CN107245171A - A kind of electricity cables for technical installations sheath CSM material - Google Patents

A kind of electricity cables for technical installations sheath CSM material Download PDF

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Publication number
CN107245171A
CN107245171A CN201710484741.5A CN201710484741A CN107245171A CN 107245171 A CN107245171 A CN 107245171A CN 201710484741 A CN201710484741 A CN 201710484741A CN 107245171 A CN107245171 A CN 107245171A
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parts
sheath
attapulgite clay
csm
technical installations
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CN201710484741.5A
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Chinese (zh)
Inventor
荔建荣
柏建华
董文锋
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ANHUI JI'AN SPECIAL WIRE AND CABLE MANUFACTURING Co Ltd
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ANHUI JI'AN SPECIAL WIRE AND CABLE MANUFACTURING Co Ltd
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Priority to CN201710484741.5A priority Critical patent/CN107245171A/en
Publication of CN107245171A publication Critical patent/CN107245171A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L11/00Compositions of homopolymers or copolymers of chloroprene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • C08K2003/282Binary compounds of nitrogen with aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/324Alkali metal phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of electricity cables for technical installations sheath CSM material, its raw material includes by weight:40 50 parts of chlorosulfonated polyethylene, 30 40 parts of acrylonitrile butadiene styrene plastic, 60 70 parts of neoprene, 24 parts of dimethyl silicone polymer, 24 parts of calcium stearate, 46 parts of polyethylene glycol, 24 parts of barium stearate, 24 parts of styrene butadiene styrene block copolymer, 25 parts of crosslinking agent, 0.4 1 parts of dioctyl adipate, 0.8 1.6 parts of triphenyl phosphate, 15 25 parts of nanometer calcinated argil, 20 30 parts of diatomite, attapulgite clay compounded 50 60 parts of thing, 2.5 3.5 parts of composite antioxidant.Compactness of the present invention is high, and damping capaicty is strong, and durability can be excellent, and heat endurance is good under the conditions of long term high temperature, the formation in reduction internal flaw and cavity, can effectively alleviate the effect of the external force such as bending, impact, can the resonance of attenuating cable sheath.

Description

A kind of electricity cables for technical installations sheath CSM material
Technical field
Chlorosulfonated polyethylene rubber is used the present invention relates to shock absorber part technical field, more particularly to a kind of electricity cables for technical installations sheath Glue material.
Background technology
Electric wire is widely used in every field, is related to people's lives, industrial production every field, at present, especially in work The cable used in industry equipment, quality requirement is especially high, and with the fast development of economic technology, people are to industrial equipment quality It is required that more and more higher, the requirement for the cable performance being particularly used for.During the use of industrial equipment, cable is with work The vibrations of industry equipment are resonated, and the damping capaicty, impact resistance to cable cover(ing) propose higher requirement, as current The technical issues that need to address.
The content of the invention
The technical problem existed based on background technology, the present invention is proposed a kind of electricity cables for technical installations sheath chlorosulfonation and gathered Ethylene rubber material, compactness is high, and damping capaicty is strong, and durability can be excellent, and heat endurance is good under the conditions of long term high temperature, in reduction Portion's defect and the formation in cavity, can effectively alleviate the effect of the external force such as bending, impact, can the resonance of attenuating cable sheath.
A kind of electricity cables for technical installations sheath CSM material proposed by the present invention, its raw material is by weight Including:40-50 parts of chlorosulfonated polyethylene, 30-40 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 60-70 parts of neoprene, poly- two 2-4 parts of methylsiloxane, 2-4 parts of calcium stearate, 4-6 parts of polyethylene glycol, 2-4 parts of barium stearate, styrene-butadiene-benzene second 2-4 parts of alkene block copolymer, 2-5 parts of crosslinking agent, 0.4-1 parts of dioctyl adipate, 0.8-1.6 parts of triphenyl phosphate, nanometer is forged Burn 15-25 parts of clay, 20-30 parts of diatomite, attapulgite clay compounded thing 50-60 parts, 2.5-3.5 parts of composite antioxidant.
Preferably, attapulgite clay compounded thing is prepared using following technique:Attapulgite is heated up, calcined, cooling is placed in hydrogen Sodium hydroxide solution immersion, is washed, and is dried, and is added aluminium nitride, graphite, sodium tripolyphosphate, soybean oil and is stirred, addition cornstarch, Sodium sulphate, water stir, and are 8-8.5 with sodium hydroxide regulation system pH value, add the chloro- 2- Hydroxyproyl Trimethyls chlorinations of 3- Ammonium, dodecenylsuccinic anhydride continue to stir, and with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains bumps Rod soil compound.
