CN107974019A - A kind of additive for lifting acryl plates service life - Google Patents

A kind of additive for lifting acryl plates service life Download PDF

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Publication number
CN107974019A
CN107974019A CN201711324360.7A CN201711324360A CN107974019A CN 107974019 A CN107974019 A CN 107974019A CN 201711324360 A CN201711324360 A CN 201711324360A CN 107974019 A CN107974019 A CN 107974019A
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parts
particle
additive
service life
attapulgite
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吴二胜
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Anhui Xinsheng Plastic Technology Co Ltd
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Anhui Xinsheng Plastic Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/08Ingredients agglomerated by treatment with a binding agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of additive for lifting acryl plates service life, by following material composition:Functional stuffing, silane coupling agent, neopelex, fatty alcohol polyoxyethylene ether, age resister, ultra-violet absorber, glycerine, water.A kind of special additive of the present invention, can effectively lift the characteristics such as the wear-resisting of acryl plates, corrosion resistant, intensity, antibacterial, hence it is evident that extend its service life, great popularizing value.

Description

A kind of additive for lifting acryl plates service life
Technical field
The invention belongs to acrylic working process technical field, and in particular to a kind of lifting acryl plates service life Additive.
Background technology
Acrylic, chemical name are polymethyl methacrylate, its transparency is as glass.Acrylic has preferable Chemical stability, easy dyeing, easy processing and grace appearance and extensively liked by people.Though existing acrylic has above-mentioned excellent Point, but it does not have special functional quality, and it is easy to aging, the service life needs to be further improved, and have impact on it and preferably pushes away Wide application.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided it is a kind of lifted acryl plates service life addition Agent.
The present invention is achieved by the following technical solutions:
A kind of additive for lifting acryl plates service life, by the material composition of following parts by weight:
10 ~ 15 parts of functional stuffings, 7 ~ 10 parts of silane coupling agents, 3 ~ 5 parts of neopelexes, 4 ~ 6 parts of fatty alcohol polyoxy second Alkene ether, 2 ~ 3 parts of age resisters, 0.5 ~ 1 part of ultra-violet absorber, 30 ~ 40 parts of glycerine, 180 ~ 200 parts of water.
Preferably, by the material composition of following parts by weight:
13 ~ 15 parts of functional stuffings, 9 ~ 10 parts of silane coupling agents, 4 ~ 5 parts of neopelexes, 5 ~ 6 parts of fatty alcohol polyoxy second Alkene ether, 2.5 ~ 3 parts of age resisters, 0.8 ~ 1 part of ultra-violet absorber, 35 ~ 40 parts of glycerine, 190 ~ 200 parts of water.
Preferably, by the material composition of following parts by weight:
13 parts of functional stuffings, 9 parts of silane coupling agents, 4 parts of neopelexes, 5 parts of fatty alcohol polyoxyethylene ether, 2.5 parts Age resister, 0.8 part of ultra-violet absorber, 35 parts of glycerine, 190 parts of water.
Further, the preparation method of the functional stuffing includes the following steps:
(1)Attapulgite is first put into 7 ~ 9min of immersion treatment in the hydrochloric acid solution that mass fraction is 8 ~ 10%, then takes out and puts Enter 5 ~ 7min of immersion treatment into the sodium hydroxide solution that mass fraction is 10 ~ 12%, finally take out and use deionized water rinsing one time It is spare afterwards;
(2)By step(1)Attapulgite after processing, which is put into calcining furnace, carries out calcination processing, is taken out after 50 ~ 60min standby With;
(3)By step(2)Attapulgite after processing is put into immersion treatment in modification liquid A, during which persistently carries out at ultrasonic wave Manage, filter out attapulgite after 30 ~ 40min rear spare;The modification liquid A by following parts by weight material composition:25 ~ 30 parts are received Rice carbon pipe, 6 ~ 8 parts of magnesium stearates, 4 ~ 7 parts of calgons, 8 ~ 10 parts of polyethylene glycol, 340 ~ 360 parts of water;
(4)By step(3)Attapulgite after processing is put into immersion treatment in modification liquid B, after high-speed stirred handles 1 ~ 1.5h Attapulgite is filtered out spare;The modification liquid B by following parts by weight material composition:3 ~ 4 parts of Chinese medical extracts, 10 ~ 13 parts Water;
(5)By step(4)Attapulgite after processing, which is put into drying box, is dried processing, after the completion of take out be put into powder Pulverization process is carried out in broken machine, and it is divided into three grades according to granular size, respectively particle A, particle B and particle C, institute The particle diameter for stating particle A is 300 ~ 400nm, and the particle diameter of particle B is 1 ~ 15 μm, and the particle diameter of particle C is 60 ~ 80 μ M, the particle A, particle B and particle C correspond to the weight ratio mixed:5~6:2~3:3~4.
