CN106432954A - Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material - Google Patents

Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material Download PDF

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Publication number
CN106432954A
CN106432954A CN201610847860.8A CN201610847860A CN106432954A CN 106432954 A CN106432954 A CN 106432954A CN 201610847860 A CN201610847860 A CN 201610847860A CN 106432954 A CN106432954 A CN 106432954A
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parts
flame
powder
cable material
resistant
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CN201610847860.8A
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高团结
李万敏
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention provides a flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material. The cable material is prepared from, by weight, 100 parts of polyvinyl chloride SG-3, 10-20 parts of butadiene-acrylonitrile rubber N26, 10-15 parts of polycarbonate, 10-15 parts of polyethylene glycol terephthalate-1,4-cyclohexanedimethanol terephthalate, 15-20 parts of silane coupling agent, 30-40 parts of bisphenol A diphosphate, 20-30 parts of calcium carbonate, 1-2 parts of calcium silicate, 30-50 parts of barium stearate, 10-15 parts of cresyl diphenyl phosphate, 3-4 parts of glycerol trioleate, 2-3 parts of cross-linking agent TAIC, 2-3 parts of stearic acid, 1-2 parts of N,N-m-phenylenedimaleimide, 5-8 parts of texanol, 0.5-1.0 part of PE wax, 1-2 parts of aluminum nitride, 1-2 parts of jade powder and 8-10 parts of modified filler. The flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material has the advantages of being retardant to flame, resistant to oil and ageing, resistant to acid and alkali, low in specific gravity and low in manufacturing cost.

