CN102838910A - Preparation method for cationic silicone/acrylic emulsion alkali resistant seal primer - Google Patents
Preparation method for cationic silicone/acrylic emulsion alkali resistant seal primer Download PDFInfo
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- CN102838910A CN102838910A CN2012103512197A CN201210351219A CN102838910A CN 102838910 A CN102838910 A CN 102838910A CN 2012103512197 A CN2012103512197 A CN 2012103512197A CN 201210351219 A CN201210351219 A CN 201210351219A CN 102838910 A CN102838910 A CN 102838910A
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- alkali resistant
- resistant seal
- crylic acid
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- charged ion
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Abstract
The invention relates to a preparation method for a cationic silicone/acrylic emulsion alkali resistant seal primer. The basic formula of the seal primer is as follows: 30% to 50% of emulsion, 4% to 8% of titanium dioxide, 5% to 12% of ground limestone, 5% to 10% of kaolin, 1% to 3% of talcum powder, 2% to 6% of coalescing agent, 1% to 5% of propylene glycol, 0.5% to 3% of thickening rheological agent, 2% to 5% of assistant and 20% to 35% of deionized water. The seal primer has the advantages of strong permeability, excellent weather and water resistance, good adhesion with substrate and paint, good self cleanness and environmental friendliness, excellent sealing performance, excellent alkali resistance and higher alkali and salting-out resisting performance. Therefore, the seal primer is suitable for being coated on the surfaces of external walls, internal walls, cement walls, concrete, gypsum boards, asbestos plates and the like.
Description
Technical field
The present invention relates to a kind of preparation method of trade sales coating priming paint, relate in particular to a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat that is applicable to various coating for internal and external wall.
Background technology
Mostly the base material of skin is sand-cement slurry or concrete surface, and its characteristics are that porous crack, alkalescence are strong.Wherein vesicular structure makes its water-absorbent strong, causes the decorative coveringn surface smooth inadequately, causes easily to film wrinklingly, and possibly cause dried coating film too fast and cause finish paint cracking; Alkalescence can cause the chemical degradation of resin in the coating by force, quickens to film ager process, reduces the working life of coating, causes granules of pigments exposed simultaneously, and the protection that loses resin causes fading.Based on this characteristics of base material, require it must use alkali resistant priming paint, stop separating out of alkali, salinity effectively, and, could keep the beautiful lasting of decorative coveringn at the bottom of finish paint provides a firm adherance.
Existing phenylpropyl alcohol seal coat, sealing acrylic priming paint generally all are that the modulation of anionic emulsion forms, but have poor adhesive force, the shortcoming that alkali resistance is weak; Particle size of emulsion is bigger, and surface tension is also very big, generally is difficult to be penetrated in the inner tiny pore of ground, so can only rely on the effect that density that substrate surface films realizes back cover.
Because the film forming singularity of latex coating; Between the polymer chemical reaction film forming can not take place, just according to self moisture evaporation, the polymer micelle is softening and then mutual extrusion film forming under the effect of film coalescence aid; So paint film is not tight; The space is more more, forms the porous coating of similar human skin after the film forming, and the water vapor in the base material can slowly appear.When it was used for some cement walls that do not parch fully, in the slow drying process of body of wall, the alkali in the cement divided and soluble salt can ooze out through coating from the cement kapillary with aqueous solution form, runs into airborne C0
2Generate the carbonate of indissoluble, this white mass extremely difficulty is removed fully, problem that it not only can cause that the coating variable color is grown dim, peeled off etc., and also the white thing of part can also form tear stains by the downward sagging of rain drop erosion, have a strong impact on the decoration and the protective value of filming.The effect of alkali resistant priming paint is exactly salt, the upwards migration of alkaline matter of sealing in the base material, to reduce the erosion to finish paint, increases the sticking power of finish paint, and can stop finish paint too much to be penetrated into base material inside, reduces the consumption of finish paint.In the exterior wall coating application, the alkali resistant seal coat matched coating that is absolutely necessary.
