CN102767097B - Processing method of three-proofing easy-care clothing fabric - Google Patents

Processing method of three-proofing easy-care clothing fabric Download PDF

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CN102767097B
CN102767097B CN201210272038.5A CN201210272038A CN102767097B CN 102767097 B CN102767097 B CN 102767097B CN 201210272038 A CN201210272038 A CN 201210272038A CN 102767097 B CN102767097 B CN 102767097B
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fabric
agent
processing method
proofing
acetic acid
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CN102767097A (en
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王尚美
郑琪
吴蓬云
黄邓军
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Rimula Men (shanghai) Co Ltd
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Rimula Men (shanghai) Co Ltd
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Abstract

A processing method of a three-proofing easy-care clothing fabric relates to a processing method of fabrics. The processing method includes: pretreating to remove slurry during spinning and extra oiling agent of a chemical and blended fabric; dyeing; washing by one dipping one pressing at normal temperature using an evenness calendar; and post-finishing by padding plus preshrinking, padding, drying, curing, and preshrinking to obtain the three-proofing easy-care chemical and blended fabric. By the aid of padding, three-proofing finishing agent is co-bathed with soil-releasing finishing agent to apply to the fabric. By the aid of drying and curing, permanent water proofing, oil proofing, dirt proofing and soil releasing of the fabric are achieved. A functional polymer resin film layer which is fine in water-oil-proof effect is formed on the surface of the fabric, solid dirt is not easy to attach to the fabric, and the solid dirt attached on the fabric can be washed off in water easily. The three-proofing easy-care clothing fabric is waterproof, oil-proof, and dirt-proof, and dirt attached to the fabric can be washed off easily.

