CN102910973A - High-activity nitrification inhibition type multifunction fertilizer synergist and preparation method thereof - Google Patents

High-activity nitrification inhibition type multifunction fertilizer synergist and preparation method thereof Download PDF

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Publication number
CN102910973A
CN102910973A CN2012104425124A CN201210442512A CN102910973A CN 102910973 A CN102910973 A CN 102910973A CN 2012104425124 A CN2012104425124 A CN 2012104425124A CN 201210442512 A CN201210442512 A CN 201210442512A CN 102910973 A CN102910973 A CN 102910973A
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China
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plant
high reactivity
sodium
synergistic agent
type multifunctional
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CN2012104425124A
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陈海军
闭革林
陈成
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GUANGXI NEW ORIENTATION CHEMICAL INDUSTRY CO LTD
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GUANGXI NEW ORIENTATION CHEMICAL INDUSTRY CO LTD
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Priority to CN2012104425124A priority Critical patent/CN102910973A/en
Publication of CN102910973A publication Critical patent/CN102910973A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Abstract

The invention relates to a high-activity nitrification inhibition type multifunction fertilizer synergist and is applicable to the field of agriculture and forestry. The high-activity nitrification inhibition type multifunction fertilizer synergist is composed of following raw materials of, by weight, 3-35% of vitamin C, 3-35% of N-acyl sodium glutamate, 3-35% of 3,4-dimethylpyrazole phosphate (DMPP), 3-35% of farm-oriented rare earth, 5-35% of fulvic acid, 0.5-2.5% of compound sodium nitrophenolate, 15-45% of vermiculite and 15-45% of medical stones. The raw materials are smashed, screened by a 30-100 mesh screen, then stirred and mixed according to a certain ratio to obtain the fertilizer synergist. The fertilizer synergist is applicable to slow-acting nitrogen fertilizers or composite nitrogen fertilizers which use ammonium nitrogen fertilizers or urea as raw materials and is capable of being matched with the ammonium nitrogen fertilizers or the urea to be simultaneously applied to various types of soil, the fertilizer efficiency period of nitrogen fertilizers with the added multifunction fertilizer synergist can be prolonged to 90-110 days, abilities of drought resistance and disease resistance can be obviously improved, soil microorganism activities and crop root system activities can be stimulated, effectiveness and utilization efficiencies of soil fertilizers can be improved, and residual effects on crops are obvious.

