CN106046609A - Extra-weather-resistant ultraviolet-proof electric wire PVC material - Google Patents

Extra-weather-resistant ultraviolet-proof electric wire PVC material Download PDF

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Publication number
CN106046609A
CN106046609A CN201610522260.4A CN201610522260A CN106046609A CN 106046609 A CN106046609 A CN 106046609A CN 201610522260 A CN201610522260 A CN 201610522260A CN 106046609 A CN106046609 A CN 106046609A
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China
Prior art keywords
parts
ultraviolet
electric wire
weather
extra
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610522260.4A
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Chinese (zh)
Inventor
曹惠忠
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Taicang Linyuan Electric Wire & Cable Co Ltd
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Taicang Linyuan Electric Wire & Cable Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Taicang Linyuan Electric Wire & Cable Co Ltd filed Critical Taicang Linyuan Electric Wire & Cable Co Ltd
Priority to CN201610522260.4A priority Critical patent/CN106046609A/en
Publication of CN106046609A publication Critical patent/CN106046609A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

Abstract

The invention provides an extra-weather-resistant ultraviolet-proof electric wire PVC material. The extra-weather-resistant ultraviolet-proof electric wire PVC material is characterized by comprising the following components in parts by weight: 70-100 parts of polyvinyl chloride, 15-25 parts of dimethoxymethylphenylsilane, 6-12 parts of an anti-ultraviolet agent, 3-5 parts of nano-magnesium hydroxide, 1-3 parts of aluminium triphosphate, 0.5-2.5 parts of a plasticizer, 1-5 parts of an anti-ageing agent, 0.5-2 parts of an antioxidant, 1-4 parts of an impact modifier, and 0.5-1 part of carbon black. The various components compounded in the electric wire PVC material are in synergistic effect, so that the PVC material has good weather resistance, ageing resistance, flame retardance and ultraviolet resistance, and cannot be aged easily even if the PVC material is exposed in sunlight for a long time, the service life of the electric wire PVC material is prolonged, and the economic benefit of factories is increased.

