CN103571087B - A kind of environmental protection filled cable material - Google Patents
A kind of environmental protection filled cable material Download PDFInfo
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- CN103571087B CN103571087B CN201310464262.9A CN201310464262A CN103571087B CN 103571087 B CN103571087 B CN 103571087B CN 201310464262 A CN201310464262 A CN 201310464262A CN 103571087 B CN103571087 B CN 103571087B
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Abstract
The invention provides a kind of environmental protection filled cable material, be made up of the raw material of following weight part: polyvinyl chloride (PVC) RESINS 80-90, stabilizer 5-8, modifier CPE? 1-2, barium stearate 1-2, light calcium carbonate 40-50, hollow glass microbead 10-15, talcum powder 5-8, molybdenum oxide 4-5, cupric oxide 3-4, tributyl citrate 50-60, calcium stearate 0.1-1, nanometer jade powder 5-6, tripoly phosphate sodium STPP 15-25, PE wax 0.5-1.0, urotropine 1-2, modified filler 12-15.Environmental protection stopping composition of the present invention has environmental protection, good, high temperature resistant, the low cigarette of flame retardant properties, easily peels off, consistency is good, forming.Preparation method is simple, is convenient to suitability for industrialized production, and the environmental protection filled cable material steady quality produced, cost is low.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of environmental protection filled cable material and preparation method thereof.
Background technology
Along with the fast development of global economy, and the enhancing of mankind's environmental consciousness, the requirement of each field to the quality and performance of electric wire is more and more higher, because of electric wire, cable aging and fire that is that cause also gets more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the production of current halide-free low-smoke fireproof cable material is in polyolefin substrate, add a large amount of magnesium hydroxides or magnesium hydroxide to reach flame retardant effect mostly, but, adding of a large amount of inorganic materials, have impact on physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, its at normal temperatures softness, weathering resistance poor, oil-proofness, resistance to low temperature be not fine.
Summary of the invention
The invention provides a kind of environmental protection filled cable material and preparation method thereof.
The technical solution used in the present invention is:
A kind of environmental protection filled cable material, is characterized in that: be made up of the raw material of following weight part: polyvinyl chloride (PVC) RESINS 80-90, stabilizer 5-8, modifier CPE 1-2, barium stearate 1-2, light calcium carbonate 40-50, hollow glass microbead 10-15, talcum powder 5-8, molybdenum oxide 4-5, cupric oxide 3-4, tributyl citrate 50-60, calcium stearate 0.1-1, nanometer jade powder 5-6, tripoly phosphate sodium STPP 15-25, PE wax 0.5-1.0, urotropine 1-2, modified filler 12-15.
Described environmental protection filled cable material, it is characterized in that, be made up of the raw material of following weight: polyvinyl chloride (PVC) RESINS 88, stabilizer 6, modifier CPE 1, barium stearate 2, light calcium carbonate 43, hollow glass microbead 12, talcum powder 7, molybdenum oxide 5, cupric oxide 3, tributyl citrate 55, calcium stearate 0.5, nanometer jade powder 6, tripoly phosphate sodium STPP 18, PE wax 0.6, urotropine 1, modified filler 14.
Described environmental protection filled cable material, is characterized in that, described modified filler is prepared by following method and obtains:
Zeolite is calcined 3-4 hour at 500-550 DEG C, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the sandalwood essential oil being equivalent to powder weight 1-2% is added in gained powder, 4-5% nanometer jade powder, the zinc palmitate of 1-2%, the calcium stearate of 1-2%, after co-ground 1-2 hour, add the Union carbide A-162 being equivalent to powder weight 2-3% again, 2-3% polyethylene glycol 6000, the morpholine of 2-3%, the high speed dispersion of 10000-13000 rev/min is even, obtain.
Each component raw material is taken by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 150-180 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, i.e. obtained environmental protection filled cable material finished product.
Beneficial effect
Environmental protection stopping composition of the present invention has environmental protection, good, high temperature resistant, the low cigarette of flame retardant properties, easily peels off, consistency is good, forming.Preparation method is simple, is convenient to suitability for industrialized production, and the environmental protection filled cable material steady quality produced, cost is low.
Embodiment
Environmental protection filled cable material, be made up of the raw material of following weight (kg):
Polyvinyl chloride (PVC) RESINS 88, stabilizer 6, modifier CPE 1, barium stearate 2, light calcium carbonate 43, hollow glass microbead 12, talcum powder 7, molybdenum oxide 5, cupric oxide 3, tributyl citrate 55, calcium stearate 0.5, nanometer jade powder 6, tripoly phosphate sodium STPP 18, PE wax 0.6, urotropine 1, modified filler 14.
The preparation method of CABLE MATERIALS of the present invention:
Each component raw material is taken by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 150-180 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, i.e. obtained environmental protection filled cable material finished product.
