CN105420849A - Fire-retardant-adding environment-friendly brush wire - Google Patents

Fire-retardant-adding environment-friendly brush wire Download PDF

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Publication number
CN105420849A
CN105420849A CN201510920333.0A CN201510920333A CN105420849A CN 105420849 A CN105420849 A CN 105420849A CN 201510920333 A CN201510920333 A CN 201510920333A CN 105420849 A CN105420849 A CN 105420849A
Authority
CN
China
Prior art keywords
fire retardant
fire
agent
retardant
environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510920333.0A
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Chinese (zh)
Inventor
仰云龙
余勤俭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Tianrui Plastic Co Ltd
Original Assignee
Anhui Tianrui Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Tianrui Plastic Co Ltd filed Critical Anhui Tianrui Plastic Co Ltd
Priority to CN201510920333.0A priority Critical patent/CN105420849A/en
Publication of CN105420849A publication Critical patent/CN105420849A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/07Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a fire-retardant-adding environment-friendly brush wire. The environment-friendly brush wire is prepared from, by weight, 10%-15% of PA66, 25%-40% of PBT resin, 6%-8% of coupling agent, 2%-5% of aminopropyltriethoxysilane, 2%-5% of aminopropyltrimethoxysilane, 0.5%-1% of lubricating agent, 0.05%-1% of copper silicon powder, 0.05%-1% of anti-wear agent, 0.05%-1% of toughening agent, 0.05%-1% of anti-aging agent, 1%-2% of temperature-resisting agent, 0.05%-1% of plasticizer, 0.05%-1% of chain extender, 0.05%-1% of acetone, 1%-2% of ethyl alcohol, 10%-15% of diamond and 4%-8% of fire retardant. Compared with the prior art, the fire retardant is an environment-friendly product, and is reasonable in formula, nontoxic, free of corrosiveness, good in fire prevention effect, low in price and convenient to use, the fire retardant performance of materials treated by the fire retardant can meet the 'Fire Resistance B1' national standard, fire resistance or non-flammability is achieved, the low heat conductivity coefficient is further achieved, and the fire retardant effect is good.

