CN105860476A - Anti-static LED lamp light guide plate formulation - Google Patents

Anti-static LED lamp light guide plate formulation Download PDF

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Publication number
CN105860476A
CN105860476A CN201610238567.1A CN201610238567A CN105860476A CN 105860476 A CN105860476 A CN 105860476A CN 201610238567 A CN201610238567 A CN 201610238567A CN 105860476 A CN105860476 A CN 105860476A
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CN
China
Prior art keywords
light guide
guide plate
parts
anlistatig
led light
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610238567.1A
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Chinese (zh)
Inventor
王玲
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Kunshan Chuben Electronic Technology Co Ltd
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Kunshan Chuben Electronic Technology Co Ltd
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Priority to CN201610238567.1A priority Critical patent/CN105860476A/en
Publication of CN105860476A publication Critical patent/CN105860476A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/22Halogen free composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses an anti-static LED lamp light guide plate formulation. The anti-static LED lamp light guide plate is characterized by being prepared from, by weight, 100 parts of PC, 1-8 parts of flexibilizer, 15-20 parts of low smoke zero halogen flame retardant, 2-5 parts of lubricant, 0.3-1 part of antioyxgen, 2-5 parts of heat conducting powder, 3-6 parts of titanium dioxide, 0.4-0.8 part of anti-drip agent, 3-6 parts of weather-proof agent, 0.1-0.5 part of organosilicone powder, 0.1-0.5 part of silver powder and 0.5-2.5 parts of antistatic agent. The anti-static LED lamp light guide plate has the effects of being resistant to static and flames, not prone to dust accumulation, high in safety, low in smoke, free of halogen, not prone to aging, long in service life, resistant to radiation and the like.

Description

A kind of anlistatig LED Lamp light guide plate formula
Technical field
The present invention relates to a kind of anlistatig LED light guide plate formula, belong to technical field of polymer materials.
Background technology
Merlon (being called for short PC) is described as transparent metal.Firm and flexible, has the use temperature that high impact properties, the dimensional stability of height and scope are the widest, mainly for the production of industrial product, is used for replacing metal and other alloy, makees the parts of impact resistance and high intensity in mechanical industry.
But, existing PC material, when LED light guide plate, exists the most aging, and service life is short, poor safety performance, inflammable, is easily generated the problems such as harmful gas, and radiation human body during burning.
Any object is all with the electrostatic charge of itself, this electric charge can be negative charge can also be positive charge, the gathering of electrostatic charge makes life or commercial production be affected and even endanger, and the deleterious charge of gathering guides/eliminates the chemicals making it not bring inconvenience production/life or to endanger and is referred to as antistatic additive.
Human body, for a long time under static radiation, can make people's lather, headache, uncomfortable in chest, dyspnea, cough.In the middle of family life, electrostatic not only chemical fibre clothes has, and the carpet of underfooting, daily plastic items, varnishes furniture and is all likely to occur electrostatic phenomenon to various household electrical appliances.Substantial amounts of dust in the adsorbable air of electrostatic and charging property is the biggest, absorption dust quantity the most, and dust often contains multiple noxious substance and pathogenic bacteria, light then stimulate skin, cutaneous gloss and delicacy, heavy then make skin play the raw skin ulcer of abnormal pigmentary deposit on the skin, more serious also can cause the disease such as bronchial asthma and arrhythmia.
Current LED light guide plate is general causes the existing easy laying dust of LED light guide plate without anti-static function, and portable noxious substance and pathogenic bacteria, sanitary standard is the most up to standard, affects health.
Summary of the invention
Present invention solves the technical problem that and be to provide a kind of LED light guide plate formula having antistatic radiation function;Further, the present invention provides a kind of safety high, fire-retardant, the anlistatig LED light guide plate formula of low smoke and zero halogen;Further, it is aging that the present invention provides one to be difficult to, service life length anlistatig LED light guide plate formula;Further, the present invention provides a kind of anlistatig LED light guide plate formula having radiation proof function.
For solving above-mentioned technical problem, the technical solution used in the present invention is:
A kind of anlistatig LED light guide plate formula, it is characterised in that: comprise each component of following weight portion: PC:100 part;Toughener: 1 ~ 8 part;Low-smoke non-halogen flame-retardant agent: 15 ~ 20 parts;Lubricant: 2 ~ 5 parts;Antioxidant: 0.3 ~ 1 part;Conductive powder 2 ~ 5 parts;Titanium dioxide 3 ~ 6 parts;Anti-dripping agent: 0.4 ~ 0.8 part;Weather resisting agent: 3 ~ 6 parts;Organosilicon powder: 0.1 ~ 0.5 part;Argentum powder: 0.1 ~ 0.5 part;Antistatic additive: 0.5 ~ 2.5 part.
