CN102977614A - Mouse, high temperature, low temperature and oil resistant environmentally-friendly cable material and its preparation method - Google Patents
Mouse, high temperature, low temperature and oil resistant environmentally-friendly cable material and its preparation method Download PDFInfo
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- CN102977614A CN102977614A CN2012104354576A CN201210435457A CN102977614A CN 102977614 A CN102977614 A CN 102977614A CN 2012104354576 A CN2012104354576 A CN 2012104354576A CN 201210435457 A CN201210435457 A CN 201210435457A CN 102977614 A CN102977614 A CN 102977614A
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- 239000000463 material Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims abstract description 7
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 6
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960002504 capsaicin Drugs 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 3
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 17
- 239000002956 ash Substances 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 12
- 229920001971 elastomer Polymers 0.000 claims description 11
- 239000005060 rubber Substances 0.000 claims description 11
- 241000283984 Rodentia Species 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 230000003712 anti-aging effect Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 8
- 229920001897 terpolymer Polymers 0.000 claims description 8
- -1 trifluoropropyl siloxane Chemical class 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000004073 vulcanization Methods 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000000779 smoke Substances 0.000 abstract description 5
- 241000256602 Isoptera Species 0.000 abstract description 4
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 abstract 1
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- 241000699666 Mus <mouse, genus> Species 0.000 abstract 1
- 241000699670 Mus sp. Species 0.000 abstract 1
- XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000017663 capsaicin Nutrition 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 229920005560 fluorosilicone rubber Polymers 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 235000019504 cigarettes Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Abstract
The invention provides a mouse, high temperature, low temperature and oil resistant environmentally-friendly cable material. The cable material is prepared from the following raw materials, by weight, 20-30 parts of ethylene propylene diene monomer, 60-80 parts of fluorosilicone rubber, 8-10 parts of chlorinated polyethylene, 8-10 parts of chlorinated paraffin, 0.5-1.0 part of stearic acid, 1-3 parts of modified tree ash, 20-30 parts of triethyl citrate, 4-6 parts of iron oxide, 0.5-1.0 part of molybdenum trioxide, 30-50 parts of precipitated silica, 10-13 parts of diatomite, 0.5-1.0 part of capsaicin, 0.1-0.3 parts of an antioxidant H, 0.2-0.5 parts of an antioxidant 4040, 0.5-1.5 parts of a promoter TMTD, 0.5-1 part of a vulcanizing agent DCP, 3-5 parts of decabromodiphenylethane, 12-15 parts of antimony (III) oxide, and 6-8 parts of zinc borate. The cable material has the advantages of excellent flame retardation, very less smoke in combustion, no generation of toxic gases or corrosive gases, good high and low temperature resistances, good oil resistance, and good abrasion resistance, and cables prepared through using the cable material can prevent the harms of mice and termites to the cables and simultaneously have the efficacies of low smoke, environmental protection and flame retardation.
Description
Technical field
The present invention relates to the CABLE MATERIALS field, be specifically related to a kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof.
Background technology
Fast development along with global economy, and the enhancing of human environmental consciousness, each field is more and more higher to the requirement of the quality and performance of electric wire, mouse, termite are one of three large main harm of harm plastic jacketed cable, optical cable, cause every year many accidents to occur, cause economically huge loss.
Electric wire grandmotherization and the fire that causes is also more and more, how to reduce the incidence of fire and presence of fire the time mortality ratio, low cigarette, Halogen, fire-retardant, developing direction that environmental protection also becomes wires and cables industry.Wherein the demand of halide-free low-smoke fireproof cable material is increasing, the at present production of halide-free low-smoke fireproof cable material is to add a large amount of clorafin or clorafins to reach flame retardant effect in polyolefin substrate mostly, yet, the adding of a large amount of inorganic materials, affected physical and mechanical properties and the process industrial art performance of CABLE MATERIALS, poor, oil-proofness of softness, weathering resistance, resistance to low temperature are not fine at normal temperatures for they.
