CN106046610A - Anti-fouling flame-retardant wire PVC (polyvinyl chloride) material - Google Patents
Anti-fouling flame-retardant wire PVC (polyvinyl chloride) material Download PDFInfo
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- CN106046610A CN106046610A CN201610522680.2A CN201610522680A CN106046610A CN 106046610 A CN106046610 A CN 106046610A CN 201610522680 A CN201610522680 A CN 201610522680A CN 106046610 A CN106046610 A CN 106046610A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an anti-fouling flame-retardant wire PVC (polyvinyl chloride) material, characterized by comprising the following components according to parts by weight: 70-100 parts of polyvinyl chloride, 25-40 parts of fluorosilicon resin, 10-15 parts of methyl silicone resin, 6-12 parts of a flame retardant, 3-5 parts of nano titanium dioxide particles, 1-3 parts of nano calcium carbonate, 0.5-1.5 parts of a plasticizer, 1.5-3 parts of an antiaging agent, 0.3-1.2 parts of an antioxidant, and 0.3-0.8 part of carbon black. The wire PVC material has good wear resistance, aging resistance and flame retardancy, surface anti-fouling performance of the wire PVC material can be improved, and the material has self-cleaning effect so that dust in surrounding air rarely attaches to the surface of the wire PVC material, avoiding safety hazards during usage and greatly improving safety of the material.
Description
Technical field
The present invention relates to electric wire field, particularly to a kind of anti-soil fire-resistant wire PVC material.
Background technology
Electric wire is a kind of in order to transmit electricity (magnetic) energy, information and the wire product realizing electromagnetic energy conversion.Electric wire electricity
The main carriers that cable transmits as electric power, is widely used in the aspects such as appliance equipment, illuminating line, household electrical appliance, its quality
Quality directly influences the security of the lives and property of construction quality and consumer.Although a wires and cables industry simply supporting row
Industry, but in occupation of the output value of China's electrician trade 1/4.Its product category is numerous, and range of application is quite varied, relate to electric power,
Build, communicate, the industry such as manufacture, the most closely related with each department of national economy.Electric wire is also known as national economy
" tremulous pulse " and " neural ", be conveying electric energy, transmission information and manufacture various motor, instrument, instrument, it is achieved electromagnetic energy is changed
Indispensable basic equipment, is basic product necessary in following electrification, informationized society.
Current electric wire divides from material and includes the multiple electric wire such as PVC, PE, PP.PVC product is good with it
Decay resistance is widely used in various fields with shock resistance.In electric wire field due to security performance and environmental protection
The high request of performance so that the application of PVC material also receives the biggest challenge.
Electric wire is typically used for outdoor, and a large amount of dust is distributed in the air of the exterior space.Dust is usually by powder
Dirt forms, and composition is more complicated, is wherein no lack of particle such as breeze etc of conduction, and general dust lane negative charge, electric wire band is just
Electricity, then dust will be adsorbed onto around by electric wire, runs into the environment of humidity, and the voltage within electric wire will puncture
Insulating barrier, to components and parts around or atmospherical discharges, causes a series of potential safety hazard.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of anti-soil fire-resistant wire PVC material.Described electricity
Line PVC material has good corrosion resistance, ageing resistance and anti-flammability, and is added with fluorine silicon resin and methyl silicon resin, it is possible to
Improve the anti-soil anti-pollution characteristic on electric wire PVC material surface so that the dust in ambient atmosphere is difficult to be attached to electric wire PVC and expects surface；
Additionally, the titanium dioxide nanoparticle contained can give electric wire PVC expects surface micronano structure, there is automatically cleaning effect, enter
One step improves the anti-soil anti-pollution characteristic of electric wire PVC material, thus avoids in use being formed potential safety hazard, is greatly improved its peace
Full performance.
For reaching above-mentioned purpose, the technical scheme is that
A kind of anti-soil fire-resistant wire PVC material, including the component of following parts by weight: polrvinyl chloride: 70-100 part, fluorine silicon tree
Fat: 25-40 part, methyl silicon resin: 10-15 part, fire retardant: 6-12 part, titanium dioxide nanoparticle: 3-5 part, nano-calcium carbonate
Calcium: 1-3 part, plasticizer: 0.5-1.5 part, age resistor: 1.5-3 part, antioxidant: 0.3-1.2 part, white carbon black: 0.3-0.8 part.
