CN102767097A - Processing method of three-proofing easy-care clothing fabric - Google Patents
Processing method of three-proofing easy-care clothing fabric Download PDFInfo
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Abstract
A processing method of a three-proofing easy-care clothing fabric relates to a processing method of fabrics. The processing method includes: pretreating to remove slurry during spinning and extra oiling agent of a chemical and blended fabric; dyeing; washing by one dipping one pressing at normal temperature using an evenness calendar; and post-finishing by padding plus preshrinking, padding, drying, curing, and preshrinking to obtain the three-proofing easy-care chemical and blended fabric. By the aid of padding, three-proofing finishing agent is co-bathed with soil-releasing finishing agent to apply to the fabric. By the aid of drying and curing, permanent water proofing, oil proofing, dirt proofing and soil releasing of the fabric are achieved. A functional polymer resin film layer which is fine in water-oil-proof effect is formed on the surface of the fabric, solid dirt is not easy to attach to the fabric, and the solid dirt attached on the fabric can be washed off in water easily. The three-proofing easy-care clothing fabric is waterproof, oil-proof, and dirt-proof, and dirt attached to the fabric can be washed off easily.
Description
Technical field
The present invention relates to a kind of processing method of lining, especially relate to a kind of three anti-processing methods that are prone to the care garment lining.
Background technology
The quickening of Along with people's growth in the living standard and work rhythm, for the clothes safeguard function require increasingly high.The textiles of simple function can not satisfy needs of people, and the textiles of multi-functional arrangement just more and more receives people's attention and likes because of its good performance.Textiles is in the process of using, and positions such as its cuff and neckline are stain dirty easily, chemical fibre class clothes especially, in case after the contamination of positions such as neckline and cuff, under the normal washing condition, the dirt utmost point is not easy eccysis.
Through the fabric of general dyeing and finishing technology,, can not prevent that greasy dirt and solid dirt be infected with though its conventional WATER REPELLENT TREATMENT can reach good waterproof effect; Durability is relatively poor, and in a single day fabric tarnish, and just extremely difficult the cleaning removed; Even, still can not remove through repeatedly washing.
Chinese patent CN2409047 discloses a kind of by fabric and the windproof air-moisture-permeable chemical & blended fabric of film, silk or waterproof composite material; Science fabric is outer; The windproof waterproof breathable moisture-permeable film is the intermediate layer, and the science fabric lining is an internal layer, and three layers are combined into one.That the windproof air-moisture-permeable chemical & blended fabric of this waterproof has is wet, moisture absorption, ventilative, windproof, waterproof, warming characteristics.In addition, also wash resistant, intensity is high, resilience is good.With all kinds of clothes that this kind lining is processed, warmth retention property, pass through wet, gas permeability is fabulous, fully feels after the people is worn comfortablely, light and handy, has no abundant, burdensome sense.
Summary of the invention
The object of the present invention is to provide a kind of three anti-processing methods that are prone to the care garment lining.
The present invention includes following steps:
1) slurry and unnecessary finish in the chemical & blended fabric spinning process are removed in pre-treatment;
2) dyeing, concrete grammar is: at 40 ℃ of following adding glacial acetic acid, add and disperse levelling agent; The back that stirs adds dyestuff, be warming up to 80 ℃ with the speed of 1.5 ℃/min after, the speed that changes with 2 ℃/min is warming up to 130～140 ℃; Insulation 30～45min, the speed with 2 ℃/min is cooled to 40 ℃ afterwards, washing; In the time of 40 ℃, add soda ash and sodium hydrosulfite, be warming up to 70 ℃ with the speed of 1.5 ℃/min and handle 20min, reduce to room temperature washing 2 times with the speed of 2 ℃/min at last;
Dye bath prescription: disperse levelling agent: 2～5g/L, glacial acetic acid: regulate pH to 5～7, sodium hydrosulfite: 2～5g/L, caustic soda: 1～5g/L;
3) washing adopts evenness calender one to soak a method of pressing at normal temperatures;
Prescription: detergent FK-9508:1～2g/L, HAc (acetic acid): 1～3g/L;
Decatize dyeing machine washing steam box: the washing of 1～5 lattice, temperature is 40～50 ℃; The washing of 6～7 lattice, normal temperature; 8 lattice add acetic acid: 2～3g/L, normal temperature; Cropping contains damp rate: 5%～8%;
4) back arrangement: adopt and pad the method that adds preshrunk, concrete steps are following: pad afterwards earlier and dry, bake back preshrunk again, promptly get the three anti-nursing chemical & blended fabric linings that are prone to.
