CN107384049A - A kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof - Google Patents
A kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof Download PDFInfo
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- CN107384049A CN107384049A CN201710867361.XA CN201710867361A CN107384049A CN 107384049 A CN107384049 A CN 107384049A CN 201710867361 A CN201710867361 A CN 201710867361A CN 107384049 A CN107384049 A CN 107384049A
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- alkali
- resistant primer
- exterior wall
- adhesion force
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof, the alkali-resistant primer includes the composition of following parts by weight:Organosilicon modified styrene AA emulsion:30 ~ 40 parts, calcium carbonate:15 ~ 25 parts, hydroxyethyl cellulose:10 ~ 15 parts, mica powder:5 ~ 10 parts, kaolin:5 ~ 10 parts, propane diols:1 ~ 5 part, polyvinyl alcohol:10 ~ 15 parts, titanium dioxide:1 ~ 5 part, mould inhibitor:1 ~ 5 part, coalescents:1 ~ 5 part, anti-accumulation of salt in the surface soil agent:1 ~ 5 part, levelling agent:1 ~ 5 part, dispersant:1 ~ 5 part, deionized water:40 ~ 50 parts.The alkali-resistant primer is environment-friendlywater-based water-based paint, suitable for the bottom closing paint on the surfaces such as cement brick wall structure, has good adhesive force and preferable permeance property, has alkali resistant effect, can effectively keep surface layer emulsion paint color and luster steady quality.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of high adhesion force high osmosis exterior wall alkali-resistant primer and its system
Preparation Method.
Background technology
Alkali-resistant primer is to use European high-quality raw material and advanced lacquer craftwork of making to refine a kind of novel aqueous height formed
Quality environment protection architecture decorative paint.In professional metope engineering construction field, this concept is carried by the engineer of rococo chemical industry
Out.Various basal plane ground closing alkalescence are aimed to prevent that water dissolved salt from being separated out and the thing followed is peeled off, while face can be saved
Paint and the decoration performance for improving finish paint.
Alkali-resistant primer is to use European high-quality raw material and advanced lacquer craftwork of making to refine a kind of novel aqueous height formed
Quality environment protection architecture decorative paint.In professional metope engineering construction field, this concept is carried by the engineer of rococo chemical industry
Out.Various basal plane ground closing alkalescence are aimed to prevent that water dissolved salt from being separated out and the thing followed is peeled off, while face can be saved
Paint and the decoration performance for improving finish paint.
For exterior wall alkali-resistant primer, the current country is primarily present following patent document:
Publication No. 105482570A Chinese patent discloses a kind of exterior wall alkali-resistant primer and preparation method thereof, wherein described
Exterior wall alkali-resistant primer raw material includes aqueous priming paint emulsion 30.00%~45.00% by mass percentage;Pigment 5.10-
12.00%;Filler 15.00~35.00%;Wetting agent 0.10-0.20%;Dispersant 0.30~0.60%;PH conditioning agents 0.05
~0.15%;Defoamer 0.10~0.50%;Preservative 0.10~0.30%;Hydroxyethyl cellulose 0.10-0.30%;Thickener
0.20~0.60%;Coalescents 2.60~4.00%;Antifreezing agent 0.10~0.20%;Spacetabs type naphthalene water reducer is organic base
Modified naphthalene sulfonate formaldehyde condensation products 2.00~5.00% and water 18.00~25.00%.The exterior wall employed in the invention resists
Alkali priming paint and preparation method thereof, play closing basic unit alkalescence for exterior wall putty or mortar, reduce and painted caused by the accumulation of salt in the surface soil
Film disadvantage, improve the coating system life-span, it is low to basic unit's screed or putty layer curing requirements, shorten the exterior wall coating decoration phase, symbol
Domestic decoration of exterior wall actual conditions before being fated, there is very extensive promotional value.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of high adhesion force high osmosis exterior wall alkali resistant
Priming paint and preparation method thereof, the alkali-resistant primer are environment-friendlywater-based water-based paints, suitable for the back cover on the surfaces such as cement brick wall structure
Paint, has good adhesive force and preferable permeance property, has alkali resistant effect, can effectively keep surface layer emulsion paint color and luster matter
Amount is stable.
To reach above-mentioned purpose, the technical scheme is that:
A kind of high adhesion force high osmosis exterior wall alkali-resistant primer, the alkali-resistant primer include the composition of following parts by weight:Organosilicon
Modified phenylethylene AA emulsion:30 ~ 40 parts, calcium carbonate:15 ~ 25 parts, hydroxyethyl cellulose:10 ~ 15 parts, mica
Powder:5 ~ 10 parts, kaolin:5 ~ 10 parts, propane diols:1 ~ 5 part, polyvinyl alcohol:10 ~ 15 parts, titanium dioxide:1 ~ 5 part, mould inhibitor:1~5
Part, coalescents:1 ~ 5 part, anti-accumulation of salt in the surface soil agent:1 ~ 5 part, levelling agent:1 ~ 5 part, dispersant:1 ~ 5 part, deionized water:40 ~ 50 parts.
