CN103524913B - A kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material - Google Patents
A kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material Download PDFInfo
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- CN103524913B CN103524913B CN201310460221.2A CN201310460221A CN103524913B CN 103524913 B CN103524913 B CN 103524913B CN 201310460221 A CN201310460221 A CN 201310460221A CN 103524913 B CN103524913 B CN 103524913B
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Abstract
The invention provides a kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, be made up of the raw material of following weight part: polyvinyl chloride SG-3? 100, butadiene-acrylonitrile rubber N26? 10-20, polycarbonate 10-15, polyethylene terephthalate-1, 4-cyclohexanedimethanoester ester 10-15, silane coupling agent 15-20, tetraphenyl-(bisphenol-A) bisphosphate 30-40, calcium carbonate 20-30, Calucium Silicate powder 1-2, barium stearate 30-50, phosphate toluene diphenyl ester 10-15, glycerol glycerinate 3-4, linking agent TAIC2-3, stearic acid, 2-3, N, a N '-penylene bismaleimides 1-2, alcohol ester 12 5-8, PE wax 0.5-1.0, aluminum nitride powder 1-2, jade powder 1-2, modified filler 8-10.Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material of the present invention has the feature of fire-retardant, oil resistant, ageing-resistant, acid and alkali-resistance, and proportion is lower, cheap.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material and preparation method thereof.
Background technology
Along with the fast development of global economy, and the enhancing of mankind's environmental consciousness, the requirement of each field to the quality and performance of electric wire is more and more higher, because of electric wire, cable aging and fire that is that cause also gets more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the production of current halide-free low-smoke fireproof cable material is in polyolefin substrate, add a large amount of magnesium hydroxides or magnesium hydroxide to reach flame retardant effect mostly, but, adding of a large amount of inorganic materials, have impact on physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, its at normal temperatures softness, weathering resistance poor, oil-proofness, resistance to low temperature be not fine.
Summary of the invention
The invention provides a kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material.
The technical solution used in the present invention is:
A kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, it is characterized in that: be made up of the raw material of following weight part: polyvinyl chloride SG-3100, butadiene-acrylonitrile rubber N2610-20, polycarbonate 10-15, polyethylene terephthalate-1, 4-cyclohexanedimethanoester ester 10-15, silane coupling agent 15-20, tetraphenyl-(bisphenol-A) bisphosphate 30-40, calcium carbonate 20-30, Calucium Silicate powder 1-2, barium stearate 30-50, phosphate toluene diphenyl ester 10-15, glycerol glycerinate 3-4, linking agent TAIC2-3, stearic acid, 2-3, N, a N '-penylene bismaleimides 1-2, alcohol ester 12 5-8, PE wax 0.5-1.0, aluminum nitride powder 1-2, jade powder 1-2, modified filler 8-10.
Described Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl chloride SG-3100, butadiene-acrylonitrile rubber N2615, polycarbonate 12, polyethylene terephthalate-1, 4-cyclohexanedimethanoester ester 2, silane coupling agent 18, tetraphenyl-(bisphenol-A) bisphosphate 35, calcium carbonate 25, Calucium Silicate powder 2, barium stearate 35, phosphate toluene diphenyl ester 12, glycerol glycerinate 3, linking agent TAIC2, stearic acid, 2, N, a N '-penylene bismaleimides 1, alcohol ester 12, PE wax 0.8, aluminum nitride powder 1, jade powder 2, modified filler 9.
Described Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, it is characterized in that, described modified filler is prepared by following method and obtains: attapulgite is calcined at 540-580 DEG C 3-4 hour, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then in gained powder, the tea tree ethereal oil being equivalent to powder weight 1-2% is added, the zinc oxide of 1-2%, the tetramethylolmethane of 1-2%, 2-3% nanometer jade powder, after co-ground 1-2 hour, add the aminopropyl triethoxysilane being equivalent to powder weight 2-3% again, 4-5% polyethylene glycol 6000, the morpholine of 2-3%, even with the high speed dispersion of 11000-12000 rev/min, obtain.