Summary of the invention
The invention provides a kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof.The existing anti-mouse of cable of being processed into by CABLE MATERIALS of the present invention, termite have the effect of low cigarette environmental protection flame retardant simultaneously to the harm of cable.
The technical solution used in the present invention is:
The anti-height of a kind of protection against rodents, low temperature oil-proofness environment-friendly cable material, it is characterized in that: the raw material by following weight part is made: terpolymer EP rubber 20-30 part, trifluoropropyl siloxane 60-80 part, chlorinatedpolyethylene 8-10 part, clorafin 8-10 part, stearic acid 0.5-1.0 part, modification trees ashes 1-3 part, triethyl citrate 20-30 part, ferric oxide 4-6 part, molybdic oxide 0.5-1.0 part, precipitated silica 30-50 part, diatomite 10-13 part, 0.5-1.0 part of capsaicine, antioxidant H 0.1-0.3 part, anti-aging agent 4040 0.2-0.5 parts, Vulcanization accelerator TMTD 0.5-1.5 part, 0.5～1 part of vulcanizing agent DCP, TDE 3-5 part, antimonous oxide 12-15 part, zinc borate 6-8 part.
Described modification trees ashes prepare by the following method:
(1), the trees ashes are with 10-15% salt acid soak 3-4 hour, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in the trees ashes is added to the water, add again sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that is equivalent to trees ashes weight 2-3%, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder.
The anti-height of described protection against rodents, low temperature oil-proofness environment-friendly cable material, it is characterized in that: the raw material by following weight part is made: 25 parts of terpolymer EP rubbers, 70 parts of trifluoropropyl siloxane, 9 parts of chlorinatedpolyethylenees, 9 parts of clorafins, 0.8 part of stearic acid, 2 parts in modification trees ashes, 27 parts of triethyl citrates, 5 parts of ferric oxide, 0.6 part of molybdic oxide, 35 parts of precipitated silicas, 11 parts in diatomite, 0.8 part of capsaicine, 0.2 part of antioxidant H, 4,040 0.4 parts in anti-aging agent, 1.0 parts of Vulcanization accelerator TMTDs, 0.8 part of vulcanizing agent DCP, 4 parts of TDE, 13 parts of antimonous oxides, 7 parts of zinc borates.
The preparation method of described protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material is characterized in that:
(1) presses formula rate terpolymer EP rubber, trifluoropropyl siloxane, chlorinatedpolyethylene and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 70-80 ℃;
(2) fillers such as diatomite, ferric oxide, precipitated silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, granulation gets final product.
Beneficial effect
CABLE MATERIALS of the present invention not only has excellent flame retardancy and flame-retarding power not; The amount of being fuming is considerably less during burning, does not produce toxic gas, does not produce corrosive gases, and has simultaneously good high-low temperature resistant, oil-proofness, wear resistance.The existing anti-mouse of cable of being processed into by CABLE MATERIALS of the present invention, termite have the effect of low cigarette environmental protection flame retardant simultaneously to the harm of cable.
Embodiment
The anti-height of protection against rodents, low temperature oil-proofness environment-friendly cable material is made by the raw material of following weight part: 25 parts of terpolymer EP rubbers, 70 parts of trifluoropropyl siloxane, 9 parts of chlorinatedpolyethylenees, 9 parts of clorafins, 0.8 part of stearic acid, 2 parts in modification trees ashes, 27 parts of triethyl citrates, 5 parts of ferric oxide, 0.6 part of molybdic oxide, 35 parts of precipitated silicas, 11 parts in diatomite, 0.8 part of capsaicine, 0.2 part of antioxidant H, 4,040 0.4 parts in anti-aging agent, 1.0 parts of Vulcanization accelerator TMTDs, 0.8 part of vulcanizing agent DCP, 4 parts of TDE, 13 parts of antimonous oxides, 7 parts of zinc borates.
