CN102977611A - Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method - Google Patents

Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method Download PDF

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Publication number
CN102977611A
CN102977611A CN2012104355136A CN201210435513A CN102977611A CN 102977611 A CN102977611 A CN 102977611A CN 2012104355136 A CN2012104355136 A CN 2012104355136A CN 201210435513 A CN201210435513 A CN 201210435513A CN 102977611 A CN102977611 A CN 102977611A
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China
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parts
clay
cable material
antioxidant
potter
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CN2012104355136A
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CN102977611B (en
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姜睿
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Bengbu Shangwei Intellectual Property Operations Co., Ltd.
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Anhui Jinqiao Cable Co Ltd
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Abstract

The invention provides a zero-halogen and low-smoke flame retardant cable material for computers. The cable material is prepared from the following raw materials, by weight, 20-30 parts of polypropylene, 60-80 parts of methyl-vinyl silicone rubber, 10-20 parts of an EVA resin, 8-10 parts of aluminum hydroxide, 0.5-1.0 part of butyl stearate, 1-3 parts of zinc stearate, 8-12 parts of epoxy soybean oil, 4-6 parts of zinc oxide, 0.5-1.0 part of molybdenum trioxide, 30-50 parts of fumed silica, 10-13 parts of modified argil, 0.5-1.0 part of an antioxidant H, 0.1-0.3 parts of an antioxidant AW, 0.5-1.5 parts of a promoter NOBS, 0.2-0.5 parts of a vulcanizing agent DCBP, 8-10 parts of ammonium polyphosphate, 12-15 parts of antimony (III) oxide and 6-8 parts of zinc borate hydrate. The cable material has the advantages of excellent flame retardation, very less smoke in combustion, no generation of toxic gases or corrosive gases, good weather resistance, good abrasion resistance and good insulation property.

