CN102382391B - Polyvinyl chloride cable material - Google Patents
Polyvinyl chloride cable material Download PDFInfo
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- CN102382391B CN102382391B CN 201110277402 CN201110277402A CN102382391B CN 102382391 B CN102382391 B CN 102382391B CN 201110277402 CN201110277402 CN 201110277402 CN 201110277402 A CN201110277402 A CN 201110277402A CN 102382391 B CN102382391 B CN 102382391B
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- polyvinyl chloride
- cable material
- chloride cable
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Abstract
The invention relates to a polyvinyl chloride cable material having excellent performances. The polyvinyl chloride cable material having excellent performances comprises: by weight, 100 parts of polyvinyl chloride resin, 25 parts of one or more inorganic filling materials, 4 parts of triphenyl phosphate, 10 parts of epoxy butyl oleate, 24 parts of aluminum hydroxide, 0.6 parts of an anti-oxidant 1010, 1.8 parts of an anti-oxidant 1024, 2 parts of magnesium oxide, 3 parts of zinc oxide, 2 parts of eleaostearic acid and 0.6 parts of an aluminate coupling agent. The polyvinyl chloride cable material having excellent performances has excellent weatherability, cold resistance, aging resistance, oxidation resistance and copper corrosion resistance.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS, especially have the polyvinyl chloride cable material of excellent properties.
Background technology
In the cable production process, the copper conductor oxidation stain is hard nut to crack, and conventional solution is to intercept contacting of copper and air with physical method, generates passive film obstruct copper conductor oxidation etc. with chemical process.The thermoplastics isolator is under normal circumstances on not impact of copper wire oxidation.But used raw and auxiliary material inferior in existing many CABLE MATERIALS, although the conventional sense qualified, life-time service will cause damage to copper wire.PVC softening agent commonly used, all exist the free acid ion to separate out such as dioctyl phthalate (DOP), dioctyl sebacate, two 11 esters of phthalic acid, trioctyl trimellitate, clorafin etc., corrode copper wire and the oxidation blackout, have a strong impact on the problem of cable performance.And how suppressing the generation of this phenomenon, production is very important for cable.
Summary of the invention
For addressing the above problem, the inventor is by test, creatively find the CABLE MATERIALS that various raw materials and auxiliary agent by following cooperation form, excellence aspect the weathering resistance of routine, winter hardiness, ageing-resistant performance not only, but also have excellent antioxidant copper resistant performance.
Therefore, the invention provides a kind of polyvinyl chloride cable material, it is comprised of following each component, and their parts by weight are as follows:
Preferably, in above-mentioned CABLE MATERIALS, described mineral filler comprises one or more in calcium carbonate, silicon-dioxide, carbon black, titanium dioxide, talcum powder, kaolin, wollastonite, polynite and the mica powder.
Each raw material that the present invention is used and auxiliary agent all are commercially available, wherein polyvinyl chloride (PVC) RESINS is that company produces, triphenylphosphate is that company produces, the epoxyoleic acid butyl ester is that company produces, antioxidant 1010,1024 is for company produces, and magnesium oxide, zinc oxide, stearic acid, aluminate coupling agent be that company produces.
The application adopts triphenylphosphate and the composite use of epoxyoleic acid butyl ester, can so that gained CABLE MATERIALS flame retardant resistance, winter hardiness all be improved; Antioxidant 1010 and 1024 use that proportions has namely improved antioxygen, has increased again anti-copper corrosion performance; Magnesium oxide, zinc oxide and stearic being used in conjunction with can obtain the higher material of thermostability; Being used in conjunction with of aluminium hydroxide and antioxidant 1010 and aluminate coupling agent makes good flame retardation effect, plays the effect of cooperative flame retardant.The raising of these performances all is vital for CABLE MATERIALS.
Embodiment
Below in conjunction with the embodiment of the invention technical scheme of the present invention is clearly and completely described.
Embodiment 1:
CABLE MATERIALS prescription following (weight part):
By above-mentioned prescription raw material and auxiliary agent are added in the homogenizer, under low speed 220rpm, mixed 2 minutes first, then mixed 3 minutes under the high speed 1300rpm, obtain mixed powder, obtain cable granules through single screw extrusion machine at 140-180 ℃ of lower extruding pelletization.
Claims (2)
1. polyvinyl chloride cable material, it is comprised of following each component, and their parts by weight are as follows:
By above-mentioned prescription raw material and auxiliary agent are added in the homogenizer; under low speed 220rpm, mixed 2 minutes first; then mixed 3 minutes under the high speed 1300rpm, obtain mixed powder, obtain described polyvinyl chloride cable material through single screw extrusion machine at 140-180 ℃ of lower extruding pelletization.
