CN103524845B - A kind of halogen-free flame-retardant thermoplastic polyolefin cable - Google Patents
A kind of halogen-free flame-retardant thermoplastic polyolefin cable Download PDFInfo
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- CN103524845B CN103524845B CN201310461375.3A CN201310461375A CN103524845B CN 103524845 B CN103524845 B CN 103524845B CN 201310461375 A CN201310461375 A CN 201310461375A CN 103524845 B CN103524845 B CN 103524845B
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- retardant
- fire retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 23
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 12
- 229920002397 thermoplastic olefin Polymers 0.000 title abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims abstract description 6
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims abstract description 6
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 6
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 6
- 235000011187 glycerol Nutrition 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 6
- 150000003014 phosphoric acid esters Chemical class 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 6
- 229920003987 resole Polymers 0.000 claims abstract description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 β-chloropropyl Chemical group 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 241000221035 Santalaceae Species 0.000 claims description 3
- 235000008632 Santalum album Nutrition 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 239000010977 jade Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229940093429 polyethylene glycol 6000 Drugs 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- 239000000341 volatile oil Substances 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 229940012185 zinc palmitate Drugs 0.000 claims description 3
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- 239000000779 smoke Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002485 combustion reaction Methods 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 abstract description 2
- 239000002574 poison Substances 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a kind of halogen-free flame-retardant thermoplastic polyolefin cable, be made up of the raw material of following weight part: polyvinyl resin 20-30, resol 10-15, E-12 epoxy resin 10-20, ethylene copolymer 20-30, ammonium polyphosphate 10-15, zinc borate 5-10, three TCPP fire retardant three (β-chloropropyl) phosphoric acid ester 5-10, tributyl citrate 10-14, calcinated argil 4-5, plam oil 10-15, glycerine 5-7,3-aminopropyl trimethoxysilane 5-8, dihydroxyphenyl propane? 2-3, hypo-aluminum orthophosphate 12-15, tetrafluoroethylene 1-2, modified filler 7-9.Fire retardant in cable material formula of the present invention is by borate family fire retardant and phosphor nitrogen combustion inhibitor is composite forms, adding a small amount of retardant synergist just makes CABLE MATERIALS have good flame retardant effect and excellent smoke suppressing effect, and the smoke density of this CABLE MATERIALS is low, poison exponent is low.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of halogen-free flame-retardant thermoplastic polyolefin cable.
Background technology
Along with the fast development of global economy, and the enhancing of mankind's environmental consciousness, the requirement of each field to the quality and performance of electric wire is more and more higher, because of electric wire, cable aging and fire that is that cause also gets more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the production of current halide-free low-smoke fireproof cable material is in polyolefin substrate, add a large amount of magnesium hydroxides or magnesium hydroxide to reach flame retardant effect mostly, but, adding of a large amount of inorganic materials, have impact on physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, its at normal temperatures softness, weathering resistance poor, oil-proofness, resistance to low temperature be not fine.
Summary of the invention
The invention provides a kind of halogen-free flame-retardant thermoplastic polyolefin cable.
The technical solution used in the present invention is:
A kind of halogen-free flame-retardant thermoplastic polyolefin cable, is characterized in that: be made up of the raw material of following weight part: polyvinyl resin 20-30, resol 10-15, E-12 epoxy resin 10-20, ethylene copolymer 20-30, ammonium polyphosphate 10-15, zinc borate 5-10, three TCPP fire retardant three (β-chloropropyl) phosphoric acid ester 5-10, tributyl citrate 10-14, calcinated argil 4-5, plam oil 10-15, glycerine 5-7,3-aminopropyl trimethoxysilane 5-8, dihydroxyphenyl propane 2-3, hypo-aluminum orthophosphate 12-15, tetrafluoroethylene 1-2, modified filler 7-9.
Described halogen-free flame-retardant thermoplastic polyolefin cable, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl resin 28, resol 14, E-12 epoxy resin 16, ethylene copolymer 25, ammonium polyphosphate 14, zinc borate 8, three TCPP fire retardant three (β-chloropropyl) phosphoric acid ester 6, tributyl citrate 13, calcinated argil 5, plam oil 12, glycerine 6,3-aminopropyl trimethoxysilane 6, dihydroxyphenyl propane 3, hypo-aluminum orthophosphate 14, tetrafluoroethylene 1, modified filler 8.