Further, step(2)Described in calcination processing when to control temperature in calcining furnace be 750 ~ 800 DEG C.
Further, step(3)Described in the frequency of ultrasonication be 100 ~ 105kHz.
Further, step(4)Described in the preparation method of Chinese medical extract be:By chinaberry, rhizoma menispermi, Radix Paeoniae Alba, The coptis, illiciumverum are corresponding according to weight ratio 5:4:6:9:3 carry out co-grindings, are then mixed jointly with the clear water of 8 times of its gross mass It is put into pot, heating boiling is filtered after boiling processing 1.5h, finally concentrates the filtrate to the 1/12 of original volume again.
Further, step(5)Described in drying process when to control temperature in drying box be 80 ~ 85 DEG C.
The present invention is prepared for a kind of additive, effectively improves the use quality of acryl plates, wherein that adds is anti-ageing Agent enhances overall anti-aging property, and the ultra-violet absorber of addition enhances its anti-uv-ray, and with the addition of one The special functional stuffing of kind, it is to be modified to form as matrix using attapulgite, has first carried out soda acid immersion treatment to it, has had Effect eliminates its impurity component, has dredged channel design, has then carried out calcination processing, has further improved the ratio of attapulgite Surface area and characterization of adsorption, have then carried out modification to attapulgite with modification liquid A again, have been grafted carbon nanotubes after processing It is inserted in attapulgite, the adsorption capacity of attapulgite is further increased using the middle outage characterization of adsorption of carbon nanotubes, Immersion treatment then is carried out to attapulgite with the modification liquid B with antibacterial characteristics, enhances the anti-microbial property of attapulgite, most Crushing and classification processing has been carried out to its granular size afterwards, has improved the effect of filling well, the particle after classification processing disperses Property is good, is not easy to reunite, enhances the mechanical qualities such as overall intensity, has more preferable filling effect.
The present invention has the following advantages compared with prior art:
A kind of special additive of the present invention, can effectively lift the characteristics such as the wear-resisting of acryl plates, corrosion resistant, intensity, antibacterial, It has been obviously prolonged its service life, great popularizing value.
Embodiment
Embodiment 1
A kind of additive for lifting acryl plates service life, by the material composition of following parts by weight:
10 parts of functional stuffings, 7 parts of silane coupling agents, 3 parts of neopelexes, 4 parts of fatty alcohol polyoxyethylene ether, 2 parts it is anti- Aging agent, 0.5 part of ultra-violet absorber, 30 parts of glycerine, 180 parts of water.
Further, the preparation method of the functional stuffing includes the following steps:
(1)Attapulgite is first put into immersion treatment 7min in the hydrochloric acid solution that mass fraction is 8%, then takes out and is put into Immersion treatment 5min in the sodium hydroxide solution that mass fraction is 10%, finally takes out with spare after deionized water rinsing one time;
(2)By step(1)Attapulgite after processing, which is put into calcining furnace, carries out calcination processing, is taken out after 50min spare;
(3)By step(2)Attapulgite after processing is put into immersion treatment in modification liquid A, during which persistently carries out at ultrasonic wave Manage, filter out attapulgite after 30min rear spare;The modification liquid A by following parts by weight material composition:25 parts of nano-sized carbons Pipe, 6 parts of magnesium stearates, 4 parts of calgons, 8 parts of polyethylene glycol, 340 parts of water;
(4)By step(3)Attapulgite after processing is put into immersion treatment in modification liquid B, will be recessed after high-speed stirred processing 1h Convex rod soil filters out spare;The modification liquid B by following parts by weight material composition:3 parts of Chinese medical extracts, 10 parts of water;
(5)By step(4)Attapulgite after processing, which is put into drying box, is dried processing, after the completion of take out be put into powder Pulverization process is carried out in broken machine, and it is divided into three grades according to granular size, respectively particle A, particle B and particle C, institute The particle diameter for stating particle A is 300 ~ 400nm, and the particle diameter of particle B is 1 ~ 15 μm, and the particle diameter of particle C is 60 ~ 80 μ M, the particle A, particle B and particle C correspond to the weight ratio mixed:5:2:3.
