CN102936304B - 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 - Google Patents
乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 Download PDFInfo
- Publication number
- CN102936304B CN102936304B CN201210350138.5A CN201210350138A CN102936304B CN 102936304 B CN102936304 B CN 102936304B CN 201210350138 A CN201210350138 A CN 201210350138A CN 102936304 B CN102936304 B CN 102936304B
- Authority
- CN
- China
- Prior art keywords
- ethylene
- polymer
- determined
- less
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000005977 Ethylene Substances 0.000 title claims abstract description 38
- 239000000203 mixture Substances 0.000 title claims description 96
- 229920000642 polymer Polymers 0.000 claims abstract description 104
- 239000003054 catalyst Substances 0.000 claims abstract description 56
- 238000000034 method Methods 0.000 claims abstract description 56
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 44
- 230000008569 process Effects 0.000 claims abstract description 34
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 23
- 239000004711 α-olefin Substances 0.000 claims abstract description 18
- 239000012190 activator Substances 0.000 claims abstract description 16
- -1 ethylene, propylene Chemical group 0.000 claims abstract description 16
- 229920001971 elastomer Polymers 0.000 claims abstract description 12
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 12
- 150000003624 transition metals Chemical class 0.000 claims abstract description 12
- 150000001450 anions Chemical class 0.000 claims abstract description 7
- 239000000806 elastomer Substances 0.000 claims abstract description 7
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- 239000003446 ligand Substances 0.000 claims abstract description 6
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 3
- 229920001577 copolymer Polymers 0.000 claims description 15
- 230000032683 aging Effects 0.000 claims description 12
- 238000009826 distribution Methods 0.000 claims description 12
- 229920001897 terpolymer Polymers 0.000 claims description 10
- 238000009616 inductively coupled plasma Methods 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical class [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 7
- 150000001993 dienes Chemical class 0.000 claims description 6
- 125000003367 polycyclic group Chemical group 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 4
- 238000005054 agglomeration Methods 0.000 claims description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 2
- 238000001637 plasma atomic emission spectroscopy Methods 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 1
- 239000012986 chain transfer agent Substances 0.000 claims 1
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 10
- 239000005060 rubber Substances 0.000 abstract description 5
- 125000004122 cyclic group Chemical group 0.000 abstract description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 description 39
- 230000000694 effects Effects 0.000 description 25
- 239000000178 monomer Substances 0.000 description 23
- 150000001875 compounds Chemical class 0.000 description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000010348 incorporation Methods 0.000 description 12
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 11
- 239000000945 filler Substances 0.000 description 10
- 239000004033 plastic Substances 0.000 description 10
- 229920003023 plastic Polymers 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 229910000464 lead oxide Inorganic materials 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 239000012968 metallocene catalyst Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 230000037048 polymerization activity Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55591404P | 2004-03-24 | 2004-03-24 | |
| US60/555,914 | 2004-03-24 | ||
| US61196304P | 2004-09-22 | 2004-09-22 | |
| US60/611,963 | 2004-09-22 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200580015544 Division CN101001893A (zh) | 2004-03-24 | 2005-03-21 | 生产乙烯共聚体的方法和由此制备的共聚体；含有这样的共聚体的组合物和电装置 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102936304A CN102936304A (zh) | 2013-02-20 |
| CN102936304B true CN102936304B (zh) | 2014-10-22 |
Family
ID=34964820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210350138.5A Expired - Lifetime CN102936304B (zh) | 2004-03-24 | 2005-03-21 | 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8263722B2 (https=) |