Summary of the invention
The present invention selects self-crosslinking positively charged ion organosilicon crylic acid latex for use, at room temperature need not add other auxiliary agent and just can take place crosslinked.Compare with traditional solvent bottom paint or anionic emulsion seal coat; This seal coat has following characteristic:
self-crosslinking, closure strong: after the moisture evaporation in the polymkeric substance; Promptly begin self-crosslinking reaction; Heat, alkaline matter all can promote crosslinking reaction; Can improve polymerization crosslinking density, improve closure.
good sticking power: superior ground perviousness, adhere to well with ground, finish paint.Stability to aging, water-repellancy that
is excellent: in drying process, crosslinked paint film has fabulous water-repellancy and stability to aging.
cationic characteristic: crosslinked under alkaline condition, alkali-resistivity, the anti-performance of saltouing are fabulous.
feature of environmental protection: solvent-free, self-cleaning function.
So the seal coat perviousness that the present invention processes is strong, good weathering resistance, water tolerance and sticking power, and excellent closure and alkali-resistivity have higher alkali resistant, the anti-performance of saltouing.
In order to solve technical problem recited above; The present invention takes following technical scheme: the present invention relates to a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat, its basic recipe is: emulsion 30%~50%, white titanium pigment 4%~8%, water-ground limestone 5%~12%, kaolin 5%~10%, talcum powder 1%~3%, film coalescence aid 2%~6%, Ucar 35 1%~5%, thickener rheology agent 0.5%~3%, auxiliary agent 2%~5%, deionized water 20%~35%.
Wherein, emulsion is selected self-crosslinking positively charged ion organosilicon crylic acid latex for use.
White titanium pigment is selected one or more combination of rutile titanium white powder or anatase thpe white powder for use.
Water-ground limestone is selected 1000 purpose powders for use.
Kaolin is selected 1000 purpose powders for use.
Talcum powder is selected 1000 purpose powders for use.
Film coalescence aid is selected one or more combination of glycol ether, propylene glycol and alcohol ester-12 for use.
Auxiliary agent comprises one or more combination of dispersion agent, wetting agent, skimmer, PH regulator and anticorrosion and bactericidal agent at least.
Thickener rheology agent is one or more combination of association type propenoate, hydrophobic association type polyurethane and Natvosol.
It is following that the present invention proposes a kind of preparation method preparation technology that all can the alkali resistant seal coat: be added to water, skimmer, dispersion agent, wetting agent and sterilant in the stirred pot by the formulation weight ratio; After being uniformly dispersed, low speed adds powder white titanium pigment, lime carbonate, high mountain range scholar and talcum powder; High speed dispersion 15min~30min then; After treating that the fineness of slurry is qualified, the middling speed state adds organosilicon crylic acid latex down, at the uniform velocity adds film coalescence aid then; Good viscosity of stirring and adjusting and pH value promptly make a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat.
The seal coat perviousness that the present invention processes is strong, good weathering resistance, water tolerance and sticking power, and excellent closure and alkali-resistivity have higher alkali resistant, the anti-performance of saltouing.Be applicable to the application on surfaces such as interior exterior wall, cement wall, concrete, plasterboard, asbestos plate.
Embodiment
Embodiment 1:
A kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat is according to following raw materials according formulation weight ratio, stirs through the stirrer high speed dispersion and processes: 20%~35% deionized water, 1%~5% Ucar 35,0.1%~0.5% skimmer, 0.5%~2% dispersion agent, 0.05%~0.3% wetting agent, 0.1%~0.4% sterilant, 4%~8% white titanium pigment, 5%~12% water-ground limestone, 5%~10% kaolin, 1%~3% talcum powder, 30%~50% uncle's acrylic emulsion, 2%~6% film coalescence aid, 0.5%~3% thickener rheology agent, 0.2%~1%pH regulator.
According to relevant national standard, the fundamental property of positively charged ion organosilicon crylic acid latex alkali resistant seal coat of the present invention is detected, test result is as shown in table 1.