Description

A kind of computer is with halide-free low-smoke fireproof cable material and preparation method thereof
Technical field
The present invention relates to the CABLE MATERIALS field, be specifically related to a kind of computer with halide-free low-smoke fireproof cable material and preparation method thereof.
Background technology
Fast development along with global economy, and the enhancing of human environmental consciousness, each field is more and more higher to the requirement of the quality and performance of electric wire, the fire that causes because of wearing out of electric wire, cable also gets more and more, how to reduce the incidence of fire and presence of fire the time mortality ratio, low cigarette, Halogen, fire-retardant, developing direction that environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the at present production of halide-free low-smoke fireproof cable material is to add a large amount of aluminium hydroxide or magnesium hydroxides to reach flame retardant effect in polyolefin substrate mostly, yet, the adding of a large amount of inorganic materials, affected physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, poor, oil-proofness of softness, weathering resistance and flame retardant resistance are not fine at normal temperatures for they.
Summary of the invention
The invention provides a kind of computer with halide-free low-smoke fireproof cable material and preparation method thereof.
The technical solution used in the present invention is:
A kind of computer halide-free low-smoke fireproof cable material is characterized in that: the raw material by following weight part is made: polypropylene 20-30 part, methyl vinyl silicone rubber 60-80 part, EVA resin 10-20 part, aluminium hydroxide 8-10 part, butyl stearate 0.5-1.0 part, Zinic stearas 1-3 part, epoxy soybean oil 8-12 part, zinc oxide 4-6 part, molybdic oxide 0.5-1.0 part, gas-phase silica 30-50 part, modification potter's clay 10-13,0.5-1.0 part of antioxidant H, antioxidant A W 0.1-0.3 part, accelerant NOBS 0.5-1.5 part, vulcanizing agent DCBP 0.2-0.5 part, ammonium polyphosphate 8-10 part, antimonous oxide 12-15 part, hydration zinc borate 6-8 part.
Described computer halide-free low-smoke fireproof cable material is characterized in that: the raw material by following weight part is made: polipropene 25 part, methyl vinyl silicone rubber 70, EVA resin 15,9 parts in aluminium hydroxide, 0.6 part of butyl stearate, Zinic stearas 2,10 parts of epoxy soybean oils, 5 parts in zinc oxide, 0.8 part of molybdic oxide, 40 parts of gas-phase silicas, modification potter's clay 12,0.8 part of antioxidant H, 0.2 part of antioxidant A W, 0.8 part of accelerant NOBS, vulcanizing agent DCBP 0.4, ammonium polyphosphate 9, antimonous oxide 14, hydration zinc borate 7.
Described computer is characterized in that with the preparation method of halide-free low-smoke fireproof cable material:
(1) presses formula rate polypropylene, methyl vinyl silicone rubber, EVA resin and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 70-80 ℃;
(2) fillers such as modification potter's clay, zinc oxide, gas-phase silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, by twin screw extruder plasticizing extruding pelletization, get final product, the extrusion temperature of forcing machine is 120-150 ℃.
Beneficial effect
CABLE MATERIALS of the present invention not only has excellent flame retardancy and flame-retarding power not; . the amount of being fuming is considerably less during burning, do not produce toxic gas, do not produce corrosive gases, and have simultaneously good weathering resistance, a wear resistance, good insulating has overcome the adding because of a large amount of aluminium hydroxide or magnesium hydroxide in prescription of existing non-halogen flame-retardant cable and has caused the physical and mechanical properties of CABLE MATERIALS and the defective that process industrial art performance descends.
Embodiment
Computer halide-free low-smoke fireproof cable material is made by the raw material of following weight part: polipropene 25 part, methyl vinyl silicone rubber 70, EVA resin 15,9 parts in aluminium hydroxide, 0.6 part of butyl stearate, Zinic stearas 2,10 parts of epoxy soybean oils, 5 parts in zinc oxide, 0.8 part of molybdic oxide, 40 parts of gas-phase silicas, modification potter's clay 12,0.8 part of antioxidant H, 0.2 part of antioxidant A W, 0.8 part of accelerant NOBS, vulcanizing agent DCBP 0.4, ammonium polyphosphate 9, antimonous oxide 14, hydration zinc borate 7.
The preparation method:
(1) presses formula rate polypropylene, methyl vinyl silicone rubber, EVA resin and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 70-80 ℃;
(2) fillers such as modification potter's clay, zinc oxide, gas-phase silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, by twin screw extruder plasticizing extruding pelletization, get final product, the extrusion temperature of forcing machine is 120-150 ℃.
The CABLE MATERIALS that processes with present embodiment is pressed into test piece after 160 ℃ * 40min thermal ageing, and it is as follows to record its performance:
Project The result
Tensile strength MPa 10.5
Elongation at break % 360
Volume specific resistance Ω .cm 6.5×10 12
Oxygen index % 39
135 ℃ * 168h thermal ageing back draft intensity 〉= 20.7MPa
The unit mass smoke density 14.3g

Claims (3)