Modification trees ashes prepare by the following method:
(1), the trees ashes are with 10% salt acid soak 3 hours, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3 hours, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in the trees ashes is added to the water, add again and be equivalent to the sodium laurylsulfate of trees ashes weight 3%, 1% zinc oxide, 2% diatomite, 5% aluminium hydroxide, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder.
The preparation method:
(1) presses formula rate terpolymer EP rubber, trifluoropropyl siloxane, chlorinatedpolyethylene and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 70-80 ℃;
(2) fillers such as diatomite, ferric oxide, precipitated silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, granulation gets final product.
The CABLE MATERIALS that processes with present embodiment is pressed into test piece after 160 ℃ * 40min thermal ageing, and it is as follows to record its performance:
| Project | The result |
| Tensile strength MPa | 18.5 |
| Elongation at break % | 370 |
| Volume specific resistance Ω .cm | 9.0×10 12 |
| Oxygen index % | 46 |
| 135 ℃ * 168h thermal ageing back draft intensity 〉= | 28.7MPa |
| The unit mass smoke density | 9.3g |
| The thermal ageing mass loss≤ | 20.5g/m2 |
Claims (3)
1. anti-height of protection against rodents, low temperature oil-proofness environment-friendly cable material, it is characterized in that: the raw material by following weight part is made: terpolymer EP rubber 20-30 part, trifluoropropyl siloxane 60-80 part, chlorinatedpolyethylene 8-10 part, clorafin 8-10 part, stearic acid 0.5-1.0 part, modification trees ashes 1-3 part, triethyl citrate 20-30 part, ferric oxide 4-6 part, molybdic oxide 0.5-1.0 part, precipitated silica 30-50 part, diatomite 10-13 part, 0.5-1.0 part of capsaicine, antioxidant H 0.1-0.3 part, anti-aging agent 4040 0.2-0.5 parts, Vulcanization accelerator TMTD 0.5-1.5 part, 0.5～1 part of vulcanizing agent DCP, TDE 3-5 part, antimonous oxide 12-15 part, zinc borate 6-8 part;
Described modification trees ashes prepare by the following method:
(1), the trees ashes are with 10-15% salt acid soak 3-4 hour, deionized water wash, again with 10-12% hydrogen peroxide leaching solution bubble 3-4 hour, again with deionized water wash to neutral, oven dry;
(2), will be dissolved in the trees ashes is added to the water, add again sodium laurylsulfate, the zinc oxide of 1-2%, the diatomite of 2-3%, the 3-5% aluminium hydroxide that is equivalent to trees ashes weight 2-3%, high speed 1200-1500 rev/min of stirring obtains dispersion liquid, and the dispersion liquid ovendry power is broken into ultrafine powder.
2. the anti-height of protection against rodents according to claim 1, low temperature oil-proofness environment-friendly cable material, it is characterized in that: the raw material by following weight part is made: 25 parts of terpolymer EP rubbers, 70 parts of trifluoropropyl siloxane, 9 parts of chlorinatedpolyethylenees, 9 parts of clorafins, 0.8 part of stearic acid, 2 parts in modification trees ashes, 27 parts of triethyl citrates, 5 parts of ferric oxide, 0.6 part of molybdic oxide, 35 parts of precipitated silicas, 11 parts in diatomite, 0.8 part of capsaicine, 0.2 part of antioxidant H, 4,040 0.4 parts in anti-aging agent, 1.0 parts of Vulcanization accelerator TMTDs, 0.8 part of vulcanizing agent DCP, 4 parts of TDE, 13 parts of antimonous oxides, 7 parts of zinc borates.
