CN104650670A - Low-cost high-performance fireproof paint - Google Patents

Low-cost high-performance fireproof paint Download PDF

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Publication number
CN104650670A
CN104650670A CN201310592859.1A CN201310592859A CN104650670A CN 104650670 A CN104650670 A CN 104650670A CN 201310592859 A CN201310592859 A CN 201310592859A CN 104650670 A CN104650670 A CN 104650670A
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CN
China
Prior art keywords
low
performance
cost
cost high
fireproof paint
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Pending
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CN201310592859.1A
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Chinese (zh)
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不公告发明人
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Individual
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Individual
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Priority to CN201310592859.1A priority Critical patent/CN104650670A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34922—Melamine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates

Abstract

The invention discloses low-cost high-performance fireproof paint. The low-cost high-performance fireproof paint comprises, by mass, 30-40% of vinyl acetate emulsion, 10-15% of melamine polyphosphate, 15-25% of pentaerythritol, 2-8% of boric acid, 2-15% of aluminum hydroxide, 2-15% of montmorillonite, 2-6% of sodium molybdate, 0.1-1% of an aluminum-titanium composite coupling agent and 0.1-1% of pentaerythritol stearate. The low-cost high-performance fireproof paint has the advantages of cheap and easily available raw materials, low cost, no halogen, no toxicity, good coated object flame retardation, smoke inhibition, wear resistance, wear resistance, heat resistance, aging resistance, coating toughness and high bonding intensity, can be used for fireproof coating on the surfaces of timber and a steel structure, has good use effects and is economic.

Description

A kind of low-cost and high-performance frie retardant coating
Technical field
The present invention relates to frie retardant coating technical field, specifically a kind of low-cost and high-performance frie retardant coating.
Background technology
Frie retardant coating is a kind ofly coated in body surface, can reduces, retardance fire rapid spread flammable by painting surface and the kind coating in order to improve coated article body fire endurance.Because frie retardant coating difficulty itself is fired or do not fire, there is better protecting effect when meeting fire to base material, for fire extinguishing and personnel withdraw the time won.Therefore its investigation and application has been caused to the great attention of countries in the world.Along with the development of society and the progress of science and technology, kind and the range of application of frie retardant coating constantly expand.And the low cost of frie retardant coating, high-performance, low stain, the energy-conservation hot subject having become social concerns, be also the later important development direction of frie retardant coating, and be suitable for the needs of socio-economic development.
Summary of the invention
The object of the present invention is to provide a kind of low-cost and high-performance frie retardant coating.
The technical solution adopted for the present invention to solve the technical problems is: a kind of low-cost and high-performance frie retardant coating, and its component by mass percent proportioning is: acetate emulsion 30% ~ 40%, melamine polyphosphate 10% ~ 15%, tetramethylolmethane 15% ~ 25%, boric acid 2% ~ 8%, aluminium hydroxide 2% ~ 15%, polynite 2% ~ 15%, Sodium orthomolybdate 2% ~ 6%, aluminium titanium composite coupler 0.1% ~ 1%, pentaerythritol stearate 0.1% ~ 1%.
The preparation method of a kind of low-cost and high-performance frie retardant coating of the present invention, comprises the following steps:
(1) each component is taken by mass percent proportioning;
(2), by aluminium hydroxide, polynite and aluminium titanium composite coupler add a material temperature degree in the mixing machine of 80 DEG C ~ 120 DEG C, and stir 10 ~ 60 minutes under rotating speed 3000 ~ 6000 revs/min, be cooled to greenhouse, discharging is stand-by;
(3), acetate emulsion, melamine polyphosphate, tetramethylolmethane, boric acid, Sodium orthomolybdate and pentaerythritol stearate is added in the reactor, and add the material that step (2) obtains, make fully to grind Agitation and mixing evenly after, discharging, obtains the present invention.
The invention has the beneficial effects as follows, compared with prior art, cheaper starting materials of the present invention is easy to get, cost is low, not halogen-containing composition, toxicological harmless, and to coated object have well fire-retardant, press down cigarette, anticorrosion antiwear, heat-resisting, ageing-resistant and coating is tough and tensile, cohesive strength advantages of higher, can be used for the fire prevention coating on the surface such as timber, steel construction, result of use is good, and economical.
Embodiment
Technical scheme of the present invention is further illustrated below in conjunction with concrete preferred embodiment.
A kind of low-cost and high-performance frie retardant coating, its component by mass percent proportioning is: acetate emulsion 37%, melamine polyphosphate 15%, tetramethylolmethane 15%, boric acid 5%, aluminium hydroxide 10%, polynite 10%, Sodium orthomolybdate 6%, aluminium titanium composite coupler 1%, pentaerythritol stearate 1%.
Its preparation method is: (1) takes each component by mass percent proportioning; (2), by aluminium hydroxide, polynite and aluminium titanium composite coupler add a material temperature degree in the mixing machine of 80 DEG C ~ 120 DEG C, and stir 10 ~ 60 minutes under rotating speed 3000 ~ 6000 revs/min, be cooled to greenhouse, discharging is stand-by; (3), acetate emulsion, melamine polyphosphate, tetramethylolmethane, boric acid, Sodium orthomolybdate and pentaerythritol stearate is added in the reactor, and add the material that step (2) obtains, make fully to grind Agitation and mixing evenly after, discharging, obtains the present invention.