1. computer halide-free low-smoke fireproof cable material, it is characterized in that: the raw material by following weight part is made: polypropylene 20-30 part, methyl vinyl silicone rubber 60-80 part, EVA resin 10-20 part, aluminium hydroxide 8-10 part, butyl stearate 0.5-1.0 part, Zinic stearas 1-3 part, epoxy soybean oil 8-12 part, zinc oxide 4-6 part, molybdic oxide 0.5-1.0 part, gas-phase silica 30-50 part, modification potter's clay 10-13,0.5-1.0 part of antioxidant H, antioxidant A W 0.1-0.3 part, accelerant NOBS 0.5-1.5 part, vulcanizing agent DCBP 0.2-0.5 part, ammonium polyphosphate 8-10 part, antimonous oxide 12-15 part, hydration zinc borate 6-8 part;
Described modification potter's clay prepares by the following method:
(1), potter's clay is with 10-15% salt acid soak 3-4 hour, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in potter's clay is added to the water, add again sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that is equivalent to potter's clay weight 2-3%, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder.
2. computer according to claim 1 halide-free low-smoke fireproof cable material, it is characterized in that: the raw material by following weight part is made: polipropene 25 part, methyl vinyl silicone rubber 70, EVA resin 15,9 parts in aluminium hydroxide, 0.6 part of butyl stearate, Zinic stearas 2,10 parts of epoxy soybean oils, 5 parts in zinc oxide, 0.8 part of molybdic oxide, 40 parts of gas-phase silicas, modification potter's clay 12,0.8 part of antioxidant H, 0.2 part of antioxidant A W, 0.8 part of accelerant NOBS, vulcanizing agent DCBP 0.4, ammonium polyphosphate 9, antimonous oxide 14, hydration zinc borate 7.
3. a computer as claimed in claim 1 or 2 is characterized in that with the preparation method of halide-free low-smoke fireproof cable material:
(1) presses formula rate polypropylene, methyl vinyl silicone rubber, EVA resin and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 70-80 ℃;
(2) fillers such as modification potter's clay, zinc oxide, gas-phase silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, by twin screw extruder plasticizing extruding pelletization, get final product, the extrusion temperature of forcing machine is 120-150 ℃.
CN201210435513.6A 2012-11-05 2012-11-05 A kind of computer halide-free low-smoke fireproof cable material and preparation method thereof Active CN102977611B (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467998A (en) * 2013-08-26 2013-12-25 晶锋集团股份有限公司 Anti-cracking silicone rubber cable material and preparation method thereof
CN103509234A (en) * 2013-10-12 2014-01-15 绿宝电缆(集团)有限公司 Halogen-free, environment-friendly and flame-retardant polyolefin cable material containing polysiloxane
CN104725865A (en) * 2014-12-17 2015-06-24 苏州锦腾电子科技有限公司 Wear-resistant and high-temperature resistant silicone rubber and preparation method thereof
CN104945916A (en) * 2015-07-16 2015-09-30 常州市武进凯利达电子有限公司 High temperature resistance flaming-retardant silicone rubber cable material for electric power and preparing method thereof
CN105199225A (en) * 2015-09-29 2015-12-30 安徽蓝德集团股份有限公司 Heat conducting flame-retardant control cable
CN105754352A (en) * 2016-05-12 2016-07-13 王维娜 Flame-retardant fire-resistant power cable material and preparation method thereof
CN105860183A (en) * 2016-05-18 2016-08-17 安徽华星电缆集团有限公司 Formula and preparation method of anti-aging high-temperature-resistant cable sheath
CN105885430A (en) * 2016-05-04 2016-08-24 安徽省康利亚股份有限公司 High-wear-resistance tensile environmental-friendly high-speed rail cable material
CN105924783A (en) * 2016-06-03 2016-09-07 繁昌县菲德通讯材料设计有限公司 Corrosion-resistant ship cable sheath material
CN105949784A (en) * 2016-05-12 2016-09-21 东莞市联洲知识产权运营管理有限公司 Efficient insulating heat-resisting silicone rubber cable material and preparation method thereof
CN106433138A (en) * 2016-09-21 2017-02-22 苏州直角新材料有限公司 Heatproof nanometer silicon rubber and preparing method thereof
CN108165020A (en) * 2017-11-28 2018-06-15 安徽伟合电子科技有限公司 A kind of automobile instrument harness method for preparing rubber
CN108395700A (en) * 2018-04-13 2018-08-14 山东迪龙电缆有限公司 A kind of LSOH anti-flaming rubber cable material
CN109370040A (en) * 2018-07-31 2019-02-22 中广核高新核材科技(苏州)有限公司 Motor lead-in flame-proof polyolefine cable material of resisting impregnation paint and preparation method thereof
CN111647271A (en) * 2020-06-13 2020-09-11 湖北科普达光电材料有限公司 High-temperature-resistant flame-retardant organic silicon elastomer cable material and preparation method thereof
CN115477806A (en) * 2022-10-12 2022-12-16 盐城市顺泽工贸有限公司 Low-smoke halogen-free flame-retardant sheath material

