CN104292575A - Glass fiber reinforced plastic for mining cables - Google Patents

Glass fiber reinforced plastic for mining cables Download PDF

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Publication number
CN104292575A
CN104292575A CN201410229255.5A CN201410229255A CN104292575A CN 104292575 A CN104292575 A CN 104292575A CN 201410229255 A CN201410229255 A CN 201410229255A CN 104292575 A CN104292575 A CN 104292575A
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parts
mixture
glass fiber
mould
stir
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CN104292575B (en
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金立胜
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ANHUI NINGGUO HIGH-NEW PIPE INDUSTRY Co Ltd
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ANHUI NINGGUO HIGH-NEW PIPE INDUSTRY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/016Additives defined by their aspect ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses a glass fiber reinforced plastic for mining cables. Raw materials of the glass fiber reinforced plastic for mining cables include, by weight, 15-20 parts of polyethylene (PE), 5-10 parts of polybutylene terephthalate (PBT), 20-25 parts of polyethylene terephthalate (PET), 20-24 parts of short glass fiber, 6-8 parts of carbon fiber, 4-6 parts of colloidal calcium carbonate, 4-6 pars of a ligand titanate coupling agent, 3-4 parts of iron hydroxide colloid, 4-6 parts of aluminum hydroxide, 1-3 parts of an antioxidant, 0.5-0.9 parts of an antioxidant 2246, 1-3 parts of magnesium stearate and 0.5-1.5 parts of zinc stearate. The glass fiber reinforced plastic has the advantages of excellent mechanical strength, excellent electrical properties, excellent corrosion resistance and excellent wear resistance, and is suitable for being used in the mining cables.

Description

A kind of mining area cable glass filament reinforced plastics
Technical field
The present invention relates to cable material technical field, particularly relate to a kind of mining area cable glass filament reinforced plastics.
Background technology
Along with the development of open coal mine and Underground Mine electric coal winning machine tool, also more strict to the performance requriements of mine cable, not only require that the insulation layer of cable has excellent electric property, require that sheath material has excellent physical and mechanical properties simultaneously.Inevitably there is methane gas in mine, have the danger of combustion explosion, need to lay large numbers of various cable to provide electric energy, control signal and monitoring in mining well, also require that cable has effective flame retardant properties.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of mining area cable glass filament reinforced plastics, has excellent physical strength and electric property, also has excellent corrosion resistance nature and wear resisting property, is suitable for mining area cable and uses.
A kind of mining area cable glass filament reinforced plastics that the present invention proposes, its raw material comprises by weight: polythene PE 15-20 part, polybutylene terephthalate PBT5-10 part, polyethylene terephtalate 20-25 part, short glass fiber 20-24 part, carbon fiber 6-8 part, gel calcium carbonate 4-6 part, coordination build titanate coupling agent 4-6 part, ferric hydroxide colloid 3-4 part, aluminium hydroxide 4-6 part, antiaging agent 1-3 part, antioxidant 2246 0.5-0.9 part, Magnesium Stearate 1-3 part, Zinic stearas 0.5-1.5 part; Following technique is adopted to prepare:
S1, by tetrachloromethane and dimethylbenzene by volume for 1-2:1-2 is mixed to get mixing solutions, polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate are placed in after mixing solutions is heated to 88-92 DEG C, stir 0.8-1.2h obtain mixture A with the stir speed (S.S.) of 900-1200rpm;
S2, by mixture A take out be placed in mixing roll, add gel calcium carbonate, coordination build titanate coupling agent, ferric hydroxide colloid, aluminium hydroxide, antiaging agent, antioxidant 2246, Magnesium Stearate and Zinic stearas again, stir 2-2.5h with the stir speed (S.S.) of 700-900rpm and obtain mixture B;
S3, short glass fiber and carbon fiber are added in mixture B, stir 0.3-0.5h final vacuum suction filtration with the stir speed (S.S.) of 100-200rpm and obtain mixture C;
S4, vacuum drying oven is warming up to 170-175 DEG C, mixture C is placed in the drying basin that bottom is covered with polysulfone membrane, drying basin is together put into the dry 1.6-2h of vacuum drying oven with the mixture C being placed in drying basin and obtains mixture D, drying temperature is 182-184 DEG C, and maintaining negative pressure in drying process is 95-100kPa;
S5, to be taken out by mixture D and put into mould, then mould and the mixture D that is placed in mould are together put into vacuum drying oven melting 22-26min obtain mixture E, melt temperature is 280-300 DEG C, and maintaining negative pressure in melting process is 95-100kPa;
S6, thermocompressor is warming up to 275-280 DEG C, mould and the mixture E being placed in mould are placed in thermocompressor hot pressing 1.2-1.5min, hot pressing pressure is 22-24MPa, and hot pressing temperature is 275-280 DEG C, takes out cooling and obtains mining area cable glass filament reinforced plastics.