Described antistatic additive includes non-ionic surfactant antistatic additive;Described non-ionic surfactant antistatic additive includes ethoxylated alkylamine or ethoxylated alkyl acid amide.
Described weather resisting agent includes UV absorbent, absorbing material and heat stabilizer.
The weight ratio of described UV absorbent, absorbing material and heat stabilizer is 1:(0.1 ~ 1): (3 ~ 5).
Described absorbing material includes polycrystalline iron fiber absorbing material;Described UV absorbent includes salicylate compounds;Described heat stabilizer includes hindered phenol compound.
Described toughener includes PET toughener and maleic anhydride grafting EVA;The weight ratio of described PET toughener and maleic anhydride grafting EVA is 1:(8 ~ 10).
Described low-smoke non-halogen flame-retardant agent includes one or both in flame retardant of magnesium hydroxide and aluminium hydroxide fire retardant.
Described anti-dripping agent includes cladded type polytetrafluoroethyl-ne vinyl compound, and the particle diameter of described anti-dripping agent is 400 ~ 500 μm.
Described titanium dioxide is Rutile type titanium dioxide or anatase thpe white powder.
Described conductive powder includes one or both in micrometer alumina and silicon powder.
Described antioxidant includes that primary antioxidant and auxiliary antioxidant, described primary antioxidant include that aromatic amine antioxidant, described auxiliary antioxidant include organic compounds containing sulfur;Described aromatic amine antioxidant includes diphenylamines, p-phenylenediamine or dihydroquinoline;Described organic compounds containing sulfur includes thio-2 acid dibasic acid esters;The weight of described primary antioxidant and auxiliary antioxidant is 1:1.
The one anlistatig LED light guide plate formula that the present invention provides, the setting of antistatic additive, make the present invention can give the certain lubricity of LED light guide plate surface, reduce coefficient of friction, suppress and reduce electrostatic charge generation, there is antistatic, be difficult to the functions such as laying dust;The setting of low-smoke non-halogen flame-retardant agent, makes the present invention fire-retardant, even if burning is also low smoke and zero halogen, will not produce toxic and harmful, and safety is high;Weather resisting agent and the setting of antioxidant, the dual present invention of guarantee is difficult to aging, is greatly prolonged the service life of the present invention;The setting of UV absorbent, absorbing material and argentum powder, makes the present invention possess ultra-violet radiation resisting and electromagnetic radiation resisting function;It addition, the setting of various granules, such as the setting of titanium dioxide, anti-dripping agent, absorbing material, organosilicon powder and argentum powder, make the present invention that light to dissipate performance good, i.e. utilize LED free from glare prepared by the present invention.
Detailed description of the invention
In conjunction with specific examples below, the present invention is described in further detail, and following instance is merely illustrative, and the protection content of the present invention is not limited to this.
Embodiment 1 :
A kind of anlistatig LED light guide plate formula, it is characterised in that: comprise each component of following weight portion: PC:100 part;Toughener: 1 part;Low-smoke non-halogen flame-retardant agent: 15 parts;Lubricant: 2 parts;Antioxidant: 0.3 part;Conductive powder 2 parts;Titanium dioxide 3 parts;Anti-dripping agent: 0.4 part;Weather resisting agent: 3 parts;Organosilicon powder: 0.1 part;Argentum powder: 0.1 part;Antistatic additive: 0.5 part.
Described antistatic additive includes non-ionic surfactant antistatic additive;Described non-ionic surfactant antistatic additive is ethoxylated alkylamine.
Described weather resisting agent is UV absorbent, absorbing material and heat stabilizer.
The weight ratio of described UV absorbent, absorbing material and heat stabilizer is 1:0.1:3.
Described absorbing material is polycrystalline iron fiber absorbing material;Described UV absorbent includes salicylate compounds;Described heat stabilizer includes hindered phenol compound.
Described toughener includes PET toughener and maleic anhydride grafting EVA;The weight ratio of described PET toughener and maleic anhydride grafting EVA is 1:8.
Described low-smoke non-halogen flame-retardant agent is flame retardant of magnesium hydroxide.
Described anti-dripping agent includes cladded type polytetrafluoroethyl-ne vinyl compound, and the particle diameter of described anti-dripping agent is 400 μm.
Described titanium dioxide is Rutile type titanium dioxide.
Described conductive powder is micrometer alumina.
Described antioxidant includes that primary antioxidant and auxiliary antioxidant, described primary antioxidant include that aromatic amine antioxidant, described auxiliary antioxidant include organic compounds containing sulfur;Described aromatic amine antioxidant includes diphenylamines, p-phenylenediamine or dihydroquinoline;Described organic compounds containing sulfur includes thio-2 acid dibasic acid esters;The weight of described primary antioxidant and auxiliary antioxidant is 1:1.
