CN107722856A - A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof - Google Patents

A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof Download PDF

Info

Publication number
CN107722856A
CN107722856A CN201711107854.XA CN201711107854A CN107722856A CN 107722856 A CN107722856 A CN 107722856A CN 201711107854 A CN201711107854 A CN 201711107854A CN 107722856 A CN107722856 A CN 107722856A
Authority
CN
China
Prior art keywords
bonding
fire retardant
adhesive plaster
sail
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711107854.XA
Other languages
Chinese (zh)
Inventor
张红芸
李鹏
葛慧宪
胡国银
杨沛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CTA HI-TECH TEXTILES Co Ltd
Original Assignee
CTA HI-TECH TEXTILES Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CTA HI-TECH TEXTILES Co Ltd filed Critical CTA HI-TECH TEXTILES Co Ltd
Priority to CN201711107854.XA priority Critical patent/CN107722856A/en
Publication of CN107722856A publication Critical patent/CN107722856A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B17/00—Vessels parts, details, or accessories, not otherwise provided for
    • B63B17/02—Awnings, including rigid weather protection structures, e.g. sunroofs; Tarpaulins; Accessories for awnings or tarpaulins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/208—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being constituted by at least two or more adjacent or superposed adhesive layers, e.g. multilayer adhesive
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C09J2400/263—Presence of textile or fabric in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00—Presence of polyurethane

Abstract

The invention provides a kind of novel environment friendly water proof fire retardant sail adhesive plaster, including base cloth layer compound successively, bonding bottom and bonding top layer, wherein：The base cloth layer is bright and beautiful silk；The bonding bottom includes 90 110 parts of EU, 58 parts of bottom curing agent, 15 20 parts of bottom solvent；The bonding top layer includes 90 110 parts of flame-retardant polyurethane, 0.5 1 parts of surface solidifying agent, 5 10 parts of top layer solvent.The invention overcome the deficiencies in the prior art, there is provided a kind of in light weight, high intensity, wear-resisting fluffy lid adhesive plaster material.

