CN103525092B - A kind of Ceramic silicone rubber cable material and preparation method thereof - Google Patents
A kind of Ceramic silicone rubber cable material and preparation method thereof Download PDFInfo
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- CN103525092B CN103525092B CN201310463784.7A CN201310463784A CN103525092B CN 103525092 B CN103525092 B CN 103525092B CN 201310463784 A CN201310463784 A CN 201310463784A CN 103525092 B CN103525092 B CN 103525092B
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- 239000000463 material Substances 0.000 title claims abstract description 28
- 229920002379 silicone rubber Polymers 0.000 title claims abstract description 21
- 239000000919 ceramic Substances 0.000 title claims abstract description 15
- 239000004945 silicone rubber Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 6
- 239000008116 calcium stearate Substances 0.000 claims abstract description 6
- 239000006229 carbon black Substances 0.000 claims abstract description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 6
- 239000011707 mineral Substances 0.000 claims abstract description 6
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 6
- 229920001194 natural rubber Polymers 0.000 claims abstract description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims abstract description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007921 spray Substances 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 6
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 3
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 3
- 101100099988 Arabidopsis thaliana TPD1 gene Proteins 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 241000723346 Cinnamomum camphora Species 0.000 claims description 3
- 101100352918 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) PTC1 gene Proteins 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229960000846 camphor Drugs 0.000 claims description 3
- 229930008380 camphor Natural products 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- -1 poly(oxyethylene glycol) Polymers 0.000 claims description 3
- 239000000341 volatile oil Substances 0.000 claims description 3
- 230000005611 electricity Effects 0.000 abstract description 2
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- 239000003063 flame retardant Substances 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 239000004703 cross-linked polyethylene Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 150000001282 organosilanes Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 206010023126 Jaundice Diseases 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Abstract
The invention provides a kind of Ceramic silicone rubber cable material, prepared by the component raw material of following weight part and obtain: silicon rubber 80-90, natural rubber 10-20, mineral silicate 20-30, antimonous oxide 10-15, ammonium polyphosphate 10-20, zinc oxide 4-6, antioxidant D TPD1-2, spray carbon black 20-30, light calcium carbonate 10-20, hypo-aluminum orthophosphate 14-16, calcium stearate 1-2, tetramethylolmethane 1-2, talcum powder 1-2, modified filler 12-14.CABLE MATERIALS of the present invention not only has excellent flame retardancy and not flame-retarding power; During burning, the amount of being fuming is considerably less simultaneously, does not produce toxic gas, does not produce corrosive gases, and can form hard housing after burning simultaneously, not coming off, protecting the cable by burning not to be damaged, and ensures to transmit electricity normally.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of Ceramic silicone rubber cable material and preparation method thereof.
Background technology
Electric wire is important materials indispensable in industrial and agricultural production and the modern life, China is that the maximum electric wire in the whole world produces country, wires and cables industry occupies very important status in the national economy of China, but, at present, CABLE MATERIALS on market also exists non-refractory, not ageing-resistant, and after weathering test, material occurs that jaundice becomes fragile phenomenon.Electric wire is aging and fire that is that cause also gets more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free smokeless Ceramic silicone rubber cable material is increasing, the production of current halide-free smokeless Ceramic silicone rubber cable material is in polyolefin substrate, add a large amount of Shawinigan blacks or Shawinigan black to reach flame retardant effect mostly, but, adding of a large amount of inorganic materials, have impact on physical and mechanical properties and the processing of CABLE MATERIALS.Fire-retardant, low cigarette, environmental protection, good weatherability, CABLE MATERIALS that cost is low become the direction of CABLE MATERIALS development.
Summary of the invention
The invention provides a kind of Ceramic silicone rubber cable material and preparation method thereof.The cable be processed into by CABLE MATERIALS of the present invention has good weatherability, low cigarette, ageing-resistant, and flame retardant properties is good.
