CN104327372A - Modified polyvinyl chloride cable plastic - Google Patents

Modified polyvinyl chloride cable plastic Download PDF

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Publication number
CN104327372A
CN104327372A CN201410514917.3A CN201410514917A CN104327372A CN 104327372 A CN104327372 A CN 104327372A CN 201410514917 A CN201410514917 A CN 201410514917A CN 104327372 A CN104327372 A CN 104327372A
Authority
CN
China
Prior art keywords
polyvinyl chloride
modified polyvinyl
parts
chloride cable
cable plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410514917.3A
Other languages
Chinese (zh)
Inventor
李耀东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QINGDAO DONGTAI CHENG'EN NEW MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
QINGDAO DONGTAI CHENG'EN NEW MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QINGDAO DONGTAI CHENG'EN NEW MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd filed Critical QINGDAO DONGTAI CHENG'EN NEW MATERIAL TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201410514917.3A priority Critical patent/CN104327372A/en
Publication of CN104327372A publication Critical patent/CN104327372A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a modified polyvinyl chloride cable plastic and belongs to the field of plastic compositions. The modified polyvinyl chloride cable plastic comprises following components: polyvinyl chloride, polypropylene, triphenyl phosphate, hydrogenated nitrile butadiene rubber, polycarbonate, polylactic acid, magnesium hydroxide, a calcium-zinc stabilizing agent, stearic acid, an anti-oxidant and butadiene. The modified polyvinyl chloride cable plastic is good in thermally-stabilizing performance, flexible performance and fire resistance, is excellent in weather resistant performance, is not liable to be aged and is long in service life.

Description

A kind of modified polyvinyl chloride cable plastics
Technical field
The present invention relates to a kind of modified polyvinyl chloride cable plastics, belong to plastic fraction technical field.
Background technology
Igelite, as one of the main raw of cable material, needs it to take into account snappiness, oxidation-resistance, fire performance, the premium propertiess such as weathering resistance simultaneously.But the thermal stability of polyvinyl chloride own is poor, flexility also needs further lifting, and duration of service is long simultaneously, easily occurs aging.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of modified polyvinyl chloride cable plastics, and improving thermal stability of polyvinyl chloride by blending and modifying can be poor, and snappiness is not good, and easy aging grade is not enough.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of modified polyvinyl chloride cable plastics, is characterized in that: the component comprising following weight part, polyvinyl chloride 12-18 part, polypropylene 22-26 part, triphenylphosphate 0.3-1.6 part, hydrogenated nitrile-butadiene rubber 5-8 part, polycarbonate 4-6 part, poly(lactic acid) 3-4 part, magnesium hydroxide 0.5-1.2 part, calcium zinc stabilizer 1-5 part, stearic acid 2-8 part, oxidation inhibitor 0.3-1.8 part, divinyl 0.6-1.4 part.
The modified polyvinyl chloride cable plastics adopting technique scheme to produce has following beneficial effect, and thermal stability is good, and flexility is good, and fire performance is good, and weather resistance is excellent, not easily aging, long service life.
Embodiment
Below in conjunction with concrete implementation column, the present invention is set forth further, but do not limit the present invention.
Embodiment 1
A kind of modified polyvinyl chloride cable plastics, is characterized in that: the component comprising following weight part, polyvinyl chloride 12 parts, polypropylene 22 parts, triphenylphosphate 0.3 part, hydrogenated nitrile-butadiene rubber 5 parts, polycarbonate 4 parts, poly(lactic acid) 3 parts, magnesium hydroxide 0.5 part, calcium zinc stabilizer 1 part, stearic acid 2 parts, 0.3 part, oxidation inhibitor, divinyl 0.6 part.
Embodiment 2
A kind of modified polyvinyl chloride cable plastics, is characterized in that: the component comprising following weight part, polyvinyl chloride 18 parts, polypropylene 26 parts, triphenylphosphate 1.6 parts, hydrogenated nitrile-butadiene rubber 8 parts, polycarbonate 6 parts, poly(lactic acid) 4 parts, magnesium hydroxide 1.2 parts, calcium zinc stabilizer 5 parts, stearic acid 8 parts, 1.8 parts, oxidation inhibitor, divinyl 1.4 parts.
Embodiment 3
A kind of modified polyvinyl chloride cable plastics, is characterized in that: the component comprising following weight part, polyvinyl chloride 16 parts, polypropylene 24 parts, polyvinyl chloride 12 parts, triphenylphosphate 1.3 parts, hydrogenated nitrile-butadiene rubber 6 parts, polycarbonate 5 parts, poly(lactic acid) 3.5 parts, magnesium hydroxide 1 part, calcium zinc stabilizer 3 parts, stearic acid 6 parts, 1.2 parts, oxidation inhibitor, divinyl 0.9 part.
Test the plastics according to embodiment 1 to 3 gained, heat resistance is tested according to standard ISO 6721-2, and rate of compression is tested according to ISO815, and test adaptability to changes according to standard ISO 5217-1, result is as shown in table 1.
Table 1
Project Heat resistance 100 DEG C (MPA) Rate of compression 24h(%) Rate of compression 72h(%) 100% adaptability to changes 200mm/min(MPA) 300% adaptability to changes 200mm/min(MPA)
Embodiment 1 Pass through 45-58 23-32 2-6 8-14
Embodiment 2 Pass through 48-59 28-35 3-9 9-15
Embodiment 3 Pass through 52-60 31-36 5-10 12-17