Description

A kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material
Technical field
The present invention relates to CABLE MATERIALS field and in particular to a kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material and its Preparation method.
Background technology
With the fast development of global economy, and the enhancing of mankind's environmental consciousness, each field to the quality of electric wire and How the requirement more and more higher of performance, because electric wire, cable aging and fire that cause also get more and more, reduce the generation of fire Rate and occur fire when the death rate, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein The demand of halide-free low-smoke fireproof cable material is increasing, and the production of current halide-free low-smoke fireproof cable material is in polyolefin mostly Substantial amounts of magnesium hydroxide or magnesium hydroxide is added to reach flame retardant effect in base material, however, the addition of a large amount of inorganic material, impact The physical and mechanical properties of CABLE MATERIALS and process industrial art performance, softness, against weather be poor at normal temperatures for it, oil resistivity, resistance to Cryogenic property is not fine.
Content of the invention
A kind of the invention aims to solve above-mentioned technical problem, the invention provides the ageing-resistant thermoplastic of Flame-Retardant and Oil-Resistant Property elastomer cable material.
In order to realize above-mentioned technical purpose, reach above-mentioned technical requirements, the technical solution used in the present invention is：A kind of resistance Combustion the ageing-resistant thermoplastic elastomer cable material of oil resistant it is characterised in that：It is prepared by the raw materials in：Polyvinyl chloride SG- 3100th, NBR N2610-20, Merlon 10-15, polyethylene terephthalate -1,4 cyclohexane dimethanol ester 10- 15th, silane coupler 15-20, tetraphenyl-(bisphenol-A) bisphosphate 30-40, calcium carbonate 20-30, calcium silicates 1-2, stearic acid Barium 30-50, phosphate toluene diphenyl ester 10-15, glycerine glycerinate 3-4, crosslinking agent TAIC2-3, stearic acid, 2-3, N, N A '-penylene BMI 1-2, alcohol ester 12 5-8, PE wax 0.5-1.0, aluminum nitride powder 1-2, jade powder 1-2, modification are filled out Material 8-10.
Described Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material is it is characterised in that component by following weight portion Raw material is prepared：Polyvinyl chloride SG-3100, NBR N2615, Merlon 12, polyethylene terephthalate -1,4- Cyclohexanedimethanoester ester 2, silane coupler 18, tetraphenyl-(bisphenol-A) bisphosphate 35, calcium carbonate 25, calcium silicates 2, tristearin Sour barium 35, phosphate toluene diphenyl ester 12, glycerine glycerinate 3, crosslinking agent TAIC2, stearic acid, 2, N, a N '-penylene is double Maleimide 1, alcohol ester 12, PE wax 0.8, aluminum nitride powder 1, jade powder 2, modified filler 9.
Described Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material is it is characterised in that described modified filler is logical Cross following method to be prepared：Attapulgite is calcined 3-4 hour at 540-580 DEG C, after taking-up, adds the hydroxide of 3-4% Grind 1-2 hour in sodium solution, then, add the hydrochloric acid solution of 12-15%, regulation pH value is 4-5, is aged 10-15 hour, then It is neutrality that hydro-oxidation sodium solution adjusts lapping liquid pH, filters, and dries and obtains filler powder, then adds phase in gained powder When in the tea tree ethereal oil of powder weight 1-2%, the zinc oxide of 1-2%, the pentaerythrite of 1-2%, 2-3% nanometer jade powder, jointly grind After mill 1-2 hour, add and be equivalent to the aminopropyl triethoxysilane of powder weight 2-3%, 4-5% Macrogol 6000,2- 3% morpholine, is uniformly dispersed with 11000-12000 rev/min of high speed, obtains final product.
Weigh each component raw material by formula rate, the component raw material weighing stirs in high-speed mixer, then Through banbury banburying, twin-screw extrusion under 115-145 DEG C of temperature range, flour milling earnestly granulates, cyclopneumatic separator feeding, vibration Sieve screening and then packaging, that is, be obtained CABLE MATERIALS finished product.
This Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material has the characteristics that fire-retardant, oil resistant, ageing-resistant, acid and alkali-resistance, and compares Weight is relatively low, cheap.
Specific embodiment
Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material, by following weight（kg）Raw material make：
Polyvinyl chloride SG-3100, NBR N2615, Merlon 12, polyethylene terephthalate -1,4- hexamethylene two Methyl alcohol ester 2, silane coupler 18, tetraphenyl-(bisphenol-A) bisphosphate 35, calcium carbonate 25, calcium silicates 2, barium stearate 35, phosphorus Sour toluene diphenyl ester 12, glycerine glycerinate 3, crosslinking agent TAIC2, stearic acid, 2, N, a N '-penylene BMI 1st, alcohol ester 12, PE wax 0.8, aluminum nitride powder 1, jade powder 2, modified filler 9,
Wherein, modified filler is to be prepared by following method：
Attapulgite is calcined 3-4 hour at 540-580 DEG C, after taking-up, adds and in the sodium hydroxide solution of 3-4%, grind 1-2 Hour, then, add the hydrochloric acid solution of 12-15%, regulation pH value is 4-5, is aged 10-15 hour, and repeated hydrogenation sodium hydroxide solution is adjusted Section lapping liquid pH is neutrality, filters, and dries and obtains filler powder, then adds in gained powder and is equivalent to powder weight 1-2% Tea tree ethereal oil, the zinc oxide of 1-2%, the pentaerythrite of 1-2%, 2-3% nanometer jade powder, after co-ground 1-2 hour, then plus Enter to be equivalent to the aminopropyl triethoxysilane of powder weight 2-3%, 4-5% Macrogol 6000, the morpholine of 2-3%, with 11000- 12000 revs/min of high speed is uniformly dispersed, and obtains final product.
The preparation method of finished cable material：
Weigh each component raw material by formula rate, the component raw material weighing stirs in high-speed mixer, then in 115- Through banbury banburying, twin-screw extrusion under 145 DEG C of temperature range, flour milling earnestly granulates, cyclopneumatic separator feeding, Vibration Screen Divide and then pack, that is, CABLE MATERIALS finished product is obtained.Above-described embodiment is only used for that the present invention will be described, and not constituting will to right Ask the restriction of scope, it may occur to persons skilled in the art that other alternative means, all within the scope of the invention as claimed.