In step 1), said slurry and the method for unnecessary finish of removing in the chemical & blended fabric spinning process can adopt jet overflow dyeing machine destarch refining process, stirs after adding auxiliary agent, under 80～90 ℃ of conditions, handles 20～30min after washing and gets final product;
Process conditions: bath raio 1: 10;
Prescription: 30% caustic soda: 2～10g/L, sodium hydrosulfite: 1～2g/L, desizing agent (YZ-1121): 1～5g/L, chelated dispersants (YZ-1123): 1～4g/L, scouring agent (scouring agent 204): 1～5g/L.
In step 4), the consisting of of the said dressing liquid that pads:
Soil-releasing finishing agent 30～80g/L, three-proof finishing agent 30～70g/L, fiber protective agent 30～100g/L, bleeding agent 3g/L, synergist 0～30g/L, acetic acid (HAc) 5～40g/L (regulating pH to 6～7).
Said soil-releasing finishing agent can adopt PM-90 etc.
Said three-proof finishing agent can adopt a kind of among Oleophobol CP-R, Oleophobol CP-SLA, the PM-90 etc.
Said fiber protective agent can adopt Oleophobol CP-R etc.
Said bleeding agent can adopt INVADINE PBN etc.
Said synergist can adopt Phobol XAN etc.
The teflon product that Oleophobol CP-R, Oleophobol CP-SLA, INVADINE PBN, Phobol XAN etc. can adopt the Huntsman Hensel to step.
PM-90 can adopt the product of Minnesota Mining and Manufacturing Company.
It is the fine lining of tatting purifying that the present invention processes the three anti-nursing chemical & blended fabric linings that are prone to that obtain, and its grammes per square metre is at 60～200g/m
2Between.
The present invention adopts the method for padding, and prevents that with three (being that waterproof and oilproof is antifouling, down together) finishing agents and soil-releasing finishing agent with bathing, are applied on the fabric, through drying and baking, makes it to obtain the antifouling and decontaminable effect of nonvolatil waterproof and oilproof again.Through the three anti-chemical & blended fabrics that add soil-releasing finiss, surface property changes, and critical surface tension reduces significantly, and water-based spot, oil-dirt and solid dirt all are difficult to stain fabric face.Fabric face has formed one deck functional high-polymer resin molding, and when in air, its hydrophobic group is exposed to the outside, makes that fabric is difficult for tarnishing; When in water, its hydrophobic group turns to the fabric inner surface, and hydrophilic radical aligns in fabric exterior, make on the fabric dirt more easily in water by eccysis.Fabric after this arrangement has waterproof oil-proof result preferably, is not easy to stain solid dirt, and after fabric tarnishes, also can be at an easy rate in water by eccysis.
Through this three anti-chemical fiber plus material that adds soil-releasing finiss the waterproof and oilproof anti-fouling functions is arranged not only, and dirt is prone to eccysis after contamination, has decontaminable effect.The ultra clean jacket of planting the chemical fiber plus material making thus not only has the effect of protection dirt, and has decontaminable function, thereby makes that clothes are easy to arrange.
The present invention's prepared three anti-nursing chemical & blended fabric linings that are prone to are a kind of new ultra Uncontaminated garments; It runs into water stain in daily life or oil stain splashes and can not be infected with water stain or greasy dirt; Be difficult for absorption solid dirt and dust, can keep good clean and tidy effect lastingly.And after it was infected with dirt or oil stain, dirt or oil stain can be removed very easily.
Description of drawings
Fig. 1 is the dyeing curve.
The specific embodiment
The present invention includes following steps:
1) slurry and unnecessary finish in the chemical & blended fabric spinning process are removed in pre-treatment, can adopt jet overflow dyeing machine destarch refining process, stir after adding auxiliary agent, under 80～90 ℃ of conditions, handle 20～30min after washing and get final product;
Process conditions: bath raio 1: 10;
Prescription: 30% caustic soda: 2～10g/L, sodium hydrosulfite: 1～2g/L, desizing agent (YZ-1121): 1～5g/L, chelated dispersants (YZ-1123): 1～4g/L, scouring agent (scouring agent 204): 1～5g/L;
2) dyeing, concrete grammar is: at 40 ℃ of following adding glacial acetic acid, add and disperse levelling agent; The back that stirs adds dyestuff, be warming up to 80 ℃ with the speed of 1.5 ℃/min after, the speed that changes with 2 ℃/min is warming up to 130～140 ℃; Insulation 30～45min, the speed with 2 ℃/min is cooled to 40 ℃ afterwards, washing; In the time of 40 ℃, add soda ash and sodium hydrosulfite, be warming up to 70 ℃ with the speed of 1.5 ℃/min and handle 20min, reduce to room temperature washing 2 times with the speed of 2 ℃/min at last;
Dye bath prescription: disperse levelling agent: 2～5g/L, glacial acetic acid: regulate pH to 5～7, sodium hydrosulfite: 2～5g/L, caustic soda: 1～5g/L;
The dyeing curve is referring to Fig. 1.