Description

A kind of extra-weather-proof anti-ultraviolet electric wire PVC material
Technical field
The present invention relates to electric wire field, expect particularly to a kind of extra-weather-proof anti-ultraviolet electric wire PVC.
Background technology
Electric wire is a kind of in order to transmit electricity (magnetic) energy, information and the wire product realizing electromagnetic energy conversion.Electric wire electricity The main carriers that cable transmits as electric power, is widely used in the aspects such as appliance equipment, illuminating line, household electrical appliance, its quality Quality directly influences the security of the lives and property of construction quality and consumer.Although a wires and cables industry simply supporting row Industry, but in occupation of the output value of China's electrician trade 1/4.Its product category is numerous, and range of application is quite varied, relate to electric power, Build, communicate, the industry such as manufacture, the most closely related with each department of national economy.Electric wire is also known as national economy " tremulous pulse " and " neural ", be conveying electric energy, transmission information and manufacture various motor, instrument, instrument, it is achieved electromagnetic energy is changed Indispensable basic equipment, is basic product necessary in following electrification, informationized society.
Current electric wire divides from material and includes the multiple electric wire such as PVC, PE, PP.PVC product is good with it Decay resistance is widely used in various fields with shock resistance.In electric wire field due to security performance and environmental protection The high request of performance so that the application of PVC material also receives the biggest challenge.
Electric wire is typically used for outdoor, being exposed to for a long time under the irradiation of sunlight, and sunray contains Ultraviolet can speed up the aging of wire cable material, has a strong impact on its service life, accordingly, it would be desirable to a kind of anti-ultraviolet electric wire PVC expects.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of extra-weather-proof anti-ultraviolet electric wire PVC material. Each component generation synergism compounding in described electric wire PVC material so that it is there is good weatherability, ageing resistance, anti-flammability And ability and ultraviolet resistance, it is exposed to for a long time under the irradiation of sunlight, also cannot be easily caused the aging of electric wire PVC material, extend electricity In the service life of line PVC material, increase the economic benefit of factory.
For reaching above-mentioned purpose, the technical scheme is that
A kind of extra-weather-proof anti-ultraviolet electric wire PVC material, including the component of following parts by weight: polrvinyl chloride: 70-100 part, Aminomethyl phenyl dimethoxysilane: 15-25 part, ultraviolet (UV) resistant agent: 6-12 part, nano-sized magnesium hydroxide: 3-5 part, aluminium triphosphate: 1-3 part, plasticizer: 0.5-2.5 part, age resistor: 1-5 part, antioxidant: 0.5-2 part, impact modifier: 1-4 part, white carbon black: 0.5-1 part.
Further, including the component of following parts by weight: polrvinyl chloride: 80-90 part, aminomethyl phenyl dimethoxy silicon Alkane: 18-22 part, ultraviolet (UV) resistant agent: 7-10 part, nano-sized magnesium hydroxide: 3-4 part, aluminium triphosphate: 1-2 part, plasticizer: 1.5- 2.5 parts, age resistor: 1-3 part, antioxidant: 0.5-1 part, impact modifier: 1-2.5 part, white carbon black: 0.7-1 part.
Further, including the component of following parts by weight: polrvinyl chloride: 81 parts, aminomethyl phenyl dimethoxysilane: 19 Part, ultraviolet (UV) resistant agent: 8 parts, nano-sized magnesium hydroxide: 3.4 parts, aluminium triphosphate: 1.6 parts, plasticizer: 2 parts, age resistor: 2.8 Part, antioxidant: 0.9 part, impact modifier: 2.1 parts, white carbon black: 0.8 part.
Further, described ultraviolet (UV) resistant agent is benzoic acids ultraviolet (UV) resistant agent, benzophenone ultraviolet (UV) resistant agent, benzotriazole Any one in class ultraviolet (UV) resistant agent.
And have, the particle diameter of described nano-sized magnesium hydroxide is less than 100nm.
Separately, described plasticizer is any one in dioctyl phthalate or octyl epoxy stearate, described age resistor For any one in antioxidant A or antioxidant MB or antioxidant BLE-C, described antioxidant is antioxidant BTH, antioxidant 1010, any one in antioxidant 168.
Simultaneously, it is characterised in that described impact modifier is styrene-butadiene-styrene ternary block copolymer.
The beneficial effects of the present invention is:
The one extra-weather-proof anti-ultraviolet electric wire PVC material that the present invention provides, compounding each component generation synergism so that it is There is good weatherability, ageing resistance, anti-flammability and ability and ultraviolet resistance, be exposed to for a long time under the irradiation of sunlight, also Cannot be easily caused the aging of electric wire PVC material, in the service life of extending wire PVC material, increase the economic benefit of factory.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, the most detailed below in conjunction with embodiment Describe in detail bright.
Table 1 is that the embodiment of the present invention extra-weather-proof anti-ultraviolet electric wire PVC expects ingredient lists.
Table 1. embodiment extra-weather-proof anti-ultraviolet electric wire PVC material composition (unit: part)
The one extra-weather-proof anti-ultraviolet electric wire PVC material that the present invention provides, compounding each component generation synergism so that it is There is good weatherability, ageing resistance, anti-flammability and ability and ultraviolet resistance, be exposed to for a long time under the irradiation of sunlight, also Cannot be easily caused the aging of electric wire PVC material, in the service life of extending wire PVC material, increase the economic benefit of factory.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should contain the power in the present invention In profit claimed range.

