CN102911467A - Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material - Google Patents
Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material Download PDFInfo
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- CN102911467A CN102911467A CN2012103461104A CN201210346110A CN102911467A CN 102911467 A CN102911467 A CN 102911467A CN 2012103461104 A CN2012103461104 A CN 2012103461104A CN 201210346110 A CN201210346110 A CN 201210346110A CN 102911467 A CN102911467 A CN 102911467A
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Abstract
The invention discloses a tensile, waterproof, double-shielding control cable material and a preparation method the tensile, waterproof, double-shielding control cable material, wherein the control cable material comprises following materials in terms of parts by weight: a mixture A: 30-40 parts of methyl vinyl silicone rubber, 20-30 parts of acrylonitrile-butadiene rubber, 10-20 parts of silicon rubber, 30-40 parts of maleic anhydride grafted ethylene-ethyl acetate copolymer, 1-3 parts of semi-reinforcing carbon black, 40-60 parts of modified nanometer powder, 1-3 parts of bisphenol A, 1.5-2.5 parts of 3- aminopropyl trimethoxysilane, 1-3 parts of zinc stearate, 3-4 parts of antioxidant 168, 1-3 parts of double-myristyl alcohol, 10-20 parts of talcum powder and 1-3 parts of smoke sheet rubber; a mixture B: 50-70 parts of maleic anhydride grafted PE (poly ethylene), 20-40 parts of methyl vinyl silicone rubber, 20-30 parts of polyacrylate, 0.3-0.5 parts of poly-4-methyl-1-amylene, 2-4 parts of anti-aging agent ODA, 5-10 parts of polycaprolactone, 2-3 parts of cross-linking agent TAIC (triallyl isocyanurate), 1-3 parts of chlorinated paraffin, 5-8 parts of zinc borate and 1-3 parts of calcium stearate. The control cable material has simple preparation method and rational proportion, and drastically improves performance such as tensile strength, elongation at break, tensile strength retention rate and elongation at break retention rate after aging, and impacts brittle temperature performance while obtains excellent performances.
Description
Technical field
The present invention relates to a kind of tension waterproof double shield control cables material and preparation method thereof, belong to the CABLE MATERIALS technical field.
Technical field
The present invention relates to a kind of tension waterproof double shield control cables material and preparation method thereof, belong to the CABLE MATERIALS technical field.
Background technology
Along with developing rapidly of economy, electric wire is at industry-by-industry, all be widely used in the field, frequent occurrence along with the electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually, discharge a large amount of smog and poisonous during cable fire, corrosive gas is Hazard Factor in the fire, people's safe escape and fire-fighting work in fire, have been hindered, make lives and properties suffer heavy losses, simultaneously along with communication career, the development of automotive industry and computer industry, wire peculiar to vessel particularly, line for cars, the high temperature instrument cable, many occasions such as oil drilling platform cable, tension waterproof double shield control cables material also is absolutely necessary certainly.
Background technology
Along with developing rapidly of economy, electric wire is at industry-by-industry, all be widely used in the field, frequent occurrence along with the electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually, discharge a large amount of smog and poisonous during cable fire, corrosive gas is Hazard Factor in the fire, people's safe escape and fire-fighting work in fire, have been hindered, make lives and properties suffer heavy losses, simultaneously along with communication career, the development of automotive industry and computer industry, wire peculiar to vessel particularly, line for cars, the high temperature instrument cable, many occasions such as oil drilling platform cable, tension waterproof double shield control cables material also is absolutely necessary certainly.
Summary of the invention
The purpose of this invention is to provide a kind of tension waterproof double shield control cables material and preparation method thereof, preparation method of the present invention is simple, the constitutive material prescription is reasonable, performance improves greatly, conservation rate is stretched out in tensile strength, tension set, stretching strength retentivity and fracture after aging, impacts embrittlement temperature and can obtain simultaneously excellent performance.