3) washing adopts evenness calender one to soak a method of pressing at normal temperatures;
Prescription: detergent FK-9508:1～2g/L, HAc (acetic acid): 1～3g/L;
Decatize dyeing machine washing steam box: the washing of 1～5 lattice, temperature is 40～50 ℃; The washing of 6～7 lattice, normal temperature; 8 lattice add acetic acid: 2～3g/L, normal temperature; Cropping contains damp rate: 5%～8%;
4) back arrangement: adopt and pad the method that adds preshrunk, concrete steps are following: pad afterwards earlier and dry, bake back preshrunk again, promptly get the three anti-nursing chemical & blended fabric linings that are prone to.Consisting of of the said dressing liquid that pads:
Soil-releasing finishing agent 30～80g/L, three-proof finishing agent 30～70g/L, fiber protective agent 30～100g/L, bleeding agent 3g/L, synergist 0～30g/L, acetic acid (HAc) 5～40g/L (regulating pH to 6～7).
Said soil-releasing finishing agent can adopt PM-90 etc.
Said three-proof finishing agent can adopt a kind of among Oleophobol CP-R, Oleophobol CP-SLA, the PM-90 etc.
Said fiber protective agent can adopt Oleophobol CP-R etc.
Said bleeding agent can adopt INVADINE PBN etc.
Said synergist can adopt Phobol XAN etc.
The teflon product that Oleophobol CP-R, Oleophobol CP-SLA, INVADINE PBN, Phobol XAN etc. can adopt the Huntsman Hensel to step.
PM-90 can adopt the product of Minnesota Mining and Manufacturing Company.
It is the fine lining of tatting purifying that the present invention processes the three anti-nursing chemical & blended fabric linings that are prone to that obtain, and its grammes per square metre is at 60～200g/m
2Between.
Embodiment 1: (the teflon product of selecting for use the Huntsman Hensel to step)
Embodiment 2: (selecting the product of Minnesota Mining and Manufacturing Company for use)
PM-90：60g/L
HAc (acetic acid) 5ml/L
Said PM-90 is three-proof finishing agent and soil-releasing finishing agent.(in addition not using other auxiliary agents)
Change the material order:
In changing the material cylinder, add soft cold water, add bleeding agent, agent for three purposes and soil-releasing finishing agent again, add synergist again, the back that stirs adds HAc (acetic acid), adds water at last and stirs and get final product.
Process conditions:
Temperature: below 40 ℃, pH:6～7;
The speed of a motor vehicle: 35～40m/min, pressure: 1.5～2MPa;
Pick-up 70%～80%;
Oven dry: temperature: 90～120 ℃, the time: 1～2min;
Bake: the speed of a motor vehicle: 35～40m/min, temperature: 150～180 ℃, the time: 40～50s
Preshrunk: the speed of a motor vehicle: 35～40m/min, normal pressure: 15～20cm, side pressure: 30～40cm, vapour pressure: 0.15～0.25MPa, shrinkage: 2%～3%.
The relevant issues of in padding finishing, noting are following:
1) control charging rate and mixing speed are stained with roller in case produce foam.
2) note the temperature and time that strict control bakes, otherwise can influence the brute force and the four anti-effects of fabric.
3) equipment and instrument of doing padding finishing will be cleaned before use, influences waterproof oil-proof result in order to avoid be infected with the silicone oil compound on the equipment.
The problem of in dyeing and back arrangement process, noting is following:
When 1) carrying out three-prevention finishing, before arrangement, fabric is cleaned up, will wash fully after the arrangement, guarantee the effect of the soil-releasing finiss of back.
2) process conditions of wanting strict control oven dry and baking guarantee the powerful excessive damage that do not receive.
3) in dyeing course, want science screening and strict dying of control material, reductant, oxidant, color-fixing agent, soaping agent and amount of surfactant, otherwise increase the weight of road, back washing burden easily, even cause water not wash clean and influence four and prevent effects.
4) can adopt for dark kind and use earlier acid scouring agent, afterwards soap and add chelated dispersants, can effectively remove loose colour like this and improve the crock fastness of finished product with the basic soap lotion.
With reference to test index:
Waterproof: AATCC 193 moisture-resistant lubricant natures: the experiment of waterproof/ethanolic solution; The spray test of AATCC22--2005 waterproof.
Grease proofing: the AATCC118--2002 grease proofness: anti-hydrocarbon test.
Antifouling: the AATCC130--2000 dirt removal: oil stain is removed method.
