CN102977611A - Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method - Google Patents
Zero-halogen and low-smoke flame retardant cable material for computers, and its preparation method Download PDFInfo
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- CN102977611A CN102977611A CN2012104355136A CN201210435513A CN102977611A CN 102977611 A CN102977611 A CN 102977611A CN 2012104355136 A CN2012104355136 A CN 2012104355136A CN 201210435513 A CN201210435513 A CN 201210435513A CN 102977611 A CN102977611 A CN 102977611A
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- cable material
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- 239000000463 material Substances 0.000 title claims abstract description 27
- 239000000779 smoke Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000003063 flame retardant Substances 0.000 title abstract description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 5
- 229910052736 halogen Inorganic materials 0.000 title abstract description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 9
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 9
- 239000004945 silicone rubber Substances 0.000 claims abstract description 9
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 7
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- OKISUZLXOYGIFP-UHFFFAOYSA-N 4,4'-dichlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=C(Cl)C=C1 OKISUZLXOYGIFP-UHFFFAOYSA-N 0.000 claims abstract description 6
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 6
- 239000004593 Epoxy Substances 0.000 claims abstract description 6
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004743 Polypropylene Substances 0.000 claims abstract description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 6
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- -1 polypropylene Polymers 0.000 claims abstract description 6
- 229920001155 polypropylene Polymers 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 6
- 239000003549 soybean oil Substances 0.000 claims abstract description 6
- 239000004927 clay Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 8
- 230000036571 hydration Effects 0.000 claims description 5
- 238000006703 hydration reaction Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 230000003712 anti-aging effect Effects 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 239000008367 deionised water Substances 0.000 claims 2
- 229910021641 deionized water Inorganic materials 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- WGKLIJDVPACLGG-UHFFFAOYSA-N trizinc diborate hydrate Chemical compound O.[Zn++].[Zn++].[Zn++].[O-]B([O-])[O-].[O-]B([O-])[O-] WGKLIJDVPACLGG-UHFFFAOYSA-N 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Abstract
Description
Project | The result |
Tensile strength MPa | 10.5 |
Elongation at break % | 360 |
Volume specific resistance Ω .cm | 6.5×10 12 |
Oxygen index % | 39 |
135 ℃ * 168h thermal ageing back draft intensity 〉= | 20.7MPa |
The unit mass smoke density | 14.3g |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210435513.6A CN102977611B (en) | 2012-11-05 | 2012-11-05 | A kind of computer halide-free low-smoke fireproof cable material and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210435513.6A CN102977611B (en) | 2012-11-05 | 2012-11-05 | A kind of computer halide-free low-smoke fireproof cable material and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102977611A true CN102977611A (en) | 2013-03-20 |
CN102977611B CN102977611B (en) | 2016-01-20 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201210435513.6A Active CN102977611B (en) | 2012-11-05 | 2012-11-05 | A kind of computer halide-free low-smoke fireproof cable material and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN102977611B (en) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103467998A (en) * | 2013-08-26 | 2013-12-25 | 晶锋集团股份有限公司 | Anti-cracking silicone rubber cable material and preparation method thereof |
CN103509234A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆(集团)有限公司 | Halogen-free, environment-friendly and flame-retardant polyolefin cable material containing polysiloxane |
CN104725865A (en) * | 2014-12-17 | 2015-06-24 | 苏州锦腾电子科技有限公司 | Wear-resistant and high-temperature resistant silicone rubber and preparation method thereof |
CN104945916A (en) * | 2015-07-16 | 2015-09-30 | 常州市武进凯利达电子有限公司 | High temperature resistance flaming-retardant silicone rubber cable material for electric power and preparing method thereof |
CN105199225A (en) * | 2015-09-29 | 2015-12-30 | 安徽蓝德集团股份有限公司 | Heat conducting flame-retardant control cable |
CN105754352A (en) * | 2016-05-12 | 2016-07-13 | 王维娜 | Flame-retardant fire-resistant power cable material and preparation method thereof |
CN105860183A (en) * | 2016-05-18 | 2016-08-17 | 安徽华星电缆集团有限公司 | Formula and preparation method of anti-aging high-temperature-resistant cable sheath |
CN105885430A (en) * | 2016-05-04 | 2016-08-24 | 安徽省康利亚股份有限公司 | High-wear-resistance tensile environmental-friendly high-speed rail cable material |
CN105924783A (en) * | 2016-06-03 | 2016-09-07 | 繁昌县菲德通讯材料设计有限公司 | Corrosion-resistant ship cable sheath material |
CN105949784A (en) * | 2016-05-12 | 2016-09-21 | 东莞市联洲知识产权运营管理有限公司 | Efficient insulating heat-resisting silicone rubber cable material and preparation method thereof |
CN106433138A (en) * | 2016-09-21 | 2017-02-22 | 苏州直角新材料有限公司 | Heatproof nanometer silicon rubber and preparing method thereof |
CN108165020A (en) * | 2017-11-28 | 2018-06-15 | 安徽伟合电子科技有限公司 | A kind of automobile instrument harness method for preparing rubber |
CN108395700A (en) * | 2018-04-13 | 2018-08-14 | 山东迪龙电缆有限公司 | A kind of LSOH anti-flaming rubber cable material |
CN109370040A (en) * | 2018-07-31 | 2019-02-22 | 中广核高新核材科技(苏州)有限公司 | Motor lead-in flame-proof polyolefine cable material of resisting impregnation paint and preparation method thereof |