The following technical scheme of employing of the present invention for achieving the above object:
Tension waterproof double shield control cables material, the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 30-40, paracril 20-30, dimethyl silicone rubber 10-20, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 30-40, semi-reinforcing hydrocarbon black 1-3, modified Nano powder 40-60, dihydroxyphenyl propane 1-3,3-aminopropyl trimethoxysilane 1.5-2.5, Zinic stearas 1-3, irgasfos 168 3-4, two ten four carbon alcohols ester 1-3, talcum powder 10-20 and smoke sheet rubber 1-3;
Compound B: vinegar 5-10, linking agent TAIC 2-3, clorafin 1-3, zinc borate 5-8 and calcium stearate 1-3 in maleic anhydride graft PE 50-70, methyl vinyl silicone rubber 20-40, polyacrylic ester 20-30, poly--4-methyl-1-pentene 0.3-0.5, anti-aging agent ODA 2-4, the poly-caproic acid.
Tension waterproof double shield control cables material, the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 35, paracril 25, dimethyl silicone rubber 15, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 35, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, dihydroxyphenyl propane 2,3-aminopropyl trimethoxysilane 2, Zinic stearas 2, irgasfos 168 3.5, two ten four carbon alcohols esters 2, talcum powder 15 and smoke sheet rubber 2;
Vinegar 8, linking agent TAIC 2.5, clorafin 2, zinc borate 7 and calcium stearate 2 in compound B: maleic anhydride graft PE 60, methyl vinyl silicone rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent ODA 3, the poly-caproic acid.
The preparation method of tension waterproof double shield control cables material may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 10-20 minute again, the control temperature was plasticated 3-5 minute discharging at last at 130-150 ℃ under 140-150 ℃.
Described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 700-900 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
Advantage of the present invention:
Preparation method of the present invention is simple, and the constitutive material prescription is reasonable, and performance improves greatly, and conservation rate is stretched out in tensile strength, tension set, stretching strength retentivity and fracture after aging, impacts embrittlement temperature and can obtain simultaneously excellent performance.
Summary of the invention
The purpose of this invention is to provide a kind of tension waterproof double shield control cables material and preparation method thereof, preparation method of the present invention is simple, the constitutive material prescription is reasonable, performance improves greatly, conservation rate is stretched out in tensile strength, tension set, stretching strength retentivity and fracture after aging, impacts embrittlement temperature and can obtain simultaneously excellent performance.
The following technical scheme of employing of the present invention for achieving the above object:
Tension waterproof double shield control cables material, the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 30-40, paracril 20-30, dimethyl silicone rubber 10-20, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 30-40, semi-reinforcing hydrocarbon black 1-3, modified Nano powder 40-60, dihydroxyphenyl propane 1-3,3-aminopropyl trimethoxysilane 1.5-2.5, Zinic stearas 1-3, irgasfos 168 3-4, two ten four carbon alcohols ester 1-3, talcum powder 10-20 and smoke sheet rubber 1-3;
Compound B: vinegar 5-10, linking agent TAIC 2-3, clorafin 1-3, zinc borate 5-8 and calcium stearate 1-3 in maleic anhydride graft PE 50-70, methyl vinyl silicone rubber 20-40, polyacrylic ester 20-30, poly--4-methyl-1-pentene 0.3-0.5, anti-aging agent ODA 2-4, the poly-caproic acid.
Tension waterproof double shield control cables material, the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 35, paracril 25, dimethyl silicone rubber 15, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 35, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, dihydroxyphenyl propane 2,3-aminopropyl trimethoxysilane 2, Zinic stearas 2, irgasfos 168 3.5, two ten four carbon alcohols esters 2, talcum powder 15 and smoke sheet rubber 2;
Vinegar 8, linking agent TAIC 2.5, clorafin 2, zinc borate 7 and calcium stearate 2 in compound B: maleic anhydride graft PE 60, methyl vinyl silicone rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent ODA 3, the poly-caproic acid.
The preparation method of tension waterproof double shield control cables material may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 10-20 minute again, the control temperature was plasticated 3-5 minute discharging at last at 130-150 ℃ under 140-150 ℃.
Described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 700-900 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
Advantage of the present invention:
Preparation method of the present invention is simple, and the constitutive material prescription is reasonable, and performance improves greatly, and conservation rate is stretched out in tensile strength, tension set, stretching strength retentivity and fracture after aging, impacts embrittlement temperature and can obtain simultaneously excellent performance.