Be prone to decontamination: the AATCC130--2000 dirt removal: oil stain is removed method.
Claims (8)
1. anti-processing method that is prone to the care garment lining is characterized in that may further comprise the steps:
1) slurry and unnecessary finish in the chemical & blended fabric spinning process are removed in pre-treatment;
2) dyeing, concrete grammar is: at 40 ℃ of following adding glacial acetic acid, add and disperse levelling agent; The back that stirs adds dyestuff, be warming up to 80 ℃ with the speed of 1.5 ℃/min after, the speed that changes with 2 ℃/min is warming up to 130～140 ℃; Insulation 30～45min, the speed with 2 ℃/min is cooled to 40 ℃ afterwards, washing; In the time of 40 ℃, add soda ash and sodium hydrosulfite, be warming up to 70 ℃ with the speed of 1.5 ℃/min and handle 20min, reduce to room temperature washing 2 times with the speed of 2 ℃/min at last;
Dye bath prescription: disperse levelling agent: 2～5g/L, glacial acetic acid: regulate pH to 5～7, sodium hydrosulfite: 2～5g/L, caustic soda: 1～5g/L;
3) washing adopts evenness calender one to soak a method of pressing at normal temperatures;
Prescription: detergent: 1～2g/L, acetic acid: 1～3g/L;
Decatize dyeing machine washing steam box: the washing of 1～5 lattice, temperature is 40～50 ℃; The washing of 6～7 lattice, normal temperature; 8 lattice add acetic acid: 2～3g/L, normal temperature; Cropping contains damp rate: 5%～8%;
4) back arrangement: adopt and pad the method that adds preshrunk, concrete steps are following: pad afterwards earlier and dry, bake back preshrunk again, promptly get the three anti-nursing chemical & blended fabric linings that are prone to.
2. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment lining; It is characterized in that in step 1); Said slurry and the method for unnecessary finish of removing in the chemical & blended fabric spinning process adopts jet overflow dyeing machine destarch refining process; Stir after adding auxiliary agent, under 80～90 ℃ of conditions, handle 20～30min after washing and get final product;
Process conditions: bath raio 1: 10;
Prescription: 30% caustic soda: 2～10g/L, sodium hydrosulfite: 1～2g/L, desizing agent: 1～5g/L, chelated dispersants: 1～4g/L, scouring agent: 1～5g/L.
3. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment linings is characterized in that in step 4), the consisting of of the said dressing liquid that pads:
Soil-releasing finishing agent 30～80g/L, three-proof finishing agent 30～70g/L, fiber protective agent 30～100g/L, bleeding agent 3g/L, synergist 0～30g/L, acetic acid 5～40g/L regulates pH to 6～7.
4. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment lining is characterized in that in step 4) said soil-releasing finishing agent adopts PM-90.
5. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment linings is characterized in that in step 4), and said three-proof finishing agent adopts a kind of among Oleophobol CP-R, Oleophobol CP-SLA, the PM-90.
6. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment lining is characterized in that in step 4) said fiber protective agent adopts Oleophobol CP-R.
7. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment lining is characterized in that in step 4) said bleeding agent adopts INVADINE PBN.
8. the as claimed in claim 1 a kind of three anti-processing methods that are prone to the care garment lining is characterized in that in step 4) said synergist adopts Phobol XAN.
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| CN103321046A (en) * | 2013-06-17 | 2013-09-25 | 常熟市建华织造有限责任公司 | Environment-friendly waterproof and oil-proof antifouling blanket and finishing method thereof |
| CN103741513A (en) * | 2013-12-12 | 2014-04-23 | 浙江安诺其助剂有限公司 | Additive for neutral desizing, oil removing and one-bath dyeing of chemical fiber fabrics and preparation method thereof |
| CN104195846A (en) * | 2014-09-03 | 2014-12-10 | 山东千榕家纺有限公司 | Durable waterproof oil-proof stain-repellent easily-stain-removing garment fabric and preparation method thereof |
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| CN105088816A (en) * | 2015-07-17 | 2015-11-25 | 安徽贵谷电子商务有限公司 | Durable waterproof oil-resistant antifouling easily-decontaminating garment material and preparation method thereof |
| CN105506989A (en) * | 2015-12-24 | 2016-04-20 | 北京中纺化工股份有限公司 | Three-proofing and soil-release textile fabric and preparation method thereof |
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| CN108642900A (en) * | 2018-06-01 | 2018-10-12 | 郑佳 | The preparation method and application of camouflage cover cloth |
| CN111118715A (en) * | 2019-12-31 | 2020-05-08 | 江苏东源纺织科技实业有限公司 | Production process of easy-to-clean moisture-absorbing sweat-releasing fabric |
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