Preferably, attapulgite clay compounded thing is prepared using following technique:25-30 parts of attapulgites are heated up by weight, Calcining, cooling is placed in concentration and soaked for 2-2.4mol/L sodium hydroxide solutions, washed, dried, adds 4-8 parts of aluminium nitride, 4-8 Part graphite, 1-2 parts of sodium tripolyphosphates, 30-50 parts of soybean oils stirrings, add 8-12 parts of cornstarch, 4-8 parts of sodium sulphate, 140- 180 parts of water stir, and are 8-8.5 with sodium hydroxide regulation system pH value, add the chloro- 2- Hydroxyproyl Trimethyls chlorine of 4-8 parts of 3- Change ammonium, 2-4 parts of dodecenylsuccinic anhydrides to continue to stir, with hydrochloric acid regulation system pH value in neutrality, filtering is spray-dried To attapulgite clay compounded thing.
Preferably, attapulgite clay compounded thing is prepared using following technique:25-30 parts of attapulgites are warming up to by weight 700-740 DEG C, 4-8h is calcined, cooling is placed in concentration and soaked 1-2 days for 2-2.4mol/L sodium hydroxide solutions, washed, dried, 4-8 portions of aluminium nitride, 4-8 portions of graphite, 1-2 portions of sodium tripolyphosphates, 30-50 portions of soybean oils are added with 2000-2400r/min rotating speed 80-120min is stirred, 8-12 parts of cornstarch, 4-8 parts of sodium sulphate, 140-180 parts of water is added and stirs, adjusted with sodium hydroxide Section system pH be 8-8.5, add 4-8 parts of 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, 2-4 parts of dodecenylsuccinic anhydrides after Continuous stirring 4-8h, with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains attapulgite clay compounded thing.
Preferably, crosslinking agent includes by weight:1-2 parts of benzoyl peroxide, 0.8-1.2 parts of diethylenetriamines, three Paracyanogen 2-4 parts of triallyl of acid.
Preferably, composite antioxidant includes by weight:0.8-1.6 parts of styrenyl-N- phenylanilines, 3,5- bis- uncles 0.6-1.2 parts of butyl -4- hydroxycinnamic acids, phosphorous acid three (2,4- bis- 2-methyl-2-phenylpropane base) 1-2 parts of ester.
The present invention is using neoprene, acrylonitrile-butadiene-styrene (ABS) plastics, chlorosulfonated polyethylene synergy conduct Base material, benzoyl peroxide, diethylenetriamines, TAC collaboration make densification of the invention as vulcanizing system Property it is high, damping capaicty is strong, and durability can be excellent;In attapulgite clay compounded thing, attapulgite through calcining, alkalization after, with aluminium nitride, Graphite, sodium tripolyphosphate compounding, then after soybean oil high-speed stirred, mutual good dispersion, after being well mixed with cornstarch, Acted on through sodium peroxydisulfate, the reactive groups of 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides can with hydroxy combining in above-mentioned material, then It is esterified, is obtained containing quaternary ammonium cation group, hydroxy-acid group and alkenyl long chain group product, flowing using alkenyl succinic anhydride Property is good, and filling capacity is excellent;Attapulgite clay compounded thing and diatomite, nanometer calcinated argil as filler reinforcement material, and Compounded with dimethyl silicone polymer, SBS, make the present invention under the conditions of long term high temperature Heat endurance is good, and filling capacity is good, not only can effectively alleviate the effect of the external force such as bending, impact, and can be effectively in the present invention Portion's structure is safeguarded;Triphenyl phosphate, dioctyl adipate can increase the interior lubricity of material, reduce internal flaw of the present invention With the formation in cavity, further compounded with attapulgite clay compounded thing, not only fillibility is good, and storeroom is uniformly dispersed, and it is fine and close Performance is high, and damping capaicty is further enhanced, can the resonance of attenuating cable sheath, and cost is low, and effect is obvious;Styryl Change-N- phenylanilines, 3,5- di-t-butyl -4- hydroxycinnamic acids and (the 2-methyl-2-phenylpropane bases of the 2,4- bis-) ester of phosphorous acid three are as compound anti- Oxygen agent, not only can effectively slow down aging speed of the present invention, and elongation at break conservation rate is high, and mechanical property is good, service life It is long.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of electricity cables for technical installations sheath CSM material proposed by the present invention, its raw material is by weight Including:40 parts of chlorosulfonated polyethylene, 40 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 60 parts of neoprene, polydimethylsiloxanes 4 parts of alkane, 2 parts of calcium stearate, 6 parts of polyethylene glycol, 2 parts of barium stearate, 4 parts of SBS, 2 parts of crosslinking agent, 1 part of dioctyl adipate, 0.8 part of triphenyl phosphate, 25 parts of nanometer calcinated argil, 20 parts of diatomite, concave convex rod Native 60 parts of compound, 2.5 parts of composite antioxidant.