Embodiment 2 :
A kind of anlistatig LED light guide plate formula, it is characterised in that: comprise each component of following weight portion: PC:100 part;Toughener: 8 parts;Low-smoke non-halogen flame-retardant agent: 20 parts;Lubricant: 5 parts;Antioxidant: 1 part;Conductive powder 5 parts;Titanium dioxide 6 parts;Anti-dripping agent: 0.8 part;Weather resisting agent: 6 parts;Organosilicon powder: 0.5 part;Argentum powder: 0.5 part;Antistatic additive: 2.5 parts.
Described antistatic additive includes non-ionic surfactant antistatic additive;Described non-ionic surfactant antistatic additive is ethoxylated alkyl acid amide.
Described weather resisting agent is UV absorbent, absorbing material and heat stabilizer.
The weight ratio of described UV absorbent, absorbing material and heat stabilizer is 1:1:5.
Described absorbing material is polycrystalline iron fiber absorbing material;Described UV absorbent includes salicylate compounds;Described heat stabilizer includes hindered phenol compound.
Described toughener includes PET toughener and maleic anhydride grafting EVA;The weight ratio of described PET toughener and maleic anhydride grafting EVA is 1:10.
Described low-smoke non-halogen flame-retardant agent is aluminium hydroxide fire retardant.
Described anti-dripping agent includes cladded type polytetrafluoroethyl-ne vinyl compound, and the particle diameter of described anti-dripping agent is 500 μm.
Described titanium dioxide is anatase thpe white powder.
Described conductive powder is silicon powder.
Described antioxidant includes that primary antioxidant and auxiliary antioxidant, described primary antioxidant include that aromatic amine antioxidant, described auxiliary antioxidant include organic compounds containing sulfur;Described aromatic amine antioxidant includes diphenylamines, p-phenylenediamine or dihydroquinoline;Described organic compounds containing sulfur includes thio-2 acid dibasic acid esters;The weight of described primary antioxidant and auxiliary antioxidant is 1:1.
Embodiment 3 :
A kind of anlistatig LED light guide plate formula, it is characterised in that: comprise each component of following weight portion: PC:100 part;Toughener: 4 parts;Low-smoke non-halogen flame-retardant agent: 17 parts;Lubricant: 3 parts;Antioxidant: 0.5 part;Conductive powder 3 parts;Titanium dioxide 4 parts;Anti-dripping agent: 0.5 part;Weather resisting agent: 5 parts;Organosilicon powder: 0.3 part;Argentum powder: 0.2 part;Antistatic additive: 1 part.
Described antistatic additive includes non-ionic surfactant antistatic additive;Described non-ionic surfactant antistatic additive includes ethoxylated alkylamine or ethoxylated alkyl acid amide.
Described weather resisting agent is UV absorbent, absorbing material and heat stabilizer.
The weight ratio of described UV absorbent, absorbing material and heat stabilizer is 1:0.5:4.
Described absorbing material is polycrystalline iron fiber absorbing material;Described UV absorbent includes salicylate compounds;Described heat stabilizer includes hindered phenol compound.
Described toughener includes PET toughener and maleic anhydride grafting EVA;The weight ratio of described PET toughener and maleic anhydride grafting EVA is 1:9.
Described low-smoke non-halogen flame-retardant agent be the weight ratio of flame retardant of magnesium hydroxide and aluminium hydroxide fire retardant, flame retardant of magnesium hydroxide and aluminium hydroxide fire retardant be 1:1.
Described anti-dripping agent includes cladded type polytetrafluoroethyl-ne vinyl compound, and the particle diameter of described anti-dripping agent is 450 μm.
Described titanium dioxide is Rutile type titanium dioxide.
Described conductive powder is micrometer alumina and silicon powder, and the weight ratio of described micrometer alumina and silicon powder is 2:1.
Described antioxidant includes that primary antioxidant and auxiliary antioxidant, described primary antioxidant include that aromatic amine antioxidant, described auxiliary antioxidant include organic compounds containing sulfur;Described aromatic amine antioxidant includes diphenylamines, p-phenylenediamine or dihydroquinoline;Described organic compounds containing sulfur includes thio-2 acid dibasic acid esters;The weight of described primary antioxidant and auxiliary antioxidant is 1:1.
