparing of high tenacity is as follows:
S1,7 parts of polyparaphenylene's Benzo-dioxazole fibers are put into 10 part of first preformed solution by weight, first is prefabricated It is 3 by volume by acetone, absolute ethyl alcohol that solution, which is,:1 is mixed, and after immersion 14h, dries, and the broken length that obtains is 3mm Material A;After material A, 5 parts of silane coupler KH-560 are stirred, carry out oxygen plasma processing and obtain modified poly- pair Penylene Benzo-dioxazole fiber, the pressure of oxygen plasma processing is 39Pa, and the power of oxygen plasma processing is 230W, oxygen The time of plasma treatment is 13min;
S2, by molar part by 0.7 part of titanium dioxide, 0.4 part of modified polyparaphenylene's Benzo-dioxazole fiber, 6 parts of positive silicic acid After ethyl ester, 15 parts of absolute ethyl alcohol mixing, progress is ultrasonically treated to obtain material B, and ultrasonically treated power is 330W, ultrasonically treated Power is 60kHz, and the ultrasonically treated time is 33min;Material B pH value is adjusted to after 3.5,60 DEG C, insulation are warming up to 22min;The ammoniacal liquor that 0.7 part of concentration is 8mol/L is subsequently added into, 60min is stood after stirring and obtains gel;
S3,5 parts of gels are put into 15 part of second prefabricated cleaning solution by weight, the second preformed solution is by positive silicic acid second Ester, absolute ethyl alcohol are 3 by volume:7 are mixed, and after immersion 24h, continuously add 13 parts of hexamethylenes, stand after 2h, mistake Filter, is dried to obtain the high heat-proof quality gel of high tenacity.
Embodiment 3
A kind of ship proposed by the present invention high-toughness wear-resistant damping cable, including conductor 1, the insulating barrier of coating conductor 1 2nd, the packed layer 3 of coated insulation layer 2, the screen layer 4 for coating packed layer 3, the armor 5 of cladding screen layer 4 and cladding armor 5 Oversheath 6;
The raw material of wherein oversheath 6 includes by weight:56 parts of high-cis butadiene rubber, 21 parts of ethylene propylene diene rubber, chlorine Change 17 parts of polyethylene 140B, 9 parts of the high heat-proof quality gel of high tenacity, 1.4 parts of Cosan, 1.5 parts of altax, accelerator 2.3 parts of TMTM, 5.5 parts of trioctyl trimellitate (TOTM), 3.2 parts of ATBC, 26 parts of blanc fixe, 19 parts of high wear-resistant carbon black, 13 parts of nano-calcium carbonate, 9 parts of superfine talcum powder, 7 parts of hard (china) clay, 7 parts of kaolin, 2.5 parts of red phosphorus, 0.5 part of NOBS prevents old 0.6 part of agent RD, 3.4 parts of anti-aging agent RD;
The above-mentioned high heat-proof quality gel process for preparing of high tenacity is as follows:
S1,5 parts of polyparaphenylene's Benzo-dioxazole fibers are put into 12 part of first preformed solution by weight, first is prefabricated It is 4 by volume by acetone, absolute ethyl alcohol that solution, which is,:1.5 are mixed, and after immersion 12.5h, dry, broken to obtain length For 4mm material A;After material A, 6 parts of silane coupler KH-560 are stirred, carry out oxygen plasma processing and be modified Polyparaphenylene's Benzo-dioxazole fiber, the pressure of oxygen plasma processing is 37Pa, and the power of oxygen plasma processing is 240W, The time of oxygen plasma processing is 11min;
S2, by molar part by 0.5 part of titanium dioxide, 0.6 part of modified polyparaphenylene's Benzo-dioxazole fiber, 4.5 parts of positive silicon After acetoacetic ester, 17 parts of absolute ethyl alcohol mixing, progress is ultrasonically treated to obtain material B, and ultrasonically treated power is 310W, ultrasonically treated Power be 63kHz, ultrasonically treated time is 31min;Material B pH value is adjusted to after 3.7,58 DEG C, insulation are warming up to 24min;The ammoniacal liquor that 0.5 part of concentration is 9mol/L is subsequently added into, 54min is stood after stirring and obtains gel;
S3,6 parts of gels are put into 12 part of second prefabricated cleaning solution by weight, the second preformed solution is by positive silicic acid second Ester, absolute ethyl alcohol are 2 by volume:7 are mixed, and after immersion 25h, continuously add 11 parts of hexamethylenes, stand after 2.5h, mistake Filter, is dried to obtain the high heat-proof quality gel of high tenacity.