Embodiment 2
A kind of electricity cables for technical installations sheath CSM material proposed by the present invention, its raw material is by weight Including:50 parts of chlorosulfonated polyethylene, 30 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 70 parts of neoprene, polydimethylsiloxanes 2 parts of alkane, 4 parts of calcium stearate, 4 parts of polyethylene glycol, 4 parts of barium stearate, 2 parts of SBS, 5 parts of crosslinking agent, 0.4 part of dioctyl adipate, 1.6 parts of triphenyl phosphate, 15 parts of nanometer calcinated argil, 30 parts of diatomite is concavo-convex Rod 50 parts of compound of soil, 3.5 parts of composite antioxidant.
Attapulgite clay compounded thing is prepared using following technique:Attapulgite is heated up, calcined, cooling is placed in sodium hydroxide Solution soak, wash, dry, add aluminium nitride, graphite, sodium tripolyphosphate, soybean oil stirring, add cornstarch, sodium sulphate, Water stirs, and is 8-8.5 with sodium hydroxide regulation system pH value, adds 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, laurylene Base succinic anhydride continues to stir, and with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains attapulgite clay compounded Thing.
Embodiment 3
A kind of electricity cables for technical installations sheath CSM material proposed by the present invention, its raw material is by weight Including:42 parts of chlorosulfonated polyethylene, 38 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 66 parts of neoprene, polydimethylsiloxanes 3.5 parts of alkane, 2.5 parts of calcium stearate, 5.5 parts of polyethylene glycol, 2.5 parts of barium stearate, s-B-S block is total to 3.5 parts of polymers, 3 parts of crosslinking agent, 0.8 part of dioctyl adipate, 1 part of triphenyl phosphate, 22 parts of nanometer calcinated argil, diatomite 22 Part, attapulgite clay compounded 57 parts of thing, 2.8 parts of composite antioxidant.
Attapulgite clay compounded thing is prepared using following technique:28 parts of attapulgites are heated up by weight, calcined, cooling, It is placed in concentration to soak for 2.2mol/L sodium hydroxide solutions, washs, dry, adds 6 parts of aluminium nitride, 6 parts of graphite, 1.5 parts of trimerizations Sodium phosphate, 40 parts of soybean oil stirrings, add 10 parts of cornstarch, 6 parts of sodium sulphate, 160 parts of water and stir, adjusted with sodium hydroxide Section system pH is 8-8.5, adds 6 parts of 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, 3 parts of dodecenylsuccinic anhydrides and continues to stir Mix, with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains attapulgite clay compounded thing.
Crosslinking agent includes by weight:1 part of benzoyl peroxide, 1.2 parts of diethylenetriamines, TAC 2 parts.Composite antioxidant includes by weight:1.6 parts of styrenyl-N- phenylanilines, 3,5- di-t-butyl -4- hydroxy cinnamates 0.6 part of acid, phosphorous acid three (2,4- bis- 2-methyl-2-phenylpropane base) 2 parts of ester.
Embodiment 4
A kind of electricity cables for technical installations sheath CSM material proposed by the present invention, its raw material is by weight Including:48 parts of chlorosulfonated polyethylene, 32 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 68 parts of neoprene, polydimethylsiloxanes 2.5 parts of alkane, 3.5 parts of calcium stearate, 4.5 parts of polyethylene glycol, 3.5 parts of barium stearate, s-B-S block is total to 2.5 parts of polymers, 4 parts of crosslinking agent, 0.6 part of dioctyl adipate, 1.4 parts of triphenyl phosphate, 18 parts of nanometer calcinated argil, diatomite 28 parts, attapulgite clay compounded 53 parts of thing, 3.2 parts of composite antioxidant.