Take each component raw material by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 115-145 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, i.e. obtained CABLE MATERIALS finished product.
Beneficial effect
This Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material has the feature of fire-retardant, oil resistant, ageing-resistant, acid and alkali-resistance, and proportion is lower, cheap.
Embodiment
Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, be made up of the raw material of following weight (kg):
Polyvinyl chloride SG-3100, butadiene-acrylonitrile rubber N2615, polycarbonate 12, polyethylene terephthalate-1,4-cyclohexanedimethanoester ester 2, silane coupling agent 18, tetraphenyl-(bisphenol-A) bisphosphate 35, calcium carbonate 25, Calucium Silicate powder 2, barium stearate 35, phosphate toluene diphenyl ester 12, glycerol glycerinate 3, linking agent TAIC2, stearic acid, 2, N, a N '-penylene bismaleimides 1, alcohol ester 12, PE wax 0.8, aluminum nitride powder 1, jade powder 2, modified filler 9
Wherein, modified filler is prepared by following method and obtains:
Attapulgite is calcined 3-4 hour at 540-580 DEG C, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then in gained powder, the tea tree ethereal oil being equivalent to powder weight 1-2% is added, the zinc oxide of 1-2%, the tetramethylolmethane of 1-2%, 2-3% nanometer jade powder, after co-ground 1-2 hour, add the aminopropyl triethoxysilane being equivalent to powder weight 2-3% again, 4-5% polyethylene glycol 6000, the morpholine of 2-3%, even with the high speed dispersion of 11000-12000 rev/min, obtain.
The preparation method of finished cable material:
Take each component raw material by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 115-145 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, i.e. obtained CABLE MATERIALS finished product.
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:
Claims (1)
1. a Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, it is characterized in that: be made up of the raw material of following weight part: polyvinyl chloride SG-3100, butadiene-acrylonitrile rubber N2610-20, polycarbonate 10-15, polyethylene terephthalate-1, 4-cyclohexanedimethanoester ester 10-15, silane coupling agent 15-20, tetraphenyl-(bisphenol-A) bisphosphate 30-40, calcium carbonate 20-30, Calucium Silicate powder 1-2, barium stearate 30-50, phosphate toluene diphenyl ester 10-15, glycerol glycerinate 3-4, linking agent TAIC2-3, stearic acid 2-3, N, a N '-penylene bismaleimides 1-2, alcohol ester 12 5-8, PE wax 0.5-1.0, aluminum nitride powder 1-2, jade powder 1-2, modified filler 8-10,
Described modified filler is prepared by following method and obtains: attapulgite is calcined at 540-580 DEG C 3-4 hour, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then in gained powder, the tea tree ethereal oil being equivalent to powder weight 1-2% is added, the zinc oxide of 1-2%, the tetramethylolmethane of 1-2%, 2-3% nanometer jade powder, after co-ground 1-2 hour, add the aminopropyl triethoxysilane being equivalent to powder weight 2-3% again, 4-5% polyethylene glycol 6000, the morpholine of 2-3%, even with the high speed dispersion of 11000-12000 rev/min, obtain.