In specific embodiment, the weight part of polythene PE can be 15 parts, 17 parts, 18 parts, 19 parts, 20 parts, polybutylene terephthalate PBT5 part, 7 parts, 8 parts, 9 parts, 10 parts, polyethylene terephtalate 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, short glass fiber 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 6 parts, carbon fiber, 6.5 part, 7 parts, 7.5 part, 8 parts, gel calcium carbonate 4 parts, 4.5 part, 5 parts, 5.5 part, 6 parts, coordination build titanate coupling agent 4 parts, 4.5 part, 5 parts, 5.5 part, 6 parts, ferric hydroxide colloid 3 parts, 3.2 part, 3.6 part, 3.8 part, 4 parts, 4 parts, aluminium hydroxide, 4.2 part, 4.8 part, 5 parts, 5.6 part, 5.6 part, 6 parts, antiaging agent 1 part, 1.3 part, 1.7 part, 2 parts, 2.5 part, 2.7 part, 3 parts, antioxidant 2246 0.5 part, 0.6 part, 0.7 part, 0.8 part, 0.9 part, Magnesium Stearate 1 part, 1.6 part, 1.8 part, 2.3 part, 2.7 part, 3 parts, Zinic stearas 0.5 part, 0.9 part, 1 part, 1.2 part, 1.5 part.
Preferably, short glass fiber length-to-diameter ratio is 10-12:1.
Preferably, polythene PE 17-19 part, polybutylene terephthalate PBT7-9 part, polyethylene terephtalate 21-23 part, short glass fiber 22-23 part, carbon fiber 6.5-7.5 part, gel calcium carbonate 4.5-5.5 part, coordination build titanate coupling agent 4.5-5.5 part, 4.2-5.6 part, antiaging agent 1.3-2.7 part, antioxidant 2246 0.7-0.8 part, Magnesium Stearate 1.6-2.3 part, Zinic stearas 0.9-1.2 part.
The present invention has excellent physical strength and electric property, also has excellent corrosion resistance nature and wear resisting property, is suitable for mining area cable and uses.The present invention adopts polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate is major ingredient, and short glass fiber, carbon fiber with the use of, using two kinds of blending in of fibers as skeleton, significantly improve physical strength of the present invention and corrosion resistance nature, due to the use of short glass fiber, also improve electric property of the present invention, and add gel calcium carbonate, ferric hydroxide colloid and aluminium hydroxide are as weighting agent, improve wear resisting property of the present invention, and ferric hydroxide colloid and aluminium hydroxide form flame-retardant system, make heat-proof combustion-resistant performance of the present invention excellent, Magnesium Stearate and Zinic stearas coordinate as stablizer, ensure that performance of the present invention remains stable, increase the service life.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of mining area cable glass filament reinforced plastics that the present invention proposes, its raw material comprises by weight: polythene PE 15 parts, polybutylene terephthalate PBT10 part, polyethylene terephtalate 20 parts, short glass fiber 24 parts, 6 parts, carbon fiber, gel calcium carbonate 6 parts, coordination build titanate coupling agent 4 parts, ferric hydroxide colloid 4 parts, 4 parts, aluminium hydroxide, antiaging agent 3 parts, antioxidant 2246 0.9 part, Magnesium Stearate 1 part, Zinic stearas 1.5 parts, wherein short glass fiber length-to-diameter ratio is 10:1; Following technique is adopted to prepare:
S1, by tetrachloromethane and dimethylbenzene by volume for 1:2 is mixed to get mixing solutions, polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate are placed in after mixing solutions is heated to 88-92 DEG C, stir 0.8-1.2h obtain mixture A with the stir speed (S.S.) of 900-1200rpm;
S2, by mixture A take out be placed in mixing roll, add gel calcium carbonate, coordination build titanate coupling agent, ferric hydroxide colloid, aluminium hydroxide, antiaging agent, antioxidant 2246, Magnesium Stearate and Zinic stearas again, stir 2-2.5h with the stir speed (S.S.) of 700-900rpm and obtain mixture B;
S3, short glass fiber and carbon fiber are added in mixture B, stir 0.3-0.5h final vacuum suction filtration with the stir speed (S.S.) of 100-200rpm and obtain mixture C;
S4, vacuum drying oven is warming up to 170-175 DEG C, mixture C is placed in the drying basin that bottom is covered with polysulfone membrane, drying basin is together put into the dry 1.6-2h of vacuum drying oven with the mixture C being placed in drying basin and obtains mixture D, drying temperature is 182-184 DEG C, and maintaining negative pressure in drying process is 95-100kPa;
S5, to be taken out by mixture D and put into mould, then mould and the mixture D that is placed in mould are together put into vacuum drying oven melting 22-26min obtain mixture E, melt temperature is 280-300 DEG C, and maintaining negative pressure in melting process is 95-100kPa;
S6, thermocompressor is warming up to 275-280 DEG C, mould and the mixture E being placed in mould are placed in thermocompressor hot pressing 1.2-1.5min, hot pressing pressure is 22-24MPa, and hot pressing temperature is 275-280 DEG C, takes out cooling and obtains mining area cable glass filament reinforced plastics.