Attapulgite clay compounded thing is prepared using following technique:25 parts of attapulgites are warming up to 740 DEG C, calcining by weight 4h, cooling is placed in concentration and soaked 1 day for 2.4mol/L sodium hydroxide solutions, washed, dried, adds 8 parts of aluminium nitride, 4 parts of stones Ink, 2 parts of sodium tripolyphosphates, 30 portions of soybean oils stir 80min with 2400r/min rotating speed, add 12 parts of cornstarch, 4 parts of sulphur Sour sodium, 180 parts of water stir, and are 8-8.5 with sodium hydroxide regulation system pH value, add the chloro- 2- Hydroxyproyl Trimethyls of 4 parts of 3- Ammonium chloride, 4 parts of dodecenylsuccinic anhydrides continue to stir 4h, with hydrochloric acid regulation system pH value in neutrality, filter, spray drying Obtain attapulgite clay compounded thing.
Crosslinking agent includes by weight:1.5 parts of benzoyl peroxide, 1 part of diethylenetriamines, TAC 3 parts.Composite antioxidant includes by weight:1.2 parts of styrenyl-N- phenylanilines, 3,5- di-t-butyl -4- hydroxy cinnamates 0.9 part of acid, phosphorous acid three (2,4- bis- 2-methyl-2-phenylpropane base) 1.5 parts of ester.
Embodiment 5
A kind of electricity cables for technical installations sheath CSM material proposed by the present invention, its raw material is by weight Including:45 parts of chlorosulfonated polyethylene, 35 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 67 parts of neoprene, polydimethylsiloxanes 3 parts of alkane, 3 parts of calcium stearate, 5 parts of polyethylene glycol, 3 parts of barium stearate, 3 parts of SBS, 3.5 parts of crosslinking agent, 0.7 part of dioctyl adipate, 1.2 parts of triphenyl phosphate, 20 parts of nanometer calcinated argil, 25 parts of diatomite is recessed Native 55 parts of the compound of convex rod, 3 parts of composite antioxidant.
Attapulgite clay compounded thing is prepared using following technique:30 parts of attapulgites are warming up to 700 DEG C, calcining by weight 8h, cooling is placed in concentration and soaked 2 days for 2mol/L sodium hydroxide solutions, washed, dried, adds 4 parts of aluminium nitride, 8 parts of graphite, 1 Part sodium tripolyphosphate, 50 portions of soybean oils stir 120min with 2000r/min rotating speed, add 8 parts of cornstarch, 8 parts of sodium sulphate, 140 parts of water stir, and are 8-8.5 with sodium hydroxide regulation system pH value, add the chloro- 2- Hydroxyproyl Trimethyls chlorinations of 8 parts of 3- Ammonium, 2 parts of dodecenylsuccinic anhydrides continue to stir 8h, and with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying is obtained Attapulgite clay compounded thing.
Crosslinking agent includes by weight:2 parts of benzoyl peroxide, 0.8 part of diethylenetriamines, TAC 4 parts.Composite antioxidant includes by weight:0.8 part of styrenyl-N- phenylanilines, 3,5- di-t-butyl -4- hydroxy cinnamates 1.2 parts of acid, phosphorous acid three (2,4- bis- 2-methyl-2-phenylpropane base) 1 part of ester.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (6)

1. a kind of electricity cables for technical installations sheath CSM material, it is characterised in that its raw material is wrapped by weight Include:40-50 parts of chlorosulfonated polyethylene, 30-40 parts of acrylonitrile-butadiene-styrene (ABS) plastics, 60-70 parts of neoprene, poly- diformazan 2-4 parts of radical siloxane, 2-4 parts of calcium stearate, 4-6 parts of polyethylene glycol, 2-4 parts of barium stearate, s-B-S 2-4 parts of block copolymer, 2-5 parts of crosslinking agent, 0.4-1 parts of dioctyl adipate, 0.8-1.6 parts of triphenyl phosphate, nanometer calcining 15-25 parts of clay, 20-30 parts of diatomite, attapulgite clay compounded thing 50-60 parts, 2.5-3.5 parts of composite antioxidant.