Further, including the component of following parts by weight: polrvinyl chloride: 75-90 part, fluorine silicon resin: 32-40 part, first
Base silicones: 12-15 part, fire retardant: 9-12 part, titanium dioxide nanoparticle: 3.5-4.5 part, nano-calcium carbonate: 1.8-3 part,
Plasticizer: 0.9-1.5 part, age resistor: 2-3 part, antioxidant: 0.6-1.2 part, white carbon black: 0.3-0.5 part.
Further, including the component of following parts by weight: polrvinyl chloride: 88 parts, fluorine silicon resin: 35 parts, methyl silicon tree
Fat: 13 parts, fire retardant: 10 parts, titanium dioxide nanoparticle: 3.8 parts, nano-calcium carbonate: 2.5 parts, plasticizer: 1.2 parts, anti-old
Agent: 2.6 parts, antioxidant: 0.8 part, white carbon black: 0.4 part.
Further, described fire retardant is any one in halogen flame or halogen-free flame retardants.
And have, described halogen flame is decabromodiphenyl oxide.
Separately, the particle diameter of described titanium dioxide nanoparticle is 50-80nm.
Meanwhile, described plasticizer is any one in dioctyl phthalate or octyl epoxy stearate, described anti-old
Agent is any one in antioxidant A or antioxidant MB or antioxidant BLE-C, and described antioxidant is antioxidant BTH, antioxidation
Any one in agent 1010, antioxidant 168.
The beneficial effects of the present invention is:
A kind of anti-soil fire-resistant wire PVC material that the present invention provides, has good corrosion resistance, ageing resistance and fire-retardant
Property, and it is added with fluorine silicon resin and methyl silicon resin, it is possible to increase the anti-soil anti-pollution characteristic on electric wire PVC material surface so that around
Dust in air is difficult to be attached to electric wire PVC and expects surface；Additionally, the titanium dioxide nanoparticle contained can give electric wire
PVC expects surface micronano structure, has automatically cleaning effect, improves the anti-soil anti-pollution characteristic of electric wire PVC material further, thus avoids
In use form potential safety hazard, be greatly improved its security performance.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, the most detailed below in conjunction with embodiment
Describe in detail bright.
Table 1 is that embodiment of the present invention anti-soil fire-resistant wire PVC expects ingredient lists.
The feed ingredient (unit: part) of table 1. embodiment anti-soil fire-resistant wire PVC material
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Polrvinyl chloride | 75 | 70 | 88 | 90 | 100 |
| Fluorine silicon resin | 25 | 30 | 35 | 40 | 30 |
| Methyl silicon resin | 15 | 10 | 13 | 12 | 12 |
| Fire retardant | 6 | 8 | 10 | 10 | 12 |
| Titanium dioxide nanoparticle | 3 | 3 | 3.8 | 4.5 | 5 |
| Nano-calcium carbonate | 1 | 1 | 2.5 | 2 | 3 |
| Plasticizer | 0.5 | 1 | 1.2 | 0.8 | 1.5 |
| Age resistor | 2 | 1.5 | 2.6 | 3 | 2 |
| Antioxidant | 0.3 | 0.6 | 0.8 | 1 | 1.2 |
| White carbon black | 0.5 | 0.3 | 0.4 | 0.8 | 0.5 |
A kind of anti-soil fire-resistant wire PVC material that the present invention provides, has good corrosion resistance, ageing resistance and fire-retardant
Property, and it is added with fluorine silicon resin and methyl silicon resin, it is possible to increase the anti-soil anti-pollution characteristic on electric wire PVC material surface so that around
Dust in air is difficult to be attached to electric wire PVC and expects surface；Additionally, the titanium dioxide nanoparticle contained can give electric wire
PVC expects surface micronano structure, has automatically cleaning effect, improves the anti-soil anti-pollution characteristic of electric wire PVC material further, thus
Avoid in use being formed potential safety hazard, be greatly improved its security performance.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively
The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention
In profit claimed range.
Claims (7)
1. anti-soil fire-resistant wire PVC material, it is characterised in that include the component of following parts by weight: polrvinyl chloride: 70-100
Part, fluorine silicon resin: 25-40 part, methyl silicon resin: 10-15 part, fire retardant: 6-12 part, titanium dioxide nanoparticle: 3-5 part,
Nano-calcium carbonate: 1-3 part, plasticizer: 0.5-1.5 part, age resistor: 1.5-3 part, antioxidant: 0.3-1.2 part, white carbon black: 0.3-
0.8 part.
