CN103160034A - Environment-friendly inflaming retarding rubber composite materials - Google Patents
Environment-friendly inflaming retarding rubber composite materials Download PDFInfo
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- CN103160034A CN103160034A CN2013100539934A CN201310053993A CN103160034A CN 103160034 A CN103160034 A CN 103160034A CN 2013100539934 A CN2013100539934 A CN 2013100539934A CN 201310053993 A CN201310053993 A CN 201310053993A CN 103160034 A CN103160034 A CN 103160034A
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Abstract
The invention discloses an environment-friendly inflaming retarding rubber composite material which is characterized by comprising following components part by weight of 100 parts of chlorinated polyethylene rubber, 10-30 parts of ethylene propylene rubber, 2-4 parts of vulcanizing agent, 0.3-5 parts of accelerant M, 1-5 parts of zinc oxide, 20-40 parts of fire retardant, 1-5 parts of lubricant, 2-5 parts of flatting agent, 5-10 parts of silane coupling agent and 0-3 parts of fortifier. The material which is prepared by using the components is good in inflaming retarding effect, excellent in mechanical property and abrasion-resistance property, low in production cost and easy to implement.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of environmental protection flame retardant rubber composite.
Background technology
Elastomeric material is widely used in automobile, household electrical appliance, office appliance, machinery, aerospace, field, hypogee due to characteristics such as its high own elasticity, electrical insulation capability, chemical-resistant and resistance to air loss.Most of rubber is all flammable or inflammable, so rubber item presence of fire the dangerous and hazardness of environment is increased greatly, therefore, the flame retardant resistance that improves rubber and goods thereof is very important.Traditional halogen fire retardant is effective, but it can discharge toxic and harmful in combustion processes, be detrimental to health, and also environment is impacted simultaneously, could satisfy flame retardant properties and inorganic combustion inhibitor often needs to add very large amount, but can affect the performance of material.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection flame retardant rubber composite.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of environment-friendly rubber flame-proof composite material it is characterized in that being comprised of the component of following weight part: 100 parts of chlorinated polyethylene rubbers, ethylene-propylene rubber(EPR) 10-30 part, vulcanizing agent 2-4 part, captax 0.3-5 part, zinc oxide 1-5 part, fire retardant 20-40 part, lubricant 1-5 part, flow agent 2-5 part, silane coupling agent 5-10 part, strengthening agent 0-3 part.
Described fire retardant is the mixing of nano-sized magnesium hydroxide, zinc borate and trimeric cyanamide.
Described strengthening agent is white carbon black.
The preparation method of environment-friendly rubber flame-proof composite material of the present invention, get the raw material of above-mentioned weight part, successively chlorinated polyethylene rubber, ethylene-propylene rubber(EPR), vulcanizing agent, captax, zinc oxide, fire retardant, lubricant, flow agent, silane coupling agent, strengthening agent are placed in mill, mixing 45min at the temperature of 76 ℃ namely obtains environmental protection flame retardant rubber composite of the present invention.
Beneficial effect of the present invention: the environmental protection flame retardant rubber composite of the present invention's preparation, good flame retardation effect, mechanical property and wear resisting property are good, and production cost is low, and is easy to implement.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
A kind of environment-friendly rubber flame-proof composite material is got each following raw material of weight part: 100 parts of chlorinated polyethylene rubbers, 10 parts, ethylene-propylene rubber(EPR), 2 parts of vulcanizing agents, 1 part of captax, 2 parts, zinc oxide, 20 parts of fire retardants, 2 parts of lubricants, 2 parts of flow agents, 5 parts of silane coupling agents, 1 part of strengthening agent.Successively chlorinated polyethylene rubber, ethylene-propylene rubber(EPR), vulcanizing agent, captax, zinc oxide, fire retardant, lubricant, flow agent, silane coupling agent, strengthening agent are placed in mill, mixing 45min at the temperature of 76 ℃ namely obtains environmental protection flame retardant rubber composite of the present invention.
Embodiment 2
A kind of environment-friendly rubber flame-proof composite material is got each following raw material of weight part: 3 parts of 100 parts of chlorinated polyethylene rubbers, 20 parts, ethylene-propylene rubber(EPR), 4 parts of vulcanizing agents, 0.3 part of captax, 1 part, zinc oxide, 25 parts of fire retardants, 1 part of lubricant, 5 parts of flow agents, silane coupled 8 parts, strengthening agent.Successively chlorinated polyethylene rubber, ethylene-propylene rubber(EPR), vulcanizing agent, captax, zinc oxide, fire retardant, lubricant, flow agent, silane coupling agent, strengthening agent are placed in mill, mixing 45min at the temperature of 76 ℃ namely obtains environmental protection flame retardant rubber composite of the present invention.
Embodiment 3
A kind of environment-friendly rubber flame-proof composite material is got each following raw material of weight part: 100 parts of chlorinated polyethylene rubbers, 15 parts, ethylene-propylene rubber(EPR), 3 parts of vulcanizing agents, 5 parts of captaxs, 4 parts, zinc oxide, 40 parts of fire retardants, 5 parts of lubricants, 4 parts of flow agents, 6 parts of silane coupling agents, 2 parts of strengthening agents.Successively chlorinated polyethylene rubber, ethylene-propylene rubber(EPR), vulcanizing agent, captax, zinc oxide, fire retardant, lubricant, flow agent, silane coupling agent, strengthening agent are placed in mill, mixing 45min at the temperature of 76 ℃ namely obtains environmental protection flame retardant rubber composite of the present invention.
