CN103232674A - ABS flame retardant alloy - Google Patents
ABS flame retardant alloy Download PDFInfo
- Publication number
- CN103232674A CN103232674A CN 201310107751 CN201310107751A CN103232674A CN 103232674 A CN103232674 A CN 103232674A CN 201310107751 CN201310107751 CN 201310107751 CN 201310107751 A CN201310107751 A CN 201310107751A CN 103232674 A CN103232674 A CN 103232674A
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- flame retardant
- abs
- montmorillonite
- halogen
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Abstract
The invention discloses an ABS flame retardant alloy, which comprises the following materials by weight: 1-2 parts of PE ester, 2-8 parts of zinc borate, 1-9 parts of an acetylacetonate salt, 10-30 parts of PBT, 30-40 parts of ABS, 20-30 parts of styrene, 10-18 parts of montmorillonite, 1-9 parts of an antioxidant, 1-7 parts of a flame retardant APP (ammonium polyphosphate), 1-8 parts of a flame retardant PER (pentaerythritol), 3-9 parts of trichloroethyl phosphate, and 2-9 parts of a halogen-free intumescent flame retardant. By utilizing the synergistic effect of the montmorillonite and the halogen-free flame retardant, the ABS flame retardant alloy disclosed in the invention abandons the traditional flame retardant system, has excellent flame retardant performance and mechanical properties, is harmless to the environment and human health, thus belonging to an environmental protection product. Moreover, the use of montmorillonite reduces the flame retardant dosage, so that the mechanical properties and heat resistance of flame retardant materials are improved to a large extent. More importantly, the production cost is greatly reduced.
Description
Technical field
The present invention relates to a kind of ABS flame-retardant alloy.
Background technology
The used fire retardant nearly 95% of present flame-retardant PBT/ABS is halogen containing flame-retardant, performance impact to material is little, and moderate, its usefulness/price can be equal to than non-other fire retardants, so 70% ~ 80% all uses this based flame retardant in China's electric series products for export.But halogen flame is subjected to the puzzlement of dioxin problem in recent years, the time can generate a large amount of flue dust and corrosive gases with its fire-retardant macromolecular material in thermo-cracking and burning simultaneously, at present European Union and Japan oneself put into effect in succession that it is forbidden by decree to uses this based flame retardant.European Union rises on July 1st, 2006 and implements in full the ROHS instruction, and the electronic and electrical equipment that this decree requires to throw in European Union must not contain poly-Australia hexichol vinegar, poly-Australia biphenyl, and this decree has seriously restricted the outlet of China's electronic and electrical equipment.
Summary of the invention
Technical problem to be solved by this invention provides a kind of ABS flame-retardant alloy.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of ABS flame-retardant alloy comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, vinylbenzene 20-30 part, polynite 10-18 part, oxidation inhibitor 1-9 part, fire retardant APP(ammonium polyphosphate) 1-7 part, fire retardant PER(tetramethylolmethane) 1-8 part, Trichloroethyl Phosphate 3-9 part, halogen-free expansion fire retardant 2-9 part.
The invention has the beneficial effects as follows: utilize the synergistic effect of Meng Tuoshi and halogen-free flame retardants, not only abandoned traditional flame-retardant system, have excellent flame-retardant and mechanical property, do not endanger environment and health of human body, belong to environmentfriendly products; And using polynite to reduce the usage quantity of fire retardant, this has improved mechanical property and the resistance toheat of fire retardant material to a great extent, the more important thing is greatly to reduce production costs.
Embodiment
Embodiment 1
A kind of ABS flame-retardant alloy comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, vinylbenzene 20-30 part, polynite 10-18 part, oxidation inhibitor 1-9 part, fire retardant APP(ammonium polyphosphate) 1-7 part, fire retardant PER(tetramethylolmethane) 1-8 part, Trichloroethyl Phosphate 3-9 part, halogen-free expansion fire retardant 2-9 part.
Claims (1)
1. an ABS flame-retardant alloy is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, vinylbenzene 20-30 part, polynite 10-18 part, oxidation inhibitor 1-9 part, fire retardant APP(ammonium polyphosphate) 1-7 part, fire retardant PER(tetramethylolmethane) 1-8 part, Trichloroethyl Phosphate 3-9 part, halogen-free expansion fire retardant 2-9 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201310107751 CN103232674A (en) | 2013-03-31 | 2013-03-31 | ABS flame retardant alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201310107751 CN103232674A (en) | 2013-03-31 | 2013-03-31 | ABS flame retardant alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103232674A true CN103232674A (en) | 2013-08-07 |
Family
ID=48880749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201310107751 Pending CN103232674A (en) | 2013-03-31 | 2013-03-31 | ABS flame retardant alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103232674A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602034A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Modified alloy material |
| CN103602037A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Environment-friendly ABS (acrylonitrile-butadiene-styrene) flame-retardant alloy material |
| CN103602024A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Environment-friendly flame retardant alloy |
| CN104559031A (en) * | 2014-12-30 | 2015-04-29 | 苏州康华净化系统工程有限公司 | Fire-retardant ABS material and preparation method thereof |
| CN109111677A (en) * | 2018-07-17 | 2019-01-01 | 广东聚石化学股份有限公司 | A kind of UL94-5VA grade anti-flaming ABS material of low smoke density and preparation method thereof |
-
2013
- 2013-03-31 CN CN 201310107751 patent/CN103232674A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602034A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Modified alloy material |
| CN103602037A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Environment-friendly ABS (acrylonitrile-butadiene-styrene) flame-retardant alloy material |
| CN103602024A (en) * | 2013-11-12 | 2014-02-26 | 青岛广联达精密机械有限公司 | Environment-friendly flame retardant alloy |
| CN104559031A (en) * | 2014-12-30 | 2015-04-29 | 苏州康华净化系统工程有限公司 | Fire-retardant ABS material and preparation method thereof |
| CN109111677A (en) * | 2018-07-17 | 2019-01-01 | 广东聚石化学股份有限公司 | A kind of UL94-5VA grade anti-flaming ABS material of low smoke density and preparation method thereof |
| CN109111677B (en) * | 2018-07-17 | 2021-03-19 | 广东聚石化学股份有限公司 | Low-smoke-density UL94-5 VA-grade flame-retardant ABS material and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130807 |