Table 1 alkali resistant seal coat fundamental property test result
Test event | Test result |
At condition in container | No lump, uniform state |
Application property | Brush accessible |
Low-temperature stability | Through |
Paint film appearance | Normally |
Water tolerance 96h | No abnormal |
Alkali resistance 48h | No abnormal |
Sticking power | 1 grade |
Water-permeable | <=0.2 passes through |
Alkali-resistivity 72h | No abnormal |
Anti-saltouing property 144h | No abnormal |
[0021] although the present invention has done to specify and quoted embodiment as proof, for those of ordinary skill in the art, various schemes, modification and the change that obviously can make according to above-mentioned explanation all should be included within the scope of claim.
Claims (6)
1. positively charged ion organosilicon crylic acid latex alkali resistant seal coat; It is characterized in that: by weight percentage, comprise following component: emulsion 30%~50%, white titanium pigment 4%~8%, water-ground limestone 5%~12%, kaolin 5%~10%, talcum powder 1%~3%, film coalescence aid 2%~6%, Ucar 35 1%~5%, thickener rheology agent 0.5%~3%, auxiliary agent 2%~5%, deionized water 20%~35%.
2. a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat as claimed in claim 1, it is characterized in that: said emulsion is selected self-crosslinking positively charged ion organosilicon crylic acid latex for use.
3. a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat as claimed in claim 1 is characterized in that: said white titanium pigment is selected one or more combination of rutile titanium white powder or anatase thpe white powder for use.
4. a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat as claimed in claim 1 is characterized in that: said auxiliary agent comprises one or more combination of dispersion agent, wetting agent, skimmer, PH regulator and sterilant at least.
5. a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat as claimed in claim 1 is characterized in that: said thickener rheology agent is one or more combination of association type propenoate, hydrophobic association type polyurethane and Natvosol.
6. the preparation method of an a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat as claimed in claim 1; It is characterized in that: said preparation method comprises: by formulation weight than joining deionized water, skimmer, dispersion agent, wetting agent and sterilant in the stirred pot successively in order; The low speed back that is uniformly dispersed adds white titanium pigment, water-ground limestone, kaolin, talcum powder, high speed dispersion 15min~30min then, treat that the fineness of slurry is qualified after; The middling speed state adds organosilicon crylic acid latex down; At the uniform velocity add film coalescence aid then, good viscosity of stirring and adjusting and pH value promptly make a kind of positively charged ion organosilicon crylic acid latex alkali resistant seal coat.
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103923541A (en) * | 2013-01-15 | 2014-07-16 | 佛山市康威涂料实业有限公司 | Preparation method for universal alkali-resistant seal primer |
CN104250492A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Alkali-resistant water-based primer and preparation method thereof |
CN105419526A (en) * | 2015-12-16 | 2016-03-23 | 亚士漆(上海)有限公司 | Transparent priming paint for construction and preparation method thereof |
CN105462327A (en) * | 2015-12-28 | 2016-04-06 | 卓达新材料科技集团有限公司 | Production process of insulation decoration integrated board |
CN105482590A (en) * | 2016-01-27 | 2016-04-13 | 吴征 | Seal primer special for heat-insulating waterproof paint and preparation method of seal primer |
CN105482570A (en) * | 2016-01-14 | 2016-04-13 | 上海三银涂料科技股份有限公司 | Alkali-resistant primer for external wall and preparation method of alkali-resistant primer |
CN106810968A (en) * | 2015-12-01 | 2017-06-09 | 北京东方雨虹防水技术股份有限公司 | Impervious antireflective coating material and compound water-proof |
