CN103509293B - A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable - Google Patents
A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable Download PDFInfo
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- CN103509293B CN103509293B CN201310473887.1A CN201310473887A CN103509293B CN 103509293 B CN103509293 B CN 103509293B CN 201310473887 A CN201310473887 A CN 201310473887A CN 103509293 B CN103509293 B CN 103509293B
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Abstract
The invention provides a kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, prepared by the component raw material of following weight part and obtain: polyvinyl chloride 60-70, polysiloxane 10-15, silicon rubber 8-10, dioctyl terephthalate 12-15, triethylene glycol two 2-ethylhexoate 5-10, epoxidation tri-glyceride 3-5, Tributyl O-acetylcitrate 8-10, cobalt naphthenate 1-2, ethyl silicon oil 0.2-0.3, chlorinatedpolyethylene 2-5, aluminium hydroxide 10-15, triphenylphosphate 5-6, decabromodiphynly oxide 4-6, light active calcium carbonate 8-10, wilkinite 5-8, zinc oxide 1-2, titanium dioxide 1-2, volcanic ash 5-6, high wear-resistant carbon black 6-8, Ca-Zn one package stabilizer 2-3, antioxidant 1076? 0.1-1, dicumyl peroxide DCP? 0.1-0.3, butyl stearate 0.2-0.3, barium stearate 1-2, Zinic stearas 0.1-0.5, modified filler 8-10.Under CABLE MATERIALS cold condition obtained by the present invention, shock resistance is good, has the feature of environmental protection, thus solves the problem of existing polyvinyl chloride cable material shock resistance difference not environmentally and under cold condition.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable.
Background technology
Electric wire is important materials indispensable in industrial and agricultural production and the modern life, China is that the maximum electric wire in the whole world produces country, wires and cables industry occupies very important status in the national economy of China, but, at present, the shock strength that CABLE MATERIALS on market also exists under cold condition is not high, the invention provides the environment-friendly cable material that shock strength under a kind of low temperature is good.
Summary of the invention
The invention provides a kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable.The cable be processed into by CABLE MATERIALS of the present invention has the good feature of shock resistance under cold condition.
The technical solution used in the present invention is:
A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride 60-70, polysiloxane 10-15, silicon rubber 8-10, dioctyl terephthalate 12-15, triethylene glycol two 2-ethylhexoate 5-10, epoxidation tri-glyceride 3-5, Tributyl O-acetylcitrate 8-10, cobalt naphthenate 1-2, ethyl silicon oil 0.2-0.3, chlorinatedpolyethylene 2-5, aluminium hydroxide 10-15, triphenylphosphate 5-6, decabromodiphynly oxide 4-6, light active calcium carbonate 8-10, wilkinite 5-8, zinc oxide 1-2, titanium dioxide 1-2, volcanic ash 5-6, high wear-resistant carbon black 6-8, Ca-Zn one package stabilizer 2-3, antioxidant 1076 0.1-1, dicumyl peroxide DCP0.1-0.3, butyl stearate 0.2-0.3, barium stearate 1-2, Zinic stearas 0.1-0.5, modified filler 8-10,
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
Described Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride 65, polysiloxane 14, silicon rubber 9, dioctyl terephthalate 13, triethylene glycol two 2-ethylhexoate 9, epoxidation tri-glyceride 5, Tributyl O-acetylcitrate 8, cobalt naphthenate 1, ethyl silicon oil 0.2, chlorinatedpolyethylene 4, aluminium hydroxide 14, triphenylphosphate 6, decabromodiphynly oxide 5, light active calcium carbonate 9, wilkinite 6, zinc oxide 1, titanium dioxide 2, volcanic ash 5, high wear-resistant carbon black 7, Ca-Zn one package stabilizer 2, antioxidant 1076 0.5, dicumyl peroxide DCP0.2, butyl stearate 0.3, barium stearate 2, Zinic stearas 0.4, modified filler 9,
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 205, algae soil 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
The preparation method of CABLE MATERIALS of the present invention:
Take each constitutive material by formula rate, constitutive material is dropped into homogenizer mixing 4-5min, blowing, the material mixed is put in twin screw extruder, extruding pelletization, then after entering and carrying out drying in hot air dryer, obtain Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, when extruding, twin screw extruder temperature is set to: feeding section 118 DEG C, melt zone 168 DEG C, melt conveying zone 168-178 DEG C, mixing section 180 DEG C, homogenizing zone 181 DEG C, head metering zone 182 DEG C.
Beneficial effect
CABLE MATERIALS obtained by the present invention normally can use under the low temperature environment of-40 DEG C ~-50 DEG C, and under cold condition, shock resistance is good, has the feature of environmental protection, thus solves the problem of existing polyvinyl chloride cable material shock resistance difference not environmentally and under cold condition.
Embodiment
A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, prepared by the component raw material of following weight (kg) and obtain:
Polyvinyl chloride 65, polysiloxane 14, silicon rubber 9, dioctyl terephthalate 13, triethylene glycol two 2-ethylhexoate 9, epoxidation tri-glyceride 5, Tributyl O-acetylcitrate 8, cobalt naphthenate 1, ethyl silicon oil 0.2, chlorinatedpolyethylene 4, aluminium hydroxide 14, triphenylphosphate 6, decabromodiphynly oxide 5, light active calcium carbonate 9, wilkinite 6, zinc oxide 1, titanium dioxide 2, volcanic ash 5, high wear-resistant carbon black 7, Ca-Zn one package stabilizer 2, antioxidant 1076 0.5, dicumyl peroxide DCP0.2, butyl stearate 0.3, barium stearate 2, Zinic stearas 0.4, modified filler 9,
Wherein, modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
The preparation method of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable:
Take each constitutive material by formula rate, constitutive material is dropped into homogenizer mixing 4-5min, blowing, the material mixed is put in twin screw extruder, extruding pelletization, then after entering and carrying out drying in hot air dryer, obtain Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, when extruding, twin screw extruder temperature is set to: feeding section 118 DEG C, melt zone 168 DEG C, melt conveying zone 168-178 DEG C, mixing section 180 DEG C, homogenizing zone 181 DEG C, head metering zone 182 DEG C.