CN111647271A (en) * | 2020-06-13 | 2020-09-11 | 湖北科普达光电材料有限公司 | High-temperature-resistant flame-retardant organic silicon elastomer cable material and preparation method thereof |
CN115477806A (en) * | 2022-10-12 | 2022-12-16 | 盐城市顺泽工贸有限公司 | Low-smoke halogen-free flame-retardant sheath material |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0393813B1 (en) * | 1989-04-19 | 1994-05-04 | The Furukawa Electric Co., Ltd. | Flame retardant and a flame-retardant resin composition containing the same |
US20060014859A1 (en) * | 2002-11-19 | 2006-01-19 | Fujikura Ltd. | Flame retardant ethylene family resin composite and flame retardant electric wire or cable |
CN102911504A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Environment-friendly waterproof and double-shielding control cable material and preparation method thereof |
CN102911467A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material |
-
2012
- 2012-11-05 CN CN201210435513.6A patent/CN102977611B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0393813B1 (en) * | 1989-04-19 | 1994-05-04 | The Furukawa Electric Co., Ltd. | Flame retardant and a flame-retardant resin composition containing the same |
US20060014859A1 (en) * | 2002-11-19 | 2006-01-19 | Fujikura Ltd. | Flame retardant ethylene family resin composite and flame retardant electric wire or cable |
CN102911504A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Environment-friendly waterproof and double-shielding control cable material and preparation method thereof |
CN102911467A (en) * | 2012-09-18 | 2013-02-06 | 铜陵市铜都特种线缆厂 | Tensile, waterproof, double-shielding control cable material and preparation method of tensile, waterproof, double-shielding control cable material |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103467998A (en) * | 2013-08-26 | 2013-12-25 | 晶锋集团股份有限公司 | Anti-cracking silicone rubber cable material and preparation method thereof |
CN103509234A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆(集团)有限公司 | Halogen-free, environment-friendly and flame-retardant polyolefin cable material containing polysiloxane |
CN103509234B (en) * | 2013-10-12 | 2016-04-13 | 绿宝电缆(集团)有限公司 | A kind of halogen-free environment-friendly flame-proof cable material of polyolefin containing polysiloxane |
CN104725865A (en) * | 2014-12-17 | 2015-06-24 | 苏州锦腾电子科技有限公司 | Wear-resistant and high-temperature resistant silicone rubber and preparation method thereof |
CN104945916A (en) * | 2015-07-16 | 2015-09-30 | 常州市武进凯利达电子有限公司 | High temperature resistance flaming-retardant silicone rubber cable material for electric power and preparing method thereof |
CN105199225A (en) * | 2015-09-29 | 2015-12-30 | 安徽蓝德集团股份有限公司 | Heat conducting flame-retardant control cable |
CN105885430A (en) * | 2016-05-04 | 2016-08-24 | 安徽省康利亚股份有限公司 | High-wear-resistance tensile environmental-friendly high-speed rail cable material |
CN105754352A (en) * | 2016-05-12 | 2016-07-13 | 王维娜 | Flame-retardant fire-resistant power cable material and preparation method thereof |
CN105949784A (en) * | 2016-05-12 | 2016-09-21 | 东莞市联洲知识产权运营管理有限公司 | Efficient insulating heat-resisting silicone rubber cable material and preparation method thereof |
CN105860183A (en) * | 2016-05-18 | 2016-08-17 | 安徽华星电缆集团有限公司 | Formula and preparation method of anti-aging high-temperature-resistant cable sheath |
CN105924783A (en) * | 2016-06-03 | 2016-09-07 | 繁昌县菲德通讯材料设计有限公司 | Corrosion-resistant ship cable sheath material |
CN106433138A (en) * | 2016-09-21 | 2017-02-22 | 苏州直角新材料有限公司 | Heatproof nanometer silicon rubber and preparing method thereof |
CN108165020A (en) * | 2017-11-28 | 2018-06-15 | 安徽伟合电子科技有限公司 | A kind of automobile instrument harness method for preparing rubber |
CN108395700A (en) * | 2018-04-13 | 2018-08-14 | 山东迪龙电缆有限公司 | A kind of LSOH anti-flaming rubber cable material |
CN109370040A (en) * | 2018-07-31 | 2019-02-22 | 中广核高新核材科技(苏州)有限公司 | Motor lead-in flame-proof polyolefine cable material of resisting impregnation paint and preparation method thereof |
CN111647271A (en) * | 2020-06-13 | 2020-09-11 | 湖北科普达光电材料有限公司 | High-temperature-resistant flame-retardant organic silicon elastomer cable material and preparation method thereof |
CN115477806A (en) * | 2022-10-12 | 2022-12-16 | 盐城市顺泽工贸有限公司 | Low-smoke halogen-free flame-retardant sheath material |
Also Published As
Publication number | Publication date |
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CN102977611B (en) | 2016-01-20 |
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Inventor after: Wang Donghua Inventor before: Jiang Rui |
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Effective date of registration: 20171009 Address after: 075001 Cemetery Road 1, Qiaodong District, Hebei, Zhangjiakou Patentee after: Wang Donghua Address before: 244121 Tongling Jinqiao Industrial Park, Tongling, Anhui Patentee before: Anhui Jinqiao Cable Co., Ltd. |
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CP02 | Change in the address of a patent holder |
Address after: 210000 Jinyu Central Building 101, 33 Mufu West Road, Gulou District, Nanjing City, Jiangsu Province Patentee after: Wang Donghua Address before: 075001 No. 1 Lingyuan Road, Qiaodong District, Zhangjiakou City, Hebei Province Patentee before: Wang Donghua |
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Effective date of registration: 20190925 Address after: 233090 No. 10, 32 blocks, Guangcai Dachang 8 District, Bengbu City, Anhui Province Patentee after: Bengbu Shangwei Intellectual Property Operations Co., Ltd. Address before: 210000 Jinyu Central Building 101, 33 Mufu West Road, Gulou District, Nanjing City, Jiangsu Province Patentee before: Wang Dong Hua |
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