2. polyvinyl chloride cable material according to claim 1 is characterized in that, described mineral filler comprises one or more in calcium carbonate, silicon-dioxide, carbon black, titanium dioxide, talcum powder, kaolin, wollastonite, polynite and the mica powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110277402 CN102382391B (en) | 2011-09-19 | 2011-09-19 | Polyvinyl chloride cable material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110277402 CN102382391B (en) | 2011-09-19 | 2011-09-19 | Polyvinyl chloride cable material |
Publications (2)
Publication Number | Publication Date |
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CN102382391A CN102382391A (en) | 2012-03-21 |
CN102382391B true CN102382391B (en) | 2013-04-10 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 201110277402 Expired - Fee Related CN102382391B (en) | 2011-09-19 | 2011-09-19 | Polyvinyl chloride cable material |
Country Status (1)
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CN (1) | CN102382391B (en) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103571075A (en) * | 2012-07-19 | 2014-02-12 | 远东电缆有限公司 | PVC sheath rubber |
CN102964723B (en) * | 2012-11-29 | 2014-06-18 | 江苏亨通线缆科技有限公司 | Polyvinyl chloride (PVC) cable material for automobile data transmission wire |
CN104045938B (en) * | 2012-11-29 | 2017-01-11 | 江苏亨通线缆科技有限公司 | Heat-resistance PVC (polyvinyl chloride) cable material |
CN104045941B (en) * | 2012-11-29 | 2016-07-06 | 江苏亨通线缆科技有限公司 | Data transmission automotive line CABLE MATERIALS |
CN104045939A (en) * | 2012-11-29 | 2014-09-17 | 江苏亨通线缆科技有限公司 | Modified polyvinyl chloride (PVC) cable material for data cables |
CN103304916B (en) * | 2013-05-14 | 2016-06-29 | 安徽旺达铜业发展有限公司 | A kind of polyvinyl chloride cable material containing modified magnesium hydroxide |
CN103304941A (en) * | 2013-05-14 | 2013-09-18 | 安徽旺达铜业发展有限公司 | Triphenyl phosphate modified cable sheathing compound |
CN103333429B (en) * | 2013-06-05 | 2016-05-04 | 安徽荣玖光纤通信科技有限公司 | A kind of ageing-resistant polyvinyl chloride cable material |
CN103509282B (en) * | 2013-09-06 | 2016-03-02 | 安徽华通电缆集团有限公司 | A kind of polyvinyl chloride cable material with excellent properties |
CN103509293B (en) * | 2013-10-12 | 2016-04-13 | 绿宝电缆(集团)有限公司 | A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable |
CN103509294B (en) * | 2013-10-12 | 2016-03-02 | 绿宝电缆(集团)有限公司 | A kind of cold-resistant fire-retardant PVC CABLE MATERIALS |
CN104558906A (en) * | 2013-10-22 | 2015-04-29 | 宁夏金黄河塑业有限责任公司 | Rare earth wire shielded PVC cable sheath |
CN103709551A (en) * | 2013-12-06 | 2014-04-09 | 上海特种电线电缆(集团)有限公司 | High-temperature resistant fireproof nano insulating material |
CN103724871A (en) * | 2013-12-10 | 2014-04-16 | 芜湖佳诚电子科技有限公司 | Environmentally friendly inflaming retarding type PVC cable material and preparation method thereof |
CN103724872A (en) * | 2013-12-10 | 2014-04-16 | 芜湖佳诚电子科技有限公司 | Environmentally-friendly PVC cable material and preparation method thereof |
CN103849090A (en) * | 2014-03-10 | 2014-06-11 | 深圳市领亚电子有限公司 | High-performance polyvinyl chloride composite material for wires and cables and preparation method thereof |
CN104194188A (en) * | 2014-07-28 | 2014-12-10 | 安徽威萨重工机械有限公司 | Polyvinyl chloride cable material |
CN104558966A (en) * | 2015-01-15 | 2015-04-29 | 无为县华祥电缆材料有限公司 | Chlorinated-esterified polybutadiene rubber modified polyvinyl chloride cable material |
CN105255063A (en) * | 2015-11-17 | 2016-01-20 | 王芳 | Preparing method for flame-retardant PVC power cable |
CN106916390A (en) * | 2017-03-22 | 2017-07-04 | 安徽星鑫化工科技有限公司 | A kind of preparation method of the sol-gel modified flame retardance of polymer CABLE MATERIALS of ion |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1294148A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Non-toxic polyvinyl chloride composition and its preparing process |
CN101319078A (en) * | 2008-07-03 | 2008-12-10 | 聊城大学 | Manufacture of silicone hydride crosslinked non-halogen flame-proof polyvinyl chloride granula for cable by employing novel catalyst |
CN101613504A (en) * | 2009-07-24 | 2009-12-30 | 青岛中阳消防科技有限公司 | A kind of material and preparation method with temperature sensing cable material of CRT characteristic |
-
2011
- 2011-09-19 CN CN 201110277402 patent/CN102382391B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1294148A (en) * | 1999-11-02 | 2001-05-09 | 海尔科化工程塑料国家工程研究中心有限公司 | Non-toxic polyvinyl chloride composition and its preparing process |
CN101319078A (en) * | 2008-07-03 | 2008-12-10 | 聊城大学 | Manufacture of silicone hydride crosslinked non-halogen flame-proof polyvinyl chloride granula for cable by employing novel catalyst |
CN101613504A (en) * | 2009-07-24 | 2009-12-30 | 青岛中阳消防科技有限公司 | A kind of material and preparation method with temperature sensing cable material of CRT characteristic |
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