The above is only the preferred embodiment of the present invention; it is noted that, for those skilled in the art; under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (10)

1. an anlistatig LED light guide plate formula, it is characterised in that: comprise each component of following weight portion: PC:100 part;Toughener: 1 ~ 8 part;Low-smoke non-halogen flame-retardant agent: 15 ~ 20 parts;Lubricant: 2 ~ 5 parts;Antioxidant: 0.3 ~ 1 part;Conductive powder 2 ~ 5 parts;Titanium dioxide 3 ~ 6 parts;Anti-dripping agent: 0.4 ~ 0.8 part;Weather resisting agent: 3 ~ 6 parts;Organosilicon powder: 0.1 ~ 0.5 part;Argentum powder: 0.1 ~ 0.5 part;Antistatic additive: 0.5 ~ 2.5 part.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described antistatic additive includes non-ionic surfactant antistatic additive;Described non-ionic surfactant antistatic additive includes ethoxylated alkylamine or ethoxylated alkyl acid amide.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described weather resisting agent includes UV absorbent, absorbing material and heat stabilizer.
One the most according to claim 3 anlistatig LED light guide plate formula, it is characterised in that: the weight ratio of described UV absorbent, absorbing material and heat stabilizer is 1:(0.1 ~ 1): (3 ~ 5);Described absorbing material includes polycrystalline iron fiber absorbing material;Described UV absorbent includes salicylate compounds;Described heat stabilizer includes hindered phenol compound.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described toughener includes PET toughener and maleic anhydride grafting EVA;The weight ratio of described PET toughener and maleic anhydride grafting EVA is 1:(8 ~ 10).
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described low-smoke non-halogen flame-retardant agent includes one or both in flame retardant of magnesium hydroxide and aluminium hydroxide fire retardant.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described anti-dripping agent includes cladded type polytetrafluoroethyl-ne vinyl compound, and the particle diameter of described anti-dripping agent is 400 ~ 500 μm.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described titanium dioxide is Rutile type titanium dioxide or anatase thpe white powder.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterised in that: described conductive powder includes one or both in micrometer alumina and silicon powder.
One the most according to claim 1 anlistatig LED light guide plate formula, it is characterized in that: described antioxidant includes primary antioxidant and auxiliary antioxidant, described primary antioxidant includes that aromatic amine antioxidant, described auxiliary antioxidant include organic compounds containing sulfur;Described aromatic amine antioxidant includes diphenylamines, p-phenylenediamine or dihydroquinoline;Described organic compounds containing sulfur includes thio-2 acid dibasic acid esters;The weight of described primary antioxidant and auxiliary antioxidant is 1:1.
CN201610238567.1A 2016-04-18 2016-04-18 Anti-static LED lamp light guide plate formulation Pending CN105860476A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112457643A (en) * 2020-10-15 2021-03-09 苏州彤帆智能科技有限公司 PC super-tough material formula
CN114316553A (en) * 2021-11-29 2022-04-12 中广核俊尔(浙江)新材料有限公司 Halogen-free flame-retardant antistatic PC material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532844A (en) * 2011-12-09 2012-07-04 上海锦湖日丽塑料有限公司 Light transmission color selecting type photodiffusion polycarbonate composition and preparation method thereof
CN104262929A (en) * 2014-09-19 2015-01-07 银禧工程塑料(东莞)有限公司 Flame-retardant PC (Poly Carbonate)/ABC composite material capable of shielding high-frequency electromagnetic wave and preparation method thereof
CN104497533A (en) * 2014-12-17 2015-04-08 安徽科聚新材料有限公司 Halogen-free flame-retardant high-gloss reflective heat-conducting polycarbonate material and preparation method thereof
CN104927327A (en) * 2015-03-30 2015-09-23 成都康鸿塑胶制品有限公司 LED translucent panel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532844A (en) * 2011-12-09 2012-07-04 上海锦湖日丽塑料有限公司 Light transmission color selecting type photodiffusion polycarbonate composition and preparation method thereof
CN104262929A (en) * 2014-09-19 2015-01-07 银禧工程塑料(东莞)有限公司 Flame-retardant PC (Poly Carbonate)/ABC composite material capable of shielding high-frequency electromagnetic wave and preparation method thereof
CN104497533A (en) * 2014-12-17 2015-04-08 安徽科聚新材料有限公司 Halogen-free flame-retardant high-gloss reflective heat-conducting polycarbonate material and preparation method thereof
CN104927327A (en) * 2015-03-30 2015-09-23 成都康鸿塑胶制品有限公司 LED translucent panel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112457643A (en) * 2020-10-15 2021-03-09 苏州彤帆智能科技有限公司 PC super-tough material formula
CN114316553A (en) * 2021-11-29 2022-04-12 中广核俊尔(浙江)新材料有限公司 Halogen-free flame-retardant antistatic PC material and preparation method thereof

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