Description

The processing method of a kind of three anti-easy care garment fabrics
Technical field
The present invention relates to a kind of processing method of fabric, especially relate to the processing method of a kind of three anti-easy care garment fabrics.
Background technology
Along with the raising of people's living standard and the quickening of work rhythm, the requirement for clothes safeguard function is more and more higher.The textiles of simple function can not meet the needs of people, and the textiles of Multifunctional finishing just more and more receives the concern of people and likes because of its excellent performance.Textiles is in the process used, and its position such as cuff and neckline is easily stain dirty, especially chemical fibre class clothes, once after the position such as neckline and cuff is stain, under normal wash conditions, dirt pole is not easy eccysis.
Through the fabric of general dyeing and finishing technology, although the WATER REPELLENT TREATMENT of its routine can reach the effect of waterproof, greasy dirt and solid dirt can not be prevented to be infected with, durability is poor, and fabric is once tarnish, just extremely difficult cleaning removing, even if through repeatedly washing, still can not remove.
Chinese patent CN2409047 is open a kind of by fabric and film, silk or Water-proof wind-proof poromeric moisture permeable chemical fibre fabric composite shell fabric, science fabric is outer, windproof waterproof breathable moisture-permeable film is intermediate layer, and science fabric fabric is internal layer, and three layers are combined into one.This water proof wind proof air-moisture-permeable chemical & blended fabric has moisture-inhibiting, moisture absorption, ventilative, windproof, waterproof, warming feature.In addition, go back wash resistant, intensity is high, resilience good.With all kinds of clothes that this kind of fabric is made, warmth retention property, moisture-inhibiting, gas permeability are fabulous, fully feel comfortable, light and handy, have no abundant, burdensome sense after people is worn.
Summary of the invention
The object of the present invention is to provide the processing method of a kind of three anti-easy care garment fabrics.
The present invention includes following steps:
1) pre-treatment, the slurry in removing chemical & blended fabric spinning process and unnecessary finish;
2) dye, concrete grammar is: at 40 DEG C, add glacial acetic acid, then add Disperse Leveler, add dyestuff after stirring, with after the ramp to 80 of 1.5 DEG C/min DEG C, change with ramp to 130 ~ 140 DEG C of 2 DEG C/min, insulation 30 ~ 45min, is cooled to 40 DEG C with the speed of 2 DEG C/min afterwards, washing, 40 DEG C time, add soda ash and sodium hydrosulfite, with the ramp to 70 of 1.5 DEG C/min DEG C process 20min, be finally down to room temperature with the speed of 2 DEG C/min and wash 2 times;
Dye bath formulation: Disperse Leveler: 2 ~ 5g/L, glacial acetic acid: regulate pH to 5 ~ 7, sodium hydrosulfite: 2 ~ 5g/L, caustic soda: 1 ~ 5g/L;
3) wash, adopt the method that an evenness calender leaching one is at normal temperatures pressed;
Formula: detergent FK-9508:1 ~ 2g/L, HAc(acetic acid): 1 ~ 3g/L;
Decatize dyeing machine washing steam box: 1 ~ 5 lattice washing, temperature is 40 ~ 50 DEG C; 6 ~ 7 lattice washings, normal temperature; 8 lattice add acetic acid: 2 ~ 3g/L, normal temperature; Cropping is containing damp rate: 5% ~ 8%;
4) Final finishing: adopt and pad the method adding preshrunk, concrete steps are as follows: first pad post-drying, then bake rear preshrunk, obtains three anti-easily nursing chemical & blended fabric fabrics.
In step 1), the slurry in described removing chemical & blended fabric spinning process and the method for unnecessary finish can adopt jet overflow dyeing machine destarch refining process, stir after adding auxiliary agent, under 80 ~ 90 DEG C of conditions, process 20 ~ 30min after washing;
Process conditions: bath raio 1: 10;
Formula: 30% caustic soda: 2 ~ 10g/L, sodium hydrosulfite: 1 ~ 2g/L, desizing agent (YZ-1121): 1 ~ 5g/L, chelated dispersants (YZ-1123): 1 ~ 4g/L, scouring agent (scouring agent 204): 1 ~ 5g/L.
In step 4), described in the consisting of of dressing liquid of padding:
Soil-releasing finishing agent 30 ~ 80g/L, three-proof finishing agent 30 ~ 70g/L, fiber protection agent 30 ~ 100g/L, bleeding agent 3g/L, synergist 0 ~ 30g/L, acetic acid (HAc) 5 ~ 40g/L(regulates pH to 6 ~ 7).
Described soil-releasing finishing agent can adopt PM-90 etc.
Described three-proof finishing agent can adopt the one in Oleophobol CP-R, Oleophobol CP-SLA, PM-90 etc.
Described fiber protection agent can adopt Oleophobol CP-R etc.
Described bleeding agent can adopt INVADINE PBN etc.
Described synergist can adopt Phobol XAN etc.
The teflon products that Oleophobol CP-R, Oleophobol CP-SLA, INVADINE PBN, Phobol XAN etc. can adopt Huntsman Hensel to step.
PM-90 can adopt the product of Minnesota Mining and Manufacturing Company.
The present invention process acquisition three anti-easily nursing chemical & blended fabric fabrics be tatting pure chemical fiber fabric, its grammes per square metre is at 60 ~ 200g/m 2between.
The present invention adopts the method for padding, and prevents that (namely waterproof and oilproof is antifouling, lower same) finishing agents and soil-releasing finishing agent are with bathing, and are applied on fabric, then by drying and baking, make it to obtain the antifouling and decontaminable effect of permanent waterproof and oilproof by three.Through the three anti-chemical & blended fabrics adding soil-releasing finiss, surface property changes, and critical surface tension significantly reduces, and water-based spot, oil-dirt and solid dirt are all difficult to stain fabric surface.Fabric face defines one deck functional high-polymer resin molding, and when in atmosphere, its hydrophobic group is exposed to outside, and fabric is not easily tarnished; When in water, its hydrophobic group turns to fabric inner surface, and hydrophilic radical aligns in fabric exterior, make the dirt on fabric easier in water by eccysis.Fabric after this arranges, has good waterproof oil-proof result, is not easy to stain solid dirt, and after fabric tarnishes, also can easily in water by eccysis.