CN106833222A (en) * | 2017-01-12 | 2017-06-13 | 北京东方雨虹防水工程有限公司 | Anti- viscous weatherability coating, the adhesive linkage for being bonded waterstop and concrete, composite waterproof system |
CN107384049A (en) * | 2017-09-22 | 2017-11-24 | 苏州振振好新型建材科技有限公司 | A kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof |
CN108456475A (en) * | 2018-04-12 | 2018-08-28 | 漳州三德利油漆涂料有限公司 | A kind of high adhesion force Waterproof priming paint and its preparation method and application |
CN108753174A (en) * | 2018-06-21 | 2018-11-06 | 广东高登刷新科技有限责任公司 | High osmosis consolidates wall alkali-resistant sealing primer |
CN109705687A (en) * | 2018-12-25 | 2019-05-03 | 广东美涂士建材股份有限公司 | A kind of priming paint and preparation method thereof for PVC board |
CN109943159A (en) * | 2019-03-26 | 2019-06-28 | 上海中南建筑材料有限公司 | A kind of exterior wall seal coat for building and preparation method thereof |
CN110655836A (en) * | 2019-10-29 | 2020-01-07 | 西洞庭凯兴建材有限公司 | Alkali-resistant primer and preparation method thereof |
CN113201283A (en) * | 2021-05-31 | 2021-08-03 | 山西红塔涂料科技有限公司 | Permeable alkali-resistant seal primer |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102127344A (en) * | 2010-01-13 | 2011-07-20 | 亚士漆(上海)有限公司 | Waterproof primer for buildings |
CN102443324A (en) * | 2010-10-07 | 2012-05-09 | 艾永平 | Interior and exterior wall paint and production method thereof |
-
2012
- 2012-09-20 CN CN2012103512197A patent/CN102838910A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102127344A (en) * | 2010-01-13 | 2011-07-20 | 亚士漆(上海)有限公司 | Waterproof primer for buildings |
CN102443324A (en) * | 2010-10-07 | 2012-05-09 | 艾永平 | Interior and exterior wall paint and production method thereof |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103923541A (en) * | 2013-01-15 | 2014-07-16 | 佛山市康威涂料实业有限公司 | Preparation method for universal alkali-resistant seal primer |
CN104250492A (en) * | 2014-09-27 | 2014-12-31 | 安徽铁创新材料科技有限公司 | Alkali-resistant water-based primer and preparation method thereof |
CN106810968A (en) * | 2015-12-01 | 2017-06-09 | 北京东方雨虹防水技术股份有限公司 | Impervious antireflective coating material and compound water-proof |
CN105419526A (en) * | 2015-12-16 | 2016-03-23 | 亚士漆(上海)有限公司 | Transparent priming paint for construction and preparation method thereof |
CN105462327A (en) * | 2015-12-28 | 2016-04-06 | 卓达新材料科技集团有限公司 | Production process of insulation decoration integrated board |
CN105482570A (en) * | 2016-01-14 | 2016-04-13 | 上海三银涂料科技股份有限公司 | Alkali-resistant primer for external wall and preparation method of alkali-resistant primer |
CN105482590A (en) * | 2016-01-27 | 2016-04-13 | 吴征 | Seal primer special for heat-insulating waterproof paint and preparation method of seal primer |
CN106833222B (en) * | 2017-01-12 | 2019-12-10 | 北京东方雨虹防水工程有限公司 | anti-adhesion weather-resistant coating, adhesive layer for adhering water stop and concrete, and composite waterproof system |
CN106833222A (en) * | 2017-01-12 | 2017-06-13 | 北京东方雨虹防水工程有限公司 | Anti- viscous weatherability coating, the adhesive linkage for being bonded waterstop and concrete, composite waterproof system |
CN107384049A (en) * | 2017-09-22 | 2017-11-24 | 苏州振振好新型建材科技有限公司 | A kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof |
CN108456475A (en) * | 2018-04-12 | 2018-08-28 | 漳州三德利油漆涂料有限公司 | A kind of high adhesion force Waterproof priming paint and its preparation method and application |
CN108753174A (en) * | 2018-06-21 | 2018-11-06 | 广东高登刷新科技有限责任公司 | High osmosis consolidates wall alkali-resistant sealing primer |
CN109705687A (en) * | 2018-12-25 | 2019-05-03 | 广东美涂士建材股份有限公司 | A kind of priming paint and preparation method thereof for PVC board |
CN109943159A (en) * | 2019-03-26 | 2019-06-28 | 上海中南建筑材料有限公司 | A kind of exterior wall seal coat for building and preparation method thereof |
CN110655836A (en) * | 2019-10-29 | 2020-01-07 | 西洞庭凯兴建材有限公司 | Alkali-resistant primer and preparation method thereof |
CN113201283A (en) * | 2021-05-31 | 2021-08-03 | 山西红塔涂料科技有限公司 | Permeable alkali-resistant seal primer |
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Application publication date: 20121226 |