Described halogen-free flame-retardant thermoplastic polyolefin cable, is characterized in that, described modified filler is prepared by following method and obtains:
Zeolite is calcined 3-4 hour at 500-550 DEG C, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjustment pH value is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the sandalwood essential oil being equivalent to powder weight 1-2% is added in gained powder, 4-5% nanometer jade powder, the zinc palmitate of 1-2%, the calcium stearate of 1-2%, after co-ground 1-2 hour, add the Union carbide A-162 being equivalent to powder weight 2-3% again, 2-3% polyethylene glycol 6000, the morpholine of 2-3%, the high speed dispersion of 10000-13000 rev/min is even, obtain.
Take each component raw material by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 145-175 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, and namely obtains CABLE MATERIALS finished product.
Beneficial effect
Fire retardant in cable material formula of the present invention is by borate family fire retardant and phosphor nitrogen combustion inhibitor is composite forms, adding a small amount of retardant synergist just makes CABLE MATERIALS have good flame retardant effect and excellent smoke suppressing effect, and the smoke density of this CABLE MATERIALS is low, poison exponent is low.
Embodiment
Halogen-free flame-retardant thermoplastic polyolefin cable, be made up of the raw material of following weight (kg):
Polyvinyl resin 28, resol 14, E-12 epoxy resin 16, ethylene copolymer 25, ammonium polyphosphate 14, zinc borate 8, three TCPP fire retardant three (β-chloropropyl) phosphoric acid ester 6, tributyl citrate 13, calcinated argil 5, plam oil 12, glycerine 6,3-aminopropyl trimethoxysilane 6, dihydroxyphenyl propane 3, hypo-aluminum orthophosphate 14, tetrafluoroethylene 1, modified filler 8.
The preparation method of CABLE MATERIALS of the present invention:
Take each component raw material by formula rate, by the component raw material taken, stir in high-speed mixer, again under the temperature range of 145-175 DEG C through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, and namely obtains CABLE MATERIALS finished product.
Wherein, modified filler is prepared by following method and obtains:
Zeolite is calcined 4 hours at 520 DEG C, after taking-up, add in the sodium hydroxide solution of 4% and grind 1.5 hours, then, add the hydrochloric acid soln of 15%, pH value is regulated to be 4, ageing 12 hours, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the sandalwood essential oil being equivalent to powder weight 1% is added in gained powder, 4.5% nanometer jade powder, the zinc palmitate of 2%, the calcium stearate of 1%, co-ground is after 2 hours, add the Union carbide A-162 being equivalent to powder weight 3% again, 2% polyethylene glycol 6000, the morpholine of 2%, the high speed dispersion of 10000-13000 rev/min is even, obtain.
The performance test results of the CABLE MATERIALS that the present embodiment obtains is as following table:
Claims (2)
1. a flame-proofed thermoplastic cable material of polyolefin, is characterized in that: be made up of the raw material of following weight part: polyvinyl resin 20-30, resol 10-15, E-12 epoxy resin 10-20, ethylene copolymer 20-30, ammonium polyphosphate 10-15, zinc borate 5-10, TCPP fire retardant three (β-chloropropyl) phosphoric acid ester 5-10, tributyl citrate 10-14, calcinated argil 4-5, plam oil 10-15, glycerine 5-7,3-aminopropyl trimethoxysilane 5-8, dihydroxyphenyl propane 2-3, hypo-aluminum orthophosphate 12-15, tetrafluoroethylene 1-2, modified filler 7-9;
Described modified filler is prepared by following method and obtains: zeolite is calcined at 500-550 DEG C 3-4 hour, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjust ph is 4-5, ageing 10-15 hour, repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH to be neutral, filter, oven dry obtains filler powder, then, the sandalwood essential oil being equivalent to powder weight 1-2% is added in gained powder, 4-5% nanometer jade powder, the zinc palmitate of 1-2%, the calcium stearate of 1-2%, after co-ground 1-2 hour, add the Union carbide A-162 being equivalent to powder weight 2-3% again, 2-3% polyethylene glycol 6000, the morpholine of 2-3%, the high speed dispersion of 10000-13000 rev/min is even, obtain.
