CN103571009A - Low-smoke halogen-free flame-retardant cable material - Google Patents
Low-smoke halogen-free flame-retardant cable material Download PDFInfo
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- CN103571009A CN103571009A CN201310464629.7A CN201310464629A CN103571009A CN 103571009 A CN103571009 A CN 103571009A CN 201310464629 A CN201310464629 A CN 201310464629A CN 103571009 A CN103571009 A CN 103571009A
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- 239000000463 material Substances 0.000 title claims abstract description 22
- 239000000779 smoke Substances 0.000 title abstract description 6
- 239000003063 flame retardant Substances 0.000 title abstract description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000002745 absorbent Effects 0.000 claims abstract description 6
- 239000002250 absorbent Substances 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000008116 calcium stearate Substances 0.000 claims abstract description 6
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 6
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 6
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 6
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 polyethylene Polymers 0.000 claims abstract description 6
- 229920000573 polyethylene Polymers 0.000 claims abstract description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 238000004079 fireproofing Methods 0.000 claims description 10
- 150000004820 halides Chemical class 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 239000005543 nano-size silicon particle Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims description 3
- 240000003553 Leptospermum scoparium Species 0.000 claims description 3
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 239000010977 jade Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 229940093429 polyethylene glycol 6000 Drugs 0.000 claims description 3
- 239000000341 volatile oil Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 abstract description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 2
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 2
- 238000005121 nitriding Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 230000007096 poisonous effect Effects 0.000 abstract 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
The invention provides a low-smoke halogen-free flame-retardant cable material. The low-smoke halogen-free flame-retardant cable material is prepared from the following raw materials in parts by weight: 30-40 parts of polyethylene, 20-30 parts of EVA (ethylene-vinyl acetate), 40-60 parts of magnesium hydroxide, 5-6 parts of nanometer silicon carbide, 0.2-0.4 part of nanometer nitriding aluminum powder, 4-6 parts of hydrotalcite, 2-3 parts of zinc molybdate, 2-4 parts of ethylene-octene copolymer grafted maleic anhydride, 0.1-1 part of tricresyl phosphate, 1-2 parts of calcium stearate, 0.5-1.0 part of stearic acid, 0.2-0.4 part of ultraviolet absorbent UV-531 and 8-10 parts of modified filler. The cable material provided by the invention has excellent flame resistance and incombustibility, generates little smoke during burning, does not generate poisonous gases and corrosive gases and meanwhile has good low temperature resistance, oil resistance and ultraviolet light resistance.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to fireproofing cable material without halide.
Background technology
Fast development along with global economy, and the enhancing of mankind's environmental consciousness, each field is more and more higher to the requirement of the quality and performance of electric wire, because of the aging fire causing of electric wire, cable also more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the production of halide-free low-smoke fireproof cable material is in polyolefin substrate, to add a large amount of magnesium hydroxides or aluminium hydroxide to reach flame retardant effect mostly at present, yet, adding of a large amount of inorganic materials, affected physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, poor, oil-proofness of softness, weathering resistance, resistance to low temperature are not fine at normal temperatures for they.
Summary of the invention
The invention provides fireproofing cable material without halide and preparation method thereof.
The technical solution used in the present invention is:
Fireproofing cable material without halide, is characterized in that: the raw material by following weight part is made: polyethylene 30-40, EVA20-30, magnesium hydroxide 40-60, nanometer silicon carbide 5-6, nano silicon nitride aluminium powder 0.2-0.4, hydrotalcite 4-6, zinc molybdate 2-3, ethylene-octene copolymer grafted maleic anhydride 2-4, Tritolyl Phosphate 0.1-1, calcium stearate 1-2, stearic acid 0.5-1.0, ultraviolet absorbent UV-531 0.2-0.4, modified filler 8-10.