Claims (3)

1. a kind of Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material it is characterised in that：It is prepared by the raw materials in： Polyvinyl chloride SG-3 100, NBR N26 10-20, Merlon 10-15, polyethylene terephthalate -1,4- hexamethylene Alkane diformazan alcohol ester 10-15, silane coupler 15-20, tetraphenyl-(bisphenol-A) bisphosphate 30-40, calcium carbonate 20-30, Calcium silicates 1-2, barium stearate 30-50, phosphate toluene diphenyl ester 10-15, glycerine glycerinate 3-4, crosslinking agent TAIC2- 3rd, stearic acid 2-3, N, a N '-penylene BMI 1-2, alcohol ester 12 5-8, PE wax 0.5-1.0, aluminum nitride powder 1-2, jade Stone flour 1-2, modified filler 8-10.
2. Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material according to claim 1 is it is characterised in that by following heavy The component raw material of amount part is prepared：Polyvinyl chloride SG-3 100, NBR N26 15, Merlon 12, poly terephthalic acid Glycol ester -1,4 cyclohexane dimethanol ester 2, silane coupler 18, tetraphenyl-(bisphenol-A) bisphosphate 35, carbonic acid Calcium 25, calcium silicates 2, barium stearate 35, phosphate toluene diphenyl ester 12, glycerine glycerinate 3, crosslinking agent TAIC 2, tristearin Acid, 2, N, a N '-penylene BMI 1, alcohol ester 12, PE wax 0.8, aluminum nitride powder 1, jade powder 2, modified filler 9.
3. Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material according to claim 1 and 2 is it is characterised in that described Modified filler be to be prepared by following method：Attapulgite is calcined 3-4 hour at 540-580 DEG C, after taking-up, plus Enter grinding 1-2 hour in the sodium hydroxide solution of 3-4%, then, add the hydrochloric acid solution of 12-15%, regulation pH value is 4-5, old Change 10-15 hour, it is neutrality that repeated hydrogenation sodium hydroxide solution adjusts lapping liquid pH, filters, and dries and obtains filler powder, then to institute Add in powder and be equivalent to the tea tree ethereal oil of powder weight 1-2%, the zinc oxide of 1-2%, the pentaerythrite of 1-2%, 2-3% nanometer Jade powder, after co-ground 1-2 hour, add be equivalent to the aminopropyl triethoxysilane of powder weight 2-3%, 4-5% gathers Ethylene glycol 6000, the morpholine of 2-3%, are uniformly dispersed with 11000-12000 rev/min of high speed, obtain final product.
CN201610847860.8A 2016-09-26 2016-09-26 Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material Pending CN106432954A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107974019A (en) * 2017-12-13 2018-05-01 安徽新胜塑料科技有限公司 A kind of additive for lifting acryl plates service life
CN112126174A (en) * 2020-09-24 2020-12-25 镇江市华银仪表电器有限公司 Wear-resistant polyvinyl chloride cable sheath material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000204213A (en) * 1999-01-18 2000-07-25 Toyo Chem Co Ltd Pvc-based tape
CN102417671A (en) * 2010-09-27 2012-04-18 上海远洲管业有限公司 Preparation technology of high strength PVC non-excavation pipe fitting
CN103524913A (en) * 2013-09-30 2014-01-22 芜湖航天特种电缆厂 Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material
CN104327372A (en) * 2014-09-30 2015-02-04 青岛东泰诚恩新材料科技发展有限公司 Modified polyvinyl chloride cable plastic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000204213A (en) * 1999-01-18 2000-07-25 Toyo Chem Co Ltd Pvc-based tape
CN102417671A (en) * 2010-09-27 2012-04-18 上海远洲管业有限公司 Preparation technology of high strength PVC non-excavation pipe fitting
CN103524913A (en) * 2013-09-30 2014-01-22 芜湖航天特种电缆厂 Flame-retardant oil-resistant aging-resistant thermoplastic elastomer cable material
CN104327372A (en) * 2014-09-30 2015-02-04 青岛东泰诚恩新材料科技发展有限公司 Modified polyvinyl chloride cable plastic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107974019A (en) * 2017-12-13 2018-05-01 安徽新胜塑料科技有限公司 A kind of additive for lifting acryl plates service life
CN112126174A (en) * 2020-09-24 2020-12-25 镇江市华银仪表电器有限公司 Wear-resistant polyvinyl chloride cable sheath material

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