CN104727147A - Water repellent and oil proof finishing agent and application thereof - Google Patents
Water repellent and oil proof finishing agent and application thereof Download PDFInfo
- Publication number
- CN104727147A CN104727147A CN201310705299.6A CN201310705299A CN104727147A CN 104727147 A CN104727147 A CN 104727147A CN 201310705299 A CN201310705299 A CN 201310705299A CN 104727147 A CN104727147 A CN 104727147A
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- Prior art keywords
- water
- oil agent
- fabric
- refuse
- water anti
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Abstract
The invention discloses a water repellent and oil proof finishing agent and application thereof. The water repellent and oil proof finishing agent is composed of the following components by weight: 5-15% of a perfluoropolymer emulsion, 1-5% of dipropylene glycol, 1-5% of glacial acetic acid, 1-5% of hydrogen chloride, 0.1-1% of formaldehyde, 2-5% of an enclosed type oxime isocyanate dispersion solution, 2-5% of a modified resin aqueous solution, and the balance water. The fabric finished by the water repellent and oil proof finishing agent provided by the invention is detected by the AATCC22, AATCC135 standards, and the results are as the following: before washing, the oil repellency is above grade 4, and the water repellency is above grade 4; and after washing and natural drying, the oil repellency is above grade 3, and the water repellency is above grade 3.
Description
Technical field
The present invention relates to a kind of material treatment agent.
Background technology
For certain special dimension, as fire-fighting domain, its protective clothing needs to have special requirement, needs to possess simultaneously and refuses the grease proofing function of water.
At present, conventional way is, add the functionalization that function additive realizes fabric in the feed, but this way causes the cost of fabric to improve, and processing technology is comparatively complicated, is difficult to apply.
Summary of the invention
The object of this invention is to provide one and refuse water anti oil agent and application thereof, to overcome the defect that prior art exists, meet the needs of people.
Of the present inventionly refuse water anti oil agent, be made up of the component of following percentage by weight:
(per) fluoropolymer emulsion 5 ~ 15%
Dipropyl enediol 1-5%
Glacial acetic acid 1-5%
Hydrogen chloride 1-5%
Formaldehyde 0.1-1%
Enclosed type oximes isocyanates dispersion liquid 2 ~ 5%
The modified resin aqueous solution 2 ~ 5%
Water surplus
Described (per) fluoropolymer emulsion is commercially available prod, if Huntsman Corporation's trade mark is the product of Ole.cp-sla, is a kind of fluorinated water and oil repellent agent of weak cation.
Described enclosed type oximes isocyanates dispersion liquid is commercially available prod, if Huntsman Corporation's trade mark is the product of PhobolXAN, is a kind of grease proofing effect promoting agent of cationic/nonionic.
The described modified resin aqueous solution is organic-silicon-modified water soluble acrylic resin, is commercially available prod, if Huntsman Corporation's trade mark is the product of PhobolRSH, is that a kind of fluorine containing organosilyl cationic/nonionic element arranges synergist.
Preferably, described refuses water anti oil agent, is made up of the component of following percentage by weight:
(per) fluoropolymer emulsion 7 ~ 10%
Dipropyl enediol 2 ~ 4%
Glacial acetic acid 2 ~ 4%
Hydrogen chloride 2 ~ 4%
Formaldehyde 0.1 ~ 0.5%
Enclosed type oximes isocyanates dispersion liquid 3 ~ 4%
The modified resin aqueous solution 3 ~ 4%
Water surplus
The preparation method refusing water anti oil agent of the present invention is foolproof, is the physical mixing processes of routine, each component is mixed;
Of the present inventionly refuse water anti oil agent, what can be used for fabric refuses water oil resistant finish, and using method is as follows:
Described is refused water anti oil agent, and add water rare 8 ~ 10 times of weight, then at normal temperatures, adopts pad method, refuses water oil resistant finish to needing the fabric arranged;
The weight ratio of refusing water anti oil agent and fabric after thin up is:
Water anti oil agent 100 kilograms is refused, fabric 750 kilograms after thin up;
Described fabric comprises aramid fiber, aramid fiber blending or acrylic viscose blended;
Adopt of the present invention refuse water anti oil agent arrange after fabric, AATCC22, the AATCC135 standard of employing detects, and result is as follows:
Refuse oil more than 4 grades before washing, refuse more than 4 grades, water;
Wash rear naturally dry refuse oil more than 3 grades, refuse more than 3 grades, water;
Detailed description of the invention
Embodiment 1
Formula:
(per) fluoropolymer emulsion 10%
Dipropyl enediol 2%
Glacial acetic acid 4%
Hydrogen chloride 2%
Formaldehyde 0.5%
Enclosed type oximes isocyanates dispersion liquid 3%