Described fireproofing cable material without halide, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyethylene 40, EVA20, magnesium hydroxide 45, nanometer silicon carbide 5, nano silicon nitride aluminium powder 0.3, hydrotalcite 5, zinc molybdate 2, ethylene-octene copolymer grafted maleic anhydride 3, Tritolyl Phosphate 0.6, calcium stearate 1, stearic acid 0.6, ultraviolet absorbent UV-531 0.3, modified filler 9.
Described fireproofing cable material without halide, is characterized in that, described modified filler is to be prepared and obtained by following method:
Attapulgite is calcined to 3-4 hour at 540-580 ℃, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, the hydrochloric acid soln that adds 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filter, oven dry obtains filler powder, then in gained powder, add the tea tree ethereal oil that is equivalent to powder weight 1-2%, the zinc oxide of 1-2%, the tetramethylolmethane of 1-2%, 2-3% nanometer jade powder, common grinding after 1-2 hour, add again the aminopropyl triethoxysilane that is equivalent to powder weight 2-3%, 4-5% polyethylene glycol 6000, the morpholine of 2-3%, high speed dispersion with 11000-12000 rev/min is even, obtain.
Preparation method:
By formula rate, take each component raw material, the component raw material by taking stirs in high-speed mixer, again under the temperature range of 135-175 ℃ through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, and makes CABLE MATERIALS finished product.
Beneficial effect
CABLE MATERIALS of the present invention not only has excellent flame retardancy and flame-retarding power not; During burning, the amount of being fuming is considerably less, does not produce toxic gas, does not produce corrosive gases, and has good lower temperature resistance, uviolresistance simultaneously.
Embodiment
Fireproofing cable material without halide, by the raw material of following weight (kg), made:
Polyethylene 40, EVA20, magnesium hydroxide 45, nanometer silicon carbide 5, nano silicon nitride aluminium powder 0.3, hydrotalcite 5, zinc molybdate 2, ethylene-octene copolymer grafted maleic anhydride 3, Tritolyl Phosphate 0.6, calcium stearate 1, stearic acid 0.6, ultraviolet absorbent UV-531 0.3, modified filler 9
Preparation method:
By formula rate, take each component raw material, the component raw material by taking stirs in high-speed mixer, again under the temperature range of 135-175 ℃ through Banbury mixer banburying, twin-screw extrusion, the fervent granulation of flour milling, cyclopneumatic separator feeding, then bolting pack, and makes CABLE MATERIALS finished product.
Wherein, modified filler is to be prepared and obtained by following method:
Attapulgite is calcined 4 hours at 550 ℃, after taking-up, add in 4% sodium hydroxide solution and grind 1-2 hour, then, add 14% hydrochloric acid soln, regulating pH value is 4, ageing 12 hours, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filter, oven dry obtains filler powder, then in gained powder, add the tea tree ethereal oil that is equivalent to powder weight 2%, 1% zinc oxide, 2% tetramethylolmethane, 3% nanometer jade powder, common grinding after 1-2 hour, add again the aminopropyl triethoxysilane that is equivalent to powder weight 3%, 4% polyethylene glycol 6000, 3% morpholine, high speed dispersion with 11000-12000 rev/min is even, obtain.
The performance test results of the CABLE MATERIALS that the present embodiment makes is as following table:
Claims (3)
1. fireproofing cable material without halide, is characterized in that: the raw material by following weight part is made: polyethylene 30-40, EVA20-30, magnesium hydroxide 40-60, nanometer silicon carbide 5-6, nano silicon nitride aluminium powder 0.2-0.4, hydrotalcite 4-6, zinc molybdate 2-3, ethene-octene copolymer grafted maleic anhydride 2-4, Tritolyl Phosphate 0.1-1, calcium stearate 1-2, stearic acid 0.5-1.0, ultraviolet absorbent UV-531 0.2-0.4, modified filler 8-10.
2. fireproofing cable material without halide according to claim 1, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyethylene 40, EVA20, magnesium hydroxide 45, nanometer silicon carbide 5, nano silicon nitride aluminium powder 0.3, hydrotalcite 5, zinc molybdate 2, ethene-octene copolymer grafted maleic anhydride 3, Tritolyl Phosphate 0.6, calcium stearate 1, stearic acid 0.6, ultraviolet absorbent UV-531 0.3, modified filler 9.
