CN102382391B - Polyvinyl chloride cable material - Google Patents

Polyvinyl chloride cable material Download PDF

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Publication number
CN102382391B
CN102382391B CN 201110277402 CN201110277402A CN102382391B CN 102382391 B CN102382391 B CN 102382391B CN 201110277402 CN201110277402 CN 201110277402 CN 201110277402 A CN201110277402 A CN 201110277402A CN 102382391 B CN102382391 B CN 102382391B
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China
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parts
polyvinyl chloride
cable material
chloride cable
mixed
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Expired - Fee Related
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CN102382391A (en
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潘成玉
王汉生
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Abstract

The invention relates to a polyvinyl chloride cable material having excellent performances. The polyvinyl chloride cable material having excellent performances comprises: by weight, 100 parts of polyvinyl chloride resin, 25 parts of one or more inorganic filling materials, 4 parts of triphenyl phosphate, 10 parts of epoxy butyl oleate, 24 parts of aluminum hydroxide, 0.6 parts of an anti-oxidant 1010, 1.8 parts of an anti-oxidant 1024, 2 parts of magnesium oxide, 3 parts of zinc oxide, 2 parts of eleaostearic acid and 0.6 parts of an aluminate coupling agent. The polyvinyl chloride cable material having excellent performances has excellent weatherability, cold resistance, aging resistance, oxidation resistance and copper corrosion resistance.

Description

Polyvinyl chloride cable material
Technical field
The present invention relates to a kind of CABLE MATERIALS, especially have the polyvinyl chloride cable material of excellent properties.
Background technology
In the cable production process, the copper conductor oxidation stain is hard nut to crack, and conventional solution is to intercept contacting of copper and air with physical method, generates passive film obstruct copper conductor oxidation etc. with chemical process.The thermoplastics isolator is under normal circumstances on not impact of copper wire oxidation.But used raw and auxiliary material inferior in existing many CABLE MATERIALS, although the conventional sense qualified, life-time service will cause damage to copper wire.PVC softening agent commonly used, all exist the free acid ion to separate out such as dioctyl phthalate (DOP), dioctyl sebacate, two 11 esters of phthalic acid, trioctyl trimellitate, clorafin etc., corrode copper wire and the oxidation blackout, have a strong impact on the problem of cable performance.And how suppressing the generation of this phenomenon, production is very important for cable.
Summary of the invention
For addressing the above problem, the inventor is by test, creatively find the CABLE MATERIALS that various raw materials and auxiliary agent by following cooperation form, excellence aspect the weathering resistance of routine, winter hardiness, ageing-resistant performance not only, but also have excellent antioxidant copper resistant performance.
Therefore, the invention provides a kind of polyvinyl chloride cable material, it is comprised of following each component, and their parts by weight are as follows:
Figure BSA00000576083700011
Preferably, in above-mentioned CABLE MATERIALS, described mineral filler comprises one or more in calcium carbonate, silicon-dioxide, carbon black, titanium dioxide, talcum powder, kaolin, wollastonite, polynite and the mica powder.
Each raw material that the present invention is used and auxiliary agent all are commercially available, wherein polyvinyl chloride (PVC) RESINS is that company produces, triphenylphosphate is that company produces, the epoxyoleic acid butyl ester is that company produces, antioxidant 1010,1024 is for company produces, and magnesium oxide, zinc oxide, stearic acid, aluminate coupling agent be that company produces.
The application adopts triphenylphosphate and the composite use of epoxyoleic acid butyl ester, can so that gained CABLE MATERIALS flame retardant resistance, winter hardiness all be improved; Antioxidant 1010 and 1024 use that proportions has namely improved antioxygen, has increased again anti-copper corrosion performance; Magnesium oxide, zinc oxide and stearic being used in conjunction with can obtain the higher material of thermostability; Being used in conjunction with of aluminium hydroxide and antioxidant 1010 and aluminate coupling agent makes good flame retardation effect, plays the effect of cooperative flame retardant.The raising of these performances all is vital for CABLE MATERIALS.
Embodiment
Below in conjunction with the embodiment of the invention technical scheme of the present invention is clearly and completely described.
Embodiment 1:
CABLE MATERIALS prescription following (weight part):
Figure BSA00000576083700021
By above-mentioned prescription raw material and auxiliary agent are added in the homogenizer, under low speed 220rpm, mixed 2 minutes first, then mixed 3 minutes under the high speed 1300rpm, obtain mixed powder, obtain cable granules through single screw extrusion machine at 140-180 ℃ of lower extruding pelletization.