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| CN201310460221.2A CN103524913B (en) | 2013-09-30 | 2013-09-30 | A kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material |
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| CN201310460221.2A CN103524913B (en) | 2013-09-30 | 2013-09-30 | A kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material |
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| CN103524913A CN103524913A (en) | 2014-01-22 |
| CN103524913B true CN103524913B (en) | 2016-03-23 |
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| CN103881261A (en) * | 2014-02-14 | 2014-06-25 | 安徽旺达铜业发展有限公司 | PVC (Polyvinyl Chloride) thermoplastic elastomer cable material and preparation method thereof |
| CN103881407A (en) * | 2014-02-25 | 2014-06-25 | 安徽九州高分子科技有限公司 | Formula of butyronitrile sheath for cables |
| CN103881409A (en) * | 2014-02-25 | 2014-06-25 | 安徽九州高分子科技有限公司 | Formula for 90DEG C cable sheath |
| CN103881406A (en) * | 2014-02-25 | 2014-06-25 | 安徽九州高分子科技有限公司 | Formula of butyronitrile cable insulating sheath |
| CN103881411A (en) * | 2014-02-25 | 2014-06-25 | 安徽九州高分子科技有限公司 | Formula of 70 DEG C cable insulation sheath |
| CN103881410A (en) * | 2014-02-25 | 2014-06-25 | 安徽九州高分子科技有限公司 | Formula of 70-degree flame-retardant cable insulating sheath |
| CN103881408A (en) * | 2014-02-25 | 2014-06-25 | 安徽九州高分子科技有限公司 | Formulation of insulating sheath for 105 DEG C-grade cable |
| CN103865286B (en) * | 2014-03-19 | 2016-02-24 | 安徽电缆股份有限公司 | A kind of fold resistant, non-whitening CABLE MATERIALS |
| CN104592683A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Flame-retardant polyvinyl chloride for cable and preparation method of flame-retardant polyvinyl chloride |
| CN105131470A (en) * | 2015-09-23 | 2015-12-09 | 江苏蓝湾生物科技有限公司 | Preparation method of medical deodorization packaging material |
| CN105419286A (en) * | 2015-12-14 | 2016-03-23 | 苏州国环环境检测有限公司 | Environment-friendly communication cable material |
| CN105482190A (en) * | 2015-12-15 | 2016-04-13 | 中冠电缆有限公司 | Flame-retardant and oil-resistant modified nitrile-butadiene rubber cable material and preparation method thereof |
| CN105754314A (en) * | 2016-03-19 | 2016-07-13 | 孟根森 | Multifunctional high-voltage electric power transmission cable |
| CN105949655A (en) * | 2016-05-31 | 2016-09-21 | 苏州市奎克力电子科技有限公司 | Anti-aging insulating plastic shell material and preparation method thereof |
| CN105906865A (en) * | 2016-06-01 | 2016-08-31 | 芜湖航飞科技股份有限公司 | Nitrile butadiene rubber cable sheath material and preparation method thereof |
| CN106432954A (en) * | 2016-09-26 | 2017-02-22 | 高团结 | Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material |
| CN106675026A (en) * | 2016-12-23 | 2017-05-17 | 安徽国威电动车制造有限公司 | Heat-insulating anti-freezing electric vehicle battery shell material and preparation method thereof |
| CN109210283B (en) * | 2018-08-20 | 2020-09-25 | 江苏百通塑业发展有限公司 | High-strength PVC (polyvinyl chloride) pipe |
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| JP2000204213A (en) * | 1999-01-18 | 2000-07-25 | Toyo Chem Co Ltd | Pvc-based tape |
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Inventor after: Fu Yonghai Inventor before: He Chenglong Inventor before: He Yuan |
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Effective date of registration: 20171229 Address after: 236800 Anhui Bozhou City Qiaocheng Xintiandi WAL-MART International Shopping Plaza, Bozhou Qiaocheng District, Guangming Road, Anhui Patentee after: Bozhou Jingxing Network Technology Co. Ltd. Address before: 241002 Zhanghe Road, Yijiang District, Wuhu City, Anhui Province, hi tech Industrial Development Zone, No. 15 Patentee before: Wuhu Aerospace Special Cable Factory |
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Effective date of registration: 20191120 Address after: Zi Zi Xiang Zi Zi Cun, Quanjiao County, Chuzhou City, Anhui Province Patentee after: Chuzhou Junyue High Polymer New Material Co., Ltd. Address before: 236800 Anhui Bozhou City Qiaocheng Xintiandi WAL-MART International Shopping Plaza, Bozhou Qiaocheng District, Guangming Road, Anhui Patentee before: Bozhou Jingxing Network Technology Co. Ltd. |
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