CN102153803A - Specific antibacterial PE (polyethylene) self-sealing bag - Google Patents

Specific antibacterial PE (polyethylene) self-sealing bag Download PDF

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Publication number
CN102153803A
CN102153803A CN201110119032XA CN201110119032A CN102153803A CN 102153803 A CN102153803 A CN 102153803A CN 201110119032X A CN201110119032X A CN 201110119032XA CN 201110119032 A CN201110119032 A CN 201110119032A CN 102153803 A CN102153803 A CN 102153803A
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Prior art keywords
polyethylene
valve bag
bag
density polyethylene
silver ion
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Pending
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CN201110119032XA
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Chinese (zh)
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陈迦乐
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Individual
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Individual
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Priority to CN201110119032XA priority Critical patent/CN102153803A/en
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Abstract

The invention relates to a PE (polyethylene) self-sealing bag containing a glass-supported silver ion antibacterial agent, which contains 0.001 to 1.5 percent of glass-supported silver ion antibacterial agent on the basis of a common PE (polyethylene) self-sealing bag, or further contains one or more of 0.5 to 6 percent of antifoggant and 1 to 6 percent of degradable master batch. The PE in the PE (polyethylene) self-sealing bag is one of high-density polyethylene, low-density polyethylene or linear low-density polyethylene or is formed by mixing the high-density polyethylene, low-density polyethylene and linear low-density polyethylene according to a certain ratio. The manufacturing process is to mix and granulate the PE and the glass-supported silver ion antibacterial agent in a single-screw or double-screw extruder to obtain antibacterial master batch; and according to the formula, blowing or casting a film in an extruder, making a bag and thus, obtaining the antibacterial self-sealing bag. The finished product has remarkable antibacterial effect, can be used for a long time without changing color. The bag has a remarkable inhibiting and killing effect on bacteria, particularly Escherichia coli and staphylococcus aureus.