Description

A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent and preparation method thereof
Technical field
The present invention relates to a kind of agricultural fertilizer synergistic agent, particularly relate to a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent.
Background technology
At present, the utilization rate of fertilizer of China still remains at low levels with respect to developed country, heavy duty detergent long acting multifunction composite fertilizer (composite fertilizer) has been limited the market development space of the domestic heavy duty detergent durable composite fertilizer of China to a great extent by the shared large percentage of transnational company on the domestic market.The fertilizer efficiency length of fertilizer is mainly seen the length of fertilizer effectiveness.The long-acting inhibiting nitrification technology of nitrogen, inhibition are that domestic common import is fertile more than three times.Main Function is to control the urase that decomposes nitrogen in the Soil Biochemical environment, the activity of nitrite bacteria, and its nitrogen nutrition composition is existed with available state, reduces the leaching loss volatilization, conscientiously prolongs fertilizer efficiency.Yet conventional compound nitrogenous fertilizer price is also more expensive, fertilizer efficiency is not remarkable, the fertilizer efficiency advantages such as the En Taike series composite fertilizer of this and multinational product such as German sylvite group, the blue composite fertilizer in fragrant plant field also have very large gap, and therefore the international competitiveness of domestic composite fertilizer waits to improve.Fast development and agricultural structure for current China modern agriculture are optimized and revised, the particularly fast development of technical field of fertilizers, research and development have the compound fertilizer auxiliary agents such as synergistic agent of remarkable synergy or long-acting, when not only can improve the fertilizer efficiency of fertilizer but also can significantly reduce the fertiliser production cost, satisfy the fertile demand of using of vast farmers, have good economic results in society and wide application prospect.
Summary of the invention
The object of the invention is to provide a kind of can increase the active high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent with prolonging fertilizer effectiveness of fertilizer.
A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent provided by the invention; it is to be made of following raw materials by weight portion ratio: vitamins C 3-35%; N-acyl glutamic acid sodium 3-35%; 3; 4-dimethyl pyrazole phosphoric acid salt (DMPP) 3-35%, agricultural rare-earth 3-35%, xanthohumic acid 5-35%; sodium nitrophenolate 0.5-2.5%, vermiculite 15-45%, medical stone 15-45%.
The preparation method of a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent provided by the invention is simple and easy to do, and specification sheets 4 described raw material pulverizing are sieved after the 30-100 order, mixes according to a certain percentage and can make.
A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent provided by the invention, agricultural rare-earth wherein is one or more in rare earth nitrate, rare earth chloride or the amino-acid rare earth, and sodium nitrophenolate is two or three in sodium onitrophenol, Sodium p-nitrophenoxide and the 5 nitroguaiacol sodium.
The present invention has following features:
(1) this kind high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent contains nitrification inhibitor, can significantly suppress the activity of nitrite bacteria, thereby the control ammonium nitrogen is to the conversion of nitric nitrogen, prolong fertilizer efficiency period, make utilization rate of fertilizer can improve 20-50%, consumption reduces 15-40%.
(2) this kind high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent contains the agricultural rare-earth element, can stop plant to the absorption of heavy metal, reduces its in vivo enrichment, thereby alleviates the Lipid peroxidation of initiation, is presented as direct degeneration-resistant effect; By the regulation and control to physiological functions such as photosynthesis, nitrate reductase, degeneration-resistant enzyme system and Membrane stabilities, strengthen the resistance of plant.
(3) this kind high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent contains tensio-active agent, vitamins C and the xanthohumic acid isoreactivity factor, and preferably biological degradability and security are arranged; Can stimulate crop root to form and growth, easily absorbed by crops, have stronger biological activity, other surfactant compounds of Chang Keyu have synergistic function.