Description

A kind of environment protection brush silk adding fire retardant
Technical field
The present invention relates to brush silk field, specifically a kind of environment protection brush silk adding fire retardant.
Background technology
Fire retardant also known as incombustible agent, fire-proofing chemical or fireproof agent: the functional aid giving combustible polymers flame retardancy; Additive flame retardant and reactive flame retardant is divided into according to application mode.According to composition, additive flame retardant mainly comprises inorganic combustion inhibitor, halogenated flame retardant (organic chloride and organic bromide), phosphorus flame retardant (red phosphorus, phosphate and halogenated phosphate etc.) and nitrogenated flame retardant etc.
Along with the extensive application of organic synthesis material, its inflammable performance also becomes increasingly conspicuous.The organic polymer of difficult burning such as halogen-containing grade often causes the physical property of material to become bad, and service life shortens, price improves.Take to apply the way of fireproof paint to carry out flameproof protection on its surface, not only can keep the premium properties of original organic synthesis material, and economic and practical.The application of plastic bruss silk on organic synthesis material also holds out broad prospects, and existing brush silk Application Areas is also more and more stricter to the production requirement of brush silk, how to reduce brush silk inflammability in use, more and more comes into one's own.
Summary of the invention
The present invention aims to provide a kind of environment protection brush silk adding fire retardant.
For realizing described object, the invention provides following technical scheme:
A kind of environment protection brush silk adding fire retardant, it is made up of the raw material of following percentage by weight: PA6610%-15%, PBT resin 25%-40%, coupling agent 6%-8%, aminopropyl triethoxysilane 2%-5%, aminopropyl dimethylamino silane 2%-5%, lubricant 0.5%-1%, copper silicon powder 0.05%-1%, antiwear additive 0.05%-1%, flexibilizer 0.05%-1%, age resister 0.05%-1%, refractory agent 1%-2%, plasticizer 0.05%-1%, chain extender 0.05%-1%, acetone 0.05%-1%, ethanol 1%-2%, diamond 10%-15%, fire retardant 4-8%.
A kind of environment protection brush silk adding fire retardant according to claim 1, described fire retardant is made up of the raw material of following percentage by weight: antimony trichloride 10% ~ 15%, amine sulfate 0.5% ~ 1%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, ammonium dihydrogen phosphate (ADP) 45% ~ 60%, diammonium hydrogen phosphate 5% ~ 8%, lauryl sodium sulfate 12% ~ 18%, diatomite 25% ~ 30%.
Compared with prior art, the invention has the beneficial effects as follows: fire retardant provided by the invention is environment-friendly products, formula is rationally, nontoxic, non-corrosiveness, flameproof effect is good, cheap, easy to use, the national standard that Flame Retardancy through its process can reach " difficult combustion B1 ", have flame retardancy or noninflammability, it also has lower thermal conductivity factor simultaneously, good flame retardation effect.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1 one kinds adds the environment protection brush silk of fire retardant, it is made up of the raw material of following percentage by weight: PA6610%-15%, PBT resin 25%-40%, coupling agent 6%-8%, aminopropyl triethoxysilane 2%-5%, aminopropyl dimethylamino silane 2%-5%, lubricant 0.5%-1%, copper silicon powder 0.05%-1%, antiwear additive 0.05%-1%, flexibilizer 0.05%-1%, age resister 0.05%-1%, refractory agent 1%-2%, plasticizer 0.05%-1%, chain extender 0.05%-1%, acetone 0.05%-1%, ethanol 1%-2%, diamond 10%-15%, fire retardant 4-8%.
A kind of environment protection brush silk adding fire retardant according to claim 1, described fire retardant is made up of the raw material of following percentage by weight: antimony trichloride 10%, amine sulfate 0.5%, magnesium hydroxide 10%, citric acid 10%, ammonium dihydrogen phosphate (ADP) 45%, diammonium hydrogen phosphate 5%, lauryl sodium sulfate 12%, diatomite 25%.
Embodiment 2 one kinds adds the environment protection brush silk of fire retardant, it is made up of the raw material of following percentage by weight: PA6610%-15%, PBT resin 25%-40%, coupling agent 6%-8%, aminopropyl triethoxysilane 2%-5%, aminopropyl dimethylamino silane 2%-5%, lubricant 0.5%-1%, copper silicon powder 0.05%-1%, antiwear additive 0.05%-1%, flexibilizer 0.05%-1%, age resister 0.05%-1%, refractory agent 1%-2%, plasticizer 0.05%-1%, chain extender 0.05%-1%, acetone 0.05%-1%, ethanol 1%-2%, diamond 10%-15%, fire retardant 4-8%.
A kind of environment protection brush silk adding fire retardant according to claim 1, described fire retardant is made up of the raw material of following percentage by weight: antimony trichloride 15%, amine sulfate 1%, magnesium hydroxide 20%, citric acid 20%, ammonium dihydrogen phosphate (ADP) 60%, diammonium hydrogen phosphate 8%, lauryl sodium sulfate 18%, diatomite 30%.
Embodiment 3 one kinds adds the environment protection brush silk of fire retardant, it is made up of the raw material of following percentage by weight: PA6610%-15%, PBT resin 25%-40%, coupling agent 6%-8%, aminopropyl triethoxysilane 2%-5%, aminopropyl dimethylamino silane 2%-5%, lubricant 0.5%-1%, copper silicon powder 0.05%-1%, antiwear additive 0.05%-1%, flexibilizer 0.05%-1%, age resister 0.05%-1%, refractory agent 1%-2%, plasticizer 0.05%-1%, chain extender 0.05%-1%, acetone 0.05%-1%, ethanol 1%-2%, diamond 10%-15%, fire retardant 4-8%.
A kind of environment protection brush silk adding fire retardant according to claim 1, described fire retardant is made up of the raw material of following percentage by weight: antimony trichloride 12% ~ 15%, amine sulfate 0.8%, magnesium hydroxide 12%, citric acid 18%, ammonium dihydrogen phosphate (ADP) 50%, diammonium hydrogen phosphate 6%, lauryl sodium sulfate 15%, diatomite 28%.
To those skilled in the art, obviously the invention is not restricted to the details of described one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of described explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.In addition, be to be understood that, although this description is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of description is only for clarity sake, those skilled in the art should by description integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.