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:
Claims (2)
1. an Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride 60-70, polysiloxane 10-15, silicon rubber 8-10, dioctyl terephthalate 12-15, triethylene glycol two 2-ethylhexoate 5-10, epoxidation tri-glyceride 3-5, Tributyl O-acetylcitrate 8-10, cobalt naphthenate 1-2, ethyl silicon oil 0.2-0.3, chlorinatedpolyethylene 2-5, aluminium hydroxide 10-15, triphenylphosphate 5-6, decabromodiphynly oxide 4-6, light active calcium carbonate 8-10, wilkinite 5-8, zinc oxide 1-2, titanium dioxide 1-2, volcanic ash 5-6, high wear-resistant carbon black 6-8, Ca-Zn one package stabilizer 2-3, antioxidant 1076 0.1-1, dicumyl peroxide DCP0.1-0.3, butyl stearate 0.2-0.3, barium stearate 1-2, Zinic stearas 0.1-0.5, modified filler 8-10,
Described modified filler is prepared by following method and obtains: a, take off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
2. Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable according to claim 1, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride 65, polysiloxane 14, silicon rubber 9, dioctyl terephthalate 13, triethylene glycol two 2-ethylhexoate 9, epoxidation tri-glyceride 5, Tributyl O-acetylcitrate 8, cobalt naphthenate 1, ethyl silicon oil 0.2, chlorinatedpolyethylene 4, aluminium hydroxide 14, triphenylphosphate 6, decabromodiphynly oxide 5, light active calcium carbonate 9, wilkinite 6, zinc oxide 1, titanium dioxide 2, volcanic ash 5, high wear-resistant carbon black 7, Ca-Zn one package stabilizer 2, antioxidant 1076 0.5, dicumyl peroxide DCP0.2, butyl stearate 0.3, barium stearate 2, Zinic stearas 0.4, modified filler 9,
Described modified filler is prepared by following method and obtains: a, take off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 DEG C, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filters, dries and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, to obtain final product.
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| CN201310473887.1A CN103509293B (en) | 2013-10-12 | 2013-10-12 | A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103943215A (en) * | 2014-04-26 | 2014-07-23 | 芜湖航天特种电缆厂 | Intrinsic safety type fan-shaped round fire-resisting cable with Y-shaped nylon framework |
| JP6512003B2 (en) * | 2015-07-13 | 2019-05-15 | 日立金属株式会社 | Vinyl chloride resin composition for electric wire and cable and electric wire and cable using the same |
| JP6503946B2 (en) * | 2015-07-13 | 2019-04-24 | 日立金属株式会社 | Vinyl chloride resin composition and electric wire and cable using the same |
| JP6503947B2 (en) * | 2015-07-13 | 2019-04-24 | 日立金属株式会社 | Vinyl chloride resin composition and electric wire and cable using the same |
| CN107325452A (en) * | 2017-08-09 | 2017-11-07 | 常州市艾诺电子科技有限公司 | Cold-resistant protective layer grade polyvinyl chloride plastic and preparation method thereof |
| CN107671040A (en) * | 2017-09-25 | 2018-02-09 | 安徽中马橡塑制品有限公司 | A kind of vibrations spray screening machine of medical rubber plug |
| CN112266550A (en) * | 2020-10-26 | 2021-01-26 | 温州市瑞强鞋业有限公司 | Women's shoes with cold-resistant soles and preparation method thereof |
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| CN102382391A (en) * | 2011-09-19 | 2012-03-21 | 潘成玉 | Polyvinyl chloride cable material |
| CN102532743A (en) * | 2010-12-21 | 2012-07-04 | 天津德昊超微新材料有限公司 | Material special for flame-retarding polyvinyl chloride insulated cable |
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| CN103275428A (en) * | 2013-06-18 | 2013-09-04 | 张宇 | Cold-resistant PVC cable material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6977280B2 (en) * | 2003-06-11 | 2005-12-20 | Teknor Apex Company | Polyvinyl chloride or polyolefin melt processable compositions containing polytetrafluoroethylene micropowder |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102532743A (en) * | 2010-12-21 | 2012-07-04 | 天津德昊超微新材料有限公司 | Material special for flame-retarding polyvinyl chloride insulated cable |
| CN102382391A (en) * | 2011-09-19 | 2012-03-21 | 潘成玉 | Polyvinyl chloride cable material |
| CN103205070A (en) * | 2013-04-12 | 2013-07-17 | 江苏领瑞新材料科技有限公司 | Cold-resistant oilproof flame-retardant PVC (Polyvinyl Chloride) cable material and preparation method thereof |
| CN103275428A (en) * | 2013-06-18 | 2013-09-04 | 张宇 | Cold-resistant PVC cable material and preparation method thereof |
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Inventor after: Li Zhi Inventor before: Xie Hua |
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Effective date of registration: 20170721 Address after: 523900 Guangdong city of Dongguan province Humen Huaide community Tai Po Industrial District No. 11 -2 Patentee after: Dongguan tiger plastic Alwayseal Technology Ltd Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: Lvbao Cable (Group) Co., Ltd. |
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