Description

A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof
Technical field
The invention belongs to sail adhesive plaster field, more particularly, to a kind of novel environment friendly water proof fire retardant sail adhesive plaster and its Preparation method.
Background technology
In recent years, paulin lid adhesive plaster be widely used in military-civil drop cloth, station, port and pier, field work, car and boat transport and Storage yard etc., it is textile industry new growth engines.With the development of national economy, the continuous increasing of freight traffic Add, the paulin lid adhesive plaster demand of traffic transport industry is in ever-increasing trend.At present, China's paulin lid adhesive plaster 90% is with pure cotton Canvas, polyester-cotton blend canvas, PVC coatings cloth, PE cloth, oxford, biaxially cloth, polyvinyl or polyester staple fiber base fabric be base material tradition Type paulin lid adhesive plaster.This paulin lid adhesive plaster, the universal coarse heaviness of product, surface quality is poor, and mechanical property is low, easy to aging, uses the longevity Order short, construction inconvenience.Forklift must be used such as every more than 50kg that weighs of Ministry of Railways's tarpaulin, during construction, not only easily causes cloth cover Abrasion also bring very burden to construction.Fluffy lid adhesive plaster makes flexible tarpaulin, and in container, sea-freight etc., other transport fields should With not being very wide.Because marine environment is more severe, it is desirable to which the tarpaulin used is amenable to the attack of violent storm, mechanical property The characteristics such as good, softness.So the exploitation of new fluffy lid adhesive plaster is the direction of the market demand from now on.
The content of the invention
Technical problems to be solved first of the invention are to provide a kind of in light weight, high intensity, wear-resisting fluffy lid adhesive plaster material.
To reach above-mentioned purpose, what the technical scheme of the invention was realized in：
A kind of novel environment friendly water proof fire retardant sail adhesive plaster, including：Compound base cloth layer successively, bonding bottom and bonding table Layer, wherein：
The base cloth layer is bright and beautiful silk；
The bonding bottom includes EU 90-110 parts, bottom curing agent 5-8 parts, bottom solvent 15-20 parts；
The bonding top layer includes flame-retardant polyurethane 90-110 parts, surface solidifying agent 0.5-1 parts, top layer solvent 5-10 Part.
In such scheme, if the base cloth layer is not all reached using the ultimate strength of common polyamide fibre, terylene or polyvinyl Tarpaulin is in light weight, the requirement of ultimate strength, and the application have selected bright and beautiful silk, bright and beautiful silk one from commercially available numerous materials As be to be made into by synthetic fibers, staple fibre, long filament, disclosure satisfy that high-strength, wear-resisting requirement.
As a preferred embodiment, in the bonding bottom：
The PAUR is the high curable type polyurethane of two-liquid type, it is preferred that the high curable type viscoelastic polyurethane of two-liquid type It is 500-900ps/25 DEG C to spend scope, and 100% tensile modulus of elasticity is 10-20kg/m2, it is furthermore preferred that its 100% tensile elasticity Modulus is 12-18kg/m2, the viscoelastic polyurethane denseness of this type is high, and viscosity is strong and the polyurethane of the low this type of modulus is energy Enough ensure the soft degree of product；Such a polyurethane belongs to EU, is applied in its corresponding curing agent proportioning After layer, the peel strength of coating product can increase with the extension of curing time, ensure that the fastness of product and resistance to well Hydrolysis property.Through overtesting, other PAURs no the application from viscosity, modulus, hydrolysis and adherence adopts This EU effect is good.
The bottom curing agent is polyisocyanic acid ester type curing agent, as a kind of nonrestrictive example, more isocyanides The viscosity of acid esters type curing agent is gardner viscosity S-Z, and solid part Solid (%) is 70 ± 1.The bonding of the bonding bottom is strong Power is the important indicator of product, be influence product service life the reason for one of；But bond height and the tearing brute force, disconnected of strength Split strength, there is harmony as well as contradiction between for hydrolysis property, so from modulus is higher, the high curable type polyurethane of the slow two-liquid type of low-temperature setting, Polyisocyanic acid ester type curing agent is equipped with, its small molecule structure is netted, is advantageous to the raising peeled off, and is applied as bonding bottom Layer, final product ensure that stronger bonding force while in turn ensure that high tearing brute force and ultimate strength；
The bottom solvent is toluene or other can be molten suitable for the solvent of the bond coating composition, the bottom Agent dosage is very few, then causes described very thick, and production is not easy to operate, if very dilute coating spread can be because the relation of tension force be easy Penetrate into base fabric fiber, the tearing brute force of fabric is reduced a lot.Therefore, bottom solvent 15-20 parts are preferable scope.
As a preferred embodiment, in the bonding surface layer：
