CN103524942B - A kind of flexible polrvinyl chloride flexible cable material - Google Patents

A kind of flexible polrvinyl chloride flexible cable material Download PDF

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CN103524942B
CN103524942B CN201310474451.4A CN201310474451A CN103524942B CN 103524942 B CN103524942 B CN 103524942B CN 201310474451 A CN201310474451 A CN 201310474451A CN 103524942 B CN103524942 B CN 103524942B
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flexible
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CN103524942A (en
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谢华
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Guangdong Baijia Wire And Cable Industry Co ltd
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Lvbao Cable Group Co Ltd
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Abstract

The invention provides a kind of flexible polrvinyl chloride flexible cable material, prepared by the component raw material of following weight part and obtain: polyvinyl chloride resin 50-60, vibrin 20-40, silicone resin 10-20, precipitated silica 10-15, wollastonite powder 5-10, rhombspar 4-6, bauxitic clay 4-6, molybdenumdisulphide 4-6, tetramethylolmethane 3-5, triphenyl phosphite 0.5-1.0, oxidation inhibitor 10350.1-0.2, irgasfos 168 0.1-0.2, ferrocene 0.2-0.4, stearic amide 0.1-0.3, Zinic stearas 0.2-0.3, calcium stearate 0.1-0.3, barium stearate 0.1-0.3, polymethylphenyl siloxane fluid 0.1-0.2, modified filler 10-15.Recipe ingredient through the mixing of plastic high-speed mixer machine, after extruder plastication makes particle, being had excellent elongation, significantly enhances its elastic performance, when ensureing product electric property, reaching the elongation and tensile strength that improve finished product by the present invention.