Further, step(2)Described in calcination processing when to control temperature in calcining furnace be 750 DEG C.
Further, step(3)Described in the frequency of ultrasonication be 100kHz.
Further, step(4)Described in the preparation method of Chinese medical extract be:By chinaberry, rhizoma menispermi, Radix Paeoniae Alba, The coptis, illiciumverum are corresponding according to weight ratio 5:4:6:9:3 carry out co-grindings, are then mixed jointly with the clear water of 8 times of its gross mass It is put into pot, heating boiling is filtered after boiling processing 1.5h, finally concentrates the filtrate to the 1/12 of original volume again.
Further, step(5)Described in drying process when to control temperature in drying box be 80 DEG C.
Embodiment 2
A kind of additive for lifting acryl plates service life, by the material composition of following parts by weight:
13 parts of functional stuffings, 9 parts of silane coupling agents, 4 parts of neopelexes, 5 parts of fatty alcohol polyoxyethylene ether, 2.5 parts Age resister, 0.8 part of ultra-violet absorber, 35 parts of glycerine, 190 parts of water.
Further, the preparation method of the functional stuffing includes the following steps:
(1)Attapulgite is first put into immersion treatment 8min in the hydrochloric acid solution that mass fraction is 9%, then takes out and is put into Immersion treatment 6min in the sodium hydroxide solution that mass fraction is 11%, finally takes out with spare after deionized water rinsing one time;
(2)By step(1)Attapulgite after processing, which is put into calcining furnace, carries out calcination processing, is taken out after 55min spare;
(3)By step(2)Attapulgite after processing is put into immersion treatment in modification liquid A, during which persistently carries out at ultrasonic wave Manage, filter out attapulgite after 35min rear spare;The modification liquid A by following parts by weight material composition:28 parts of nano-sized carbons Pipe, 7 parts of magnesium stearates, 6 parts of calgons, 9 parts of polyethylene glycol, 350 parts of water;
(4)By step(3)Attapulgite after processing is put into immersion treatment in modification liquid B, will after high-speed stirred processing 1.2h Attapulgite filters out spare;The modification liquid B by following parts by weight material composition:3.5 parts of Chinese medical extracts, 12 parts of water;
(5)By step(4)Attapulgite after processing, which is put into drying box, is dried processing, after the completion of take out be put into powder Pulverization process is carried out in broken machine, and it is divided into three grades according to granular size, respectively particle A, particle B and particle C, institute The particle diameter for stating particle A is 300 ~ 400nm, and the particle diameter of particle B is 1 ~ 15 μm, and the particle diameter of particle C is 60 ~ 80 μ M, the particle A, particle B and particle C correspond to the weight ratio mixed:5.5:2.5:3.6.
Further, step(2)Described in calcination processing when to control temperature in calcining furnace be 780 DEG C.
Further, step(3)Described in the frequency of ultrasonication be 103kHz.
Further, step(4)Described in the preparation method of Chinese medical extract be:By chinaberry, rhizoma menispermi, Radix Paeoniae Alba, The coptis, illiciumverum are corresponding according to weight ratio 5:4:6:9:3 carry out co-grindings, are then mixed jointly with the clear water of 8 times of its gross mass It is put into pot, heating boiling is filtered after boiling processing 1.5h, finally concentrates the filtrate to the 1/12 of original volume again.
Further, step(5)Described in drying process when to control temperature in drying box be 82 DEG C.