Claims (2)

1. polyvinyl chloride cable material, it is comprised of following each component, and their parts by weight are as follows:
Figure FSB00000993441400011
By above-mentioned prescription raw material and auxiliary agent are added in the homogenizer; under low speed 220rpm, mixed 2 minutes first; then mixed 3 minutes under the high speed 1300rpm, obtain mixed powder, obtain described polyvinyl chloride cable material through single screw extrusion machine at 140-180 ℃ of lower extruding pelletization.
2. polyvinyl chloride cable material according to claim 1 is characterized in that, described mineral filler comprises one or more in calcium carbonate, silicon-dioxide, carbon black, titanium dioxide, talcum powder, kaolin, wollastonite, polynite and the mica powder.
CN 201110277402 2011-09-19 2011-09-19 Polyvinyl chloride cable material Expired - Fee Related CN102382391B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201110277402 CN102382391B (en) 2011-09-19 2011-09-19 Polyvinyl chloride cable material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201110277402 CN102382391B (en) 2011-09-19 2011-09-19 Polyvinyl chloride cable material

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CN102382391A CN102382391A (en) 2012-03-21
CN102382391B true CN102382391B (en) 2013-04-10

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Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103571075A (en) * 2012-07-19 2014-02-12 远东电缆有限公司 PVC sheath rubber
CN102964723B (en) * 2012-11-29 2014-06-18 江苏亨通线缆科技有限公司 Polyvinyl chloride (PVC) cable material for automobile data transmission wire
CN104045938B (en) * 2012-11-29 2017-01-11 江苏亨通线缆科技有限公司 Heat-resistance PVC (polyvinyl chloride) cable material
CN104045941B (en) * 2012-11-29 2016-07-06 江苏亨通线缆科技有限公司 Data transmission automotive line CABLE MATERIALS
CN104045939A (en) * 2012-11-29 2014-09-17 江苏亨通线缆科技有限公司 Modified polyvinyl chloride (PVC) cable material for data cables
CN103304916B (en) * 2013-05-14 2016-06-29 安徽旺达铜业发展有限公司 A kind of polyvinyl chloride cable material containing modified magnesium hydroxide
CN103304941A (en) * 2013-05-14 2013-09-18 安徽旺达铜业发展有限公司 Triphenyl phosphate modified cable sheathing compound
CN103333429B (en) * 2013-06-05 2016-05-04 安徽荣玖光纤通信科技有限公司 A kind of ageing-resistant polyvinyl chloride cable material
CN103509282B (en) * 2013-09-06 2016-03-02 安徽华通电缆集团有限公司 A kind of polyvinyl chloride cable material with excellent properties
CN103509293B (en) * 2013-10-12 2016-04-13 绿宝电缆(集团)有限公司 A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable
CN103509294B (en) * 2013-10-12 2016-03-02 绿宝电缆(集团)有限公司 A kind of cold-resistant fire-retardant PVC CABLE MATERIALS
CN104558906A (en) * 2013-10-22 2015-04-29 宁夏金黄河塑业有限责任公司 Rare earth wire shielded PVC cable sheath
CN103709551A (en) * 2013-12-06 2014-04-09 上海特种电线电缆(集团)有限公司 High-temperature resistant fireproof nano insulating material
CN103724871A (en) * 2013-12-10 2014-04-16 芜湖佳诚电子科技有限公司 Environmentally friendly inflaming retarding type PVC cable material and preparation method thereof
CN103724872A (en) * 2013-12-10 2014-04-16 芜湖佳诚电子科技有限公司 Environmentally-friendly PVC cable material and preparation method thereof
CN103849090A (en) * 2014-03-10 2014-06-11 深圳市领亚电子有限公司 High-performance polyvinyl chloride composite material for wires and cables and preparation method thereof
CN104194188A (en) * 2014-07-28 2014-12-10 安徽威萨重工机械有限公司 Polyvinyl chloride cable material
CN104558966A (en) * 2015-01-15 2015-04-29 无为县华祥电缆材料有限公司 Chlorinated-esterified polybutadiene rubber modified polyvinyl chloride cable material
CN105255063A (en) * 2015-11-17 2016-01-20 王芳 Preparing method for flame-retardant PVC power cable
CN106916390A (en) * 2017-03-22 2017-07-04 安徽星鑫化工科技有限公司 A kind of preparation method of the sol-gel modified flame retardance of polymer CABLE MATERIALS of ion

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1294148A (en) * 1999-11-02 2001-05-09 海尔科化工程塑料国家工程研究中心有限公司 Non-toxic polyvinyl chloride composition and its preparing process
CN101319078A (en) * 2008-07-03 2008-12-10 聊城大学 Manufacture of silicone hydride crosslinked non-halogen flame-proof polyvinyl chloride granula for cable by employing novel catalyst
CN101613504A (en) * 2009-07-24 2009-12-30 青岛中阳消防科技有限公司 A kind of material and preparation method with temperature sensing cable material of CRT characteristic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294148A (en) * 1999-11-02 2001-05-09 海尔科化工程塑料国家工程研究中心有限公司 Non-toxic polyvinyl chloride composition and its preparing process
CN101319078A (en) * 2008-07-03 2008-12-10 聊城大学 Manufacture of silicone hydride crosslinked non-halogen flame-proof polyvinyl chloride granula for cable by employing novel catalyst
CN101613504A (en) * 2009-07-24 2009-12-30 青岛中阳消防科技有限公司 A kind of material and preparation method with temperature sensing cable material of CRT characteristic

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