Further, the alkali-resistant primer includes the composition of following parts by weight:Organosilicon modified styrene acrylic copolymer
Emulsion:35 ~ 40 parts, calcium carbonate:15 ~ 20 parts, hydroxyethyl cellulose:10 ~ 13 parts, mica powder:7 ~ 10 parts, kaolin:5 ~ 8 parts,
Propane diols:1 ~ 3 part, polyvinyl alcohol:12 ~ 15 parts, titanium dioxide:2 ~ 5 parts, mould inhibitor:3 ~ 5 parts, coalescents:1 ~ 4 part, the anti-accumulation of salt in the surface soil
Agent:1 ~ 3 part, levelling agent:2 ~ 5 parts, dispersant:3 ~ 5 parts, deionized water:45 ~ 50 parts.
Preferably, the alkali-resistant primer includes the composition of following parts by weight:Organosilicon modified styrene acrylic copolymer
Emulsion:35 parts, calcium carbonate:20 parts, hydroxyethyl cellulose:12 parts, mica powder:7 parts, kaolin:6 parts, propane diols:3 parts, poly- second
Enol:14 parts, titanium dioxide:2 parts, mould inhibitor:5 parts, coalescents:3 parts, anti-accumulation of salt in the surface soil agent:2 parts, levelling agent:4 parts, dispersant:3
Part, deionized water:45 parts.
Preferably, the anti-accumulation of salt in the surface soil agent is modified rosin resin.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propylene glycol methyl ether acetate.
Preferably, the mould inhibitor is benzimidazole methyl carbamate.
Preferably, the dispersant is calgon.
Preferably, the levelling agent is polyurethanes levelling agent.
Meanwhile the present invention also provides a kind of high adhesion force high osmosis exterior wall as any one of claim 1 ~ 8
The preparation method of alkali-resistant primer, it is characterised in that the preparation method comprises the following steps:1) mixer is taken, by weight will
It is organosilicon modified styrene AA emulsion, calcium carbonate, hydroxyethyl cellulose, mica powder, kaolin, propane diols, poly-
The deionized water of vinyl alcohol, titanium dioxide and 50wt% is added in mixer, stir 20 under normal temperature, 600 ~ 800 revs/min of rotating speed ~
30 minutes;2) mould inhibitor, coalescents, anti-accumulation of salt in the surface soil agent, levelling agent, dispersant and remaining deionized water are added, is warming up to 30 ~ 40
DEG C, stirred 10 ~ 20 minutes under 800 ~ 1000 revs/min of rotating speed, be cooled to room temperature, filtered, stood, produce the high adhesion force
High osmosis exterior wall alkali-resistant primer.
The invention has the advantages that:
The alkali-resistant primer is environment-friendlywater-based water-based paint, suitable for the bottom closing paint on the surfaces such as cement brick wall structure, is had well
Adhesive force and preferable permeance property, there is alkali resistant effect, can effectively keep surface layer emulsion paint color and luster steady quality.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
A kind of high adhesion force high osmosis exterior wall alkali-resistant primer provided by the present invention, the alkali-resistant primer include following weight
Measure the composition of part:Organosilicon modified styrene AA emulsion:30 ~ 40 parts, calcium carbonate:15 ~ 25 parts, hydroxy ethyl fiber
Element:10 ~ 15 parts, mica powder:5 ~ 10 parts, kaolin:5 ~ 10 parts, propane diols:1 ~ 5 part, polyvinyl alcohol:10 ~ 15 parts, titanium dioxide:1
~ 5 parts, mould inhibitor:1 ~ 5 part, coalescents:1 ~ 5 part, anti-accumulation of salt in the surface soil agent:1 ~ 5 part, levelling agent:1 ~ 5 part, dispersant:1 ~ 5 part, go
Ionized water:40 ~ 50 parts.
Further, the alkali-resistant primer includes the composition of following parts by weight:Organosilicon modified styrene acrylic copolymer
Emulsion:35 ~ 40 parts, calcium carbonate:15 ~ 20 parts, hydroxyethyl cellulose:10 ~ 13 parts, mica powder:7 ~ 10 parts, kaolin:5 ~ 8 parts,
Propane diols:1 ~ 3 part, polyvinyl alcohol:12 ~ 15 parts, titanium dioxide:2 ~ 5 parts, mould inhibitor:3 ~ 5 parts, coalescents:1 ~ 4 part, the anti-accumulation of salt in the surface soil
Agent:1 ~ 3 part, levelling agent:2 ~ 5 parts, dispersant:3 ~ 5 parts, deionized water:45 ~ 50 parts.