Embodiment 3
A kind of additive for lifting acryl plates service life, by the material composition of following parts by weight:
15 parts of functional stuffings, 10 parts of silane coupling agents, 5 parts of neopelexes, 6 parts of fatty alcohol polyoxyethylene ether, 3 parts it is anti- Aging agent, 1 part of ultra-violet absorber, 40 parts of glycerine, 200 parts of water.
Further, the preparation method of the functional stuffing includes the following steps:
(1)Attapulgite is first put into immersion treatment 9min in the hydrochloric acid solution that mass fraction is 10%, then takes out and is put into Immersion treatment 7min in the sodium hydroxide solution that mass fraction is 12%, finally takes out with spare after deionized water rinsing one time;
(2)By step(1)Attapulgite after processing, which is put into calcining furnace, carries out calcination processing, is taken out after 60min spare;
(3)By step(2)Attapulgite after processing is put into immersion treatment in modification liquid A, during which persistently carries out at ultrasonic wave Manage, filter out attapulgite after 40min rear spare;The modification liquid A by following parts by weight material composition:30 parts of nano-sized carbons Pipe, 8 parts of magnesium stearates, 7 parts of calgons, 10 parts of polyethylene glycol, 360 parts of water;
(4)By step(3)Attapulgite after processing is put into immersion treatment in modification liquid B, will after high-speed stirred processing 1.5h Attapulgite filters out spare;The modification liquid B by following parts by weight material composition:4 parts of Chinese medical extracts, 13 parts of water;
(5)By step(4)Attapulgite after processing, which is put into drying box, is dried processing, after the completion of take out be put into powder Pulverization process is carried out in broken machine, and it is divided into three grades according to granular size, respectively particle A, particle B and particle C, institute The particle diameter for stating particle A is 300 ~ 400nm, and the particle diameter of particle B is 1 ~ 15 μm, and the particle diameter of particle C is 60 ~ 80 μ M, the particle A, particle B and particle C correspond to the weight ratio mixed:6:3:4.
Further, step(2)Described in calcination processing when to control temperature in calcining furnace be 800 DEG C.
Further, step(3)Described in the frequency of ultrasonication be 105kHz.
Further, step(4)Described in the preparation method of Chinese medical extract be:By chinaberry, rhizoma menispermi, Radix Paeoniae Alba, The coptis, illiciumverum are corresponding according to weight ratio 5:4:6:9:3 carry out co-grindings, are then mixed jointly with the clear water of 8 times of its gross mass It is put into pot, heating boiling is filtered after boiling processing 1.5h, finally concentrates the filtrate to the 1/12 of original volume again.
Further, step(5)Described in drying process when to control temperature in drying box be 85 DEG C.
Additive of the present invention effectively improves the integrated quality of acryl plates, impart its well it is wear-resisting, antibacterial is special Property, its impact strength, tensile strength are improved more than 30%, service life extends 25% or so, has and promotes well Use value.

Claims (8)

1. a kind of additive for lifting acryl plates service life, it is characterised in that by the material composition of following parts by weight:
10 ~ 15 parts of functional stuffings, 7 ~ 10 parts of silane coupling agents, 3 ~ 5 parts of neopelexes, 4 ~ 6 parts of fatty alcohol polyoxy second Alkene ether, 2 ~ 3 parts of age resisters, 0.5 ~ 1 part of ultra-violet absorber, 30 ~ 40 parts of glycerine, 180 ~ 200 parts of water.
2. a kind of additive for lifting acryl plates service life according to claim 1, it is characterised in that by as follows The material composition of parts by weight:
13 ~ 15 parts of functional stuffings, 9 ~ 10 parts of silane coupling agents, 4 ~ 5 parts of neopelexes, 5 ~ 6 parts of fatty alcohol polyoxy second Alkene ether, 2.5 ~ 3 parts of age resisters, 0.8 ~ 1 part of ultra-violet absorber, 35 ~ 40 parts of glycerine, 190 ~ 200 parts of water.
3. a kind of additive for lifting acryl plates service life according to claim 1, it is characterised in that by as follows The material composition of parts by weight:
13 parts of functional stuffings, 9 parts of silane coupling agents, 4 parts of neopelexes, 5 parts of fatty alcohol polyoxyethylene ether, 2.5 parts Age resister, 0.8 part of ultra-violet absorber, 35 parts of glycerine, 190 parts of water.