3. the preparation method of a protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material as claimed in claim 1 or 2 is characterized in that:
(1) presses formula rate terpolymer EP rubber, trifluoropropyl siloxane, chlorinatedpolyethylene and anti-aging agent class are dropped into mill, descended mixing 3-4 minute at 70-80 ℃;
(2) fillers such as diatomite, ferric oxide, precipitated silica are joined in the rubber unvulcanizate of step (1), after continuing mixing 2-3 minute, remaining material except vulcanizing agent, promotor is joined in the mixing materials, after mixing 4-6 minute, add again vulcanizing agent, promotor, after thin-pass 6-7 time, granulation gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210435457.6A CN102977614B (en) | 2012-11-05 | 2012-11-05 | A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210435457.6A CN102977614B (en) | 2012-11-05 | 2012-11-05 | A kind of protection against rodents high-and low-temperature resistance oil-proofness environment-friendly cable material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102977614A true CN102977614A (en) | 2013-03-20 |
| CN102977614B CN102977614B (en) | 2016-01-20 |
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| CN103304903A (en) * | 2013-05-14 | 2013-09-18 | 安徽旺达铜业发展有限公司 | Cable sheath material comprising modified aluminum hydroxide |
| CN103333418A (en) * | 2013-06-04 | 2013-10-02 | 安徽荣玖光纤通信科技有限公司 | Cold resistant cable sheath material |
| CN103483697A (en) * | 2013-08-28 | 2014-01-01 | 绿宝电缆（集团）有限公司 | Multi-nano-material cable sheath material |
| CN104592650A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Flame-retardant ethylene-propylene diene copolymer rubber sleeve for cables and preparation method thereof |
| CN104592648A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Flame-retardant ethylene propylene diene monomer for cable and preparation method of flame-retardant ethylene propylene diene monomer |
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| CN107383677A (en) * | 2017-07-25 | 2017-11-24 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly cable material and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304903A (en) * | 2013-05-14 | 2013-09-18 | 安徽旺达铜业发展有限公司 | Cable sheath material comprising modified aluminum hydroxide |
| CN103333418B (en) * | 2013-06-04 | 2016-05-04 | 安徽荣玖光纤通信科技有限公司 | A kind of cold resistant cable protective cover material |
| CN103333418A (en) * | 2013-06-04 | 2013-10-02 | 安徽荣玖光纤通信科技有限公司 | Cold resistant cable sheath material |
| CN103483697A (en) * | 2013-08-28 | 2014-01-01 | 绿宝电缆（集团）有限公司 | Multi-nano-material cable sheath material |
| CN104592650A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Flame-retardant ethylene-propylene diene copolymer rubber sleeve for cables and preparation method thereof |
| CN104592648A (en) * | 2015-01-09 | 2015-05-06 | 芜湖航天特种电缆厂 | Flame-retardant ethylene propylene diene monomer for cable and preparation method of flame-retardant ethylene propylene diene monomer |
| CN104672628A (en) * | 2015-03-12 | 2015-06-03 | 安徽特种电缆集团有限公司 | Radiation-resistant cable insulation material for nuclear power plant |
| CN105330997A (en) * | 2015-10-27 | 2016-02-17 | 苏州宽温电子科技有限公司 | Abrasion-resisting weather-resisting cable sheath material and preparation method thereof |
| CN105575544A (en) * | 2015-12-07 | 2016-05-11 | 国网山东莱阳市供电公司 | Communication cable capable of preventing saline-alkaline corrosion and rat/ant gnawing |
| CN105542477A (en) * | 2016-03-08 | 2016-05-04 | 远东电缆有限公司 | Silicone rubber expansion filler for smart energy cable |
| CN106189261A (en) * | 2016-08-08 | 2016-12-07 | 安徽埃克森科技集团有限公司 | A kind of high-tension switch cabinet Flame-Retardant and Oil-Resistant type flexible cable sheath |
| CN106832876A (en) * | 2016-12-21 | 2017-06-13 | 柳州市昌泉贸易有限公司 | A kind of preparation method of oil resistant fire-resistant cable material |
| CN107383677A (en) * | 2017-07-25 | 2017-11-24 | 合肥达户电线电缆科技有限公司 | A kind of environment-friendly cable material and preparation method thereof |
| CN112226003A (en) * | 2020-10-10 | 2021-01-15 | 安徽华宇电缆集团有限公司 | Rat-proof cable sheath material for ships and warships and preparation method and application thereof |
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