Preferably, the alkali-resistant primer includes the composition of following parts by weight:Organosilicon modified styrene acrylic copolymer
Emulsion:35 parts, calcium carbonate:20 parts, hydroxyethyl cellulose:12 parts, mica powder:7 parts, kaolin:6 parts, propane diols:3 parts, poly- second
Enol:14 parts, titanium dioxide:2 parts, mould inhibitor:5 parts, coalescents:3 parts, anti-accumulation of salt in the surface soil agent:2 parts, levelling agent:4 parts, dispersant:3
Part, deionized water:45 parts.
Preferably, the anti-accumulation of salt in the surface soil agent is modified rosin resin.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propylene glycol methyl ether acetate.
Preferably, the mould inhibitor is benzimidazole methyl carbamate.
Preferably, the dispersant is calgon.
Preferably, the levelling agent is polyurethanes levelling agent.
Meanwhile the present invention also provides a kind of high adhesion force high osmosis exterior wall as any one of claim 1 ~ 8
The preparation method of alkali-resistant primer, it is characterised in that the preparation method comprises the following steps:1) mixer is taken, by weight will
It is organosilicon modified styrene AA emulsion, calcium carbonate, hydroxyethyl cellulose, mica powder, kaolin, propane diols, poly-
The deionized water of vinyl alcohol, titanium dioxide and 50wt% is added in mixer, stir 20 under normal temperature, 600 ~ 800 revs/min of rotating speed ~
30 minutes;2) mould inhibitor, coalescents, anti-accumulation of salt in the surface soil agent, levelling agent, dispersant and remaining deionized water are added, is warming up to 30 ~ 40
DEG C, stirred 10 ~ 20 minutes under 800 ~ 1000 revs/min of rotating speed, be cooled to room temperature, filtered, stood, produce the high adhesion force
High osmosis exterior wall alkali-resistant primer.
A kind of high adhesion force high osmosis exterior wall alkali-resistant primer provided by the present invention, is environment-friendlywater-based water-based paint, is applicable
Bottom closing paint in surfaces such as cement brick wall structures, there is good adhesive force and preferable permeance property, there is alkali resistant effect, energy
Effectively keep surface layer emulsion paint color and luster steady quality.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (9)
1. a kind of high adhesion force high osmosis exterior wall alkali-resistant primer, it is characterised in that the alkali-resistant primer includes following parts by weight
Composition:Organosilicon modified styrene AA emulsion:30 ~ 40 parts, calcium carbonate:15 ~ 25 parts, hydroxyethyl cellulose:
10 ~ 15 parts, mica powder:5 ~ 10 parts, kaolin:5 ~ 10 parts, propane diols:1 ~ 5 part, polyvinyl alcohol:10 ~ 15 parts, titanium dioxide:1~5
Part, mould inhibitor:1 ~ 5 part, coalescents:1 ~ 5 part, anti-accumulation of salt in the surface soil agent:1 ~ 5 part, levelling agent:1 ~ 5 part, dispersant:1 ~ 5 part, go from
Sub- water:40 ~ 50 parts.
2. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the alkali-resistant primer
Include the composition of following parts by weight:Organosilicon modified styrene AA emulsion:35 ~ 40 parts, calcium carbonate:15 ~ 20 parts,
Hydroxyethyl cellulose:10 ~ 13 parts, mica powder:7 ~ 10 parts, kaolin:5 ~ 8 parts, propane diols:1 ~ 3 part, polyvinyl alcohol:12~15
Part, titanium dioxide:2 ~ 5 parts, mould inhibitor:3 ~ 5 parts, coalescents:1 ~ 4 part, anti-accumulation of salt in the surface soil agent:1 ~ 3 part, levelling agent:2 ~ 5 parts, disperse
Agent:3 ~ 5 parts, deionized water:45 ~ 50 parts.
3. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the alkali-resistant primer
Include the composition of following parts by weight:Organosilicon modified styrene AA emulsion:35 parts, calcium carbonate:20 parts, ethoxy
Cellulose:12 parts, mica powder:7 parts, kaolin:6 parts, propane diols:3 parts, polyvinyl alcohol:14 parts, titanium dioxide:2 parts, mould inhibitor:
5 parts, coalescents:3 parts, anti-accumulation of salt in the surface soil agent:2 parts, levelling agent:4 parts, dispersant:3 parts, deionized water:45 parts.
4. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the anti-accumulation of salt in the surface soil agent
For modified rosin resin.
5. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the coalescents
For propandiol butyl ether, alcohol ester 12 or propylene glycol methyl ether acetate.
6. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the mould inhibitor is
Benzimidazole methyl carbamate.
7. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the dispersant is
Calgon.
