CN103254550A - Modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy - Google Patents

Modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy Download PDF

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Publication number
CN103254550A
CN103254550A CN 201310129754 CN201310129754A CN103254550A CN 103254550 A CN103254550 A CN 103254550A CN 201310129754 CN201310129754 CN 201310129754 CN 201310129754 A CN201310129754 A CN 201310129754A CN 103254550 A CN103254550 A CN 103254550A
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China
Prior art keywords
parts
flame
retardant
environment
modified abs
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CN 201310129754
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Chinese (zh)
Inventor
李耀东
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QINGDAO YZZ PLASTICS CO Ltd
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QINGDAO YZZ PLASTICS CO Ltd
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Priority to CN 201310129754 priority Critical patent/CN103254550A/en
Publication of CN103254550A publication Critical patent/CN103254550A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy which comprises the following components in parts by weight: 1-2 parts of PE (Polyethylene) ester, 2-8 parts of zinc borate, 1-9 parts of diacetone salt, 10-30 parts of PBT (polybutylene terephthalate), 30-40 parts of ABS, 10-15 parts of modifier, 10-19 parts of pigments, 10-25 parts of diluent, 10-25 parts of toughening agent, 10-35 parts of active calcium, 20-35 parts of stearic acid, 21-23 parts of lithopone, 1-3 parts of carbon black, 1-9 parts of nano calcium carbonate, 1-9 parts of stearic acid, 1-8 parts of talcum powder, 2-9 parts of ethylene-propylene-diene rubber and 3-6 parts of anti-impact agent. According to the modified ABS flame-retardant environment-friendly alloy, as a synergistic effect between montmorillonite and a halogen-free flame retardant is utilized, not only is a traditional flame-retardant system eliminated, but also excellent flame-retardant property and mechanical property are achieved; the modified ABS flame-retardant environment-friendly alloy has no damage to environment and personal health, thereby belonging to an environment-friendly product; and in addition, the use amount of the flame retardant is reduced due to use of montmorillonite, so that the mechanical property and the heat resistant property of the flame-retardant material are greatly improved, and more importantly, the production cost is greatly reduced.

Description

A kind of modified ABS flame-proof environmental protection alloy
Technical field
The present invention relates to a kind of modified ABS flame-proof environmental protection alloy.
Background technology
The used fire retardant nearly 95% of present flame-retardant PBT/ABS is halogen containing flame-retardant, performance impact to material is little, and moderate, its usefulness/price can be equal to than non-other fire retardants, so 70% ~ 80% all uses this based flame retardant in China's electric series products for export.But halogen flame is subjected to the puzzlement of dioxin problem in recent years, the time can generate a large amount of flue dust and corrosive gases with its fire-retardant macromolecular material in thermo-cracking and burning simultaneously, at present European Union and Japan oneself put into effect in succession that it is forbidden by decree to uses this based flame retardant.European Union rises on July 1st, 2006 and implements in full the ROHS instruction, and the electronic and electrical equipment that this decree requires to throw in European Union must not contain poly-Australia hexichol vinegar, poly-Australia biphenyl, and this decree has seriously restricted the outlet of China's electronic and electrical equipment.
Summary of the invention
Technical problem to be solved by this invention provides a kind of modified ABS flame-proof environmental protection alloy.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of modified ABS flame-proof environmental protection alloy is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, properties-correcting agent 10-15 part, pigment 10-19 part, thinner 10-25 part, toughner 10-25 part, Calcium of intensifiens 10-35 part, stearic acid 20-35 part, zinc sulfide white 21-23 part, carbon black 1-3 part, nano-calcium carbonate 1-9 part, stearic acid 1-9 part, talcum powder 1-8 part, terpolymer EP rubber 2-9 part, anti-impact agent 3-6 part.
The invention has the beneficial effects as follows: utilize the synergistic effect of Meng Tuoshi and halogen-free flame retardants, not only abandoned traditional flame-retardant system, have excellent flame-retardant and mechanical property, do not endanger environment and health of human body, belong to environmentfriendly products; And using polynite to reduce the usage quantity of fire retardant, this has improved mechanical property and the resistance toheat of fire retardant material to a great extent, the more important thing is greatly to reduce production costs.
Embodiment
Embodiment 1
A kind of modified ABS flame-proof environmental protection alloy is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, properties-correcting agent 10-15 part, pigment 10-19 part, thinner 10-25 part, toughner 10-25 part, Calcium of intensifiens 10-35 part, stearic acid 20-35 part, zinc sulfide white 21-23 part, carbon black 1-3 part, nano-calcium carbonate 1-9 part, stearic acid 1-9 part, talcum powder 1-8 part, terpolymer EP rubber 2-9 part, anti-impact agent 3-6 part.

Claims (1)

1. a modified ABS flame-proof environmental protection alloy is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, properties-correcting agent 10-15 part, pigment 10-19 part, thinner 10-25 part, toughner 10-25 part, Calcium of intensifiens 10-35 part, stearic acid 20-35 part, zinc sulfide white 21-23 part, carbon black 1-3 part, nano-calcium carbonate 1-9 part, stearic acid 1-9 part, talcum powder 1-8 part, terpolymer EP rubber 2-9 part, anti-impact agent 3-6 part.
CN 201310129754 2013-04-16 2013-04-16 Modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy Pending CN103254550A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201310129754 CN103254550A (en) 2013-04-16 2013-04-16 Modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201310129754 CN103254550A (en) 2013-04-16 2013-04-16 Modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy

Publications (1)

Publication Number Publication Date
CN103254550A true CN103254550A (en) 2013-08-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201310129754 Pending CN103254550A (en) 2013-04-16 2013-04-16 Modified ABS (Acrylonitrile Butadiene Styrene) flame-retardant environment-friendly alloy

Country Status (1)

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CN (1) CN103254550A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602036A (en) * 2013-11-12 2014-02-26 青岛广联达精密机械有限公司 Modified wear-resistant high polymer material
CN103602033A (en) * 2013-11-12 2014-02-26 青岛广联达精密机械有限公司 Alloy material with high comprehensive performance
CN103627132A (en) * 2013-11-12 2014-03-12 青岛广联达精密机械有限公司 Modified flame retardant environment-friendly alloy material
CN106810822A (en) * 2017-01-11 2017-06-09 合肥英索莱特新材料科技有限公司 Environment-friendly epoxy electronic encapsulating material based on bromide fire retardant

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103602036A (en) * 2013-11-12 2014-02-26 青岛广联达精密机械有限公司 Modified wear-resistant high polymer material
CN103602033A (en) * 2013-11-12 2014-02-26 青岛广联达精密机械有限公司 Alloy material with high comprehensive performance
CN103627132A (en) * 2013-11-12 2014-03-12 青岛广联达精密机械有限公司 Modified flame retardant environment-friendly alloy material
CN106810822A (en) * 2017-01-11 2017-06-09 合肥英索莱特新材料科技有限公司 Environment-friendly epoxy electronic encapsulating material based on bromide fire retardant

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Application publication date: 20130821