CN103289416A - Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material - Google Patents
Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material Download PDFInfo
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- CN103289416A CN103289416A CN2013101905779A CN201310190577A CN103289416A CN 103289416 A CN103289416 A CN 103289416A CN 2013101905779 A CN2013101905779 A CN 2013101905779A CN 201310190577 A CN201310190577 A CN 201310190577A CN 103289416 A CN103289416 A CN 103289416A
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Abstract
The invention discloses an environment-friendly flame-retardant silicone rubber and butadiene rubber blending material. The environment-friendly flame-retardant silicone rubber and butadiene rubber blending material is characterized by being prepared from the following materials in parts by weight: 90-108 parts of methylvinyl silicone rubber, 40-50 parts of butadiene rubber, 8-13 parts of vinyl trimethoxy silane, 2-4 parts of antioxidant 300, 3-6 parts of titanate coupling agent, 0.5-1.5 parts of stearate, 0.05-3 parts of paraffin, 10-20 parts of carbon black, 2-4 parts of vulcanizing agent, 20-30 parts of inorganic flame retardant, 0.1-2 parts of reinforcing agent and 3-5 parts of bonding agent. The environment-friendly flame-retardant silicone rubber and butadiene rubber blending material disclosed by the invention is wearable and durable, good in mechanical performance, excellent in flame retardation, non-toxic and environment-friendly.
Description
Technical field
The present invention relates to field of rubber materials, specifically is a kind of environmental protection flame retardant silicon rubber and cis-1,4-polybutadiene rubber intermingling material.
Background technology
Silicon rubber has excellent performances such as thermotolerance, winter hardiness, dielectricity, anti-ozone and anti-atmospheric aging, and its outstanding properties is to use temperature range wide.But mechanical propertys such as the tensile strength of silicon rubber and tearing toughness are relatively poor, and its physical and mechanical properties is not as good as most of synthetic rubber at normal temperatures.Cis-1,4-polybutadiene rubber is amorphous state when normal temperature is zero load, very high deformability is arranged when bearing external force, is the best synthetic rubber of elasticity and winter hardiness, and there is the relatively poor problem of processing characteristics in cis-1,4-polybutadiene rubber.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection flame retardant silicon rubber and cis-1,4-polybutadiene rubber intermingling material.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of environmental protection flame retardant silicon rubber and cis-1,4-polybutadiene rubber intermingling material, it is characterized in that, be to be made by the raw material of following weight parts: methyl vinyl silicone rubber 90-108 part, cis-1,4-polybutadiene rubber 40-50 part, vinyltrimethoxy silane 8-13 part, antioxidant 300 2-4 part, titanate coupling agent 3-6 part, stearate 0.5-1.5 part, paraffin 0.05-3 part, carbon black 10-20 part, vulcanizing agent 2-4 part, inorganic combustion inhibitor 20-30 part, strengthening agent 0.1-2 part, tackiness agent 3-5 part.
The present invention is made by the raw material of following weight parts: 100 parts of methyl vinyl silicone rubbers, 45 parts of cis-1,4-polybutadiene rubbers, 10 parts of vinyltrimethoxy silanes, 2 parts of antioxidant 300s, 4 parts of titanate coupling agents, 1 part of stearate, 2 parts in paraffin, 20 parts of carbon blacks, 3 parts of vulcanizing agents, 30 parts of inorganic combustion inhibitors, 1 part of strengthening agent, 4 parts in tackiness agent.
Described vulcanizing agent is polysulphide polymer, urethanum or benzoyl peroxide; Inorganic combustion inhibitor is the mixture of ammonium polyphosphate and zinc borate.
Beneficial effect of the present invention: wear-resisting durable, the good mechanical property of the present invention, flame retardant properties excellence, and asepsis environment-protecting.
Embodiment
Below in conjunction with specific embodiment the present invention is further described.
Embodiment 1
A kind of environmental protection flame retardant silicon rubber and cis-1,4-polybutadiene rubber intermingling material, it is characterized in that, be to be made by the raw material of following weight parts: 90 parts of methyl vinyl silicone rubbers, 50 parts of cis-1,4-polybutadiene rubbers, 8 parts of vinyltrimethoxy silanes, 4 parts of antioxidant 300s, 6 parts of titanate coupling agents, 1.5 parts of stearate, 0.05 part in paraffin, 20 parts of carbon blacks, 4 parts of vulcanizing agents, 20 parts of inorganic combustion inhibitors, 0.1 part of strengthening agent, 5 parts in tackiness agent.
Embodiment 2
A kind of environmental protection flame retardant silicon rubber and cis-1,4-polybutadiene rubber intermingling material are to be made by the raw material of following weight parts: 100 parts of methyl vinyl silicone rubbers, 45 parts of cis-1,4-polybutadiene rubbers, 10 parts of vinyltrimethoxy silanes, 2 parts of antioxidant 300s, 4 parts of titanate coupling agents, 1 part of stearate, 2 parts in paraffin, 20 parts of carbon blacks, 3 parts of vulcanizing agents, 30 parts of inorganic combustion inhibitors, 1 part of strengthening agent, 4 parts in tackiness agent.