Embodiment 4
A kind of environment-friendly rubber flame-proof composite material is got each following raw material of weight part: 100 parts of chlorinated polyethylene rubbers, 30 parts, ethylene-propylene rubber(EPR), 4 parts of vulcanizing agents, 3 parts of captaxs, 5 parts, zinc oxide, 30 parts of fire retardants, 3 parts of lubricants, 3 parts of flow agents, 10 parts of silane coupling agents.Successively chlorinated polyethylene rubber, ethylene-propylene rubber(EPR), vulcanizing agent, captax, zinc oxide, fire retardant, lubricant, flow agent, silane coupling agent are placed in mill, mixing 45min at the temperature of 76 ℃ namely obtains environmental protection flame retardant rubber composite of the present invention.
For verifying product performance of the present invention, do following test
Tensile strength, fault growth rate and limiting oxygen index(LOI) test
The environment-friendly rubber flame-proof composite material that embodiment 1-4 makes is tested its tensile strength by GB/T 528-1998 and GB/T 529-1999, and fault growth rate and limiting oxygen index(LOI) the results are shown in Table 1, show that the present invention has good mechanical property.
Table 1 is that embodiment 1-3 prepares conductive rubber testing experiment result.
Claims (3)
1. an environmental protection flame retardant rubber composite, it is characterized in that being comprised of the component of following weight part: 100 parts of chlorinated polyethylene rubbers, ethylene-propylene rubber(EPR) 10-30 part, vulcanizing agent 2-4 part, captax 0.3-5 part, zinc oxide 1-5 part, fire retardant 20-40 part, lubricant 1-5 part, flow agent 2-5 part, silane coupling agent 5-10 part, strengthening agent 0-3 part.
2. environmental protection flame retardant rubber composite according to claim 1, is characterized in that described fire retardant is the mixing of nano-sized magnesium hydroxide, zinc borate and trimeric cyanamide.
3. environmental protection flame retardant rubber composite according to claim 1, is characterized in that described strengthening agent is white carbon black.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100539934A CN103160034A (en) | 2013-02-20 | 2013-02-20 | Environment-friendly inflaming retarding rubber composite materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100539934A CN103160034A (en) | 2013-02-20 | 2013-02-20 | Environment-friendly inflaming retarding rubber composite materials |
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| Publication Number | Publication Date |
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| CN103160034A true CN103160034A (en) | 2013-06-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2013100539934A Pending CN103160034A (en) | 2013-02-20 | 2013-02-20 | Environment-friendly inflaming retarding rubber composite materials |
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| CN (1) | CN103160034A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107134228A (en) * | 2017-07-20 | 2017-09-05 | 安徽欧品光电科技有限公司 | A kind of outdoor LED advertising board |
| CN107195256A (en) * | 2017-07-14 | 2017-09-22 | 安徽欧品光电科技有限公司 | A kind of lamp box |
| CN107195257A (en) * | 2017-07-14 | 2017-09-22 | 安徽欧品光电科技有限公司 | A kind of reflecting sign board |
| CN107314314A (en) * | 2017-07-14 | 2017-11-03 | 安徽欧品光电科技有限公司 | A kind of road illumination device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3891725A (en) * | 1974-10-04 | 1975-06-24 | Du Pont | Vulcanizable chlorinated elastomer composition |
| CN102399397A (en) * | 2011-09-29 | 2012-04-04 | 江苏亨通电力电缆有限公司 | Cold-resistant rubber cable sheath material and preparation method |
| CN102516675A (en) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | Mining cable rubber sheath glue |
-
2013
- 2013-02-20 CN CN2013100539934A patent/CN103160034A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3891725A (en) * | 1974-10-04 | 1975-06-24 | Du Pont | Vulcanizable chlorinated elastomer composition |
| CN102399397A (en) * | 2011-09-29 | 2012-04-04 | 江苏亨通电力电缆有限公司 | Cold-resistant rubber cable sheath material and preparation method |
| CN102516675A (en) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | Mining cable rubber sheath glue |
Non-Patent Citations (1)
| Title |
|---|
| 王娟等: "氢氧化镁协同阻燃剂研究进展", 《中国塑料》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107195256A (en) * | 2017-07-14 | 2017-09-22 | 安徽欧品光电科技有限公司 | A kind of lamp box |
| CN107195257A (en) * | 2017-07-14 | 2017-09-22 | 安徽欧品光电科技有限公司 | A kind of reflecting sign board |
| CN107314314A (en) * | 2017-07-14 | 2017-11-03 | 安徽欧品光电科技有限公司 | A kind of road illumination device |
| CN107134228A (en) * | 2017-07-20 | 2017-09-05 | 安徽欧品光电科技有限公司 | A kind of outdoor LED advertising board |
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Application publication date: 20130619 |
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