The viscosity of the flame-retardant polyurethane is 600-1000ps/25 DEG C, and its 100% tensile modulus of elasticity is 10-30kg/ m2, 100% tensile stress is 2-8MPa, more preferably 4MPa, and flammability rating is V0/V2 (testing standard UL94).It is such a poly- Urethane not only has fire-retardant effect as bonding top layer, but also makes coating surface smooth not viscous glutinous, has good gloss Sense, it is suitable as skin-material use；
The surface layer curing agent is polyurethanes curing agent, and its viscosity is gardner viscosity V-Z, solid part Solid (%) For 60-80, it is preferred that solid part Solid (%) is 75 ± 1；
The surface layer solvent is toluene or other can be suitable for the solvent of the cohesive surface layer composition.
Another technical problem to be solved by the present invention is that keeping the same of the fire-retardant sail adhesive plaster pliability of environment-friendly waterproof When further improve its fire resistance, specifically：
1-3 part bottom fire retardants are additionally provided with the bonding bottom, it is preferred that the bottom fire retardant is white powder Dehalogenation composite fire retardant；
10-15 part surface layer fire retardants are additionally provided with the bonding surface layer, it is preferred that the surface layer fire retardant is halogen-free environmental The compounding of type fire retardant and bromine antimony composite fire retardant, halogen-free environment-friendly type flame-proof agent main component is triphenyl phosphate, belongs to phosphorus Flame retardant, it has profit essence effect, but flame retardant effect is not fine well to fabric, as being continuously increased for dosage is fire-retardant Effect can reduce on the contrary, and the flame retardant effect of bromine antimony composite fire retardant is fine, but the pliability of product can reduce during dosage increase, Harden.It is perfect well that two kinds of fire retardant synergies obtain product.In embodiment, different flame retardant is given to coating The flame retardant effect of fabric and the influence of pliability；
It is furthermore preferred that the mass ratio of halogen-free environment-friendly type flame-proof agent and bromine antimony composite fire retardant is in the surface layer fire retardant 15:1-15:Between 8, it is preferred that mass ratio 15:4.
The another object of the invention is to propose a kind of preparation method of novel environment friendly water proof fire retardant sail adhesive plaster, is somebody's turn to do Method can ensure light final obtained product weight, high intensity, wear-resisting.
To reach above-mentioned purpose, what the technical scheme of the invention was realized in：
A kind of preparation method of novel environment friendly water proof fire retardant sail adhesive plaster, comprises the following steps：
Step 1, hot rolling base cloth layer：The base cloth layer carries out hot rolling treatment, it is preferred that the hot-rolled temperature is 120-160 DEG C, calendering roller pressure is 60-80T；
Step 2, blade coating bonding bottom：The bonding bottom is scratched on the hot rolling face of the base cloth layer, it is preferred to use Dise knife coating；
Step 3, blade coating bonding surface layer：The bonding top layer is scratched on the bonding bottom, it is preferred to use sharp knife applies Layer.
Preferably, base fabric will first carry out hot rolling treatment before coating is carried out.Technique initialization is during hot rolling in the step 1： Design temperature is 130 DEG C -150 DEG C, speed 15-20m/min.On the one hand calendering processing is carried out to base fabric makes the surface of base fabric more Add smooth, surface can also have good gloss after hot rolling treatment；On the other hand the more soft of base fabric can also be made, for most The shaping of finished product lays the first stone.Temperature during hot rolling is lower than design temperature, not only it is lackluster do not reach yet it is soft Effect.Temperature during calendering is higher than design temperature, and the outward appearance of the too strong product of glossiness of base fabric seems less soft, due to calendering The raising of temperature can also damage to base fabric, influence the ultimate strength and tearing brute force of product, so calendering temperature should be controlled System is in rational scope.
Preferably, bottom blade coating equipment is bonded in the step 2 and applies two baking equipment from two, technological parameter is:Blade coating temperature 90-150 DEG C of degree, specifically, design temperature：First 90 DEG C -120 DEG C of area, the second 130 DEG C -150 DEG C of area；Speed is 15-20m/ min.The height of design temperature and the speed of speed directly affect the bonding intensity of product and the ultimate strength of fabric, torn by force Power.Although if the too high heat seal separation strength that ensure that product of temperature, the damage to fabric is big, reduces the fracture of product Strength and tearing brute force, base cloth layer after high temperature coating also can feel it is harder, sound is very loud during rubbing, entire effect product Quality.If opposite temperature is too low, although ensure that the damage of fabric very little, because temperature is low, bottom curing agent is not allowed Easily solidification, so as to influence the heat seal separation strength of product, makes bonding intensity poor.The setting of same speed speed also influences product The pliability of heat seal separation strength and fabric.Temperature range and speed set by the application can ensure the same of product pliability When ensure product heat seal separation strength.
