CN103865286B - A kind of fold resistant, non-whitening CABLE MATERIALS - Google Patents
A kind of fold resistant, non-whitening CABLE MATERIALS Download PDFInfo
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- CN103865286B CN103865286B CN201410106225.5A CN201410106225A CN103865286B CN 103865286 B CN103865286 B CN 103865286B CN 201410106225 A CN201410106225 A CN 201410106225A CN 103865286 B CN103865286 B CN 103865286B
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- cable materials
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- 239000000463 material Substances 0.000 title claims abstract description 21
- 230000002087 whitening effect Effects 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000004113 Sepiolite Substances 0.000 claims abstract description 10
- -1 polybutylene terephthalate Polymers 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 10
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 10
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 10
- 235000006491 Acacia senegal Nutrition 0.000 claims abstract description 7
- 241000978776 Senegalia senegal Species 0.000 claims abstract description 7
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 7
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 claims abstract description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 4
- 239000004593 Epoxy Substances 0.000 claims abstract description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 4
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 4
- 239000008116 calcium stearate Substances 0.000 claims abstract description 4
- 239000004917 carbon fiber Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims abstract description 4
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 4
- 229910052919 magnesium silicate Inorganic materials 0.000 claims abstract description 4
- 235000019792 magnesium silicate Nutrition 0.000 claims abstract description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 4
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 claims abstract description 4
- 235000011006 sodium potassium tartrate Nutrition 0.000 claims abstract description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010276 construction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
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- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of fold resistant, non-whitening CABLE MATERIALS, it is made up of the raw material of following weight parts: thermoplastic elastomer TPE60-65, polybutylene terephthalate 20-30, Sudan Gum-arabic 4-6, epoxy tetrahydro-2-ethylhexyl phthalate 6-10, T800 carbon fiber 3-5, calcium stearate 3-4, PTMG 0.8-1.3, diisononyl phthalate 3-5, Nano sepiolite powder 6-10, Magnesium Silicate q-agent 1-2, clorafin 4-6, Seignette salt 1-2, compounded mix 5-10.CABLE MATERIALS damage resistant of the present invention, fold resistant, the folding and surperficial trace print being not easy appearance white of collision rift, this CABLE MATERIALS is of many uses, may be used for power cable, building line, instrument line etc., has good snappiness and workability.
Description
Technical field
The present invention relates generally to field of cables, particularly relates to a kind of fold resistant, non-whitening CABLE MATERIALS.
Background technology
Along with the fast development of cable cause, high-quality CABLE MATERIALS is subject to increasing favor, high-quality CABLE MATERIALS not only good weatherability, long service life, and safety and environmental protection, therefore pursue the competition that higher-quality CABLE MATERIALS not only can be won the market, also great support and help are served to modernization construction.
Summary of the invention
The object of the invention is just to provide a kind of fold resistant, non-whitening CABLE MATERIALS.
The present invention is achieved by the following technical solutions:
A kind of fold resistant, non-whitening CABLE MATERIALS, it is made up of the raw material of following weight parts:
Thermoplastic elastomer TPE60-65, polybutylene terephthalate 20-30, Sudan Gum-arabic 4-6, epoxy tetrahydro-2-ethylhexyl phthalate 6-10, T800 carbon fiber 3-5, calcium stearate 3-4, PTMG 0.8-1.3, diisononyl phthalate 3-5, Nano sepiolite powder 6-10, Magnesium Silicate q-agent 1-2, clorafin 4-6, Seignette salt 1-2, compounded mix 5-10;
Described compounded mix is made up of the raw material of following weight parts:
Linear low density polyethylene 25-30, sepiolite powder 10-16, pentaerythritol triacrylate 2-3, light calcium carbonate 5-10, aluminium dihydrogen phosphate 2-3, tetrafluoroethylene 3-5, polydimethylsiloxane 1-2;
By above-mentioned linear low density polyethylene, sepiolite powder mixing, stirring heating 4-10 minute at 500-600 DEG C, is cooled to normal temperature, add tetrafluoroethylene, ball grinding stirring mixing 6-8 minute, obtains Preblend, by above-mentioned light calcium carbonate, aluminium dihydrogen phosphate mixing, at 60-70 DEG C, be uniformly mixed 3-5 minute, add pentaerythritol triacrylate, be stirred to normal temperature, mix with above-mentioned Preblend, add each raw material of residue, stir post-drying, grinding, obtains described compounded mix.
A preparation method for fold resistant, non-whitening CABLE MATERIALS, comprises the following steps:
Be mixed to join in high-speed mixer by above-mentioned thermoplastic elastomer TPE, polybutylene terephthalate, then add Sudan Gum-arabic, high-speed mixing 15-20 minute, add each raw material of residue, melt extrude, cooling, granulation, obtain described CABLE MATERIALS.
Advantage of the present invention is:
CABLE MATERIALS damage resistant of the present invention, fold resistant, the folding and surperficial trace print being not easy appearance white of collision rift, this CABLE MATERIALS is of many uses, may be used for power cable, building line, instrument line etc., has good snappiness and workability.