Embodiment 2
A kind of mining area cable glass filament reinforced plastics that the present invention proposes, its raw material comprises by weight: polythene PE 20 parts, polybutylene terephthalate PBT5 part, polyethylene terephtalate 25 parts, short glass fiber 20 parts, 8 parts, carbon fiber, gel calcium carbonate 4 parts, coordination build titanate coupling agent 6 parts, ferric hydroxide colloid 3 parts, 6 parts, aluminium hydroxide, antiaging agent 1 part, antioxidant 2246 0.5 part, Magnesium Stearate 3 parts, Zinic stearas 0.5 part; Following technique is adopted to prepare:
S1, by tetrachloromethane and dimethylbenzene by volume for 2:1 is mixed to get mixing solutions, polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate are placed in after mixing solutions is heated to 88-92 DEG C, stir 0.8-1.2h obtain mixture A with the stir speed (S.S.) of 900-1200rpm;
S2, by mixture A take out be placed in mixing roll, add gel calcium carbonate, coordination build titanate coupling agent, ferric hydroxide colloid, aluminium hydroxide, antiaging agent, antioxidant 2246, Magnesium Stearate and Zinic stearas again, stir 2-2.5h with the stir speed (S.S.) of 700-900rpm and obtain mixture B;
S3, short glass fiber and carbon fiber are added in mixture B, stir 0.3-0.5h final vacuum suction filtration with the stir speed (S.S.) of 100-200rpm and obtain mixture C;
S4, vacuum drying oven is warming up to 170-175 DEG C, mixture C is placed in the drying basin that bottom is covered with polysulfone membrane, drying basin is together put into the dry 1.6-2h of vacuum drying oven with the mixture C being placed in drying basin and obtains mixture D, drying temperature is 182-184 DEG C, and maintaining negative pressure in drying process is 95-100kPa;
S5, to be taken out by mixture D and put into mould, then mould and the mixture D that is placed in mould are together put into vacuum drying oven melting 22-26min obtain mixture E, melt temperature is 280-300 DEG C, and maintaining negative pressure in melting process is 95-100kPa;
S6, thermocompressor is warming up to 275-280 DEG C, mould and the mixture E being placed in mould are placed in thermocompressor hot pressing 1.2-1.5min, hot pressing pressure is 22-24MPa, and hot pressing temperature is 275-280 DEG C, takes out cooling and obtains mining area cable glass filament reinforced plastics.