2. flame-proofed thermoplastic cable material of polyolefin according to claim 1, it is characterized in that, prepared by the component raw material of following weight part and obtain: polyvinyl resin 28, resol 14, E-12 epoxy resin 16, ethylene copolymer 25, ammonium polyphosphate 14, zinc borate 8, TCPP fire retardant three (β-chloropropyl) phosphoric acid ester 6, tributyl citrate 13, calcinated argil 5, plam oil 12, glycerine 6,3-aminopropyl trimethoxysilane 6, dihydroxyphenyl propane 3, hypo-aluminum orthophosphate 14, tetrafluoroethylene 1, modified filler 8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310461375.3A CN103524845B (en) | 2013-09-30 | 2013-09-30 | A kind of halogen-free flame-retardant thermoplastic polyolefin cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310461375.3A CN103524845B (en) | 2013-09-30 | 2013-09-30 | A kind of halogen-free flame-retardant thermoplastic polyolefin cable |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103524845A CN103524845A (en) | 2014-01-22 |
| CN103524845B true CN103524845B (en) | 2016-04-13 |
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|---|---|---|---|
| CN201310461375.3A Expired - Fee Related CN103524845B (en) | 2013-09-30 | 2013-09-30 | A kind of halogen-free flame-retardant thermoplastic polyolefin cable |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881291A (en) * | 2014-02-26 | 2014-06-25 | 黄忠娟 | Enhanced flame retardant plastic |
| CN103992541A (en) * | 2014-04-25 | 2014-08-20 | 安徽华鸿电气股份有限公司 | Wear-resistant cable material |
| CN104072848A (en) * | 2014-06-23 | 2014-10-01 | 李雪红 | Polyethylene wear-resistant plastic |
| CN105482203A (en) * | 2015-12-15 | 2016-04-13 | 中冠电缆有限公司 | Modified silicon resin-doped neoprene rubber-based cable material and preparation method thereof |
| CN105542390A (en) * | 2016-01-27 | 2016-05-04 | 安徽卓越电缆有限公司 | Preparation method of heat-resistant and flame-retardant cable insulating material |
| CN106905663A (en) * | 2017-03-24 | 2017-06-30 | 合肥羿振电力设备有限公司 | A kind of cable material and preparation method thereof |
| CN107492410A (en) * | 2017-07-04 | 2017-12-19 | 昆明三川电线电缆有限公司 | A kind of low halogen high temperature-resistant cable |
| CN110335717B (en) * | 2019-08-05 | 2021-04-09 | 江苏耘和线缆有限公司 | Flame-retardant cable and processing method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0212575A2 (en) * | 1985-08-16 | 1987-03-04 | E.I. Du Pont De Nemours And Company | Halogen-free flame resistant thermoplastic compostion |
| CN101143944A (en) * | 2006-09-13 | 2008-03-19 | 中国石油天然气股份有限公司 | Halogen-free expansion fire retardant for polyethylene |
| CN101817952A (en) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | Soft low-smoke halogen-free flame-retardant polyolefin cable material and preparation method thereof |
| CN101831100A (en) * | 2010-04-26 | 2010-09-15 | 大连圣迈新材料有限公司 | Low-smoke halogen-free flame retardant electronic wire material |
| CN102367306A (en) * | 2011-05-17 | 2012-03-07 | 顺德职业技术学院 | High efficiency halogen-free flame retardant polypropylene composite material and its preparation method |
| CN102746612A (en) * | 2012-07-05 | 2012-10-24 | 同济大学 | Preparation method for halogen-free flame-retardant toughened phenolic foamed plastics |
| CN103172918A (en) * | 2011-12-22 | 2013-06-26 | 上海杰事杰新材料(集团)股份有限公司 | Low-smoke halogen-free flame-retardant cable material and preparation method thereof |
-
2013
- 2013-09-30 CN CN201310461375.3A patent/CN103524845B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0212575A2 (en) * | 1985-08-16 | 1987-03-04 | E.I. Du Pont De Nemours And Company | Halogen-free flame resistant thermoplastic compostion |
| CN101143944A (en) * | 2006-09-13 | 2008-03-19 | 中国石油天然气股份有限公司 | Halogen-free expansion fire retardant for polyethylene |
| CN101831100A (en) * | 2010-04-26 | 2010-09-15 | 大连圣迈新材料有限公司 | Low-smoke halogen-free flame retardant electronic wire material |
| CN101817952A (en) * | 2010-05-19 | 2010-09-01 | 西安交通大学 | Soft low-smoke halogen-free flame-retardant polyolefin cable material and preparation method thereof |
| CN102367306A (en) * | 2011-05-17 | 2012-03-07 | 顺德职业技术学院 | High efficiency halogen-free flame retardant polypropylene composite material and its preparation method |
| CN103172918A (en) * | 2011-12-22 | 2013-06-26 | 上海杰事杰新材料(集团)股份有限公司 | Low-smoke halogen-free flame-retardant cable material and preparation method thereof |
| CN102746612A (en) * | 2012-07-05 | 2012-10-24 | 同济大学 | Preparation method for halogen-free flame-retardant toughened phenolic foamed plastics |
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| CN103524845A (en) | 2014-01-22 |
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