(4) this kind high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent, contain sodium nitrophenolate, the energy rapid permeability is in plant materials, the high-intensity cytoactive of giving, accelerate plant growth, reproduction, can improve product essence, improve output, improve disease-resistant, the drought resisting of crop, cold-resistant, the anti-anti-adversity ability such as saline and alkaline, resistant to lodging.
(5) adopt synergistic agent of the present invention to produce composite nitrogen fertilizer and can be used as that base manure is disposable to be manured into soil, can satisfy the full growthdevelopmental stage of crop to nitrogen and in other the trace element demand, reach simultaneously the target that reduces agriculture production cost, improve the validity of soil nutrient.The soil deep placement, the punching that utilize fertilizer synergist of the present invention to can be used for composite nitrogen fertilizer are executed etc., the yield of commercial crops such as fruit tree, vegetables are improved more than the 30-50%, food crop output increased 5-30% can significantly improve crop quality and improve crop product excellence rate.
(6) most activeconstituents of the present invention noresidue nontoxic pollution-free behind Term Fertilization, be fit to all kinds soil, rear disease-resistant, drought resisting and the root growth to crop that be manured into soil has significant promoter action, and can improve the validity of various middle trace elements in the soil.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
The present invention further is illustrated in conjunction with following instance, and can realize the liquid fertilizer of the different proportionings between the macroelement, but protection scope of the present invention is not limited to this preparation method.
Embodiment 1
A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent; its raw materials by weight portion ratio is: vitamins C 5-10%; N-acyl glutamic acid sodium 5%-10%; 3; 4-dimethyl pyrazole phosphoric acid salt (DMPP) 10-20%, agricultural rare-earth 5-10%, xanthohumic acid 10-20%; sodium nitrophenolate 1.0-2.0%, vermiculite 20-40%, medical stone 20-40%.Mix after the crushing screening 30-100 order and can make high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent.
Embodiment 2
A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent; its raw materials by weight portion ratio is: vitamins C 10-20%; N-acyl glutamic acid sodium 10%-20%; 3; 4-dimethyl pyrazole phosphoric acid salt (DMPP) 10-20%, agricultural rare-earth 10-20%, xanthohumic acid 10-20%; sodium nitrophenolate 1.0-2.0%, vermiculite 20-40%, medical stone 20-40%.Mix after the crushing screening 30-100 order and can make high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent.
Embodiment 3
A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent; its raw materials by weight portion ratio is: vitamins C 10-20%; N-acyl glutamic acid sodium 5%-10%; 3; 4-dimethyl pyrazole phosphoric acid salt (DMPP) 20-30%, agricultural rare-earth 5-10%, xanthohumic acid 20-30%; sodium nitrophenolate 1.0-2.0%, vermiculite 20-40%, medical stone 20-40%.Mix after the crushing screening 30-100 order and can make high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent.
Embodiment 4
A kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent; its raw materials by weight portion ratio is: vitamins C 20-30%; N-acyl glutamic acid sodium 5%-10%; 3; 4-dimethyl pyrazole phosphoric acid salt (DMPP) 10-20%, agricultural rare-earth 20-30%, xanthohumic acid 20-30%; sodium nitrophenolate 1.0-2.0%, vermiculite 20-40%, medical stone 20-40%.Mix after the crushing screening 30-100 order and can make high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent.
The fertilizer synergist that the present invention relates to can according to Different Crop, different soil and different fertilizer breediness, suitably be adjusted the proportioning between each component (weight percent).
Embodiment described above has just illustrated ultimate principle of the present invention; the technician of the industry will be appreciated that; it is the restriction that is subjected to above-mentioned example that the present invention has more than; without departing from the spirit and scope of the present invention; multiple changes and improvements can be arranged, so these changes and improvements should require all to fall in the claimed scope.
Weight quota unit in each technical scheme of the present invention can for gram or kilogram (kilogram) or ton, also can be other unit.