Embodiment 3
A kind of mining area cable glass filament reinforced plastics that the present invention proposes, its raw material comprises by weight: polythene PE 17 parts, polybutylene terephthalate PBT9 part, polyethylene terephtalate 21 parts, short glass fiber 23 parts, 6.5 parts, carbon fiber, gel calcium carbonate 5.5 parts, coordination build titanate coupling agent 4.5 parts, ferric hydroxide colloid 3.8 parts, 4.2 parts, aluminium hydroxide, antiaging agent 2.7 parts, antioxidant 2246 0.8 part, Magnesium Stearate 1.6 parts, Zinic stearas 1.2 parts; Following technique is adopted to prepare:
S1, by tetrachloromethane and dimethylbenzene by volume for 3:2 is mixed to get mixing solutions, polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate are placed in after mixing solutions is heated to 90 DEG C, stir 1h obtain mixture A with the stir speed (S.S.) of 1100rpm;
S2, by mixture A take out be placed in mixing roll, add gel calcium carbonate, coordination build titanate coupling agent, ferric hydroxide colloid, aluminium hydroxide, antiaging agent, antioxidant 2246, Magnesium Stearate and Zinic stearas again, stir 2.3h with the stir speed (S.S.) of 800rpm and obtain mixture B;
S3, short glass fiber and carbon fiber are added in mixture B, stir 0.4h final vacuum suction filtration with the stir speed (S.S.) of 150rpm and obtain mixture C;
S4, vacuum drying oven is warming up to 173 DEG C, mixture C is placed in the drying basin that bottom is covered with polysulfone membrane, drying basin is together put into the dry 1.8h of vacuum drying oven with the mixture C being placed in drying basin and obtains mixture D, drying temperature is 183 DEG C, and maintaining negative pressure in drying process is 97kPa;
S5, to be taken out by mixture D and put into mould, then mould and the mixture D that is placed in mould are together put into vacuum drying oven melting 24min obtain mixture E, melt temperature is 290 DEG C, and maintaining negative pressure in melting process is 98kPa;
S6, thermocompressor is warming up to 277 DEG C, mould and the mixture E that is placed in mould are placed in thermocompressor hot pressing 1.4min, and hot pressing pressure is 23MPa, and hot pressing temperature is 278 DEG C, takes out cooling and obtains mining area cable glass filament reinforced plastics.
Embodiment 4
A kind of mining area cable glass filament reinforced plastics that the present invention proposes, its raw material comprises by weight: polythene PE 19 parts, polybutylene terephthalate PBT7 part, polyethylene terephtalate 23 parts, short glass fiber 22 parts, 7.5 parts, carbon fiber, gel calcium carbonate 4.5 parts, coordination build titanate coupling agent 5.5 parts, ferric hydroxide colloid 3.2 parts, 5.6 parts, aluminium hydroxide, antiaging agent 1.3 parts, antioxidant 2246 0.7 part, Magnesium Stearate 2.3 parts, Zinic stearas 0.9 part, wherein short glass fiber length-to-diameter ratio is 12:1; Following technique is adopted to prepare:
S1, by tetrachloromethane and dimethylbenzene by volume for 2:3 is mixed to get mixing solutions, polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate are placed in after mixing solutions is heated to 89 DEG C, stir 0.9h obtain mixture A with the stir speed (S.S.) of 1000rpm;
S2, by mixture A take out be placed in mixing roll, add gel calcium carbonate, coordination build titanate coupling agent, ferric hydroxide colloid, aluminium hydroxide, antiaging agent, antioxidant 2246, Magnesium Stearate and Zinic stearas again, stir 2.2h with the stir speed (S.S.) of 750rpm and obtain mixture B;
S3, short glass fiber and carbon fiber are added in mixture B, stir 0.4h final vacuum suction filtration with the stir speed (S.S.) of 170rpm and obtain mixture C;
S4, vacuum drying oven is warming up to 172 DEG C, mixture C is placed in the drying basin that bottom is covered with polysulfone membrane, drying basin is together put into the dry 1.9h of vacuum drying oven with the mixture C being placed in drying basin and obtains mixture D, drying temperature is 183 DEG C, and maintaining negative pressure in drying process is 98kPa;
S5, to be taken out by mixture D and put into mould, then mould and the mixture D that is placed in mould are together put into vacuum drying oven melting 25min obtain mixture E, melt temperature is 285 DEG C, and maintaining negative pressure in melting process is 96kPa;
S6, thermocompressor is warming up to 276 DEG C, mould and the mixture E that is placed in mould are placed in thermocompressor hot pressing 1.3min, and hot pressing pressure is 23MPa, and hot pressing temperature is 276 DEG C, takes out cooling and obtains mining area cable glass filament reinforced plastics.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (3)