Description

A kind of specific antibacterial PE (polyethylene) valve bag
Technical field
The present invention relates to contain a kind of valve bag of antiseptic-germicide, a kind of specifically valve bag that contains the glass carrier silver ion antimicrobial agent contains this antiseptic-germicide, long, the film color nondiscoloration of the antibiotic good and timeliness of valve bag.Valve bag also can claim other titles such as airtight bag, closely knit bag, hereinafter to be referred as valve bag.
Technical background
All be common valve bag on the domestic market at present, do not contain antiseptic-germicide, do not contain the glass carrier silver ion antimicrobial agent especially.Developed countries has entered the antibiotic epoch in the eighties in last century.Domestic antibiotic in recent years industry development just begins, but technology is very different, as: antibacterial effect is not good, easy to change or the like, and problem has much room for improvement.Along with growth in the living standard, people are more and more higher to standard of living and quality, environmental requirement, to the hygiene and health conditional request more a step improve, people are also very high to the requirement of antimicrobial product.
The antibiotic valve bag that the present invention relates to has excellent inhibition or killing action to intestinal bacteria, gold-coloured staphylococci, and inhibition or killing rate reach more than 99.99%.Antiseptic-germicide of the present invention is to belong to the glass carrier silver ion antimicrobial agent, retrieves a large amount of patent documentations, and still the report of glass carrier silver ion antimicrobial agent is found to add in common polythene valve bag the inside in the end.
Summary of the invention
The present invention contains the antibiotic valve bag with glass carrier silver ion antimicrobial agent, and the antiseptic-germicide in the described antibiotic valve bag is a kind of the silver ion antimicrobial agent of glass as carrier.Described antibiotic valve bag antibacterial mechanisms is that under the condition of humidity, the present invention slowly discharges the small amount of silver ion.Because bacterium surface has negative charge, the silver ions that therefore has positive charge is attracted to bacterium surface, and then destroys its electrolyte balance, causes bacterium because cell walls is impaired and dead.
Also having a kind of viewpoint is that silver ions enters bacterium inside, with cell enzyme reaction and the chemical combination of bacterium, has suppressed the activity of cellular enzymes and the breeding regeneration of bacterium, reaches the effect of kill bacteria.In polyethylene, add inorganic antiseptic,, can produce muddy sense usually, so but the base material of silver ion antimicrobial agent of the present invention is the transparency that glass can be kept transparent resin by the control specific refractory power because of polyethylene is a transparent material.This is its advantage, and antibiotic valve bag just of the present invention has surprising nondiscoloration effect.After so-called variable color just was meant that general film adds common inorganic antiseptic, As time goes on the color of film became little Huang or brown problem,
The self-styled main points of glass carrier silver-ion antibiotic bag of the present invention are to contain and have the glass carrier silver ion antimicrobial agent that (from Ishizuka Glass, commodity are by name
Figure BSA00000491831000021
), select below following, the preferred 5um of its particle diameter 50um.Described glass carrier silver-ion antibiotic valve bag composition is polyethylene, glass carrier silver ion antimicrobial agent, or further contains in antifogging agent, the degradable master batch one or more.Respectively polyethylene more than 86.5%, glass carrier silver ion antimicrobial agent 0.001%-1.5%, antifogging agent 0.5%-6%, degradable master batch 1%-6%.
At first glass carrier silver ion antimicrobial agent and part polyethylene are passed through single screw rod or twin screw plastics extruder extruding pelletization by a certain percentage, become the antibacterial polyethylene master batch, it is than classifying glass carrier silver ion antimicrobial agent 1%-35%, polyethylene 65%-99% as, preferred glass carrier silver ion antimicrobial agent 20%, polyethylene 80%, more preferably glass carrier silver ion antimicrobial agent 10%, polyethylene 90%.Polyethylene can be high density polyethylene(HDPE), new LDPE (film grade) or linear low density polyethylene, preferably with the polyethylene of above-mentioned antibiotic valve bag homogeneity.
Above-mentioned single screw rod or twin screw plastics extruder, preferred twin screw plastics extruder, more preferably low-temperature and high-speed twin screw plastics extruder.
Above-mentioned antibacterial matrices and polyethylene in proportion in agitator the inside blend, are added the material that mixes in the plastics extruder and to melt extrude, blown film, bag, to prepare antibiotic valve bag or curtain coating, bag, prepare antibiotic valve bag.Blown film, curtain coating can be selected the single or multiple lift co-extrusion, and internal layer and skin or internal layer contain antiseptic-germicide when multi-layer co-extruded, and the middle layer can contain also can not contain antiseptic-germicide.When multi-layer co-extruded, the part by weight in ectonexine and middle layer is at 0.1%-99.9%:99.9%-0.1%.Antibiotic valve bag sealing position can be one or one or more bone bar, concavo-convex button, or clip chain.Antibiotic valve bag can be split type or integral type, the bag section of split type is phalanges bar, concavo-convex button, clip chain part and valve bag is that heat-sealing is integral, integral type be that phalanges bar, concavo-convex button, clip chain and valve bag bag section are extruded by molding machine together and formed.Bone bar, concavo-convex button, clip chain can be of the same colour or polychromes.
Concrete preferred implementation
The case study on implementation of enumerating below is to further specify the present invention, but the present invention is not limited by these embodiments, and any impartial variation and the modification change all belongs to the covering scope of claim of the present invention.
Case study on implementation 1
A kind of antibiotic valve bag that contains the glass carrier silver ion antimicrobial agent, its composition are polyethylene 95%, antibacterial polyethylene master batch 5%.
Manufacture method adds 5 kilograms of antibacterial polyethylene master batches in 95 kilograms of polyethylene, thorough mixing is even in agitator again, the material that mixes is added in the plastics extruder melt extrude, blown film, bag, prepare antibiotic valve bag.
Case study on implementation 2
A kind of antibiotic valve bag that contains the glass carrier silver ion antimicrobial agent, its composition are polyethylene 89%, antibacterial polyethylene master batch 5%, antifogging agent 3%, degradable master batch 3%.
Manufacture method, in 89 kilograms of polyethylene, add 5 kilograms of antibacterial polyethylene master batches, 3 kilograms of antifogging agents, 3 kilograms of degradable master batches, thorough mixing is even in agitator again, the material that mixes is added in the plastics extruder melt extrude, blown film, bag, prepare the antibacteria degradation valve bag.
Case study on implementation 3
A kind of antibiotic valve bag that contains the glass carrier silver ion antimicrobial agent, its composition are that internal layer and skin are polyethylene 95%, antibacterial polyethylene master batch 5%, and the middle layer is a polyethylene 100%.
Manufacture method, in 95 kilograms of polyethylene, add 5 kilograms of antibacterial polyethylene master batches, thorough mixing is even in agitator again, and the material that mixes is added in the screw cylinder under the outer and internal layer of plastics extruder, will melt extrude in the screw cylinder under 100 kilograms the polyethylene adding plastics extruder middle layer, blown film, bag, prepare antibiotic valve bag.