Description

A kind of flexible polrvinyl chloride flexible cable material
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of flexible polrvinyl chloride flexible cable material and preparation method thereof.
Background technology
Electric wire has the effect of power transmission and information conveyance, plays an important role in people's life and production.Design and prepare low cigarette, low toxicity, possessing again the CABLE MATERIALS of excellent fire-retardancy and insulating property simultaneously, become the focus of current fire-retardant research.Traditional magnesium hydroxide and aluminium hydroxide based flame retardant, although the flame retardant properties that material is good can be given, but, matrix resin due to most of CABLE MATERIALS is nonpolar polyolefins polymer, poor with the consistency of the magnesium hydroxide of polarity, aluminium hydroxide, often reduce mechanical property and the processing characteristics of material.Work out and both there is good flame retardant properties, there is environmental-protecting performance simultaneously, good machinability, preferably the CABLE MATERIALS material of insulating property become the direction of CABLE MATERIALS development, the present invention is by adding modified filler, substantially increase the consistency of storeroom, while improve the machining property of CABLE MATERIALS, also assures that the anti-flaming environment-friendly of CABLE MATERIALS.
Summary of the invention
The invention provides a kind of flexible polrvinyl chloride flexible cable material and preparation method thereof.The cable be processed into by CABLE MATERIALS of the present invention has good weatherability, low cigarette, ageing-resistant, and flame retardant properties is good.
The technical solution used in the present invention is:
A kind of flexible polrvinyl chloride flexible cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride resin 50-60, vibrin 20-40, silicone resin 10-20, precipitated silica 10-15, wollastonite powder 5-10, rhombspar 4-6, bauxitic clay 4-6, molybdenumdisulphide 4-6, tetramethylolmethane 3-5, triphenyl phosphite 0.5-1.0, oxidation inhibitor 10350.1-0.2, irgasfos 168 0.1-0.2, ferrocene 0.2-0.4, stearic amide 0.1-0.3, Zinic stearas 0.2-0.3, calcium stearate 0.1-0.3, barium stearate 0.1-0.3, polymethylphenyl siloxane fluid 0.1-0.2, modified filler 10-15,
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 180-190, medical stone 30-34, nano-sized carbon 1-2, xitix 1-2, coix seed oil 1-2, aluminum nitride powder 1-2, Zinc Gluconate 2-3, jade powder 2-3, polyisobutene 2-3, aluminate coupling agent DL-4111-2, stearic acid 2-3, antioxidant 1010 1-2;
B, kaolin, medical stone are calcined 5-6h at 450-480 DEG C, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, and repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, dry and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, to obtain final product.
Described flexible polrvinyl chloride flexible cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride resin 58, vibrin 25, silicone resin 16, precipitated silica 12, wollastonite powder 6, rhombspar 5, bauxitic clay 5, molybdenumdisulphide 4, tetramethylolmethane 5, triphenyl phosphite 0.8, oxidation inhibitor 10350.1, irgasfos 168 0.2, ferrocene 0.3, stearic amide 0.2, Zinic stearas 0.3, calcium stearate 0.2, barium stearate 0.3, polymethylphenyl siloxane fluid 0.2, modified filler 13
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 188, medical stone 32, nano-sized carbon 1-2, xitix 1, coix seed oil 1, aluminum nitride powder 2, Zinc Gluconate 3, jade powder 2, polyisobutene 2, aluminate coupling agent DL-4111, stearic acid 2, antioxidant 1010 1;
B, kaolin, medical stone are calcined 5-6h at 450-480 DEG C, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, and repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, dry and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, to obtain final product.
The preparation method of CABLE MATERIALS of the present invention:
Take material by formula rate, the material taken is dropped in high-speed mixer and mixes; To mix after 3 ~ 5 minutes forced feed in twin screw extruder extruding pelletization, after pellet enters and carries out drying in hot air dryer, obtain described flexible polrvinyl chloride flexible cable material, wherein, when extruding, twin screw extruder temperature is set to: feeding section 110 DEG C, melt zone 160 DEG C, melt conveying zone 160 ~ 170 DEG C, mixing section 185 DEG C, homogenizing zone 180 DEG C, head metering zone 185 DEG C.
Beneficial effect
Recipe ingredient through the mixing of plastic high-speed mixer machine, after extruder plastication makes particle, being had excellent elongation, significantly enhances its elastic performance, when ensureing product electric property, reaching the elongation and tensile strength that improve finished product by the present invention.
Embodiment
A kind of flexible polrvinyl chloride flexible cable material, prepared by the component raw material of following weight (kg) and obtain:
Polyvinyl chloride resin 58, vibrin 25, silicone resin 16, precipitated silica 12, wollastonite powder 6, rhombspar 5, bauxitic clay 5, molybdenumdisulphide 4, tetramethylolmethane 5, triphenyl phosphite 0.8, oxidation inhibitor 10350.1, irgasfos 168 0.2, ferrocene 0.3, stearic amide 0.2, Zinic stearas 0.3, calcium stearate 0.2, barium stearate 0.3, polymethylphenyl siloxane fluid 0.2, modified filler 13
Wherein, modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 188, medical stone 32, nano-sized carbon 1-2, xitix 1, coix seed oil 1, aluminum nitride powder 2, Zinc Gluconate 3, jade powder 2, polyisobutene 2, aluminate coupling agent DL-4111, stearic acid 2, antioxidant 1010 1;
B, kaolin, medical stone are calcined 5-6h at 450-480 DEG C, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, and repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, dry and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, to obtain final product.
The preparation method of flexible polrvinyl chloride flexible cable material:
Take material by formula rate, the material taken is dropped in high-speed mixer and mixes; To mix after 3 ~ 5 minutes forced feed in twin screw extruder extruding pelletization, after pellet enters and carries out drying in hot air dryer, obtain described flexible polrvinyl chloride flexible cable material, wherein, when extruding, twin screw extruder temperature is set to: feeding section 110 DEG C, melt zone 170 DEG C, melt conveying zone 170 ~ 185 DEG C, mixing section 200 DEG C, homogenizing zone 190 DEG C, head metering zone 190 DEG C.
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:

Claims (2)