Claims (7)

1. high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent; it is characterized in that; it is to be made of following raw materials by weight portion ratio: vitamins C 3-35%; N-acyl glutamic acid sodium 3-35%, 3,4-dimethyl pyrazole phosphoric acid salt (DMPP) 3-35%; agricultural rare-earth 3-35%; xanthohumic acid 5-35%, sodium nitrophenolate 0.5-2.5%, vermiculite 15-45%, medical stone 15-45%.
2. a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent as claimed in claim 1, what it is characterized in that described Nitrification Inhibition mainly is 3,4-dimethyl pyrazole phosphoric acid salt (DMPP), it can significantly suppress the activity of nitrite bacteria, thereby the control ammonium nitrogen prolongs fertilizer efficiency period to the conversion of nitric nitrogen.
3. a kind of high reactivity inhibiting nitrification type fertilizer synergist as claimed in claim 1, it is characterized in that agricultural rare-earth is one or more in rare earth nitrate, rare earth chloride or the amino-acid rare earth, use as plant-growth regulator, solid is blush or yellow-white powder.Arsenic determination can be used for the crops such as various grains, oil plant, sugared material, vegetables, fruit, flowers, tobacco, caddy rubber, also is used for the plantation of herbage and forest.Rare earth element can stop plant to the absorption of heavy metal, reduces its in vivo enrichment, thereby alleviates the Lipid peroxidation of initiation, is presented as direct degeneration-resistant effect; By the regulation and control to physiological functions such as photosynthesis, nitrate reductase, SOD, CAT, POD and Membrane stabilities, strengthen the resistance of plant.
4. a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent as claimed in claim 1; it is characterized in that the more anti-hard water of N-acyl glutamic acid sodium; can under alkalescence, neutrality and solutions of weak acidity, use; this bio-surfactant has obvious advantages for development, has preferably biological degradability and security.N-acyl glutamic acid sodium has certain fungistatic effect, and other surfactant compounds of Chang Keyu have synergistic function.Glutaminate is one of structure amino acid of vegetable-protein or peptide, and is total free aminoacids, by entering the plant sugar metabolism in conjunction with forming γ-aminobutyric acid.
5. a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent as claimed in claim 1, it is characterized in that described vitamins C (xitix) is the natural plant extracts such as fruit, vegetables, it is a kind of water-soluble substances, can stimulate root growth and growth, use rear nontoxic residue-free.
6. a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent as claimed in claim 1 is characterized in that xanthohumic acid is the macromolecular organic compound of humic-acid kind molecular weight.It contains various active functional group, can be water-soluble, sour, alkali, ethanol and acetone, easily by plant absorbing, have stronger biological activity, and in agriculture production, be used widely.
7. a kind of high reactivity inhibiting nitrification type multifunctional fertilizers synergistic agent as claimed in claim 1 is characterized in that sodium nitrophenolate is two or three in sodium onitrophenol, Sodium p-nitrophenoxide and the 5 nitroguaiacol sodium.Can rapid permeability in plant materials, the high-intensity cytoactive of giving is accelerated the plant-growth reproduction, can be improved quality, improves output, improves disease-resistant, the drought resisting of crop, cold-resistant, the anti-anti-adversity ability such as saline and alkaline, resistant to lodging.
CN2012104425124A 2012-11-08 2012-11-08 High-activity nitrification inhibition type multifunction fertilizer synergist and preparation method thereof Pending CN102910973A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103848691A (en) * 2014-03-21 2014-06-11 润禾泰华生物科技(北京)有限公司 Special liquid fertilizer for increasing production, killing pests and degrading pesticide residues of medlar and preparation method thereof
CN103848688A (en) * 2014-03-21 2014-06-11 润禾泰华生物科技(北京)有限公司 Special liquid pesticide-containing fertilizer capable of increasing output, killing pests and degrading pesticide residues of apples and preparation method thereof
CN103848689A (en) * 2014-03-21 2014-06-11 润禾泰华生物科技(北京)有限公司 Special liquid pesticide fertilizer for production increase, insect killing and residual reduction of tomatoes, and preparation method thereof
CN104478582A (en) * 2014-12-09 2015-04-01 贵州黔丰农兴科技有限公司 Disease-resistant organic fertilizer used in organic agricultural industrial parks and preparation method thereof
CN105061053A (en) * 2015-08-05 2015-11-18 马鞍山科邦生态肥有限公司 Organic fertilizer for promoting straw decomposition and preparation method therefor
CN105452199A (en) * 2013-07-30 2016-03-30 泰瓦尔海利科普特罗斯咨询投资有限公司 Method and liquid compound that improves results of application of ammoniacal nitrogenated fertilisers and ammonium present in the ground and preparation method thereof
CN106748201A (en) * 2016-12-29 2017-05-31 芜湖野树林生物科技有限公司 A kind of preparation method of Pleurotus citrinopileatus culture medium
DE102016107338A1 (en) 2016-04-20 2017-10-26 Skw Stickstoffwerke Piesteritz Gmbh Use of imidamide derivatives as an agent for improving the dry stress tolerance
CN108947625A (en) * 2017-05-17 2018-12-07 四川施邦威生物科技发展有限公司 A kind of fertilizer additive increasing disease-resistant crops, insect pest ability
CN115259947A (en) * 2022-08-08 2022-11-01 云南云叶化肥股份有限公司 Full-water-soluble seedling-extracting fertilizer with growth promoting function and preparation method and application thereof
CN115259946A (en) * 2022-08-08 2022-11-01 云南云叶化肥股份有限公司 Full-water-soluble fertilizer additive with growth promoting function, fertilizer and preparation method