Claims (10)

1. one kind contains glass carrier silver ion antimicrobial agent valve bag, composition: polyethylene, glass carrier silver ion antimicrobial agent, or further contain in antifogging agent, the degradable master batch one or more.
2. can all be the wherein a kind of of high density polyethylene(HDPE), new LDPE (film grade) or linear low density polyethylene according to the polyethylene material in the claim 1.Also can be that high density polyethylene(HDPE), new LDPE (film grade) and linear low density polyethylene are mixed in proportion (concrete ratio: 99.8%-0.1%: 99.8%-0.1%: 99.8%-0.1%), but preferred high density polyethylene(HDPE).
3. be to be present in valve bag inside according to the glass carrier silver ion antimicrobial agent in the claim 1, glass carrier silver ion antimicrobial agent weight in valve bag is 0.001%-1.5%.
4. can further contain wherein one or more according to the antifogging agent in the claim 1, degradable master batch.
5. according to the weight 0.5%-6% of the antifogging agent in the claim 4 in antibiotic valve bag, the weight 1%-6% of degradable master batch in antibiotic valve bag.
6. can be one or one or more bone bar, concavo-convex button according to the sealing of the antibiotic valve bag in the claim 1 position, or clip chain.Bone bar, concavo-convex button, clip chain can be of the same colour or polychromes.
7. extrude at plastics extruder according to the antibiotic valve bag in the claim 1, blown film or curtain coating, bag, make, preferred blown film.
8. be that mode with antibacterial matrices adds the polyethylene the inside according to the glass carrier silver ion antimicrobial agent in the claim 1.
9. can be that the single or multiple lift co-extrusion is extruded according to the plastics extruder in the claim 7, when multi-layer co-extruded, the part by weight in ectonexine and middle layer be at 0.001%-99.999%: 99.9999%-0.001%.
10. can be split type or integral type according to the antibiotic valve bag in the claim 1, the bag section of split type is phalanges bar, concavo-convex button, clip chain part and valve bag is that heat-sealing is integral, integral type be that phalanges bar, concavo-convex button, clip chain and valve bag bag section are extruded by molding machine together and formed.
CN201110119032XA 2011-05-03 2011-05-03 Specific antibacterial PE (polyethylene) self-sealing bag Pending CN102153803A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601951A (en) * 2013-10-20 2014-02-26 安徽嘉木橡塑工业有限公司 Insect-proof antibacterial polyethylene resealable bag
CN104327343A (en) * 2013-07-22 2015-02-04 大禹节水(天津)有限公司 Production method for antibacterial dripper for drip irrigation
CN107118423A (en) * 2017-06-16 2017-09-01 王康宁 A kind of degradable PE clip chains valve bag and production technology
CN107353488A (en) * 2017-08-15 2017-11-17 安徽华猫软包装有限公司 A kind of antibacterial valve bag and preparation method thereof
WO2018129780A1 (en) * 2017-01-13 2018-07-19 杭州星庐科技有限公司 Antibacterial packaging film and processing method
CN109016762A (en) * 2018-08-20 2018-12-18 珠海高先手术用品科技有限公司 Antibacterial plastic film and its application

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1544296A (en) * 2003-11-14 2004-11-10 吴锦生 Self-sealing plastic bag and production method thereof
CN101486394A (en) * 2009-02-24 2009-07-22 上海建中医疗器械包装有限公司 Sterilized packaging self-sealing bag for goffered paper
CN101805474A (en) * 2010-03-04 2010-08-18 国家农产品保鲜工程技术研究中心(天津) Fruit and vegetable shelf small package bag film and manufacture method
CN102001480A (en) * 2010-10-16 2011-04-06 陈迦乐 Specific antibacterial PE (Polyethylene) preserving bag

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1544296A (en) * 2003-11-14 2004-11-10 吴锦生 Self-sealing plastic bag and production method thereof
CN101486394A (en) * 2009-02-24 2009-07-22 上海建中医疗器械包装有限公司 Sterilized packaging self-sealing bag for goffered paper
CN101805474A (en) * 2010-03-04 2010-08-18 国家农产品保鲜工程技术研究中心(天津) Fruit and vegetable shelf small package bag film and manufacture method
CN102001480A (en) * 2010-10-16 2011-04-06 陈迦乐 Specific antibacterial PE (Polyethylene) preserving bag

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104327343A (en) * 2013-07-22 2015-02-04 大禹节水(天津)有限公司 Production method for antibacterial dripper for drip irrigation
CN103601951A (en) * 2013-10-20 2014-02-26 安徽嘉木橡塑工业有限公司 Insect-proof antibacterial polyethylene resealable bag
WO2018129780A1 (en) * 2017-01-13 2018-07-19 杭州星庐科技有限公司 Antibacterial packaging film and processing method
CN108299711A (en) * 2017-01-13 2018-07-20 杭州星庐科技有限公司 A kind of anti-bacterial packaging film and processing method
CN107118423A (en) * 2017-06-16 2017-09-01 王康宁 A kind of degradable PE clip chains valve bag and production technology
CN107353488A (en) * 2017-08-15 2017-11-17 安徽华猫软包装有限公司 A kind of antibacterial valve bag and preparation method thereof
CN109016762A (en) * 2018-08-20 2018-12-18 珠海高先手术用品科技有限公司 Antibacterial plastic film and its application

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Application publication date: 20110817