CN103539909A - Environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) alloy - Google Patents
Environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) alloy Download PDFInfo
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- CN103539909A CN103539909A CN201310448709.3A CN201310448709A CN103539909A CN 103539909 A CN103539909 A CN 103539909A CN 201310448709 A CN201310448709 A CN 201310448709A CN 103539909 A CN103539909 A CN 103539909A
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Abstract
The invention discloses an environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) alloy, which is characterized by comprising the following substances in parts by weight: 1-2 parts of PE (Poly Ethylene) ester, 2-8 parts of zinc borate, 1-9 parts of acetylacetonate, 10-30 parts of PBT (Polybutylece Terephthalate), 30-40 parts of ABS (Acrylonitrile Butadiene Styrene), 2-9 parts of compatilizer, 10-20 parts of organic solvent, 10-30 parts of concentrated hydrochloric acid, 20-23 parts of curing agent, 10-20 parts of methyl phenyl siloxane branched prepolymer, 20-30 parts of styrene, 10-18 parts of montmorillonite, 1-9 parts of antioxygen, 1-7 parts of APP (Ammonium polyphosphate) flame retardant and 2-9 parts of halogen-free inrumescent flame retardant. The Environment-friendly flame-retardant ABS alloy utilizes synergistic effect of the montmorillonite and the halogen-free flame retardant, abandons traditional flame-retardant systems, and also has excellent flame retardance and mechanical property.
Description
Technical field
The present invention relates to a kind of ABS environmental protection flame retardant alloy.
Background technology
Current flame-retardant PBT/ABS fire retardant nearly 95% used is halogen containing flame-retardant, performance impact to material is little, and moderate, non-other fire retardants of its usefulness/cost ratio can be equal to, so 70% ~ 80% all use this based flame retardant in China's electric series products for export.But halogen flame is subject to the puzzlement of dioxin problem in recent years, with its fire-retardant macromolecular material, in thermo-cracking and burning, time can generate a large amount of flue dust and corrosive gases simultaneously, at present European Union and Japan oneself in succession put into effect that it is forbidden by decree to uses this based flame retardant.European Union rose and implements in full ROHS instruction on July 1st, 2006, and this decree requires the electronic and electrical equipment of throwing in European Union must not contain poly-Australia hexichol Cu,Ju Australia biphenyl, and this decree has seriously restricted the outlet of China's electronic and electrical equipment.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of ABS environmental protection flame retardant alloy.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
An environmental protection flame retardant alloy, is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, compatilizer 2-9 part, organic solvent 10-20 part, concentrated hydrochloric acid 10-30 part, solidifying agent 20-23 part, methylphenyl siloxane branched chain type prepolymer 10-20 part, vinylbenzene 20-30 part, polynite 10-18 part, oxidation inhibitor 1-9 part, fire retardant APP(ammonium polyphosphate) 1-7 part, halogen-free expansion fire retardant 2-9 part.
The invention has the beneficial effects as follows: utilize the synergistic effect of Meng Tuoshi and halogen-free flame retardants, not only abandoned traditional flame-retardant system, there is excellent flame retardant properties and mechanical property, do not endanger environment and health of human body, belong to environmentfriendly products; And using polynite to reduce the usage quantity of fire retardant, this has improved mechanical property and the resistance toheat of fire retardant material to a great extent, the more important thing is greatly and reduces production costs.
Embodiment
Embodiment 1
An environmental protection flame retardant alloy, is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, compatilizer 2-9 part, organic solvent 10-20 part, concentrated hydrochloric acid 10-30 part, solidifying agent 20-23 part, methylphenyl siloxane branched chain type prepolymer 10-20 part, vinylbenzene 20-30 part, polynite 10-18 part, oxidation inhibitor 1-9 part, fire retardant APP(ammonium polyphosphate) 1-7 part, halogen-free expansion fire retardant 2-9 part.
Claims (1)
1. an ABS environmental protection flame retardant alloy, is characterized in that, comprises the material of following parts by weight: PE ester 1-2 part, zinc borate 2-8 part, acetylacetonate 1-9 part, PBT10-30 part, ABS30-40 part, compatilizer 2-9 part, organic solvent 10-20 part, concentrated hydrochloric acid 10-30 part, solidifying agent 20-23 part, methylphenyl siloxane branched chain type prepolymer 10-20 part, vinylbenzene 20-30 part, polynite 10-18 part, oxidation inhibitor 1-9 part, fire retardant APP(ammonium polyphosphate) 1-7 part, halogen-free expansion fire retardant 2-9 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310448709.3A CN103539909A (en) | 2013-09-28 | 2013-09-28 | Environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310448709.3A CN103539909A (en) | 2013-09-28 | 2013-09-28 | Environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103539909A true CN103539909A (en) | 2014-01-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310448709.3A Pending CN103539909A (en) | 2013-09-28 | 2013-09-28 | Environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) alloy |
Country Status (1)
| Country | Link |
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| CN (1) | CN103539909A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559031A (en) * | 2014-12-30 | 2015-04-29 | 苏州康华净化系统工程有限公司 | Fire-retardant ABS material and preparation method thereof |
-
2013
- 2013-09-28 CN CN201310448709.3A patent/CN103539909A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559031A (en) * | 2014-12-30 | 2015-04-29 | 苏州康华净化系统工程有限公司 | Fire-retardant ABS material and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140129 |