Embodiment
Embodiment 1:Tension waterproof double shield control cables material, the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 35, paracril 25, dimethyl silicone rubber 15, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 35, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, dihydroxyphenyl propane 2,3-aminopropyl trimethoxysilane 2, Zinic stearas 2, irgasfos 168 3.5, two ten four carbon alcohols esters 2, talcum powder 15 and smoke sheet rubber 2;
Vinegar 8, linking agent TAIC 2.5, clorafin 2, zinc borate 7 and calcium stearate 2 in compound B: maleic anhydride graft PE 60, methyl vinyl silicone rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent ODA 3, the poly-caproic acid.
The preparation method of tension waterproof double shield control cables material may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 10-20 minute again, the control temperature was plasticated 3-5 minute discharging at last at 130-150 ℃ under 140-150 ℃.
Described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 700-900 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
The tension waterproof double shield control cables material performance that the present invention makes:
A kind of tension waterproof double shield control cables material and preparation method thereof
Embodiment
Embodiment 1:Tension waterproof double shield control cables material, the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 35, paracril 25, dimethyl silicone rubber 15, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 35, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, dihydroxyphenyl propane 2,3-aminopropyl trimethoxysilane 2, Zinic stearas 2, irgasfos 168 3.5, two ten four carbon alcohols esters 2, talcum powder 15 and smoke sheet rubber 2;
Vinegar 8, linking agent TAIC 2.5, clorafin 2, zinc borate 7 and calcium stearate 2 in compound B: maleic anhydride graft PE 60, methyl vinyl silicone rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent ODA 3, the poly-caproic acid.
The preparation method of tension waterproof double shield control cables material may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 10-20 minute again, the control temperature was plasticated 3-5 minute discharging at last at 130-150 ℃ under 140-150 ℃.
Described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 700-900 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
The tension waterproof double shield control cables material performance that the present invention makes:
Claims (4)
1. tension waterproof double shield control cables material is characterized in that the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 30-40, paracril 20-30, dimethyl silicone rubber 10-20, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 30-40, semi-reinforcing hydrocarbon black 1-3, modified Nano powder 40-60, dihydroxyphenyl propane 1-3,3-aminopropyl trimethoxysilane 1.5-2.5, Zinic stearas 1-3, irgasfos 168 3-4, two ten four carbon alcohols ester 1-3, talcum powder 10-20 and smoke sheet rubber 1-3;
Compound B: vinegar 5-10, linking agent TAIC 2-3, clorafin 1-3, zinc borate 5-8 and calcium stearate 1-3 in maleic anhydride graft PE 50-70, methyl vinyl silicone rubber 20-40, polyacrylic ester 20-30, poly--4-methyl-1-pentene 0.3-0.5, anti-aging agent ODA 2-4, the poly-caproic acid.
2. tension waterproof double shield control cables material according to claim 1 is characterized in that the weight part of its constitutive material is:
Compound A: methyl vinyl silicone rubber 35, paracril 25, dimethyl silicone rubber 15, maleic anhydride grafted ethene-vinyl acetic monomer multipolymer 35, semi-reinforcing hydrocarbon black 2, modified Nano powder 50, dihydroxyphenyl propane 2,3-aminopropyl trimethoxysilane 2, Zinic stearas 2, irgasfos 168 3.5, two ten four carbon alcohols esters 2, talcum powder 15 and smoke sheet rubber 2;
Vinegar 8, linking agent TAIC 2.5, clorafin 2, zinc borate 7 and calcium stearate 2 in compound B: maleic anhydride graft PE 60, methyl vinyl silicone rubber 30, polyacrylic ester 25, poly--4-methyl-1-pentene 0.4, anti-aging agent ODA 3, the poly-caproic acid.
3. the preparation method of a tension waterproof double shield control cables material as claimed in claim 1 or 2 is characterized in that may further comprise the steps:
(1) at first takes by weighing respectively each raw material of compound A, B by the weight part of constitutive material; With the raw material of compound A, B respectively temperature 105-115 ℃ after banburying 4-6 minute, after the banburying again temperature 175-185 ℃ lower mixing 28-32 minute, obtain respectively compound A and compound B;
(2) mix compound A and compound B, added in the mixing roll mixing 10-20 minute again, the control temperature was plasticated 3-5 minute discharging at last at 130-150 ℃ under 140-150 ℃.