| EP (1) | EP1727838B1 (https=) |
| JP (1) | JP5255833B2 (https=) |
| CN (1) | CN102936304B (https=) |
| WO (1) | WO2005095475A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7750080B2 (en) * | 2001-04-23 | 2010-07-06 | Exxonmobil Chemical Patents Inc. | Blends of EPDM and metallocene plastomers for wire and cable applications |
| CN101490094B (zh) | 2006-05-17 | 2013-06-26 | 陶氏环球技术有限责任公司 | 高温聚乙烯溶液聚合法 |
| CA2656615C (en) * | 2006-06-29 | 2012-07-24 | Dow Global Technologies Inc. | Thermoplastic articles and processes for making the same using an improved masterbatch |
| US7943711B2 (en) * | 2007-05-14 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Ethylene elastomer compositions |
| DE102007037134A1 (de) * | 2007-08-07 | 2009-02-12 | Basell Polyolefine Gmbh | Rohr aus Polyolefin mit inhärenter Beständigkeit gegen thermo-oxidativen Abbau |
| KR101661484B1 (ko) * | 2008-03-14 | 2016-09-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리머 물품을 성형하기 위한 개량된 프로세스 |
| CN105348417B (zh) | 2010-01-14 | 2019-03-01 | 埃克森美孚化学专利公司 | 连续溶液聚合的方法和设备 |
| KR20120114395A (ko) | 2010-02-02 | 2012-10-16 | 에이디씨오 프로덕츠 인코포레이티드 | 수분 배리어 포팅 화합물 |
| JP6104277B2 (ja) * | 2011-12-13 | 2017-03-29 | ダウ グローバル テクノロジーズ エルエルシー | エチレン−プロピレン−ジエン共重合体組成物 |
| EP2833415B1 (en) | 2012-03-28 | 2018-05-02 | Mitsui Chemicals, Inc. | Solar cell sealing material and solar cell module |
| BR112015015531B1 (pt) * | 2012-12-29 | 2021-05-18 | Dow Global Technologies Llc | processo para preparar uma composição polimérica reticulável, processo para tratar pelo menos uma porção de uma composição polimérica reticulável e processo para produzir um condutor revestido |
| ITMI20131916A1 (it) * | 2013-11-19 | 2015-05-20 | Versalis Spa | Metodo per monitorare un parametro di controllo di una reazione di polimerizzazione e relativo apparato per attuare detto metodo |
| EP3040376B2 (en) | 2014-12-30 | 2020-09-16 | Abu Dhabi Polymers Company Limited (Borouge) L.L.C. | Multimodal polyethylene |
| EP3245253B1 (en) | 2015-01-14 | 2019-12-04 | ExxonMobil Chemical Patents Inc. | Polymer compositions and processes for their production |
| EP3274381B1 (en) * | 2015-04-20 | 2019-05-15 | ExxonMobil Chemical Patents Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
| US9771444B2 (en) | 2015-12-16 | 2017-09-26 | Exxonmobil Chemical Patents Inc. | Low crystalline polymer compositions |
| SG11201802756QA (en) * | 2015-12-16 | 2018-06-28 | Exxonmobil Chemical Patents Inc | Low crystalline polymer compositions |
| CN108883395B (zh) * | 2016-01-11 | 2021-07-09 | 北京光合新能科技有限公司 | 用于产生长链烃分子的等离激元纳米颗粒催化剂和方法 |
| CN109641990B (zh) | 2016-07-13 | 2022-08-19 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| JP6850862B2 (ja) | 2016-07-14 | 2021-03-31 | エクソンモービル・ケミカル・パテンツ・インク | 粘度調整剤として有用な、２元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| ES2758793T5 (es) * | 2016-09-12 | 2022-10-31 | Thai Polyethylene Co Ltd | Proceso para la preparación de polietileno multimodal |
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
| US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997022635A1 (en) * | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| US6300433B1 (en) * | 1998-10-23 | 2001-10-09 | Exxonmobil Chemical Patents Inc. | Olefin copolymerization process with bridged hafnocenes |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE68928696T2 (de) | 1988-12-26 | 1998-12-03 | Mitsui Chemicals, Inc., Tokio/Tokyo | Olefin-kopolymer und verfahren zur herstellung |
| US5236998A (en) * | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
| US6270856B1 (en) * | 1991-08-15 | 2001-08-07 | Exxon Mobil Chemical Patents Inc. | Electrical cables having polymeric components |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| GB9125934D0 (en) * | 1991-12-05 | 1992-02-05 | Exxon Chemical Patents Inc | Process for polymerising olefinic feeds under pressure |
| CA2117888C (en) | 1992-06-15 | 2001-05-15 | Howard William Turner | High temperature polymerization process using ionic catalysts to produce polyolefins |
| US5414040A (en) | 1992-09-15 | 1995-05-09 | The Dow Chemical Company | Formulated ethylene/α-olefin elastomeric compounds |
| US6399533B2 (en) * | 1995-05-25 | 2002-06-04 | Basell Technology Company Bv | Compounds and catalysts for the polymerization of olefins |