Claims (3)
1. an environmental protection flame retardant silicon rubber and cis-1,4-polybutadiene rubber intermingling material, it is characterized in that, be to be made by the raw material of following weight parts: methyl vinyl silicone rubber 90-108 part, cis-1,4-polybutadiene rubber 40-50 part, vinyltrimethoxy silane 8-13 part, antioxidant 300 2-4 part, titanate coupling agent 3-6 part, stearate 0.5-1.5 part, paraffin 0.05-3 part, carbon black 10-20 part, vulcanizing agent 2-4 part, inorganic combustion inhibitor 20-30 part, strengthening agent 0.1-2 part, tackiness agent 3-5 part.
2. silicon rubber and cis-1,4-polybutadiene rubber intermingling material are fired in environmental protection according to claim 1, it is characterized in that, be to be made by the raw material of following weight parts: 100 parts of methyl vinyl silicone rubbers, 45 parts of cis-1,4-polybutadiene rubbers, 10 parts of vinyltrimethoxy silanes, 2 parts of antioxidant 300s, 4 parts of titanate coupling agents, 1 part of stearate, 2 parts in paraffin, 20 parts of carbon blacks, 3 parts of vulcanizing agents, 30 parts of inorganic combustion inhibitors, 1 part of strengthening agent, 4 parts in tackiness agent.
3. environmental protection combustion silicon rubber according to claim 1 and 2 and cis-1,4-polybutadiene rubber intermingling material is characterized in that described vulcanizing agent is polysulphide polymer, urethanum or benzoyl peroxide; Inorganic combustion inhibitor is the mixture of ammonium polyphosphate and zinc borate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101905779A CN103289416A (en) | 2013-05-22 | 2013-05-22 | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101905779A CN103289416A (en) | 2013-05-22 | 2013-05-22 | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
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| CN103289416A true CN103289416A (en) | 2013-09-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2013101905779A Withdrawn CN103289416A (en) | 2013-05-22 | 2013-05-22 | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243721A (en) * | 2016-07-28 | 2016-12-21 | 陈林美 | A kind of compounded rubber formula |
| CN106810822A (en) * | 2017-01-11 | 2017-06-09 | 合肥英索莱特新材料科技有限公司 | Environment-friendly epoxy electronic encapsulating material based on bromide fire retardant |
| CN109259361A (en) * | 2018-08-13 | 2019-01-25 | 安徽微威环保科技有限公司 | A kind of Multi-functional rubber gloves |
| CN111763357A (en) * | 2019-04-02 | 2020-10-13 | 北京化工大学 | Anti-aging color-changing butadiene rubber/silicone rubber composite material and preparation method thereof |
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| CN1277221A (en) * | 2000-06-23 | 2000-12-20 | 吉林大学 | Preparation of composite conducting rubber polymer material |
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| CN102977609A (en) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method |
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| CN1277221A (en) * | 2000-06-23 | 2000-12-20 | 吉林大学 | Preparation of composite conducting rubber polymer material |
| CN1687206A (en) * | 2005-04-21 | 2005-10-26 | 上海交通大学 | Technique for producing freerise foaming material of rubber |
| CN1896123A (en) * | 2005-07-12 | 2007-01-17 | 北京化工大学 | Improvement of rubber compression elasticity at low-temperature |
| CN101186715A (en) * | 2007-11-23 | 2008-05-28 | 清华大学 | Ultra-thin complaisant conductive macromolecule sensitive film and preparation method thereof |
| CN102911467A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material |
| CN102875857A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | Fibre-reinforced damping rubber |
| CN102977609A (en) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | Oil and low-temperature resistant low-smoke and halogen-free flame retardant cable material for boats, and its preparation method |
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| 武卫莉等: "硅橡胶／顺丁橡胶／乙丙橡胶共混材料", 《弹性体》, vol. 16, no. 01, 25 February 2006 (2006-02-25), pages 43 - 46 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243721A (en) * | 2016-07-28 | 2016-12-21 | 陈林美 | A kind of compounded rubber formula |
| CN106810822A (en) * | 2017-01-11 | 2017-06-09 | 合肥英索莱特新材料科技有限公司 | Environment-friendly epoxy electronic encapsulating material based on bromide fire retardant |
| CN109259361A (en) * | 2018-08-13 | 2019-01-25 | 安徽微威环保科技有限公司 | A kind of Multi-functional rubber gloves |
| CN111763357A (en) * | 2019-04-02 | 2020-10-13 | 北京化工大学 | Anti-aging color-changing butadiene rubber/silicone rubber composite material and preparation method thereof |
| CN111763357B (en) * | 2019-04-02 | 2023-02-28 | 北京化工大学 | Anti-aging and color-changing butadiene rubber/silicone rubber composite material and preparation method thereof |
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Application publication date: 20130911 |