Through the function that this three anti-chemical fiber plus material adding soil-releasing finiss not only has waterproof and oilproof antifouling, and after contamination, dirt easily goes eccysis, has decontaminable effect.The ultra-clean jacket of planting chemical fiber plus material making thus not only has effect of protection dirt, and has decontaminable function, thus makes clothes be easy to arrange.
Obtained by the present invention three anti-easily nursing chemical & blended fabric fabric is a kind of new ultra-clean clothes, it runs into water stain or oil stain in daily life and splashes and can not be infected with water stain or greasy dirt, not easily adsorbent solid dirt and dust, can keep good clean effect lastingly.And after it is infected with dirt or oil stain, dirt or oil stain can be removed very easily.
Accompanying drawing explanation
Fig. 1 is dyeing curve.
Detailed description of the invention
The present invention includes following steps:
1) pre-treatment, the slurry in removing chemical & blended fabric spinning process and unnecessary finish, can adopt jet overflow dyeing machine destarch refining process, stir after adding auxiliary agent, under 80 ~ 90 DEG C of conditions, process 20 ~ 30min after washing;
Process conditions: bath raio 1: 10;
Formula: 30% caustic soda: 2 ~ 10g/L, sodium hydrosulfite: 1 ~ 2g/L, desizing agent (YZ-1121): 1 ~ 5g/L, chelated dispersants (YZ-1123): 1 ~ 4g/L, scouring agent (scouring agent 204): 1 ~ 5g/L;
2) dye, concrete grammar is: at 40 DEG C, add glacial acetic acid, then add Disperse Leveler, add dyestuff after stirring, with after the ramp to 80 of 1.5 DEG C/min DEG C, change with ramp to 130 ~ 140 DEG C of 2 DEG C/min, insulation 30 ~ 45min, is cooled to 40 DEG C with the speed of 2 DEG C/min afterwards, washing, 40 DEG C time, add soda ash and sodium hydrosulfite, with the ramp to 70 of 1.5 DEG C/min DEG C process 20min, be finally down to room temperature with the speed of 2 DEG C/min and wash 2 times;
Dye bath formulation: Disperse Leveler: 2 ~ 5g/L, glacial acetic acid: regulate pH to 5 ~ 7, sodium hydrosulfite: 2 ~ 5g/L, caustic soda: 1 ~ 5g/L;
Dyeing curve is see Fig. 1.
3) wash, adopt the method that an evenness calender leaching one is at normal temperatures pressed;
Formula: detergent FK-9508:1 ~ 2g/L, HAc(acetic acid): 1 ~ 3g/L;
Decatize dyeing machine washing steam box: 1 ~ 5 lattice washing, temperature is 40 ~ 50 DEG C; 6 ~ 7 lattice washings, normal temperature; 8 lattice add acetic acid: 2 ~ 3g/L, normal temperature; Cropping is containing damp rate: 5% ~ 8%;
4) Final finishing: adopt and pad the method adding preshrunk, concrete steps are as follows: first pad post-drying, then bake rear preshrunk, obtains three anti-easily nursing chemical & blended fabric fabrics.Consisting of of the described dressing liquid padded:
Soil-releasing finishing agent 30 ~ 80g/L, three-proof finishing agent 30 ~ 70g/L, fiber protection agent 30 ~ 100g/L, bleeding agent 3g/L, synergist 0 ~ 30g/L, acetic acid (HAc) 5 ~ 40g/L(regulates pH to 6 ~ 7).
Described soil-releasing finishing agent can adopt PM-90 etc.
Described three-proof finishing agent can adopt the one in Oleophobol CP-R, Oleophobol CP-SLA, PM-90 etc.
Described fiber protection agent can adopt Oleophobol CP-R etc.
Described bleeding agent can adopt INVADINE PBN etc.
Described synergist can adopt Phobol XAN etc.
The teflon products that Oleophobol CP-R, Oleophobol CP-SLA, INVADINE PBN, Phobol XAN etc. can adopt Huntsman Hensel to step.
PM-90 can adopt the product of Minnesota Mining and Manufacturing Company.
The present invention process acquisition three anti-easily nursing chemical & blended fabric fabrics be tatting pure chemical fiber fabric, its grammes per square metre is at 60 ~ 200g/m 2between.
The teflon products that embodiment 1:(selects Huntsman Hensel to step)
Embodiment 2:(selects the product of Minnesota Mining and Manufacturing Company)
PM-90:60g/L
HAc(acetic acid) 5ml/L
Described PM-90 is three-proof finishing agent and soil-releasing finishing agent.(in addition not using other auxiliary agents)
Material order:
In material cylinder, add soft cold water, then add bleeding agent, agent for three purposes and soil-releasing finishing agent, then add synergist, after stirring, add HAc(acetic acid), finally add water and stir.
Process conditions:
Temperature: less than 40 DEG C, pH:6 ~ 7;
The speed of a motor vehicle: 35 ~ 40m/min, pressure: 1.5 ~ 2MPa;
Pick-up 70% ~ 80%;
Dry: temperature: 90 ~ 120 DEG C, time: 1 ~ 2min;
Bake: the speed of a motor vehicle: 35 ~ 40m/min, temperature: 150 ~ 180 DEG C, the time: 40 ~ 50s
Preshrunk: the speed of a motor vehicle: 35 ~ 40m/min, normal pressure: 15 ~ 20cm, side pressure: 30 ~ 40cm, vapour pressure: 0.15 ~ 0.25MPa, shrinkage: 2% ~ 3%.
The relevant issues noted in padding finishing are as follows:
1) charging rate and mixing speed is controlled, in case produce foam and be stained with roller.
2) note the temperature and time strictly controlling to bake, otherwise brute force and the four anti-effects of fabric can be affected.
3) equipment and instrument doing padding finishing will be cleaned before use, in order to avoid equipment be infected with silicone oil compound and affect waterproof oil-proof result.
In dyeing and Final finishing process, Attention question is as follows:
1) when carrying out three-prevention finishing, before grooming fabric to be cleaned up, will wash fully after arrangement, ensure the effect of soil-releasing finiss below.
2) strictly to control the process conditions dried and bake, ensure powerful not by excessive damage.
3) in dyeing course, want science to screen and the strict consumption controlling dye material, reductant, oxidant, color-fixing agent, soaping agent and surfactant, otherwise easily increase the weight of rear road washing burden, even cause water do not wash clean and affect four anti-effects.
4) can adopt for dark kind and first use acid scouring agent, rear basic soap lotion is soaped and adds chelated dispersants, effectively can remove loose colour like this and improve the crock fastness of finished product.
With reference to test index:
Waterproof: AATCC 193 moisture-resistant lubricant nature: the experiment of waterproof/ethanolic solution; The spray test of AATCC22--2005 waterproof.
Grease proofing: AATCC118--2002 grease proofness: resistance to hydrocarbon test.
Antifouling: AATCC130--2000 dirt removal: oil stain removes method.
Easy decontamination: AATCC130--2000 dirt removal: oil stain removes method.