The technical solution used in the present invention is:
A kind of Ceramic silicone rubber cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: silicon rubber 80-90, natural rubber 10-20, mineral silicate 20-30, antimonous oxide 10-15, ammonium polyphosphate 10-20, zinc oxide 4-6, antioxidant D TPD1-2, spray carbon black 20-30, light calcium carbonate 10-20, hypo-aluminum orthophosphate 14-16, calcium stearate 1-2, tetramethylolmethane 1-2, talcum powder 1-2, modified filler 12-14.
Described Ceramic silicone rubber cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: silicon rubber 88, natural rubber 15, mineral silicate 25, antimonous oxide 12, ammonium polyphosphate 16, zinc oxide 5, antioxidant D TPD1, spray carbon black 25, light calcium carbonate 18, hypo-aluminum orthophosphate 15, calcium stearate 1, tetramethylolmethane 2, talcum powder 1, modified filler 13.
Described Ceramic silicone rubber cable material, is characterized in that, described modified filler is prepared by following method and obtains:
Diatomite is calcined 3-4 hour at 500-550 DEG C, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the camphor essential oil being equivalent to powder weight 1-2% is added in gained powder, the nano-sized carbon of 1-2%, 2-3% hypo-aluminum orthophosphate, after co-ground 1-2 hour, add the 3-aminopropyl trimethoxysilane being equivalent to powder weight 2-3% again, 4-5% poly(oxyethylene glycol) 400, the morpholine of 2-3%, the high speed dispersion of 12000-15000 rev/min is even, obtain.
The preparation method of Ceramic silicone rubber cable material of the present invention:
Each component raw material is taken by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 165-190 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, organosilane cross-linked poly-ethylene cable material finished product.
Beneficial effect
CABLE MATERIALS of the present invention not only has excellent flame retardancy and not flame-retarding power; During burning, the amount of being fuming is considerably less simultaneously, does not produce toxic gas, does not produce corrosive gases, and can form hard housing after burning simultaneously, not coming off, protecting the cable by burning not to be damaged, and ensures to transmit electricity normally.
Embodiment
A kind of Ceramic silicone rubber cable material, prepared by the component raw material of following weight (kg) and obtain:
Silicon rubber 88, natural rubber 15, mineral silicate 25, antimonous oxide 12, ammonium polyphosphate 16, zinc oxide 5, antioxidant D TPD1, spray carbon black 25, light calcium carbonate 18, hypo-aluminum orthophosphate 15, calcium stearate 1, tetramethylolmethane 2, talcum powder 1, modified filler 13.
Wherein, modified filler is prepared by following method and obtains:
Diatomite is calcined 3.5 hours at 540 DEG C, after taking-up, add in the sodium hydroxide solution of 3% and grind 1.5 hours, then, add the hydrochloric acid soln of 13%, adjustment pH value is 4-5, ageing 12 hours, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the camphor essential oil being equivalent to powder weight 1% is added in gained powder, the nano-sized carbon of 1%, 2% hypo-aluminum orthophosphate, co-ground is after 1.5 hours, add the 3-aminopropyl trimethoxysilane being equivalent to powder weight 2% again, 4.5% poly(oxyethylene glycol) 400, the morpholine of 2%, the high speed dispersion of 13000 revs/min is even, obtain.
The preparation method of Ceramic silicone rubber cable material:
Each component raw material is taken by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 165-190 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, organosilane cross-linked poly-ethylene cable material finished product.
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:
Claims (2)
1. a Ceramic silicone rubber cable material, it is characterized in that, prepared by the component raw material of following weight part and obtain: silicon rubber 80-90, natural rubber 10-20, mineral silicate 20-30, antimonous oxide 10-15, ammonium polyphosphate 10-20, zinc oxide 4-6, antioxidant D TPD1-2, spray carbon black 20-30, light calcium carbonate 10-20, hypo-aluminum orthophosphate 14-16, calcium stearate 1-2, tetramethylolmethane 1-2, talcum powder 1-2, modified filler 12-14;
Described modified filler is prepared by following method and obtains: diatomite is calcined at 500-550 DEG C 3-4 hour, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the camphor essential oil being equivalent to powder weight 1-2% is added in gained powder, the nano-sized carbon of 1-2%, 2-3% hypo-aluminum orthophosphate, after co-ground 1-2 hour, add the 3-aminopropyl trimethoxysilane being equivalent to powder weight 2-3% again, 4-5% poly(oxyethylene glycol) 400, the morpholine of 2-3%, the high speed dispersion of 12000-15000 rev/min is even, obtain.