Further, overcoming on hydrolysis problem：The use range of fluffy lid adhesive plaster is very wide, and transport aboard ship is also frequent Use.So in order to extend the usage time of fluffy lid adhesive plaster, hydrolysis problem is also highly important.I.e. in the feelings of long-time bubble Under condition, bonding bottom on the base cloth layer can be from splitting away off.This has outside the Pass except the selection with coating adhesive, also with processing Temperature is relevant.Coating is only carried out within the scope of specific temperature, just can guarantee that fluffy lid adhesive plaster in the case of long-time bubble Coating adhesive will not be split away off from base fabric.Such as：The high-strength bright and beautiful silks of 175T carry out during coating temperature general control in 130-150 Between DEG C, just can guarantee that be not in this phenomenon generation.By 70 DEG C/7 days bubbles test after, fluffy lid adhesive plaster it is other Hydrolysis property can also be maintained at 70%-80% while performance indications are ensured.
Preferably, the painting amount of scraping of the bonding bottom is 25-30 grams/cm2, sail adhesive plaster product not only needs physical property to refer to Mark, the Unit Weight of product are also particularly significant, it is impossible to and it is too high, also to ensure outward appearance and pliability.The finished product grammes per square metre of sail adhesive plaster Preferably control in 85-115g/cm2, in light weight, small volume when making sail product, being easy to carry about with one will not also increase to hull Too big weight, beneficial to aboard ship using.The painting amount of scraping for bonding bottom is controlled in 25-30g/cm2It can be good at ensureing product Pliability also ensure that the heat seal separation strength of product simultaneously.If apply the amount of scraping it is excessive, due to the firstth area temperature setting it is low, Speed is very fast, and coated fabric is short in the criteria thus the drying time of baking oven, and tacky situation can not be done or be occurred to coating resin, easily make coating Material is stained with the roller of machine, under the influence of the painting of a coating scrape, or even prevent production from being smoothed out.If it is very few to apply the amount of scraping, The pliability of coated fabric can be very hard, very crisp.Bonding bottom selects such a polyurethane to be on the one hand to the softness for improving product Degree, on the other hand it is to be easy to improve spread.The spread control for bonding bottom is particularly significant, it is impossible to arbitrarily with bonding top layer Spread controls the gross weight of product, and otherwise the performance of product and pliability can all change.
Further, the dosage of bottom solvent is 15-20 parts during the bonding bottom dispensing, raw if coating material is very thick Production is not easy to operate, if very dilute coating spread can be arrived in base fabric fiber because the relation of tension force is readily permeable, makes tearing for fabric Broken strength reduces a lot.In order to ensure the spread of coating, bonding bottom is scratched using dise knife.Spread is controlled in 20-35g/ m2It can be good at ensureing the pliability of product, while also ensure that the heat seal separation strength of product.If spread >=35g/ m2, because the temperature setting in the firstth area is low, speed is very fast, coated fabric is short in the criteria thus the drying time of baking oven, and coating surface can not be done Or there is tacky situation, easily coating material is adhered on the roller of machine, under the influence of the painting of a coating scrape.Pass through contrast test Obtain：If spread≤20g/m2, the pliability of coated fabric can be very hard, very crisp.So spread control of bonding bottom It is particularly significant.
Preferably, the painting amount of scraping for top layer being bonded described in the step 3 is 8-15 grams/cm2, bonding top layer uses resistance Type polyurethane is fired, there is certain anti-flammability, in order to reach the feel of flame retardant effect and product while ensure the total of product again Weight is so apply the amount of scraping control in 8-15g/cm2.In the dispensing on bonding top layer, in order to meet that flame retardant effect with the addition of further The fire retardant of compounding is added, applying the amount of scraping can be poor if less than this weight, flame retardant effect, is although met if above this grammes per square metre Flame retardant effect, but product feel can be hardened, turn white.
Relative to prior art, the invention has the advantage that：Obtained product is soft, hydrolytic Resistance is good, resistance Combustion property is good, in light weight.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention.
Wherein：1- base cloth layers；2- bonds bottom；3- bonds top layer.
Embodiment
In addition to being defined, technical term used has and the invention one of ordinary skill in the art in following examples The identical meanings being commonly understood by.Test reagent used, is routine biochemistry reagent unless otherwise specified in following examples； The experimental method, it is conventional method unless otherwise specified.