8. high adhesion force high osmosis exterior wall alkali-resistant primer according to claim 1, it is characterised in that the levelling agent is
Polyurethanes levelling agent.
9. a kind of preparation method of high adhesion force high osmosis exterior wall alkali-resistant primer as any one of claim 1 ~ 8,
Characterized in that, the preparation method comprises the following steps:1) mixer is taken, by weight by organosilicon modified styrene propylene
Acid copolymer emulsion, calcium carbonate, hydroxyethyl cellulose, mica powder, kaolin, propane diols, polyvinyl alcohol, titanium dioxide and 50wt%
Deionized water add mixer in, stirred 20 ~ 30 minutes under normal temperature, 600 ~ 800 revs/min of rotating speed;2) add mould inhibitor,
Coalescents, anti-accumulation of salt in the surface soil agent, levelling agent, dispersant and remaining deionized water, are warming up to 30 ~ 40 DEG C, at 800 ~ 1000 revs/min
Stirred 10 ~ 20 minutes under rotating speed, be cooled to room temperature, filtered, stood, produce the high adhesion force high osmosis exterior wall alkali resistant bottom
Paint.
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CN201710867361.XA CN107384049A (en) | 2017-09-22 | 2017-09-22 | A kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof |
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CN201710867361.XA CN107384049A (en) | 2017-09-22 | 2017-09-22 | A kind of high adhesion force high osmosis exterior wall alkali-resistant primer and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111117381A (en) * | 2019-12-24 | 2020-05-08 | 大连好友装饰材料有限公司 | Water-based seal primer applied to paint-free veneering paper of panel furniture and preparation method thereof |
CN111410875A (en) * | 2020-04-03 | 2020-07-14 | 沪宝新材料科技(上海)股份有限公司 | Water-based primer for plastic track and preparation method thereof |
CN113969086A (en) * | 2021-10-11 | 2022-01-25 | 安徽朗凯奇防水科技股份有限公司 | Alkali-resistant primer for interior walls and preparation method thereof |
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CN102838910A (en) * | 2012-09-20 | 2012-12-26 | 合众(佛山)化工有限公司 | Preparation method for cationic silicone/acrylic emulsion alkali resistant seal primer |
CN105176271A (en) * | 2015-10-23 | 2015-12-23 | 山西亮龙涂料有限公司 | Architectural transparent colored alkali-resistant primer |
CN105440819A (en) * | 2015-12-03 | 2016-03-30 | 三棵树涂料股份有限公司 | Dilution-free alkali-resistant seal primer for external wall and preparation method thereof |
CN105482570A (en) * | 2016-01-14 | 2016-04-13 | 上海三银涂料科技股份有限公司 | Alkali-resistant primer for external wall and preparation method of alkali-resistant primer |
CN105505063A (en) * | 2016-01-19 | 2016-04-20 | 卓达新材料科技集团有限公司 | White water-based alkali-resistant sealing primer and preparation method thereof |
CN106147485A (en) * | 2016-06-22 | 2016-11-23 | 林金溪 | A kind of resistance to salting-out anti-accumulation of salt in the surface soil seal coat and preparation method thereof |
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2017
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102838910A (en) * | 2012-09-20 | 2012-12-26 | 合众(佛山)化工有限公司 | Preparation method for cationic silicone/acrylic emulsion alkali resistant seal primer |
CN105176271A (en) * | 2015-10-23 | 2015-12-23 | 山西亮龙涂料有限公司 | Architectural transparent colored alkali-resistant primer |
CN105440819A (en) * | 2015-12-03 | 2016-03-30 | 三棵树涂料股份有限公司 | Dilution-free alkali-resistant seal primer for external wall and preparation method thereof |
CN105482570A (en) * | 2016-01-14 | 2016-04-13 | 上海三银涂料科技股份有限公司 | Alkali-resistant primer for external wall and preparation method of alkali-resistant primer |
CN105505063A (en) * | 2016-01-19 | 2016-04-20 | 卓达新材料科技集团有限公司 | White water-based alkali-resistant sealing primer and preparation method thereof |
CN106147485A (en) * | 2016-06-22 | 2016-11-23 | 林金溪 | A kind of resistance to salting-out anti-accumulation of salt in the surface soil seal coat and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111117381A (en) * | 2019-12-24 | 2020-05-08 | 大连好友装饰材料有限公司 | Water-based seal primer applied to paint-free veneering paper of panel furniture and preparation method thereof |
CN111410875A (en) * | 2020-04-03 | 2020-07-14 | 沪宝新材料科技(上海)股份有限公司 | Water-based primer for plastic track and preparation method thereof |
CN113969086A (en) * | 2021-10-11 | 2022-01-25 | 安徽朗凯奇防水科技股份有限公司 | Alkali-resistant primer for interior walls and preparation method thereof |
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