2. Ceramic silicone rubber cable material according to claim 1, it is characterized in that, prepared by the component raw material of following weight part and obtain: silicon rubber 88, natural rubber 15, mineral silicate 25, antimonous oxide 12, ammonium polyphosphate 16, zinc oxide 5, antioxidant D TPD1, spray carbon black 25, light calcium carbonate 18, hypo-aluminum orthophosphate 15, calcium stearate 1, tetramethylolmethane 2, talcum powder 1, modified filler 13.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310463784.7A CN103525092B (en) | 2013-09-30 | 2013-09-30 | A kind of Ceramic silicone rubber cable material and preparation method thereof |
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| CN201310463784.7A CN103525092B (en) | 2013-09-30 | 2013-09-30 | A kind of Ceramic silicone rubber cable material and preparation method thereof |
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| CN103525092A CN103525092A (en) | 2014-01-22 |
| CN103525092B true CN103525092B (en) | 2016-03-30 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194190A (en) * | 2014-07-29 | 2014-12-10 | 池州瑞祥钙业有限公司 | Anti-ageing modified light calcium carbonate filler and preparation method thereof |
| CN104310937B (en) * | 2014-10-15 | 2016-06-15 | 傲优新材料科技（上海）有限公司 | Ceramic silicon rubber and its preparation method and application |
| CN104292837A (en) * | 2014-10-27 | 2015-01-21 | 安徽锐视光电技术有限公司 | High-elasticity synthetic rubber for color selector and preparation method thereof |
| CN105968427A (en) * | 2016-03-14 | 2016-09-28 | 安徽电缆股份有限公司 | An insulating rubber cable sheath |
| CN106009695A (en) * | 2016-06-25 | 2016-10-12 | 陈毅忠 | Preparation method of high-strength ceramic silicone rubber |
| CN106380852A (en) * | 2016-09-21 | 2017-02-08 | 苏州直角新材料有限公司 | Flame-retardant and heat-resisting nano silicone rubber and preparation method thereof |
| CN111690215A (en) * | 2020-06-24 | 2020-09-22 | 温州网牌电线电缆有限公司 | Flame-retardant cable sheath and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55113619A (en) * | 1979-02-17 | 1980-09-02 | Okayamaken | Manufacture of calcium carbonate covered with silicon dioxide |
| CN102757651A (en) * | 2012-06-12 | 2012-10-31 | 安徽华海特种电缆集团有限公司 | Silicone rubber insulating fluororubber cable material and preparation method thereof |
| CN103289149A (en) * | 2013-05-06 | 2013-09-11 | 安徽格林生态高分子材料技术有限公司 | Modified nitrile rubber-containing cable sheath material and preparation method thereof |
-
2013
- 2013-09-30 CN CN201310463784.7A patent/CN103525092B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55113619A (en) * | 1979-02-17 | 1980-09-02 | Okayamaken | Manufacture of calcium carbonate covered with silicon dioxide |
| CN102757651A (en) * | 2012-06-12 | 2012-10-31 | 安徽华海特种电缆集团有限公司 | Silicone rubber insulating fluororubber cable material and preparation method thereof |
| CN103289149A (en) * | 2013-05-06 | 2013-09-11 | 安徽格林生态高分子材料技术有限公司 | Modified nitrile rubber-containing cable sheath material and preparation method thereof |
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Effective date of registration: 20191206 Address after: 528000 one of the 28 development road of new Kau neighborhood committee of Daliang sub district office, Shunde District, Foshan, Guangdong Patentee after: GUANGDONG XINCHENG SILICONE INDUSTRY Co.,Ltd. Address before: 236 800 Haijing Building, Baocheng District, Bozhou City, Anhui Province, 3 buildings 207 Patentee before: BOZHOU WOYE INTELLECTUAL PROPERTY SERVICE Co.,Ltd. |
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