1. a mining area cable glass filament reinforced plastics, it is characterized in that, its raw material comprises by weight: polythene PE 15-20 part, polybutylene terephthalate PBT5-10 part, polyethylene terephtalate 20-25 part, short glass fiber 20-24 part, carbon fiber 6-8 part, gel calcium carbonate 4-6 part, coordination build titanate coupling agent 4-6 part, ferric hydroxide colloid 3-4 part, aluminium hydroxide 4-6 part, antiaging agent 1-3 part, antioxidant 2246 0.5-0.9 part, Magnesium Stearate 1-3 part, Zinic stearas 0.5-1.5 part; Following technique is adopted to prepare:
S1, by tetrachloromethane and dimethylbenzene by volume for 1-2:1-2 is mixed to get mixing solutions, polythene PE, polybutylene terephthalate PBT, polyethylene terephtalate are placed in after mixing solutions is heated to 88-92 DEG C, stir 0.8-1.2h obtain mixture A with the stir speed (S.S.) of 900-1200rpm;
S2, by mixture A take out be placed in mixing roll, add gel calcium carbonate, coordination build titanate coupling agent, ferric hydroxide colloid, aluminium hydroxide, antiaging agent, antioxidant 2246, Magnesium Stearate and Zinic stearas again, stir 2-2.5h with the stir speed (S.S.) of 700-900rpm and obtain mixture B;
S3, short glass fiber and carbon fiber are added in mixture B, stir 0.3-0.5h final vacuum suction filtration with the stir speed (S.S.) of 100-200rpm and obtain mixture C;
S4, vacuum drying oven is warming up to 170-175 DEG C, mixture C is placed in the drying basin that bottom is covered with polysulfone membrane, drying basin is together put into the dry 1.6-2h of vacuum drying oven with the mixture C being placed in drying basin and obtains mixture D, drying temperature is 182-184 DEG C, and maintaining negative pressure in drying process is 95-100kPa;
S5, to be taken out by mixture D and put into mould, then mould and the mixture D that is placed in mould are together put into vacuum drying oven melting 22-26min obtain mixture E, melt temperature is 280-300 DEG C, and maintaining negative pressure in melting process is 95-100kPa;
S6, thermocompressor is warming up to 275-280 DEG C, mould and the mixture E being placed in mould are placed in thermocompressor hot pressing 1.2-1.5min, hot pressing pressure is 22-24MPa, and hot pressing temperature is 275-280 DEG C, takes out cooling and obtains mining area cable glass filament reinforced plastics.
2. mining area cable glass filament reinforced plastics as claimed in claim 1, it is characterized in that, short glass fiber length-to-diameter ratio is 10-12:1.
3. mining area cable glass filament reinforced plastics as claimed in claim 1, it is characterized in that, its raw material comprises by weight: polythene PE 17-19 part, polybutylene terephthalate PBT7-9 part, polyethylene terephtalate 21-23 part, short glass fiber 22-23 part, carbon fiber 6.5-7.5 part, gel calcium carbonate 4.5-5.5 part, coordination build titanate coupling agent 4.5-5.5 part, ferric hydroxide colloid 3.2-3.8 part, aluminium hydroxide 4.2-5.6 part, antiaging agent 1.3-2.7 part, antioxidant 2246 0.7-0.8 part, Magnesium Stearate 1.6-2.3 part, Zinic stearas 0.9-1.2 part.
CN201410229255.5A 2014-05-27 2014-05-27 A kind of mining area cable fiberglass reinforced plastics Expired - Fee Related CN104292575B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106519446A (en) * 2016-11-16 2017-03-22 湖南金富包装有限公司 High-temperature-resistant plastic bottle cap and production method thereof
CN106519447A (en) * 2016-11-16 2017-03-22 湖南金富包装有限公司 Plastic bottle cap not prone to deformation and production method thereof
CN110157163A (en) * 2019-05-27 2019-08-23 福建师范大学 A kind of assorted fibre enhancing r-PET engineering plastics and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1656171A (en) * 2002-05-28 2005-08-17 旭化成株式会社 Flame retardant composition
CN1729246A (en) * 2002-10-22 2006-02-01 可乐丽股份有限公司 Polyolefin resin composition and use thereof
CN101536117A (en) * 2006-11-09 2009-09-16 株式会社自动网络技术研究所 Flat cable

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1656171A (en) * 2002-05-28 2005-08-17 旭化成株式会社 Flame retardant composition
CN1729246A (en) * 2002-10-22 2006-02-01 可乐丽股份有限公司 Polyolefin resin composition and use thereof
CN101536117A (en) * 2006-11-09 2009-09-16 株式会社自动网络技术研究所 Flat cable

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106519446A (en) * 2016-11-16 2017-03-22 湖南金富包装有限公司 High-temperature-resistant plastic bottle cap and production method thereof
CN106519447A (en) * 2016-11-16 2017-03-22 湖南金富包装有限公司 Plastic bottle cap not prone to deformation and production method thereof
CN106519446B (en) * 2016-11-16 2019-08-20 湖南金富包装有限公司 A kind of plastic bottle closure resistant to high temperature and its production method
CN110157163A (en) * 2019-05-27 2019-08-23 福建师范大学 A kind of assorted fibre enhancing r-PET engineering plastics and preparation method thereof

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