Claims (1)

1. a modified polyvinyl chloride cable plastics, is characterized in that: the component comprising following weight part, polyvinyl chloride 12-18 part, polypropylene 22-26 part, triphenylphosphate 0.3-1.6 part, hydrogenated nitrile-butadiene rubber 5-8 part, polycarbonate 4-6 part, poly(lactic acid) 3-4 part, magnesium hydroxide 0.5-1.2 part, calcium zinc stabilizer 1-5 part, stearic acid 2-8 part, oxidation inhibitor 0.3-1.8 part, divinyl 0.6-1.4 part.
CN201410514917.3A 2014-09-30 2014-09-30 Modified polyvinyl chloride cable plastic Pending CN104327372A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410514917.3A CN104327372A (en) 2014-09-30 2014-09-30 Modified polyvinyl chloride cable plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410514917.3A CN104327372A (en) 2014-09-30 2014-09-30 Modified polyvinyl chloride cable plastic

Publications (1)

Publication Number Publication Date
CN104327372A true CN104327372A (en) 2015-02-04

Family

ID=52402181

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410514917.3A Pending CN104327372A (en) 2014-09-30 2014-09-30 Modified polyvinyl chloride cable plastic

Country Status (1)

Country Link
CN (1) CN104327372A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037994A (en) * 2015-06-23 2015-11-11 中山市鸿程科研技术服务有限公司 Corrosion-resistant flame-retardant cable material and preparation method thereof
CN106432954A (en) * 2016-09-26 2017-02-22 高团结 Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material
CN106916375A (en) * 2017-03-22 2017-07-04 合肥浦尔菲电线科技有限公司 A kind of fire-resistant wire skin and preparation method thereof
CN110903545A (en) * 2019-11-11 2020-03-24 国网山东省电力公司兰陵县供电公司 Anti-aging acid-alkali-resistant cable material and preparation method thereof
CN113004638A (en) * 2021-03-11 2021-06-22 西华大学 Flame-retardant cable material and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037994A (en) * 2015-06-23 2015-11-11 中山市鸿程科研技术服务有限公司 Corrosion-resistant flame-retardant cable material and preparation method thereof
CN106432954A (en) * 2016-09-26 2017-02-22 高团结 Flame-retardant oil-resistant anti-ageing thermoplastic elastomer cable material
CN106916375A (en) * 2017-03-22 2017-07-04 合肥浦尔菲电线科技有限公司 A kind of fire-resistant wire skin and preparation method thereof
CN110903545A (en) * 2019-11-11 2020-03-24 国网山东省电力公司兰陵县供电公司 Anti-aging acid-alkali-resistant cable material and preparation method thereof
CN113004638A (en) * 2021-03-11 2021-06-22 西华大学 Flame-retardant cable material and preparation method thereof

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C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150204

WD01 Invention patent application deemed withdrawn after publication