1. a flexible polrvinyl chloride flexible cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride resin 50-60, vibrin 20-40, silicone resin 10-20, precipitated silica 10-15, wollastonite powder 5-10, rhombspar 4-6, bauxitic clay 4-6, molybdenumdisulphide 4-6, tetramethylolmethane 3-5, triphenyl phosphite 0.5-1.0, oxidation inhibitor 10350.1-0.2, irgasfos 168 0.1-0.2, ferrocene 0.2-0.4, stearic amide 0.1-0.3, Zinic stearas 0.2-0.3, calcium stearate 0.1-0.3, barium stearate 0.1-0.3, polymethylphenyl siloxane fluid 0.1-0.2, modified filler 10-15,
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 180-190, medical stone 30-34, nano-sized carbon 1-2, xitix 1-2, coix seed oil 1-2, aluminum nitride powder 1-2, Zinc Gluconate 2-3, jade powder 2-3, polyisobutene 2-3, aluminate coupling agent DL-4111-2, stearic acid 2-3, antioxidant 1010 1-2;
B, kaolin, medical stone are calcined 5-6h at 450-480 DEG C, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, and repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, dry and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, to obtain final product.
2. flexible polrvinyl chloride flexible cable material according to claim 1, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride resin 58, vibrin 25, silicone resin 16, precipitated silica 12, wollastonite powder 6, rhombspar 5, bauxitic clay 5, molybdenumdisulphide 4, tetramethylolmethane 5, triphenyl phosphite 0.8, oxidation inhibitor 10350.1, irgasfos 168 0.2, ferrocene 0.3, stearic amide 0.2, Zinic stearas 0.3, calcium stearate 0.2, barium stearate 0.3, polymethylphenyl siloxane fluid 0.2, modified filler 13
Described modified filler is prepared by following method and obtains: a. takes off the raw material of row weight part: kaolin 188, medical stone 32, nano-sized carbon 1-2, xitix 1, coix seed oil 1, aluminum nitride powder 2, Zinc Gluconate 3, jade powder 2, polyisobutene 2, aluminate coupling agent DL-4111, stearic acid 2, antioxidant 1010 1;
B, kaolin, medical stone are calcined 5-6h at 450-480 DEG C, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, and repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, dry and obtain filler powder;
C, above-mentioned gained powder to be mixed with other remaining component, and even with the high speed dispersion of 8000-10000 rev/min, to obtain final product.
CN201310474451.4A 2013-10-12 2013-10-12 A kind of flexible polrvinyl chloride flexible cable material Active CN103524942B (en)

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CN103865211B (en) * 2014-03-27 2016-03-02 国网上海市电力公司 A kind of electric wire polyester-polyvinyl chloride composite plastic and preparation method thereof
CN103951944B (en) * 2014-05-16 2016-01-20 王崇高 A kind of electric wire penetration pipe
CN104151611A (en) * 2014-07-28 2014-11-19 淮南文峰航天电缆有限公司 Modified filler capable of improving flexibility of aviation cable material and preparation method thereof
CN105419154A (en) * 2015-11-27 2016-03-23 蚌埠海明压铸机有限公司 Heat-resistant modified plastic
CN106009660A (en) * 2016-06-28 2016-10-12 安徽富乐泰水泵系统有限公司 Composite fiber-reinforced high-performance gasket for pump
CN106046610A (en) * 2016-07-05 2016-10-26 太仓市林源电线电缆有限公司 Anti-fouling flame-retardant wire PVC (polyvinyl chloride) material
CN108440962A (en) * 2018-01-31 2018-08-24 枞阳县三金颜料有限责任公司 A kind of high hardness high toughness self-drying type organic siliconresin
CN108314863A (en) * 2018-03-29 2018-07-24 合肥励仙电力工程有限公司 Anti- solarization anticracking CABLE MATERIALS of one kind and preparation method thereof
CN108659408A (en) * 2018-06-15 2018-10-16 浙江威思康塑胶有限公司 A kind of preparation method of low temperature resistant PVC cable material
CN108707298A (en) * 2018-06-15 2018-10-26 浙江威思康塑胶有限公司 A kind of low temperature resistant PVC cable material
CN113214612B (en) * 2021-04-13 2022-12-30 中北大学 PBSeT/Zinc gluconate puncture-resistant biodegradable material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245166A (en) * 2008-02-22 2008-08-20 常熟市中联光电新材料有限责任公司 Flame-proof soft vinyl plastics for electric wire and cable
CN101812208A (en) * 2010-04-10 2010-08-25 常熟市中联光电新材料有限责任公司 Irradiation cross-linking flame-retardant flexible polyvinyl chloride plastic for wire and cable
CN102993521A (en) * 2012-11-13 2013-03-27 安徽文峰电子科技集团有限公司 Environmental-friendly termite-resistant cable sheath insulating material and method for preparing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245166A (en) * 2008-02-22 2008-08-20 常熟市中联光电新材料有限责任公司 Flame-proof soft vinyl plastics for electric wire and cable
CN101812208A (en) * 2010-04-10 2010-08-25 常熟市中联光电新材料有限责任公司 Irradiation cross-linking flame-retardant flexible polyvinyl chloride plastic for wire and cable
CN102993521A (en) * 2012-11-13 2013-03-27 安徽文峰电子科技集团有限公司 Environmental-friendly termite-resistant cable sheath insulating material and method for preparing same

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