Wherein, modified filler is prepared by following method and obtains:
Zeolite is calcined 4 hours at 520 DEG C, after taking-up, add in the sodium hydroxide solution of 4% and grind 1.5 hours, then, add the hydrochloric acid soln of 15%, pH value is regulated to be 4, ageing 12 hours, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the sandalwood essential oil being equivalent to powder weight 1% is added in gained powder, 4.5% nanometer jade powder, the zinc palmitate of 2%, the calcium stearate of 1%, co-ground is after 2 hours, add the Union carbide A-162 being equivalent to powder weight 3% again, 2% polyethylene glycol 6000, the morpholine of 2%, the high speed dispersion of 10000-13000 rev/min is even, obtain.。
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:
Claims (2)
1. an environmental protection filled cable material, is characterized in that: be made up of the raw material of following weight part: polyvinyl chloride (PVC) RESINS 80-90, stabilizer 5-8, modifier CPE 1-2, barium stearate 1-2, light calcium carbonate 40-50, hollow glass microbead 10-15, talcum powder 5-8, molybdenum oxide 4-5, cupric oxide 3-4, tributyl citrate 50-60, calcium stearate 0.1-1, nanometer jade powder 5-6, tripoly phosphate sodium STPP 15-25, PE wax 0.5-1.0, urotropine 1-2, modified filler 12-15;
Described modified filler is prepared by following method and obtains:
Zeolite is calcined 3-4 hour at 500-550 DEG C, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the sandalwood essential oil being equivalent to powder weight 1-2% is added in gained powder, 4-5% nanometer jade powder, the zinc palmitate of 1-2%, the calcium stearate of 1-2%, after co-ground 1-2 hour, add the Union carbide A-162 being equivalent to powder weight 2-3% again, 2-3% polyethylene glycol 6000, the morpholine of 2-3%, the high speed dispersion of 10000-13000 rev/min is even, obtain,
Each component raw material is taken by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 150-180 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, i.e. obtained environmental protection filled cable material finished product.
2. environmental protection filled cable material according to claim 1, it is characterized in that, be made up of the raw material of following weight: polyvinyl chloride (PVC) RESINS 88, stabilizer 6, modifier CPE 1, barium stearate 2, light calcium carbonate 43, hollow glass microbead 12, talcum powder 7, molybdenum oxide 5, cupric oxide 3, tributyl citrate 55, calcium stearate 0.5, nanometer jade powder 6, tripoly phosphate sodium STPP 18, PE wax 0.6, urotropine 1, modified filler 14.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310464262.9A CN103571087B (en) | 2013-09-30 | 2013-09-30 | A kind of environmental protection filled cable material |
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| CN201310464262.9A CN103571087B (en) | 2013-09-30 | 2013-09-30 | A kind of environmental protection filled cable material |
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| CN103571087A CN103571087A (en) | 2014-02-12 |
| CN103571087B true CN103571087B (en) | 2016-03-09 |
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| CN201310464262.9A Active CN103571087B (en) | 2013-09-30 | 2013-09-30 | A kind of environmental protection filled cable material |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861387A (en) * | 2015-04-28 | 2015-08-26 | 安徽顺驰电缆有限公司 | Novel cable stuffing material |
| CN105419165A (en) * | 2015-12-29 | 2016-03-23 | 王丽萍 | Cable filling material with water resistant effect |
| CN105482183A (en) * | 2015-12-29 | 2016-04-13 | 王璐 | Safe and environment-friendly cable filling material |
| CN108841196A (en) * | 2018-06-12 | 2018-11-20 | 杨杰 | A kind of Halogen-free low-smoke flame-retardant TPE cable material and preparation method |
| CN116396569A (en) * | 2023-06-08 | 2023-07-07 | 山东宏福化学有限公司 | Preparation method of PVC impact modifier |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481480A (en) * | 2009-01-24 | 2009-07-15 | 正威科技（深圳）有限公司 | Waterproof cold resistant heatproof flame-retardant polychloroethylene insulation material |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977280B2 (en) * | 2003-06-11 | 2005-12-20 | Teknor Apex Company | Polyvinyl chloride or polyolefin melt processable compositions containing polytetrafluoroethylene micropowder |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481480A (en) * | 2009-01-24 | 2009-07-15 | 正威科技（深圳）有限公司 | Waterproof cold resistant heatproof flame-retardant polychloroethylene insulation material |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
Non-Patent Citations (2)
| Title |
|---|
| "Mica-Filled PVC Composites:Effect of Particle Size, Filler Concentration, and Surface Treatment of the Filler, on Mechanical and Electrical Properties of the Composites";S.P.Deshmukh等;《Journal of Thermoplastic Composite Materials》;20101231;第24卷(第5期);第583-599页 * |
| "煅烧陶土在聚氯乙烯电缆料中的应用";张尔梅;《聚氯乙烯》;19810630(第3期);第13-16页 * |
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