| US5674613A (en) | 1995-06-14 | 1997-10-07 | Exxon Chemical Patents Inc. | Electrical devices including ethylene, a-olefin, vinyl norbornene elastomeric polymers |
| US5767208A (en) * | 1995-10-20 | 1998-06-16 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| PT885255E (pt) | 1996-03-05 | 2002-03-28 | Dow Chemical Co | Poliolefinas de reologia modificada |
| US5952427A (en) | 1996-12-10 | 1999-09-14 | Exxon Chemical Patents Inc. | Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers |
| US5763533A (en) * | 1996-12-10 | 1998-06-09 | Exxon Chemical Patents Inc. | Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers |
| WO1999041294A1 (en) | 1998-02-17 | 1999-08-19 | Exxon Chemical Patents Inc. | Ethylene copolymerization process |
| CN1133660C (zh) * | 1998-03-04 | 2004-01-07 | 埃克森美孚化学专利公司 | 烯烃的高温聚合方法 |
| CA2319451C (en) | 1998-04-07 | 2009-09-15 | Exxon Chemical Patents, Inc. | Polymerization process |
| US6528670B1 (en) * | 1998-10-23 | 2003-03-04 | Exxonmobil Chemical Patents Inc. | Bridged metallocenes for olefin copolymerization |
| AU761531B2 (en) * | 1998-10-23 | 2003-06-05 | Exxonmobil Chemical Patents Inc | Olefin copolymerization process with bridged hafnocenes |
| JP4990433B2 (ja) * | 1998-10-29 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | 改良された押出し加工性を有するエチレン・α−オレフィンエラストマー重合体組成物 |
| BR9916426A (pt) | 1998-12-21 | 2001-09-04 | Exxonmobil Chem Patents Inc | Composições semicristalinas de c3 etileno-propileno superior ramificado |
| SE516260C2 (sv) * | 1999-07-01 | 2001-12-10 | Borealis Polymers Oy | Isolerande komposition för en elektrisk kraftkabel |
| WO2002034795A1 (en) | 2000-10-25 | 2002-05-02 | Exxonmobil Chemical Company Inc. | Processes and apparatus for continuous solution polymerization |
| EP1349653A4 (en) * | 2000-11-06 | 2010-11-03 | Exxonmobil Chem Patents Inc | FLUORINATED ZWITTERIONIC COCATALYST ACTIVATORS FOR POLYMERIZATION OF OLEFIN |
| EP1406761B1 (en) * | 2001-06-20 | 2016-11-02 | ExxonMobil Chemical Patents Inc. | Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them |
-
2005
- 2005-03-21 JP JP2007505114A patent/JP5255833B2/ja not_active Expired - Lifetime
- 2005-03-21 US US11/086,108 patent/US8263722B2/en active Active
- 2005-03-21 CN CN201210350138.5A patent/CN102936304B/zh not_active Expired - Lifetime
- 2005-03-21 WO PCT/US2005/009575 patent/WO2005095475A1/en not_active Ceased
- 2005-03-21 EP EP05732790.0A patent/EP1727838B1/en not_active Expired - Lifetime
-
2012
- 2012-08-07 US US13/568,381 patent/US8829127B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997022635A1 (en) * | 1995-12-19 | 1997-06-26 | Exxon Chemical Patents Inc. | High temperature olefin polymerization process |
| US6300433B1 (en) * | 1998-10-23 | 2001-10-09 | Exxonmobil Chemical Patents Inc. | Olefin copolymerization process with bridged hafnocenes |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1727838B1 (en) | 2013-04-17 |
| WO2005095475A1 (en) | 2005-10-13 |
| JP5255833B2 (ja) | 2013-08-07 |
| US20130035460A1 (en) | 2013-02-07 |
| US8263722B2 (en) | 2012-09-11 |
| CN102936304A (zh) | 2013-02-20 |
| EP1727838A1 (en) | 2006-12-06 |
| US8829127B2 (en) | 2014-09-09 |
| US20050215737A1 (en) | 2005-09-29 |
| JP2007530738A (ja) | 2007-11-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102936304B (zh) | 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 | |
| EP1527112B1 (en) | Silane crosslinkable polyethylene | |
| KR100456710B1 (ko) | 모노-올레핀/폴리엔인터폴리머,이의제조방법,이를함유하는조성물및이로부터제조된제품 | |
| EP1472295B1 (en) | Multimodal ethylene, alpha-olefin and diene polymers, processes for making and devices comprising such compositions | |
| JP5331103B2 (ja) | エチレンエラストマー組成物 | |
| CN101014652B (zh) | 半导电聚合物组合物 | |
| CN1223670A (zh) | 弹性体及其制备方法 | |
| JP2002505352A (ja) | 架橋ハフノセン化合物を使用するオレフィンコポリマーの重合法 | |
| KR100581796B1 (ko) | 개선된 압출 가공성을 갖는 에틸렌 알파-올레핀엘라스토머성 중합체 조성물 | |
| CN101326204B (zh) | 烯烃聚合方法 | |
| EP0843878B2 (en) | Electrical devices including ethylene, alpha-olefin, vinyl norbornene elastomeric polymers | |
| CN1174438C (zh) | 电源电缆的绝缘组合物 | |
| JP2005206777A (ja) | エチレン系重合体およびその製造方法 | |
| EP2352769B1 (en) | Medium voltage cable sheath comprising an olefin-based polymer | |
| CN101001893A (zh) | 生产乙烯共聚体的方法和由此制备的共聚体；含有这样的共聚体的组合物和电装置 | |
| JP7433108B2 (ja) | フィルム | |
| JP2019143035A (ja) | 架橋ポリエチレン管用ポリエチレン樹脂組成物、及び、架橋ポリエチレン管 | |
| JP2021155595A (ja) | 二軸延伸フィルム |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20141022 |
|
| CX01 | Expiry of patent term |