The invention is described in detail with reference to embodiment.
Embodiment 1
Step 1, base cloth layer processing
Prepare 175T brocades silk as base cloth layer, the base cloth layer is subjected to hot rolling treatment, hot-rolled temperature is 120 DEG C, is rolled Smooth roll pressure is 60T；
Step 2, blade coating bonding bottom
Step 2-1. prepares bonding bottom, and concrete component is as follows：
EU 6065A, 90 parts；
Bottom curing agent L1470,5 parts；
Bottom solvent toluene, 18 parts；
Bottom Firemaster CA S1309-64,1 part；
The bonding bottom is applied two using two and dries equipment blade coating above the base cloth layer by step 2-2., technological parameter It is as follows：First 90 DEG C of area's temperature, second 130 DEG C of area's temperature；Speed is 15m/min, and the blade coating amount for bonding bottom is 25 grams/cm2；
Step 3, blade coating bonding top layer
Step 3-1. prepares bonding top layer, and concrete component is as follows：
Flame-retardant polyurethane 1185A, 90 parts；
Surface solidifying agent L1470,0.5 part；
8 parts of top layer solvent butanone；
Top layer fire retardant：Bromine antimony composite fire retardant CAS1309-64,3 parts；Dehalogenation composite fire retardant TX-220,10 Part；
Above-mentioned bonding top layer is scratched and bonded in described on bottom by step 3-2, using sharp knife coating, the bonding top layer The painting amount of scraping is 8 grams/cm2。
So as to finished product.
Table 1 is the performance indications contrast of the material obtained after step 2 selection different temperatures glues to high-strength bright and beautiful silk.
Table 1
Table 2 is the effect data to the bonding surface layer addition different flame retardant.
Table 2
It is different to add different types of fire retardant to the fire-retardant of coated fabric in the bonding surface layer from above-mentioned table 2 The influence of effect and pliability, when adopting with without Xi environment friendly flame retardants and during bromine antimony composite fire retardant compounding use, Neng Goubao Ensure the pliability of product while demonstrate,proving good fire resistance.
Embodiment 2
Step 1, base cloth layer processing
Prepare 175T brocades silk as base cloth layer, the base cloth layer is subjected to hot rolling treatment, hot-rolled temperature is 140 DEG C, is rolled Smooth roll pressure is 70T；
Step 2, blade coating bonding bottom
Step 2-1. prepares bonding bottom, and concrete component is as follows：
EU 6386A, 100 parts；
Bottom curing agent UN-7038,7 parts；
Bottom solvent methyl butyl ketone, 18 parts；
Bottom Firemaster CA S1309-64,2 parts；
The bonding bottom is applied two using two and dries equipment blade coating above the base cloth layer by step 2-2., technological parameter It is as follows：First 100 DEG C of area's temperature, second 140 DEG C of area's temperature；Speed is 18m/min, bond the blade coating amount of bottom for 28 grams/ cm2；
Step 3, blade coating bonding top layer
Step 3-1. prepares bonding top layer, and concrete component is as follows：
Flame-retardant polyurethane 1180A, 100 parts；
Surface solidifying agent HDF-75,1 part；
Top layer solvent butanone, 10 parts；
Top layer fire retardant：Bromine antimony composite fire retardant CAS1309-64,4 parts；Dehalogenation composite fire retardant TX-220,13 Part；
Above-mentioned bonding top layer is scratched and bonded in described on bottom by step 3-2, using sharp knife coating, the bonding top layer The painting amount of scraping is 10 grams/cm2。
So as to finished product.
Embodiment 3
Step 1, base cloth layer processing
Prepare K59225 brocades silk be used as base cloth layer, by the base cloth layer carry out hot rolling treatment, hot-rolled temperature be 160 DEG C, Calendering roller pressure is 80T；
Step 2, blade coating bonding bottom
Step 2-1. prepares bonding bottom, and concrete component is as follows：
EU 6065A, 90-110 part；
Bottom curing agent UN-7038,8 parts；
Bottom solvent toluene, 20 parts；
Bottom Firemaster CA S1309-64,2 parts；
The bonding bottom is applied two using two and dries equipment blade coating above the base cloth layer by step 2-2., technological parameter It is as follows：First 120 DEG C of area's temperature, second 150 DEG C of area's temperature；Speed is 20m/min, bond the blade coating amount of bottom for 30 grams/ cm2；
Step 3, blade coating bonding top layer
Step 3-1. prepares bonding top layer, and concrete component is as follows：
Flame-retardant polyurethane 1185A, 110 parts；
Surface solidifying agent HDF-75,1 part；
Top layer solvent toluene, 10 parts；
Top layer fire retardant：Bromine antimony composite fire retardant CAS1309-64,3 parts；Dehalogenation composite fire retardant TX-220,15 Part；
Above-mentioned bonding top layer is scratched and bonded in described on bottom by step 3-2, using sharp knife coating, the bonding top layer The painting amount of scraping is 15 grams/cm2。
So as to finished product.
Table 3 is the high-strength bright and beautiful silk base fabric performance indications of different type that the invention uses.
Table 3
The preferred embodiment of the invention is the foregoing is only, is not intended to limit the invention creation, it is all at this Within the spirit and principle of innovation and creation, any modification, equivalent substitution and improvements made etc., the invention should be included in Protection domain within.

