CN102924804B - Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof - Google Patents
Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an antibacterial anti-alga color master batch dedicated to a fishing net and a preparation method thereof. The color master batch disclosed by the invention comprises the following raw materials in weight part: 35-75 parts of carrier resin, 10-48 parts of pigment, 10-20 parts of antibacterial agent, and 0.5-3 parts of compatilizer. The preparation method for the color master batch, disclosed by the invention, is realized through the following steps: adding the pigment, the antibacterial agent and a processing agent into a grinding miller as per the raw material ratio for grinding and refining, adding the carrier resin and the compatilizer together into a high-speed mixer for uniform mixing, and finally adding the mixed material into a double-screw extruder for mixing and extruding. According to the invention, the antibacterial agent is added into the color master batch dedicated to the fishing net, and the compatilizer is added to enhance the compatibility of the prescription components, so that the antibacterial anti-alga color master batch dedicated to the fishing net can be prepared; and moreover, the color master batch has antibacterial and anti-alga functions, is convenient to add and use, and has the advantages of low toxicity, high efficiency and long antifouling period.
Description
Technical field
The present invention relates to polymeric material field, be specifically related to special antibacterial anti-algae Masterbatch of a kind of fishing lines and preparation method thereof.
Background technology
Along with developing rapidly of culture fishery, a large amount of fishing net fishing gears wherein to be used.Fishing net is normally the starting material interpolation look female yarn woven made with polyethylene, polypropylene or nylon etc.A lot of fishing net fishing gear is when producing at present, do not add the function of antibacterial anti-algae, although the function making it have antibacterial anti-algae after fishing net is made by surface-treated method had, or directly throw in algaecide in waters, but all there is a lot of not enough place in these methods, such as waters is polluted, using dosage is difficult to control, implementing process is complicated, antibacterial algae preventive effect is not good, be therefore difficult to promote the use of.
Summary of the invention
In view of this, the invention provides special antibacterial anti-algae Masterbatch of a kind of fishing lines and preparation method thereof, this Masterbatch has the function of antibacterial anti-algae, adds easy to use, has the advantage of low toxicity, length of efficient, antifouling phase.
The special antibacterial anti-algae Masterbatch of fishing lines of the present invention, described Masterbatch comprises the raw material of following parts by weight:
Vector resin 35 ~ 75 parts
Pigment 10 ~ 48 parts
Antiseptic-germicide 10 ~ 20 parts
Compatilizer 0.5 ~ 3 part;
Wherein, described antiseptic-germicide is several mixture in silver ion antimicrobial agent, mercury chloride, cupric oxide, primary ammonium phosphate, Quilonum Retard, copper sulfate, pyridine sulphur copper sodium and termil, and described compatilizer is the mixture of polyethylene maleic anhydride grafts, polypropylene maleic anhydride grafts and ethylene-octene copolymer maleic anhydride grafts.
Further, described Masterbatch also comprises the raw material of following parts by weight: processing aid 5 ~ 10 parts; Described processing aid is N, N ' mixture of-ethylenebisstearamide, polyethylene wax and coupling agent.
Further, described vector resin is one or both the mixture in linear low density polyethylene and ethylene-octene copolymer.
Further, described pigment is titanium dioxide, carbon black, ultramarine, Tai Celadon is blue and phthalein is dark green mixture.
The preparation method of the special antibacterial anti-algae Masterbatch of fishing lines of the present invention, comprises the following steps:
1) pigment, antiseptic-germicide and processing aid are added shredder grinding refinement by proportioning raw materials;
2) mixture vector resin, compatilizer and step 1) obtained mixes by adding in high-speed mixer together with proportioning raw materials;
3) by step 2) mixture that obtains adds twin screw extruder mixing extrusion, dries through cooling and dicing, the obtained special antibacterial anti-algae Masterbatch of described fishing lines.
Beneficial effect of the present invention is: the present invention with the addition of antiseptic-germicide in fishing lines special color master batch, and add the consistency that compatilizer enhances recipe ingredient, prepare the special antibacterial anti-algae Masterbatch of fishing lines, this Masterbatch has the function of antibacterial anti-algae, add easy to use, there is the advantage of low toxicity, length of efficient, antifouling phase.