2. electricity cables for technical installations sheath CSM material according to claim 1, it is characterised in that concavo-convex Rod soil compound is prepared using following technique:Attapulgite is heated up, calcined, cooling is placed in sodium hydroxide solution immersion, washed Wash, dry, add aluminium nitride, graphite, sodium tripolyphosphate, soybean oil stirring, add cornstarch, sodium sulphate, water and stir, It is 8-8.5 with sodium hydroxide regulation system pH value, adds 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, dodecenylsuccinic anhydride Continue to stir, with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains attapulgite clay compounded thing.
3. electricity cables for technical installations sheath CSM material according to claim 1 or claim 2, it is characterised in that Attapulgite clay compounded thing is prepared using following technique:25-30 parts of attapulgites are heated up by weight, calcined, cooling is placed in dense Spend and soaked for 2-2.4mol/L sodium hydroxide solutions, washed, dried, add 4-8 parts of aluminium nitride, 4-8 parts of graphite, 1-2 parts of trimerizations Sodium phosphate, 30-50 parts of soybean oil stirrings, add 8-12 parts of cornstarch, 4-8 parts of sodium sulphate, 140-180 parts of water and stir, It is 8-8.5 with sodium hydroxide regulation system pH value, adds 4-8 parts of 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, 2-4 parts of laurylenes Base succinic anhydride continues to stir, and with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains attapulgite clay compounded Thing.
4. according to any one of the claim 1-3 electricity cables for technical installations sheath CSM materials, its feature It is, attapulgite clay compounded thing is prepared using following technique:25-30 parts of attapulgites are warming up to 700-740 DEG C by weight, 4-8h is calcined, cooling is placed in concentration and soaked 1-2 days for 2-2.4mol/L sodium hydroxide solutions, washed, dried, adds 4-8 parts of nitrogen Change aluminium, 4-8 parts of graphite, 1-2 parts of sodium tripolyphosphates, 30-50 portions of soybean oils and 80- is stirred with 2000-2400r/min rotating speed 120min, adds 8-12 parts of cornstarch, 4-8 parts of sodium sulphate, 140-180 parts of water and stirs, use sodium hydroxide regulation system PH value is 8-8.5, adds 4-8 parts of 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, 2-4 parts of dodecenylsuccinic anhydrides and continues to stir 4-8h, with hydrochloric acid regulation system pH value in neutrality, filtering, spray drying obtains attapulgite clay compounded thing.
5. according to any one of the claim 1-4 electricity cables for technical installations sheath CSM materials, its feature It is, crosslinking agent includes by weight:1-2 parts of benzoyl peroxide, 0.8-1.2 parts of diethylenetriamines, cyanuric acid triolefin 2-4 parts of propyl ester.
6. according to any one of the claim 1-5 electricity cables for technical installations sheath CSM materials, its feature It is, composite antioxidant includes by weight:0.8-1.6 parts of styrenyl-N- phenylanilines, 3,5- di-t-butyl -4- hydroxyls 0.6-1.2 parts of base cinnamic acid, phosphorous acid three (2,4- bis- 2-methyl-2-phenylpropane base) 1-2 parts of ester.
CN201710484741.5A 2017-06-23 2017-06-23 A kind of electricity cables for technical installations sheath CSM material Withdrawn CN107245171A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108299783A (en) * 2018-02-15 2018-07-20 湖南辰砾新材料有限公司 A kind of high-strength anti-flaming CABLE MATERIALS and preparation method thereof
CN109181203A (en) * 2018-07-10 2019-01-11 天长市优信电器设备有限公司 A kind of electric car charger material of high tensile

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103102542A (en) * 2012-11-14 2013-05-15 安徽金桥电缆有限公司 Anticorrosive flame-resistant cable sheath insulating material and preparation method thereof
CN103102543A (en) * 2012-11-14 2013-05-15 安徽金桥电缆有限公司 Thermoplastic elastomer wire and cable material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103102542A (en) * 2012-11-14 2013-05-15 安徽金桥电缆有限公司 Anticorrosive flame-resistant cable sheath insulating material and preparation method thereof
CN103102543A (en) * 2012-11-14 2013-05-15 安徽金桥电缆有限公司 Thermoplastic elastomer wire and cable material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108299783A (en) * 2018-02-15 2018-07-20 湖南辰砾新材料有限公司 A kind of high-strength anti-flaming CABLE MATERIALS and preparation method thereof
CN109181203A (en) * 2018-07-10 2019-01-11 天长市优信电器设备有限公司 A kind of electric car charger material of high tensile

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Application publication date: 20171013