Embodiment
Embodiment 1
A kind of fold resistant, non-whitening CABLE MATERIALS, it is made up of the raw material of following weight parts (kilogram):
Thermoplastic elastomer TPE65, polybutylene terephthalate 30, Sudan Gum-arabic 6, epoxy tetrahydro-2-ethylhexyl phthalate 10, T800 carbon fiber 5, calcium stearate 4, PTMG 1.3, diisononyl phthalate 5, Nano sepiolite powder 10, Magnesium Silicate q-agent 1, clorafin 6, Seignette salt 1, compounded mix 10;
Described compounded mix is made up of the raw material of following weight parts:
Linear low density polyethylene 30, sepiolite powder 16, pentaerythritol triacrylate 3, light calcium carbonate 10, aluminium dihydrogen phosphate 2, tetrafluoroethylene 3, polydimethylsiloxane 1;
By above-mentioned linear low density polyethylene, sepiolite powder mixing, at 600 DEG C, stirring heating 10 minutes, is cooled to normal temperature, add tetrafluoroethylene, ball grinding stirring mixes 8 minutes, obtains Preblend, by above-mentioned light calcium carbonate, aluminium dihydrogen phosphate mixing, at 70 DEG C, be uniformly mixed 3 minutes, add pentaerythritol triacrylate, be stirred to normal temperature, mix with above-mentioned Preblend, add each raw material of residue, stir post-drying, grinding, obtains described compounded mix.
A preparation method for fold resistant, non-whitening CABLE MATERIALS, comprises the following steps:
Be mixed to join in high-speed mixer by above-mentioned thermoplastic elastomer TPE, polybutylene terephthalate, then add Sudan Gum-arabic, high-speed mixing 20 minutes, add each raw material of residue, melt extrude, cooling, granulation, obtain described CABLE MATERIALS.
Performance test:
Tensile strength: >=18MPa;
Elongation at break: >=360%;
Thermal shocking: 180 ± 1 DEG C/1h, do not ftracture;
Clod wash :-20 ± 2 DEG C/4h, do not ftracture.
Claims (2)
1. fold resistant, a non-whitening CABLE MATERIALS, is characterized in that what it was made up of the raw material of following weight parts:
Thermoplastic elastomer TPE60-65, polybutylene terephthalate 20-30, Sudan Gum-arabic 4-6, epoxy tetrahydro-2-ethylhexyl phthalate 6-10, T800 carbon fiber 3-5, calcium stearate 3-4, PTMG 0.8-1.3, diisononyl phthalate 3-5, Nano sepiolite powder 6-10, Magnesium Silicate q-agent 1-2, clorafin 4-6, Seignette salt 1-2, compounded mix 5-10;
Described compounded mix is made up of the raw material of following weight parts:
Linear low density polyethylene 25-30, sepiolite powder 10-16, pentaerythritol triacrylate 2-3, light calcium carbonate 5-10, aluminium dihydrogen phosphate 2-3, tetrafluoroethylene 3-5, polydimethylsiloxane 1-2;
By above-mentioned linear low density polyethylene, sepiolite powder mixing, stirring heating 4-10 minute at 500-600 DEG C, is cooled to normal temperature, add tetrafluoroethylene, ball grinding stirring mixing 6-8 minute, obtains Preblend, by above-mentioned light calcium carbonate, aluminium dihydrogen phosphate mixing, at 60-70 DEG C, be uniformly mixed 3-5 minute, add pentaerythritol triacrylate, be stirred to normal temperature, mix with above-mentioned Preblend, add each raw material of residue, stir post-drying, grinding, obtains described compounded mix.
2. a preparation method for fold resistant as claimed in claim 1, non-whitening CABLE MATERIALS, is characterized in that comprising the following steps:
Be mixed to join in high-speed mixer by above-mentioned thermoplastic elastomer TPE, polybutylene terephthalate, then add Sudan Gum-arabic, high-speed mixing 15-20 minute, add each raw material of residue, melt extrude, cooling, granulation, obtain described CABLE MATERIALS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410106225.5A CN103865286B (en) | 2014-03-19 | 2014-03-19 | A kind of fold resistant, non-whitening CABLE MATERIALS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410106225.5A CN103865286B (en) | 2014-03-19 | 2014-03-19 | A kind of fold resistant, non-whitening CABLE MATERIALS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103865286A CN103865286A (en) | 2014-06-18 |
| CN103865286B true CN103865286B (en) | 2016-02-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410106225.5A Active CN103865286B (en) | 2014-03-19 | 2014-03-19 | A kind of fold resistant, non-whitening CABLE MATERIALS |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104927385A (en) * | 2015-06-16 | 2015-09-23 | 安徽天元电缆有限公司 | High-strength cable material for power cables and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604260A (en) * | 2012-02-25 | 2012-07-25 | 安徽电缆股份有限公司 | Improved flexible polyvinyl chloride sheath cable material and preparation method thereof |
| CN102964699A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Incinerated pottery clay modified ethylene propylene diene copolymer cable material |
| CN103509274A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof |
| CN103524913A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62295948A (en) * | 1986-06-17 | 1987-12-23 | Idemitsu Petrochem Co Ltd | Polyester resin composition |
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2014
- 2014-03-19 CN CN201410106225.5A patent/CN103865286B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604260A (en) * | 2012-02-25 | 2012-07-25 | 安徽电缆股份有限公司 | Improved flexible polyvinyl chloride sheath cable material and preparation method thereof |
| CN102964699A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Incinerated pottery clay modified ethylene propylene diene copolymer cable material |
| CN103509274A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Oil-resistant cold-resistant ultraviolet-proof polyvinyl chloride/nitrile rubber composite cable material and preparation method thereof |
| CN103524913A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material |
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| CN103865286A (en) | 2014-06-18 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Folding-resistant and non-blanching cable material Effective date of registration: 20190428 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: Anhui Cable Co., Ltd. Registration number: 2019340000222 |
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Date of cancellation: 20200415 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: 2019340000222 |
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Denomination of invention: Folding-resistant and non-blanching cable material Effective date of registration: 20200421 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co., Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2020980001678 |
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Date of cancellation: 20210414 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2020980001678 |
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Denomination of invention: A folding resistant and non whitening cable material Effective date of registration: 20210416 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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Date of cancellation: 20220408 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2021980002725 |
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Denomination of invention: A folding resistant and non whitening cable material Effective date of registration: 20220414 Granted publication date: 20160224 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2022980004178 |