Embodiment 4
A kind of ship proposed by the present invention high-toughness wear-resistant damping cable, including conductor 1, the insulating barrier of coating conductor 1 2nd, the packed layer 3 of coated insulation layer 2, the screen layer 4 for coating packed layer 3, the armor 5 of cladding screen layer 4 and cladding armor 5 Oversheath 6;
The raw material of wherein oversheath 6 includes by weight:53 parts of butadiene rubber, 24 parts of ethylene propylene diene rubber, chlorinated polyethylene 16 parts of alkene 140B, 11 parts of the high heat-proof quality gel of high tenacity, 1.2 parts of Cosan, 1.6 parts of altax, TM monex TM 2.2 Part, 6 parts of trioctyl trimellitate (TOTM), 2.6 parts of ATBC, 27 parts of blanc fixe, 18 parts of high wear-resistant carbon black, nano-calcium carbonate 14 parts, 8 parts of superfine talcum powder, 8 parts of hard (china) clay, 6 parts of kaolin, 3 parts of red phosphorus, 0.4 part of NOBS, 0.7 part of anti-aging agent RD is prevented Old 2.8 parts of agent RD;
The above-mentioned high heat-proof quality gel process for preparing of high tenacity is as follows:
S1,6 parts of polyparaphenylene's Benzo-dioxazole fibers are put into 11 part of first preformed solution by weight, first is prefabricated It is 3.5 by volume by acetone, absolute ethyl alcohol that solution, which is,:2 are mixed, and after immersion 13h, dry, broken to obtain length and be 3mm material A;After material A, 5.5 parts of silane coupler KH-560 are stirred, carry out oxygen plasma processing and be modified Polyparaphenylene's Benzo-dioxazole fiber, the pressure of oxygen plasma processing is 38Pa, and the power of oxygen plasma processing is 235W, The time of oxygen plasma processing is 12min;
S2, by molar part by 0.6 part of titanium dioxide, 0.5 part of modified polyparaphenylene's Benzo-dioxazole fiber, 5 parts of positive silicic acid After ethyl ester, 16 parts of absolute ethyl alcohol mixing, progress is ultrasonically treated to obtain material B, and ultrasonically treated power is 320W, ultrasonically treated Power is 62kHz, and the ultrasonically treated time is 32min;Material B pH value is adjusted to after 3.6,59 DEG C, insulation are warming up to 23min;The ammoniacal liquor that 0.6 part of concentration is 8.5mol/L is subsequently added into, 58min is stood after stirring and obtains gel;
S3,5.5 parts of gels are put into 13 part of second prefabricated cleaning solution by weight, the second preformed solution is by positive silicic acid Ethyl ester, absolute ethyl alcohol are 3 by volume:7 are mixed, and after immersion 24.5h, continuously add 12 parts of hexamethylenes, stand 2.4h Afterwards, filter, be dried to obtain the high heat-proof quality gel of high tenacity.
Performance test is carried out to cable obtained by embodiment 1-4, it is as a result as follows using commercially available cable as control group:
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of ship high-toughness wear-resistant damping cable, it is characterised in that the insulating barrier including conductor (1), coating conductor (1) (2), the packed layer (3) of coated insulation layer (2), the screen layer (4) of cladding packed layer (3), the armor of cladding screen layer (4) (5) and cladding armor (5) oversheath (6);
The raw material of wherein oversheath (6) includes by weight:50-60 parts of butadiene rubber, 20-25 parts of ethylene propylene diene rubber, chlorination 15-18 parts of polyethylene 140B, 8-12 parts of high tenacity high heat-proof quality gel, 1-1.5 parts of Cosan, altax 1.4-1.7 Part, 2.1-2.4 parts of TM monex TM, 5-7 parts of trioctyl trimellitate (TOTM), 2-3.5 parts of ATBC, blanc fixe 25-28 Part, 17-20 parts of high wear-resistant carbon black, 12-15 parts of nano-calcium carbonate, 7-10 parts of superfine talcum powder, 6-9 parts of hard (china) clay, kaolin 5-8 parts, 2-4 parts of red phosphorus, 0.3-0.6 parts of NOBS, 0.5-1 parts of anti-aging agent RD, 2.5-4 parts of anti-aging agent RD;
The high heat-proof quality gel process for preparing of high tenacity in oversheath (6) raw material is as follows:
S1, polyparaphenylene's Benzo-dioxazole fiber put into the first preformed solution, after immersion, dried, it is broken to obtain material A; After material A, silane coupler KH-560 are stirred, carry out oxygen plasma processing and obtain being modified polyparaphenylene Ben Bing bis- Evil Azoles fiber;
S2, titanium dioxide, modified polyparaphenylene's Benzo-dioxazole fiber, tetraethyl orthosilicate, absolute ethyl alcohol are mixed after, surpassed Sonication obtains material B;After the pH value for adjusting material B, heat up, insulation;Ammoniacal liquor is subsequently added into, is stood after stirring and obtains gel;
S3, by gel put into the second prefabricated cleaning solution in, after immersion, continuously add after hexamethylene, standing, filter, be dried to obtain The high heat-proof quality gel of high tenacity;
In the S1 of the high heat-proof quality gel process for preparing of high tenacity in oversheath (6) raw material, the first preformed solution be by acetone, Absolute ethyl alcohol is 3-5 by volume:What 1-3 was mixed;
In the S3 of the high heat-proof quality gel process for preparing of high tenacity in oversheath (6) raw material, the second prefabricated cleaning solution is by just Silester, absolute ethyl alcohol are 2-3 by volume:What 7-8 was mixed.