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EP0393813B1 (en) * 1989-04-19 1994-05-04 The Furukawa Electric Co., Ltd. Flame retardant and a flame-retardant resin composition containing the same
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CN102911504A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 Environment-friendly waterproof and double-shielding control cable material and preparation method thereof
CN102911467A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material

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EP0393813B1 (en) * 1989-04-19 1994-05-04 The Furukawa Electric Co., Ltd. Flame retardant and a flame-retardant resin composition containing the same
US20060014859A1 (en) * 2002-11-19 2006-01-19 Fujikura Ltd. Flame retardant ethylene family resin composite and flame retardant electric wire or cable
CN102911504A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 Environment-friendly waterproof and double-shielding control cable material and preparation method thereof
CN102911467A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467998A (en) * 2013-08-26 2013-12-25 晶锋集团股份有限公司 Anti-cracking silicone rubber cable material and preparation method thereof
CN103509234A (en) * 2013-10-12 2014-01-15 绿宝电缆(集团)有限公司 Halogen-free, environment-friendly and flame-retardant polyolefin cable material containing polysiloxane
CN103509234B (en) * 2013-10-12 2016-04-13 绿宝电缆(集团)有限公司 A kind of halogen-free environment-friendly flame-proof cable material of polyolefin containing polysiloxane
CN104725865A (en) * 2014-12-17 2015-06-24 苏州锦腾电子科技有限公司 Wear-resistant and high-temperature resistant silicone rubber and preparation method thereof
CN104945916A (en) * 2015-07-16 2015-09-30 常州市武进凯利达电子有限公司 High temperature resistance flaming-retardant silicone rubber cable material for electric power and preparing method thereof
CN105199225A (en) * 2015-09-29 2015-12-30 安徽蓝德集团股份有限公司 Heat conducting flame-retardant control cable
CN105885430A (en) * 2016-05-04 2016-08-24 安徽省康利亚股份有限公司 High-wear-resistance tensile environmental-friendly high-speed rail cable material
CN105754352A (en) * 2016-05-12 2016-07-13 王维娜 Flame-retardant fire-resistant power cable material and preparation method thereof
CN105949784A (en) * 2016-05-12 2016-09-21 东莞市联洲知识产权运营管理有限公司 Efficient insulating heat-resisting silicone rubber cable material and preparation method thereof
CN105860183A (en) * 2016-05-18 2016-08-17 安徽华星电缆集团有限公司 Formula and preparation method of anti-aging high-temperature-resistant cable sheath
CN105924783A (en) * 2016-06-03 2016-09-07 繁昌县菲德通讯材料设计有限公司 Corrosion-resistant ship cable sheath material
CN106433138A (en) * 2016-09-21 2017-02-22 苏州直角新材料有限公司 Heatproof nanometer silicon rubber and preparing method thereof
CN108165020A (en) * 2017-11-28 2018-06-15 安徽伟合电子科技有限公司 A kind of automobile instrument harness method for preparing rubber
CN108395700A (en) * 2018-04-13 2018-08-14 山东迪龙电缆有限公司 A kind of LSOH anti-flaming rubber cable material
CN109370040A (en) * 2018-07-31 2019-02-22 中广核高新核材科技(苏州)有限公司 Motor lead-in flame-proof polyolefine cable material of resisting impregnation paint and preparation method thereof
CN111647271A (en) * 2020-06-13 2020-09-11 湖北科普达光电材料有限公司 High-temperature-resistant flame-retardant organic silicon elastomer cable material and preparation method thereof
CN115477806A (en) * 2022-10-12 2022-12-16 盐城市顺泽工贸有限公司 Low-smoke halogen-free flame-retardant sheath material

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