Claims (9)

  1. A kind of 1. novel environment friendly water proof fire retardant sail adhesive plaster, it is characterised in that：Including base cloth layer compound successively, bonding bottom and Top layer is bonded, wherein：
    The base cloth layer is bright and beautiful silk；
    The bonding bottom includes EU 90-110 parts, bottom curing agent 5-8 parts, bottom solvent 15-20 parts；
    The bonding top layer includes flame-retardant polyurethane 90-110 parts, surface solidifying agent 0.5-1 parts, top layer solvent 5-10 parts.
  2. A kind of 2. novel environment friendly water proof fire retardant sail adhesive plaster according to claim 1, it is characterised in that：The bonding bottom In：
    The PAUR is the high curable type polyurethane of two-liquid type, it is preferred that the high curable type polyurethane viscosity model of two-liquid type Enclose for 500-900ps/25 DEG C, 100% tensile modulus of elasticity is 10-20kg/m2, it is furthermore preferred that its 100% tensile modulus of elasticity For 12-18kg/m2；
    Bottom curing agent is polyisocyanic acid ester type curing agent.
  3. A kind of 3. novel environment friendly water proof fire retardant sail adhesive plaster according to claim 1, it is characterised in that：The bonding surface layer In：
    The viscosity of the flame-retardant polyurethane is 600-1000ps/25 DEG C, and its 100% tensile modulus of elasticity is 10-30kg/m2, 100% tensile stress is 2-8MPa, more preferably 4Mpa；
    The surface layer curing agent is polyurethanes curing agent.
  4. A kind of 4. novel environment friendly water proof fire retardant sail adhesive plaster according to claim 1, it is characterised in that：The bonding bottom In be additionally provided with 1-3 part bottom fire retardants, it is preferred that the bottom fire retardant is white powder dehalogenation composite fire retardant.
  5. A kind of 5. novel environment friendly water proof fire retardant sail adhesive plaster according to claim 1, it is characterised in that：The bonding surface layer In be additionally provided with 10-13 part surface layer fire retardants, it is preferred that the surface layer fire retardant be halogen-free environment-friendly type flame-proof agent and bromine antimony it is compound The compounding of fire retardant.
  6. A kind of 6. preparation method of novel environment friendly water proof fire retardant sail adhesive plaster according to claim 1, it is characterised in that：Bag Include following steps：
    Step 1, hot rolling base cloth layer：The base cloth layer carries out hot rolling treatment, it is preferred that the hot-rolled temperature is 120-160 DEG C, is rolled Smooth roll pressure is 60-80T；
    Step 2, blade coating bonding bottom：The bonding bottom is scratched on the hot rolling face of the base cloth layer, it is preferred to use dise knife Coating；
    Step 3, blade coating bonding surface layer：The bonding top layer is scratched on the bonding bottom, it is preferred to use sharp knife coating.
  7. A kind of 7. preparation method of novel environment friendly water proof fire retardant sail adhesive plaster according to claim 6, it is characterised in that：Institute Technique initialization is when stating hot rolling in step 1：Design temperature is 130 DEG C -150 DEG C, speed 15-20m/min.
  8. A kind of 8. preparation method of novel environment friendly water proof fire retardant sail adhesive plaster according to claim 6, it is characterised in that：Institute State in step 2, scratch 90-150 DEG C of temperature；
    Preferably, the bonding bottom blade coating equipment applies two baking equipment, design temperature from two：First 90 DEG C -120 DEG C of area, the Two 130 DEG C -150 DEG C of areas；Speed is 15-20m/min；
    Preferably, the painting amount of scraping of the bonding bottom is 25-30 grams/cm2。
  9. A kind of 9. preparation method of novel environment friendly water proof fire retardant sail adhesive plaster according to claim 6, it is characterised in that：Institute The painting amount of scraping for stating bonding top layer described in step 3 is 8-15 grams/cm2。
CN201711107854.XA 2017-11-10 2017-11-10 A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof Pending CN107722856A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711107854.XA CN107722856A (en) 2017-11-10 2017-11-10 A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711107854.XA CN107722856A (en) 2017-11-10 2017-11-10 A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107722856A true CN107722856A (en) 2018-02-23