4. a kind of additive of lifting acryl plates service life according to claim 1 ~ 3 any one, its feature It is, the preparation method of the functional stuffing includes the following steps:
(1)Attapulgite is first put into 7 ~ 9min of immersion treatment in the hydrochloric acid solution that mass fraction is 8 ~ 10%, then takes out and puts Enter 5 ~ 7min of immersion treatment into the sodium hydroxide solution that mass fraction is 10 ~ 12%, finally take out and use deionized water rinsing one time It is spare afterwards;
(2)By step(1)Attapulgite after processing, which is put into calcining furnace, carries out calcination processing, is taken out after 50 ~ 60min standby With;
(3)By step(2)Attapulgite after processing is put into immersion treatment in modification liquid A, during which persistently carries out at ultrasonic wave Manage, filter out attapulgite after 30 ~ 40min rear spare;The modification liquid A by following parts by weight material composition:25 ~ 30 parts are received Rice carbon pipe, 6 ~ 8 parts of magnesium stearates, 4 ~ 7 parts of calgons, 8 ~ 10 parts of polyethylene glycol, 340 ~ 360 parts of water;
(4)By step(3)Attapulgite after processing is put into immersion treatment in modification liquid B, after high-speed stirred handles 1 ~ 1.5h Attapulgite is filtered out spare;The modification liquid B by following parts by weight material composition:3 ~ 4 parts of Chinese medical extracts, 10 ~ 13 parts Water;
(5)By step(4)Attapulgite after processing, which is put into drying box, is dried processing, after the completion of take out be put into powder Pulverization process is carried out in broken machine, and it is divided into three grades according to granular size, respectively particle A, particle B and particle C, institute The particle diameter for stating particle A is 300 ~ 400nm, and the particle diameter of particle B is 1 ~ 15 μm, and the particle diameter of particle C is 60 ~ 80 μ M, the particle A, particle B and particle C correspond to the weight ratio mixed:5~6:2~3:3~4.
A kind of 5. additive for lifting acryl plates service life according to claim 4, it is characterised in that step (2)Described in calcination processing when to control temperature in calcining furnace be 750 ~ 800 DEG C.
A kind of 6. additive for lifting acryl plates service life according to claim 4, it is characterised in that step (3)Described in the frequency of ultrasonication be 100 ~ 105kHz.
A kind of 7. additive for lifting acryl plates service life according to claim 4, it is characterised in that step (4)Described in the preparation method of Chinese medical extract be:Chinaberry, rhizoma menispermi, Radix Paeoniae Alba, the coptis, illiciumverum is corresponding according to weight Than 5:4:6:9:3 carry out co-grindings, are then put into common mix of the clear water of 8 times of its gross mass in pot, heat boiling and boil place Filtered after reason 1.5h, finally concentrate the filtrate to the 1/12 of original volume again.
A kind of 8. additive for lifting acryl plates service life according to claim 4, it is characterised in that step (5)Described in drying process when to control temperature in drying box be 80 ~ 85 DEG C.
CN201711324360.7A 2017-12-13 2017-12-13 A kind of additive for lifting acryl plates service life Pending CN107974019A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108623896A (en) * 2018-05-31 2018-10-09 安徽电信器材贸易工业有限责任公司 It is a kind of to be used to shield insulating materials of optical cable and preparation method thereof
CN108753140A (en) * 2018-06-25 2018-11-06 安徽阜南县万家和工艺品有限公司 A kind of willow-plaited process product anti-fouling paint

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106432954A (en) * 2016-09-26 2017-02-22 高团结 Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106432954A (en) * 2016-09-26 2017-02-22 高团结 Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108623896A (en) * 2018-05-31 2018-10-09 安徽电信器材贸易工业有限责任公司 It is a kind of to be used to shield insulating materials of optical cable and preparation method thereof
CN108753140A (en) * 2018-06-25 2018-11-06 安徽阜南县万家和工艺品有限公司 A kind of willow-plaited process product anti-fouling paint

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Application publication date: 20180501