4. tension waterproof double shield control cables material according to claim 1 and 2, it is characterized in that: described modified Nano powder, preparation method thereof be calcium carbonate, celestite powder, feldspar in powder in the ratio of 1:1:1 temperature 700-900 ℃ lower scaling loss 4-5 hour, after grind to form nanometer powder, it is even to admix the Di(dioctylpyrophosphato) ethylene titanate agitating that is equivalent to powder weight 3-5%, oven dry is ground into powder.
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CN102977611A (en) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method |
CN103289415A (en) * | 2013-05-06 | 2013-09-11 | 安徽格林生态高分子材料技术有限公司 | Cable sheath material containing modified methyl vinyl silicone rubber and preparation method thereof |
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CN103554597A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Temperature-resistant and corrosion-resistant modified silicone rubber cable material |
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CN105802242A (en) * | 2016-04-15 | 2016-07-27 | 安徽华联电缆集团有限公司 | Stretch-proof shielding cable material formula and preparation method of stretch-proof shielding cable material |
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CN106349699A (en) * | 2016-08-23 | 2017-01-25 | 陈建琴 | Antistatic silicone rubber material for cable |
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CN101245169A (en) * | 2008-03-21 | 2008-08-20 | 江苏德威新材料股份有限公司 | Water cooking preventing low-smoke non-halogen flame-proof silicone hydride crosslinked polyolefin composition and method of producing the same |
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Patent Citations (1)
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CN101245169A (en) * | 2008-03-21 | 2008-08-20 | 江苏德威新材料股份有限公司 | Water cooking preventing low-smoke non-halogen flame-proof silicone hydride crosslinked polyolefin composition and method of producing the same |
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CN102977611B (en) * | 2012-11-05 | 2016-01-20 | 安徽金桥电缆有限公司 | A kind of computer halide-free low-smoke fireproof cable material and preparation method thereof |
CN102977611A (en) * | 2012-11-05 | 2013-03-20 | 安徽金桥电缆有限公司 | Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method |
CN103289415A (en) * | 2013-05-06 | 2013-09-11 | 安徽格林生态高分子材料技术有限公司 | Cable sheath material containing modified methyl vinyl silicone rubber and preparation method thereof |
CN103289415B (en) * | 2013-05-06 | 2015-10-07 | 安徽格林生态高分子材料技术有限公司 | A kind of cable jacket material containing modified methyl vinylsiloxane rubber and preparation method thereof |
CN103289416A (en) * | 2013-05-22 | 2013-09-11 | 吴江市德佐日用化学品有限公司 | Environment-friendly flame-retardant silicone rubber and butadiene rubber blending material |
CN103554597A (en) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | Temperature-resistant and corrosion-resistant modified silicone rubber cable material |
CN105238062A (en) * | 2015-09-25 | 2016-01-13 | 宿松县焕然机电有限责任公司 | Motor slot wedge high-temperature-resistance insulation material |
CN105330915A (en) * | 2015-12-14 | 2016-02-17 | 苏州鑫德杰电子有限公司 | Anti-aging cable sheath material and preparation method thereof |
CN105802242A (en) * | 2016-04-15 | 2016-07-27 | 安徽华联电缆集团有限公司 | Stretch-proof shielding cable material formula and preparation method of stretch-proof shielding cable material |
CN105968546A (en) * | 2016-05-18 | 2016-09-28 | 张翔 | Formula of environment-friendly flame-retardant cable sheath and preparation method thereof |
CN106084322A (en) * | 2016-06-20 | 2016-11-09 | 李文军 | A kind of low loss insulation and manufacture method thereof |
CN106349699A (en) * | 2016-08-23 | 2017-01-25 | 陈建琴 | Antistatic silicone rubber material for cable |
CN107434899A (en) * | 2017-08-31 | 2017-12-05 | 安徽华海特种电缆集团有限公司 | A kind of anti-corrosion heat-resisting tension controls CABLE MATERIALS |
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