A kind of anti-soil fire-resistant wire PVC material the most according to claim 1, it is characterised in that include following parts by weight
Component: polrvinyl chloride: 75-90 part, fluorine silicon resin: 32-40 part, methyl silicon resin: 12-15 part, fire retardant: 9-12 part, nanometer
Titanium dioxide granule: 3.5-4.5 part, nano-calcium carbonate: 1.8-3 part, plasticizer: 0.9-1.5 part, age resistor: 2-3 part, antioxygen
Agent: 0.6-1.2 part, white carbon black: 0.3-0.5 part.
A kind of anti-soil fire-resistant wire PVC material the most according to claim 1, it is characterised in that include following parts by weight
Component: polrvinyl chloride: 88 parts, fluorine silicon resin: 35 parts, methyl silicon resin: 13 parts, fire retardant: 10 parts, nano titanium oxide
Grain: 3.8 parts, nano-calcium carbonate: 2.5 parts, plasticizer: 1.2 parts, age resistor: 2.6 parts, antioxidant: 0.8 part, white carbon black: 0.4
Part.
A kind of anti-soil fire-resistant wire PVC material the most according to claim 1, it is characterised in that described fire retardant is halogen resistance
Any one in combustion agent or halogen-free flame retardants.
A kind of anti-soil fire-resistant wire PVC material the most according to claim 4, it is characterised in that described halogen flame is ten
Bromo biphenyl ether.
A kind of anti-soil fire-resistant wire PVC material the most according to claim 1, it is characterised in that described nano titanium oxide
The particle diameter of grain is 50-80nm.
A kind of anti-soil fire-resistant wire PVC material the most according to claim 1, it is characterised in that described plasticizer is adjacent benzene two
Any one in formic acid dioctyl ester or octyl epoxy stearate, described age resistor is antioxidant A or antioxidant MB or age resistor
Any one in BLE-C, described antioxidant is antioxidant BTH, any one in antioxidant 1010, antioxidant 168.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610522680.2A CN106046610A (en) | 2016-07-05 | 2016-07-05 | Anti-fouling flame-retardant wire PVC (polyvinyl chloride) material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610522680.2A CN106046610A (en) | 2016-07-05 | 2016-07-05 | Anti-fouling flame-retardant wire PVC (polyvinyl chloride) material |
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| Publication Number | Publication Date |
|---|---|
| CN106046610A true CN106046610A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610522680.2A Pending CN106046610A (en) | 2016-07-05 | 2016-07-05 | Anti-fouling flame-retardant wire PVC (polyvinyl chloride) material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073173A (en) * | 2019-12-23 | 2020-04-28 | 江西洪茂线缆有限公司 | Wire and cable protective material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964724A (en) * | 2012-11-27 | 2013-03-13 | 宁波一舟塑胶有限公司 | Thin-wall insulated wire material for automobile and preparation method thereof |
| CN103524942A (en) * | 2013-10-12 | 2014-01-22 | 绿宝电缆（集团）有限公司 | Flexible polyvinyl chloride (PVC) soft cable material |
| CN104844983A (en) * | 2015-05-29 | 2015-08-19 | 合肥得润电子器件有限公司 | Durable fluororubber modified PVC (polyvinyl chloride) cable material for automobile wire harnesses and preparation method thereof |
| CN105331089A (en) * | 2015-11-24 | 2016-02-17 | 扬州康龙环保工程有限公司 | Environment-friendly outer sheath material |
-
2016
- 2016-07-05 CN CN201610522680.2A patent/CN106046610A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964724A (en) * | 2012-11-27 | 2013-03-13 | 宁波一舟塑胶有限公司 | Thin-wall insulated wire material for automobile and preparation method thereof |
| CN103524942A (en) * | 2013-10-12 | 2014-01-22 | 绿宝电缆（集团）有限公司 | Flexible polyvinyl chloride (PVC) soft cable material |
| CN104844983A (en) * | 2015-05-29 | 2015-08-19 | 合肥得润电子器件有限公司 | Durable fluororubber modified PVC (polyvinyl chloride) cable material for automobile wire harnesses and preparation method thereof |
| CN105331089A (en) * | 2015-11-24 | 2016-02-17 | 扬州康龙环保工程有限公司 | Environment-friendly outer sheath material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073173A (en) * | 2019-12-23 | 2020-04-28 | 江西洪茂线缆有限公司 | Wire and cable protective material and preparation method thereof |
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Application publication date: 20161026 |