Claims (2)

1. one kind is added the environment protection brush silk of fire retardant, it is characterized in that, it is made up of the raw material of following percentage by weight: PA6610%-15%, PBT resin 25%-40%, coupling agent 6%-8%, aminopropyl triethoxysilane 2%-5%, aminopropyl dimethylamino silane 2%-5%, lubricant 0.5%-1%, copper silicon powder 0.05%-1%, antiwear additive 0.05%-1%, flexibilizer 0.05%-1%, age resister 0.05%-1%, refractory agent 1%-2%, plasticizer 0.05%-1%, chain extender 0.05%-1%, acetone 0.05%-1%, ethanol 1%-2%, diamond 10%-15%, fire retardant 4-8%.
2. a kind of environment protection brush silk adding fire retardant according to claim 1, it is characterized in that, described fire retardant is made up of the raw material of following percentage by weight: antimony trichloride 10% ~ 15%, amine sulfate 0.5% ~ 1%, magnesium hydroxide 10% ~ 20%, citric acid 10% ~ 20%, ammonium dihydrogen phosphate (ADP) 45% ~ 60%, diammonium hydrogen phosphate 5% ~ 8%, lauryl sodium sulfate 12% ~ 18%, diatomite 25% ~ 30%.
CN201510920333.0A 2015-12-08 2015-12-08 Fire-retardant-adding environment-friendly brush wire Pending CN105420849A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510920333.0A CN105420849A (en) 2015-12-08 2015-12-08 Fire-retardant-adding environment-friendly brush wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105803572A (en) * 2016-05-10 2016-07-27 潜山县福达橡胶刷业制品厂 Industrial high-strength alkali-resisting brush wire and preparation method thereof
CN105803851A (en) * 2016-03-31 2016-07-27 自贡市华尔美科技有限公司 Environment-friendly inflaming retardant wallpaper
CN105821520A (en) * 2016-05-10 2016-08-03 潜山县福达橡胶刷业制品厂 Efficient environment-friendly inflaming-retarding brush wire production technology
CN108660542A (en) * 2018-05-04 2018-10-16 安徽六顺达刷业有限公司 Special brush filament of a kind of interior besom and preparation method thereof
CN109625901A (en) * 2018-12-06 2019-04-16 张磊 A kind of transformer rubber coating machine automatic feed/discharge feeding positioning device
CN110448042A (en) * 2019-07-20 2019-11-15 安徽省忆德工业刷制造有限公司 A kind of industrial brush filament of environment-friendly type and preparation method thereof
CN113882035A (en) * 2021-10-22 2022-01-04 广州明晖新材料有限公司 Flame-retardant brush wire

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101002644A (en) * 2007-02-07 2007-07-25 杨里江 Method for automatically forming hair at top of tooth-brush
CN101675839A (en) * 2008-09-18 2010-03-24 E.I.内穆尔杜邦公司 Industrial brush bristles and brush comprising same
CN103074080A (en) * 2012-12-30 2013-05-01 胶州市富田化工有限公司 Flame retardant
CN104910619A (en) * 2015-06-16 2015-09-16 苏州生光塑料机械有限公司 Abrasive wire brush component and method for producing abrasive wire brush component

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101002644A (en) * 2007-02-07 2007-07-25 杨里江 Method for automatically forming hair at top of tooth-brush
CN101675839A (en) * 2008-09-18 2010-03-24 E.I.内穆尔杜邦公司 Industrial brush bristles and brush comprising same
CN103074080A (en) * 2012-12-30 2013-05-01 胶州市富田化工有限公司 Flame retardant
CN104910619A (en) * 2015-06-16 2015-09-16 苏州生光塑料机械有限公司 Abrasive wire brush component and method for producing abrasive wire brush component

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105803851A (en) * 2016-03-31 2016-07-27 自贡市华尔美科技有限公司 Environment-friendly inflaming retardant wallpaper
CN105803572A (en) * 2016-05-10 2016-07-27 潜山县福达橡胶刷业制品厂 Industrial high-strength alkali-resisting brush wire and preparation method thereof
CN105821520A (en) * 2016-05-10 2016-08-03 潜山县福达橡胶刷业制品厂 Efficient environment-friendly inflaming-retarding brush wire production technology
CN108660542A (en) * 2018-05-04 2018-10-16 安徽六顺达刷业有限公司 Special brush filament of a kind of interior besom and preparation method thereof
CN109625901A (en) * 2018-12-06 2019-04-16 张磊 A kind of transformer rubber coating machine automatic feed/discharge feeding positioning device
CN110448042A (en) * 2019-07-20 2019-11-15 安徽省忆德工业刷制造有限公司 A kind of industrial brush filament of environment-friendly type and preparation method thereof
CN113882035A (en) * 2021-10-22 2022-01-04 广州明晖新材料有限公司 Flame-retardant brush wire

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Application publication date: 20160323

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