3. fireproofing cable material without halide according to claim 1 and 2, is characterized in that, described modified filler is to be prepared and obtained by following method:
Attapulgite is calcined to 3-4 hour at 540-580 ℃, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, the hydrochloric acid soln that adds 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filter, oven dry obtains filler powder, then in gained powder, add the tea tree ethereal oil that is equivalent to powder weight 1-2%, the zinc oxide of 1-2%, the tetramethylolmethane of 1-2%, 2-3% nanometer jade powder, common grinding after 1-2 hour, add again the aminopropyl triethoxysilane that is equivalent to powder weight 2-3%, 4-5% polyethylene glycol 6000, the morpholine of 2-3%, high speed dispersion with 11000-12000 rev/min is even, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310464629.7A CN103571009B (en) | 2013-09-30 | 2013-09-30 | Fireproofing cable material without halide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310464629.7A CN103571009B (en) | 2013-09-30 | 2013-09-30 | Fireproofing cable material without halide |
Publications (2)
| Publication Number | Publication Date |
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| CN103571009A true CN103571009A (en) | 2014-02-12 |
| CN103571009B CN103571009B (en) | 2016-04-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310464629.7A Expired - Fee Related CN103571009B (en) | 2013-09-30 | 2013-09-30 | Fireproofing cable material without halide |
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| CN (1) | CN103571009B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341676A (en) * | 2014-11-03 | 2015-02-11 | 安徽天元电缆有限公司 | Novel low-smoke zero halogen flame-retardant cable material |
| CN104744800A (en) * | 2015-03-30 | 2015-07-01 | 安徽省高沟电缆有限公司 | Nano flame-retardant cable material for cable outer sheath and preparation method of nano flame-retardant cable material |
| CN104774372A (en) * | 2015-03-30 | 2015-07-15 | 安徽省高沟电缆有限公司 | High-performance flame-retardant cable material and preparation method thereof |
| CN105037892A (en) * | 2015-08-21 | 2015-11-11 | 安徽吉安特种线缆制造有限公司 | Flexible cable material with good low temperature resistance and preparation method of flexible cable material |
| CN106009153A (en) * | 2016-06-12 | 2016-10-12 | 安徽天元电缆有限公司 | Low-smoke flame-retardant cable material and preparing method thereof |
| CN106349554A (en) * | 2016-08-31 | 2017-01-25 | 欧宝聚合物江苏有限公司 | Low-smoke-amount non-halogen flame-retardant cable compound and preparation method thereof |
| JP2019137787A (en) * | 2018-02-13 | 2019-08-22 | 日立金属株式会社 | Non-halogen flame-retardant resin composition and insulated wires and cables including the same |
| CN113241218A (en) * | 2021-05-12 | 2021-08-10 | 安徽电缆股份有限公司 | Low-smoke halogen-free small-size wall-thickness cable for railway passenger car |
| CN113871083A (en) * | 2021-10-12 | 2021-12-31 | 广东金阳光电缆实业有限公司 | Low-smoke halogen-free insulated cable |
| CN115594904A (en) * | 2022-10-25 | 2023-01-13 | 南京青龙线缆材料有限公司（Cn） | Efficient ultraviolet crosslinking ageing-resistant low-smoke halogen-free cable material and preparation method thereof |
| CN116376181A (en) * | 2023-04-11 | 2023-07-04 | 江苏馨德高分子材料股份有限公司 | Low-smoke halogen-free flame retardant for anti-leakage coaxial cable |
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- 2013-09-30 CN CN201310464629.7A patent/CN103571009B/en not_active Expired - Fee Related
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| WO2013085788A1 (en) * | 2011-12-09 | 2013-06-13 | Icl-Ip America Inc. | Synergized flame retarded polyolefin polymer composition, article thereof, and method of making the same |
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