Family

ID=61215006

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711107854.XA Pending CN107722856A (en) 2017-11-10 2017-11-10 A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107722856A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112318977A (en) * 2020-10-30 2021-02-05 中纺新材料科技有限公司 TPU composite fabric
CN113403863A (en) * 2021-07-13 2021-09-17 中纺新材料科技有限公司 Waterproof flame-retardant high-strength outdoor bag fabric and preparation method thereof
CN114164665A (en) * 2021-12-23 2022-03-11 扬州纪元纺织有限公司 Coated nylon silk and processing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102268819A (en) * 2010-06-07 2011-12-07 五邑大学 Method for preparing flame retardant knitted coated fabrics
CN103211336A (en) * 2012-01-21 2013-07-24 昆山华阳复合材料科技有限公司 Coated fabric with safety protection and long-term flame-retardant effect and manufacturing process of coated fabric
CN103572612A (en) * 2012-07-18 2014-02-12 厚生股份有限公司 Moisture permeable fireproof cloth and manufacturing method thereof
CN104404769A (en) * 2014-11-25 2015-03-11 浙江传化股份有限公司 Water-based flame-retardant coating adhesive and preparation method thereof
CN104762818A (en) * 2015-04-02 2015-07-08 杭州和顺纺织品有限公司 One-side-coated anti-flame moisture-permeable waterproof cloth and preparation process thereof
CN106049049A (en) * 2016-08-02 2016-10-26 丹东优耐特纺织品有限公司 Durable flame-retardant, water-repellent, waterproof and moisture permeable finishing method of polyester fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102268819A (en) * 2010-06-07 2011-12-07 五邑大学 Method for preparing flame retardant knitted coated fabrics
CN103211336A (en) * 2012-01-21 2013-07-24 昆山华阳复合材料科技有限公司 Coated fabric with safety protection and long-term flame-retardant effect and manufacturing process of coated fabric
CN103572612A (en) * 2012-07-18 2014-02-12 厚生股份有限公司 Moisture permeable fireproof cloth and manufacturing method thereof
CN104404769A (en) * 2014-11-25 2015-03-11 浙江传化股份有限公司 Water-based flame-retardant coating adhesive and preparation method thereof
CN104762818A (en) * 2015-04-02 2015-07-08 杭州和顺纺织品有限公司 One-side-coated anti-flame moisture-permeable waterproof cloth and preparation process thereof
CN106049049A (en) * 2016-08-02 2016-10-26 丹东优耐特纺织品有限公司 Durable flame-retardant, water-repellent, waterproof and moisture permeable finishing method of polyester fabric