Claims (4)

1. a processing method for three anti-easy care garment fabrics, is characterized in that comprising the following steps:
1) pre-treatment, the slurry in removing chemical & blended fabric spinning process and unnecessary finish;
2) dye, concrete grammar is: at 40 DEG C, add glacial acetic acid, then add Disperse Leveler, add dyestuff after stirring, with after the ramp to 80 of 1.5 DEG C/min DEG C, change with ramp to 130 ~ 140 DEG C of 2 DEG C/min, insulation 30 ~ 45min, is cooled to 40 DEG C with the speed of 2 DEG C/min afterwards, washing, 40 DEG C time, add soda ash and sodium hydrosulfite, with the ramp to 70 of 1.5 DEG C/min DEG C process 20min, be finally down to room temperature with the speed of 2 DEG C/min and wash 2 times;
Dye bath formulation: Disperse Leveler: 2 ~ 5g/L, glacial acetic acid: regulate pH to 5 ~ 7, sodium hydrosulfite: 2 ~ 5g/L, caustic soda: 1 ~ 5g/L;
3) wash, adopt the method that an evenness calender leaching one is at normal temperatures rolled;
Formula: detergent: 1 ~ 2g/L, acetic acid: 1 ~ 3g/L;
Decatize dyeing machine washing steam box: 1 ~ 5 lattice washing, temperature is 40 ~ 50 DEG C; 6 ~ 7 lattice washings, normal temperature; 8 lattice add acetic acid: 2 ~ 3g/L, normal temperature; Cropping is containing damp rate: 5% ~ 8%;
4) Final finishing: adopt and pad the method adding preshrunk, concrete steps are as follows: first pad post-drying, then bake rear preshrunk, obtains three anti-easily nursing chemical & blended fabric fabrics;
Consisting of of the described dressing liquid padded:
Soil-releasing finishing agent 30 ~ 80g/L, three-proof finishing agent 30 ~ 70g/L, fiber protection agent 30 ~ 100g/L, bleeding agent 3g/L, synergist 0 ~ 30g/L, acetic acid 5 ~ 40g/L, regulate pH to 6 ~ 7;
Described three-proof finishing agent is Oleophobol CP-SLA.
2. the processing method of a kind of three anti-easy care garment fabrics as claimed in claim 1, it is characterized in that in step 1) in, the method of the slurry in described removing chemical & blended fabric spinning process and unnecessary finish adopts jet overflow dyeing machine destarch refining process, stir after adding auxiliary agent, under 80 ~ 90 DEG C of conditions, process 20 ~ 30min after washing;
Process conditions: bath raio 1: 10;
Formula: 30% caustic soda: 2 ~ 10g/L, sodium hydrosulfite: 1 ~ 2g/L, desizing agent: 1 ~ 5g/L, chelated dispersants: 1 ~ 4g/L, scouring agent: 1 ~ 5g/L.
3. the processing method of a kind of three anti-easy care garment fabrics as claimed in claim 1, is characterized in that in step 4) in, described bleeding agent adopts INVADINE PBN.
4. the processing method of a kind of three anti-easy care garment fabrics as claimed in claim 1, is characterized in that in step 4) in, described synergist adopts Phobol XAN.
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