Claims (7)

1. extra-weather-proof anti-ultraviolet electric wire PVC material, it is characterised in that include the component of following parts by weight: polrvinyl chloride: 70-100 part, aminomethyl phenyl dimethoxysilane: 15-25 part, ultraviolet (UV) resistant agent: 6-12 part, nano-sized magnesium hydroxide: 3-5 part, three Poly aluminium phosphate: 1-3 part, plasticizer: 0.5-2.5 part, age resistor: 1-5 part, antioxidant: 0.5-2 part, impact modifier: 1-4 Part, white carbon black: 0.5-1 part.
One the most according to claim 1 extra-weather-proof anti-ultraviolet electric wire PVC expects, it is characterised in that include following weight The component of number: polrvinyl chloride: 80-90 part, aminomethyl phenyl dimethoxysilane: 18-22 part, ultraviolet (UV) resistant agent: 7-10 part, receive Rice magnesium hydroxide: 3-4 part, aluminium triphosphate: 1-2 part, plasticizer: 1.5-2.5 part, age resistor: 1-3 part, antioxidant: 0.5- 1 part, impact modifier: 1-2.5 part, white carbon black: 0.7-1 part.
One the most according to claim 1 extra-weather-proof anti-ultraviolet electric wire PVC expects, it is characterised in that include following weight The component of number: polrvinyl chloride: 81 parts, aminomethyl phenyl dimethoxysilane: 19 parts, ultraviolet (UV) resistant agent: 8 parts, nanometer hydroxide Magnesium: 3.4 parts, aluminium triphosphate: 1.6 parts, plasticizer: 2 parts, age resistor: 2.8 parts, antioxidant: 0.9 part, impact modifier: 2.1 parts, white carbon black: 0.8 part.
One the most according to claim 1 extra-weather-proof anti-ultraviolet electric wire PVC expects, it is characterised in that described uvioresistant Agent is any one in benzoic acids ultraviolet (UV) resistant agent, benzophenone ultraviolet (UV) resistant agent, benzotriazole ultraviolet (UV) resistant agent.
One the most according to claim 1 extra-weather-proof anti-ultraviolet electric wire PVC expects, it is characterised in that described nanometer hydrogen-oxygen Change the particle diameter of magnesium less than 100nm.
One the most according to claim 1 extra-weather-proof anti-ultraviolet electric wire PVC expects, it is characterised in that described plasticizer is Any one in dioctyl phthalate or octyl epoxy stearate, described age resistor is antioxidant A or antioxidant MB or anti- Any one in old agent BLE-C, described antioxidant is antioxidant BTH, appointing in antioxidant 1010, antioxidant 168 A kind of.
One the most according to claim 1 extra-weather-proof anti-ultraviolet electric wire PVC expects, it is characterised in that described impact-resistant modified Agent is styrene-butadiene-styrene ternary block copolymer.
CN201610522260.4A 2016-07-05 2016-07-05 Extra-weather-resistant ultraviolet-proof electric wire PVC material Pending CN106046609A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610522260.4A CN106046609A (en) 2016-07-05 2016-07-05 Extra-weather-resistant ultraviolet-proof electric wire PVC material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610522260.4A CN106046609A (en) 2016-07-05 2016-07-05 Extra-weather-resistant ultraviolet-proof electric wire PVC material

Publications (1)

Publication Number Publication Date
CN106046609A true CN106046609A (en) 2016-10-26

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001547A (en) * 2015-06-23 2015-10-28 安徽成力特科技有限公司 Modified polyvinyl chloride cable sheath material capable of resisting ultraviolet radiation aging
CN105367952A (en) * 2015-12-10 2016-03-02 盐城市瑞通塑胶有限公司 Cold-resistant UV-resistant soft sheathing compound and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001547A (en) * 2015-06-23 2015-10-28 安徽成力特科技有限公司 Modified polyvinyl chloride cable sheath material capable of resisting ultraviolet radiation aging
CN105367952A (en) * 2015-12-10 2016-03-02 盐城市瑞通塑胶有限公司 Cold-resistant UV-resistant soft sheathing compound and preparation method thereof

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Application publication date: 20161026