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
上海市纺织工业局: "《纺织品大全 丝织物分册》", 31 December 1990, 纺织工业出版社 *
吕百龄等: "《实用工业助剂全书》", 31 August 2001, 化学工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112318977A (en) * 2020-10-30 2021-02-05 中纺新材料科技有限公司 TPU composite fabric
CN113403863A (en) * 2021-07-13 2021-09-17 中纺新材料科技有限公司 Waterproof flame-retardant high-strength outdoor bag fabric and preparation method thereof
CN113403863B (en) * 2021-07-13 2024-03-15 中纺新材料科技有限公司 Waterproof flame-retardant high-strength outdoor wrapping fabric and preparation method thereof
CN114164665A (en) * 2021-12-23 2022-03-11 扬州纪元纺织有限公司 Coated nylon silk and processing method thereof

Similar Documents

Publication Publication Date Title
CN101538800B (en) Thermoplastic resin coating film material and preparation method thereof
CN107722856A (en) A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof
CN101503861B (en) Two-liquid type rapid stripping synthetic leather composite overlay
CN105821670A (en) Novel textile downproof technology
CN101781858B (en) Dry veneering process of high weather-resistant fluorescent polyamide synthetic leather
CN102555352B (en) Glass fiber/PVC (polyvinyl chloride) composite membrane material and preparation method thereof
CN103434232B (en) A kind of highly elastic leather transfer membrane and preparation method thereof
CN103756531A (en) Double-component polyester hand feeling coating for carbon fiber composite material
CN111440569A (en) Water-based adhesive and preparation method and application thereof
CN106281119A (en) A kind of antifouling high abrasion honeycomb composite cardboard and manufacture method thereof of preventing fires
CN111286993A (en) Down jacket fabric treatment method by hot rolling lamination instead of sewing
CN111979790A (en) Light and thin flexible polyurethane leather and preparation method thereof
CN104975521A (en) Waterborne polyurethane latex emulsion for nylon fabric and preparation method thereof
KR20200010696A (en) Functional film, and laminated steel sheet and method for manufacturing the same
CN106142796B (en) A kind of preparation method of oil storage bag TPU composite material
CN109853885A (en) A kind of flexibility texture coating composite coating patch material and its manufacture and construction method
CN104233843A (en) Production process of PU transfer coating leather
CN109797571A (en) A kind of flexibility artificial granite composite coating patch material and its manufacturing method
CN102863851A (en) Matched primer special for thickened coating and preparation method for matched primer
CN114481644B (en) Waterborne polyurethane synthetic leather and preparation method thereof
CN106867380B (en) Breathable flame-retardant anti-immersion fabric and preparation method thereof
CN109881854A (en) A kind of flexible compound coating patch material of color spot and its manufacture and construction method
CN205603941U (en) Plastic flooring based on genuine leather fibre regenerated leather
CN211311986U (en) Cashmere-like polyurethane leather
CN100368624C (en) Art canvas with non-filler polyvinyl built coating and its production process

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180223