2. ship high-toughness wear-resistant damping cable according to claim 1, it is characterised in that in the raw material of oversheath (6), Butadiene rubber is high-cis butadiene rubber.
3. ship according to claim 1 or claim 2 high-toughness wear-resistant damping cable, it is characterised in that the raw material of oversheath (6) In, the weight ratio of the high heat-proof quality gel of butadiene rubber, ethylene propylene diene rubber, haloflex 140B, high tenacity is 53-56: 21-24:16-17:9-11.
4. ship according to claim 1 or claim 2 high-toughness wear-resistant damping cable, it is characterised in that the raw material of oversheath (6) Include by weight:53-56 parts of butadiene rubber, 21-24 parts of ethylene propylene diene rubber, 16-17 parts of haloflex 140B, high-ductility Property high 9-11 parts of heat-proof quality gel, 1.2-1.4 parts of Cosan, 1.5-1.6 parts of altax, TM monex TM 2.2-2.3 Part, 5.5-6 parts of trioctyl trimellitate (TOTM), 2.6-3.2 parts of ATBC, 26-27 parts of blanc fixe, high wear-resistant carbon black 18- 19 parts, 13-14 parts of nano-calcium carbonate, 8-9 parts of superfine talcum powder, 7-8 parts of hard (china) clay, 6-7 parts of kaolin, 2.5-3 parts of red phosphorus, 0.4-0.5 parts of NOBS, 0.6-0.7 parts of anti-aging agent RD, 2.8-3.4 parts of anti-aging agent RD.
5. ship high-toughness wear-resistant damping cable according to claim 1, it is characterised in that in oversheath (6) raw material The high heat-proof quality gel process for preparing of high tenacity is as follows:
S1, polyparaphenylene's Benzo-dioxazole fiber put into the first preformed solution, after immersion 12-14h, dried, it is broken to obtain Material A;After material A, silane coupler KH-560 are stirred, carry out oxygen plasma processing and obtain being modified polyparaphenylene's benzene Bing bis- oxazole fibers, the pressure of oxygen plasma processing is 36-39Pa, and the power of oxygen plasma processing is 230-250W, oxygen The time of gas plasma treatment is 10-13min;
S2, titanium dioxide, modified polyparaphenylene's Benzo-dioxazole fiber, tetraethyl orthosilicate, absolute ethyl alcohol are mixed after, surpassed Sonication obtains material B, and ultrasonically treated power is 300-330W, and ultrasonically treated power is 60-65kHz, ultrasonically treated Time is 30-33min;Material B pH value is adjusted to after 3.5-3.8,57-60 DEG C is warming up to, is incubated 22-25min;It is subsequently added into Concentration is 8-10mol/L ammoniacal liquor, and 50-60min is stood after stirring and obtains gel;
S3, gel put into the second prefabricated cleaning solution, after immersion 24-26h, continuously add hexamethylene, stand after 2-3h, mistake Filter, is dried to obtain the high heat-proof quality gel of high tenacity.
6. ship high-toughness wear-resistant damping cable according to claim 5, it is characterised in that in oversheath (6) raw material The high heat-proof quality gel process for preparing of high tenacity is as follows:
S1,4-7 parts of polyparaphenylene's Benzo-dioxazole fibers are put into 10-13 the first preformed solutions of part by weight, immersion 12- After 14h, dry, it is broken to obtain material A;After material A, 5-7 parts of silane coupler KH-560 are stirred, carry out oxygen etc. from Subprocessing obtains being modified polyparaphenylene's Benzo-dioxazole fiber, and the pressure of oxygen plasma processing is 36-39Pa, oxygen plasma The power of processing is 230-250W, and the time of oxygen plasma processing is 10-13min;
S2, by molar part by 0.4-0.7 parts of titanium dioxide, 0.4-0.7 parts of modified polyparaphenylene's Benzo-dioxazole fibers, 4-6 parts After tetraethyl orthosilicate, 15-18 parts of absolute ethyl alcohol mixing, progress is ultrasonically treated to obtain material B, and ultrasonically treated power is 300- 330W, ultrasonically treated power is 60-65kHz, and the ultrasonically treated time is 30-33min;Material B pH value is adjusted to 3.5- After 3.8,57-60 DEG C is warming up to, 22-25min is incubated;It is subsequently added into the ammoniacal liquor that 0.4-0.7 parts of concentration are 8-10mol/L, stirring 50-60min is stood afterwards obtains gel;
S3,5-7 parts of gels are put into 10-15 the second prefabricated cleaning solutions of part by weight, soak after 24-26h, continuously add 10-13 parts of hexamethylenes, stand after 2-3h, and filtering is dried to obtain the high heat-proof quality gel of high tenacity.
7. the ship high-toughness wear-resistant damping cable according to claim 5 or 6, it is characterised in that in oversheath (6) raw material The high heat-proof quality gel process for preparing of high tenacity S1 in, the length of material A is 3-5mm.
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