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JP2000053481A (en) * 1998-08-05 2000-02-22 Asahi Chem Ind Co Ltd Mixed fertilizer containing coated nitrification suppressor
CN1587236A (en) * 2004-07-12 2005-03-02 石达璘 Process for producing long-acting sterilizing pest killing poly composite fertilizer
CN101450880A (en) * 2007-12-07 2009-06-10 中国科学院沈阳应用生态研究所 Nitrogen fertilizer compound synergist and preparation method
CN102344309A (en) * 2010-07-29 2012-02-08 中国农业科学院农业环境与可持续发展研究所 Throwing applying agent and preparation method thereof

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US5024689A (en) * 1988-02-08 1991-06-18 Freeport Mcmoran Resource Partners Nitrogen fertilizer
JP2000053481A (en) * 1998-08-05 2000-02-22 Asahi Chem Ind Co Ltd Mixed fertilizer containing coated nitrification suppressor
CN1587236A (en) * 2004-07-12 2005-03-02 石达璘 Process for producing long-acting sterilizing pest killing poly composite fertilizer
CN101450880A (en) * 2007-12-07 2009-06-10 中国科学院沈阳应用生态研究所 Nitrogen fertilizer compound synergist and preparation method
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105452199A (en) * 2013-07-30 2016-03-30 泰瓦尔海利科普特罗斯咨询投资有限公司 Method and liquid compound that improves results of application of ammoniacal nitrogenated fertilisers and ammonium present in the ground and preparation method thereof
CN103848688A (en) * 2014-03-21 2014-06-11 润禾泰华生物科技(北京)有限公司 Special liquid pesticide-containing fertilizer capable of increasing output, killing pests and degrading pesticide residues of apples and preparation method thereof
CN103848689A (en) * 2014-03-21 2014-06-11 润禾泰华生物科技(北京)有限公司 Special liquid pesticide fertilizer for production increase, insect killing and residual reduction of tomatoes, and preparation method thereof
CN103848691A (en) * 2014-03-21 2014-06-11 润禾泰华生物科技(北京)有限公司 Special liquid fertilizer for increasing production, killing pests and degrading pesticide residues of medlar and preparation method thereof
CN103848688B (en) * 2014-03-21 2015-09-09 润禾泰华生物科技(北京)有限公司 Residual Special-purpose liquid pesticide-containing fertilizer of a kind of apple volume increase desinsection degraded agriculture and preparation method thereof
CN103848691B (en) * 2014-03-21 2016-06-08 润禾泰华生物科技(北京)有限公司 The worm degraded residual Special-purpose liquid pesticide-containing fertilizer of agriculture and its preparation method are killed in a kind of matrimony vine volume increase
CN103848689B (en) * 2014-03-21 2016-03-23 润禾泰华生物科技(北京)有限公司 Residual Special-purpose liquid pesticide-containing fertilizer and preparation method thereof falls in a kind of tomato volume increase desinsection
CN104478582A (en) * 2014-12-09 2015-04-01 贵州黔丰农兴科技有限公司 Disease-resistant organic fertilizer used in organic agricultural industrial parks and preparation method thereof
CN105061053A (en) * 2015-08-05 2015-11-18 马鞍山科邦生态肥有限公司 Organic fertilizer for promoting straw decomposition and preparation method therefor
DE102016107338A1 (en) 2016-04-20 2017-10-26 Skw Stickstoffwerke Piesteritz Gmbh Use of imidamide derivatives as an agent for improving the dry stress tolerance
CN106748201A (en) * 2016-12-29 2017-05-31 芜湖野树林生物科技有限公司 A kind of preparation method of Pleurotus citrinopileatus culture medium
CN108947625A (en) * 2017-05-17 2018-12-07 四川施邦威生物科技发展有限公司 A kind of fertilizer additive increasing disease-resistant crops, insect pest ability
CN115259947A (en) * 2022-08-08 2022-11-01 云南云叶化肥股份有限公司 Full-water-soluble seedling-extracting fertilizer with growth promoting function and preparation method and application thereof
CN115259946A (en) * 2022-08-08 2022-11-01 云南云叶化肥股份有限公司 Full-water-soluble fertilizer additive with growth promoting function, fertilizer and preparation method

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Application publication date: 20130206