Claims (2)

1. a low-cost and high-performance frie retardant coating, it is characterized in that, its component by mass percent proportioning is: acetate emulsion 30% ~ 40%, melamine polyphosphate 10% ~ 15%, tetramethylolmethane 15% ~ 25%, boric acid 2% ~ 8%, aluminium hydroxide 2% ~ 15%, polynite 2% ~ 15%, Sodium orthomolybdate 2% ~ 6%, aluminium titanium composite coupler 0.1% ~ 1%, pentaerythritol stearate 0.1% ~ 1%.
2. a kind of low-cost and high-performance frie retardant coating according to claim 1, is characterized in that, comprise the following steps:
(1) each component is taken by mass percent proportioning;
(2), by aluminium hydroxide, polynite and aluminium titanium composite coupler add a material temperature degree in the mixing machine of 80 DEG C ~ 120 DEG C, and stir 10 ~ 60 minutes under rotating speed 3000 ~ 6000 revs/min, be cooled to greenhouse, discharging is stand-by;
(3), acetate emulsion, melamine polyphosphate, tetramethylolmethane, boric acid, Sodium orthomolybdate and pentaerythritol stearate is added in the reactor, and add the material that step (2) obtains, make fully to grind Agitation and mixing evenly after, discharging, obtains the present invention.
CN201310592859.1A 2013-11-22 2013-11-22 Low-cost high-performance fireproof paint Pending CN104650670A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310592859.1A CN104650670A (en) 2013-11-22 2013-11-22 Low-cost high-performance fireproof paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310592859.1A CN104650670A (en) 2013-11-22 2013-11-22 Low-cost high-performance fireproof paint

Publications (1)

Publication Number Publication Date
CN104650670A true CN104650670A (en) 2015-05-27

Family

ID=53242330

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310592859.1A Pending CN104650670A (en) 2013-11-22 2013-11-22 Low-cost high-performance fireproof paint

Country Status (1)

Country Link
CN (1) CN104650670A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433341A (en) * 2016-09-13 2017-02-22 成都创慧科达科技有限公司 Indoor expansive type fireproof steel structure coating and preparation method thereof
CN110315614A (en) * 2019-07-05 2019-10-11 徐州安联木业有限公司 A kind of fire retardant and preparation method thereof, purposes
CN116640469A (en) * 2023-05-31 2023-08-25 广东聚石科技研究院有限公司 Non-expansion type gray calcium-based fireproof paint and preparation method thereof
CN116640469B (en) * 2023-05-31 2024-04-26 广东聚石科技研究院有限公司 Non-expansion type gray calcium-based fireproof paint and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433341A (en) * 2016-09-13 2017-02-22 成都创慧科达科技有限公司 Indoor expansive type fireproof steel structure coating and preparation method thereof
CN110315614A (en) * 2019-07-05 2019-10-11 徐州安联木业有限公司 A kind of fire retardant and preparation method thereof, purposes
CN116640469A (en) * 2023-05-31 2023-08-25 广东聚石科技研究院有限公司 Non-expansion type gray calcium-based fireproof paint and preparation method thereof
CN116640469B (en) * 2023-05-31 2024-04-26 广东聚石科技研究院有限公司 Non-expansion type gray calcium-based fireproof paint and preparation method thereof

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150527

WD01 Invention patent application deemed withdrawn after publication