Embodiment
Below will be described in detail the preferred embodiments of the present invention.
embodiment 1
The raw material composition of the special antibacterial anti-algae Masterbatch of fishing lines of the present embodiment and parts by weight thereof are:
Vector resin 35 parts
Pigment 48 parts
Antiseptic-germicide 10.6 parts
Compatilizer 3 parts
Processing aid 9.8 parts;
Wherein, described vector resin is linear low density polyethylene;
The composition of described pigment and parts by weight are: titanium dioxide 2 parts, carbon black 10 parts, ultramarine 0.5 part of, Tai Celadon blue 0.5 part and dark green 35 parts of phthalein;
The composition of described antiseptic-germicide and parts by weight are: silver ion antimicrobial agent 8 parts, 0.2 part, mercury chloride, cupric oxide 0.5 part, primary ammonium phosphate 0.7 part and Quilonum Retard 1.2 parts;
The composition of described compatilizer and parts by weight are: polyethylene maleic anhydride grafts 0.5 part, polypropylene maleic anhydride grafts 1.5 parts and ethylene-octene copolymer maleic anhydride grafts 1 part;
The composition of described processing aid and parts by weight are: N, N '-ethylenebisstearamide 5 parts, polyethylene wax 4 parts and coupling agent 0.8 part.
The preparation method of the special antibacterial anti-algae Masterbatch of fishing lines of the present embodiment, comprises the following steps:
1) pigment, antiseptic-germicide and processing aid are added shredder grinding refinement by proportioning raw materials;
2) mixture vector resin, compatilizer and step 1) obtained mixes by adding in high-speed mixer together with proportioning raw materials;
3) by step 2) mixture that obtains adds twin screw extruder mixing extrusion, dries through cooling and dicing, the obtained special antibacterial anti-algae Masterbatch of described fishing lines.
embodiment 2
The raw material composition of the special antibacterial anti-algae Masterbatch of fishing lines of the present embodiment and parts by weight thereof are:
Vector resin 75 parts
Pigment 17.2 parts
Antiseptic-germicide 18.4 parts
Compatilizer 0.7 part
Processing aid 6 parts;
Wherein, described vector resin is linear low density polyethylene 50 parts and ethylene-octene copolymer 25 parts;
The composition of described pigment and parts by weight are: titanium dioxide 6.2 parts, carbon black 5 parts, ultramarine 4.5 parts of, Tai Celadon blue 0.8 part and dark green 0.7 part of phthalein;
The composition of described antiseptic-germicide and parts by weight are: silver ion antimicrobial agent 8 parts, 0.2 part, mercury chloride, cupric oxide 0.5 part, primary ammonium phosphate 0.7 part, Quilonum Retard 1.2 parts, 3 parts, copper sulfate, 4 parts, pyridine sulphur copper sodium and termil 0.8 part;
The composition of described compatilizer and parts by weight are: polyethylene maleic anhydride grafts 0.2 part, polypropylene maleic anhydride grafts 0.2 part and ethylene-octene copolymer maleic anhydride grafts 0.3 part;
The composition of described processing aid and parts by weight are: N, N '-ethylenebisstearamide 4 parts, polyethylene wax 1 part and coupling agent 1 part.
The preparation method of the special antibacterial anti-algae Masterbatch of fishing lines of the present embodiment, comprises the following steps:
1) pigment, antiseptic-germicide and processing aid are added shredder grinding refinement by proportioning raw materials;
2) mixture vector resin, compatilizer and step 1) obtained mixes by adding in high-speed mixer together with proportioning raw materials;
3) by step 2) mixture that obtains adds twin screw extruder mixing extrusion, dries through cooling and dicing, the obtained special antibacterial anti-algae Masterbatch of described fishing lines.
The present invention with the addition of antiseptic-germicide in fishing lines special color master batch, and add the consistency that compatilizer enhances recipe ingredient, prepare the special antibacterial anti-algae Masterbatch of fishing lines, this Masterbatch has the function of antibacterial anti-algae, add easy to use, there is the advantage of low toxicity, length of efficient, antifouling phase.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although by referring to the preferred embodiments of the present invention, invention has been described, but those of ordinary skill in the art is to be understood that, various change can be made to it in the form and details, and not depart from the spirit and scope of the present invention that appended claims limits.
Claims (2)
1. the special antibacterial anti-algae Masterbatch of fishing lines, is characterized in that: described Masterbatch comprises the raw material of following parts by weight:
Vector resin 35 ~ 75 parts
Pigment 10 ~ 48 parts
Antiseptic-germicide 10 ~ 20 parts
Compatilizer 0.5 ~ 3 part;
Processing aid 5 ~ 10 parts;
Wherein, described antiseptic-germicide is several mixture in silver ion antimicrobial agent, mercury chloride, cupric oxide, primary ammonium phosphate, Quilonum Retard, copper sulfate, pyridine sulphur copper sodium and termil;
Described compatilizer is the mixture of polyethylene maleic anhydride grafts, polypropylene maleic anhydride grafts and ethene-octene copolymer maleic anhydride grafts;
Described processing aid is N, N ' mixture of-ethylenebisstearamide, polyethylene wax and coupling agent;
Described vector resin is one or both the mixture in linear low density polyethylene and ethene-octene copolymer;
Described pigment is titanium dioxide, carbon black, ultramarine, Tai Celadon is blue and phthalein is dark green mixture.
2. the preparation method of the special antibacterial anti-algae Masterbatch of the fishing lines described in claim 1, is characterized in that: comprise the following steps:
1) pigment, antiseptic-germicide and processing aid are added shredder grinding refinement by proportioning raw materials;
2) mixture vector resin, compatilizer and step 1) obtained mixes by adding in high-speed mixer together with proportioning raw materials;
3) by step 2) mixture that obtains adds twin screw extruder mixing extrusion, dries through cooling and dicing, the obtained special antibacterial anti-algae Masterbatch of described fishing lines.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210481411.8A CN102924804B (en) | 2012-11-23 | 2012-11-23 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210481411.8A CN102924804B (en) | 2012-11-23 | 2012-11-23 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102924804A CN102924804A (en) | 2013-02-13 |
| CN102924804B true CN102924804B (en) | 2015-03-25 |
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| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
| CN105442085A (en) * | 2015-12-18 | 2016-03-30 | 巢湖市天宇渔具有限公司 | Anti-algae fishing net |
| CN105420874B (en) * | 2016-01-06 | 2017-11-17 | 江苏工程职业技术学院 | A kind of ultralight high-strength antibacterial removes the manufacture method of algae fishing net yarn |
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| CN105860213A (en) * | 2016-05-04 | 2016-08-17 | 巢湖市强力渔业有限责任公司 | Fishing net prepared from modified nanometer clay and modified plastic |
| CN106381554A (en) * | 2016-09-10 | 2017-02-08 | 巢湖市鼎盛渔具有限公司 | Sunproof type nylon fiber wire for weaving fishing net |
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| CN108691030A (en) * | 2018-05-24 | 2018-10-23 | 王德文 | The antifouling aquiculture net cage of sterilizing and anti-virus |
| CN109161089A (en) * | 2018-07-28 | 2019-01-08 | 巢湖市瀚海渔具有限公司 | A kind of dedicated antibacterial water repellent anti-soiling aging-resisting color masterbatch of fishing lines and preparation method thereof |
| CN108930073A (en) * | 2018-08-03 | 2018-12-04 | 巢湖市渔郎渔具有限公司 | A kind of preparation method of fresh water area resistant purse seine |
| CN111303458A (en) * | 2020-04-16 | 2020-06-19 | 安徽缤飞塑胶科技有限公司 | Preparation method of light-resistant and antibacterial color master batch |
| CN113292780A (en) * | 2021-02-14 | 2021-08-24 | 保相实 | Preparation method of antibacterial color master batch |
| CN115287817B (en) * | 2022-07-28 | 2023-06-16 | 中国水产科学研究院东海水产研究所 | Preparation method of efficient antifouling netting |
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