The modified resin aqueous solution 4%
Water surplus
Each component is mixed and can obtain product;
Above-mentioned product is refused water anti oil agent, thin up 8.3 times;
To refuse water anti oil agent 100 kilograms after rear thin up, fabric 625 kilograms adopts at normal temperatures, and adopt pad method, to aramid fiber, aramid fiber blending or the viscose blended fabric of acrylic carry out refusing water oil resistant finish;
Adopt AATCC22, AATCC135 standard to detect, result is as follows:
Refuse oil more than 5 grades before washing, refuse more than 5 grades, water;
Wash post-drying to refuse oil more than 4 grades, refuse more than 4 grades, water;
Embodiment 2
Formula:
(per) fluoropolymer emulsion 7%
Dipropyl enediol 4%
Glacial acetic acid 2%
Hydrogen chloride 4%
Formaldehyde 0.1%
Enclosed type oximes isocyanates dispersion liquid 4%
The modified resin aqueous solution 3%
Water surplus
Each component is mixed and can obtain product;
Above-mentioned product is refused water anti oil agent, thin up 6.7 times;
To refuse water anti oil agent 100 kilograms after rear thin up, fabric 500 kilograms adopts at normal temperatures, and adopt pad method, to aramid fiber, aramid fiber blending or the viscose blended fabric of acrylic carry out refusing water oil resistant finish;
Adopt GB/T19977-2005, GB/T4745-1997 standard to detect, result is as follows:
Refuse oil more than 5 grades before washing, refuse more than 5 grades, water;
Wash rear naturally dry refuse oil more than 3 grades, refuse more than 3 grades, water.
Claims (6)
1. refuse water anti oil agent, it is characterized in that, be made up of the component of following percentage by weight:
(per) fluoropolymer emulsion 5 ~ 15%
Dipropyl enediol 1-5%
Glacial acetic acid 1-5%
Hydrogen chloride 1-5%
Formaldehyde 0.1-1%
Enclosed type oximes isocyanates dispersion liquid 2 ~ 5%
The modified resin aqueous solution 2 ~ 5%
Water surplus.
2. according to claim 1ly refuse water anti oil agent, it is characterized in that, the described modified resin aqueous solution is organic-silicon-modified water soluble acrylic resin.
3. refuse water anti oil agent according to according to claim 2, it is characterized in that, described refuses water anti oil agent, is made up of the component of following percentage by weight:
(per) fluoropolymer emulsion 7 ~ 10%
Dipropyl enediol 2 ~ 4%
Glacial acetic acid 2 ~ 4%
Hydrogen chloride 2 ~ 4%
Formaldehyde 0.1 ~ 0.5%
Enclosed type oximes isocyanates dispersion liquid 3 ~ 4%
The modified resin aqueous solution 3 ~ 4%
Water surplus.
4. the application refusing water anti oil agent according to claim 1,2 or 3, is characterized in that, refuses water oil resistant finish for fabric.
5. application according to claim 4, is characterized in that, using method is as follows: described is refused water anti oil agent, and add water rare 8 ~ 10 times of weight, then at normal temperatures, adopts pad method, refuses water oil resistant finish to needing the fabric arranged; The weight ratio of refusing water anti oil agent and fabric after thin up is: refuse water anti oil agent 100 kilograms, fabric 750 kilograms after thin up.
6. the application according to claim 4 or 5, is characterized in that, it is viscose blended that described fabric comprises aramid fiber, aramid fiber blending or acrylic.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310705299.6A CN104727147A (en) | 2013-12-19 | 2013-12-19 | Water repellent and oil proof finishing agent and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310705299.6A CN104727147A (en) | 2013-12-19 | 2013-12-19 | Water repellent and oil proof finishing agent and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104727147A true CN104727147A (en) | 2015-06-24 |
Family
ID=53451513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310705299.6A Pending CN104727147A (en) | 2013-12-19 | 2013-12-19 | Water repellent and oil proof finishing agent and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104727147A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019065443A (en) * | 2017-10-02 | 2019-04-25 | ダイワボウホールディングス株式会社 | Water repellent recycled cellulose fiber, manufacturing method therefor and fiber structure containing the same |
| CN109957968A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | A kind of fire-entry suit finishing agent and its preparation method and application used under room temperature |
| CN111286982A (en) * | 2020-04-14 | 2020-06-16 | 北京邦维高科特种纺织品有限责任公司 | Water-repellent and oil-repellent finishing agent, preparation method and application thereof, and water-repellent and oil-repellent treatment method |
| CN115538165A (en) * | 2022-11-01 | 2022-12-30 | 陕西元丰纺织技术研究有限公司 | Antifouling and soil-release finishing process for aramid fabric |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129573A (en) * | 1998-10-23 | 2000-05-09 | Unitika Ltd | Waterproof cellulosic fiber cloth and its production |
| JP2009102463A (en) * | 2007-10-22 | 2009-05-14 | Yunimatekku Kk | Water-repellent and oil-repellent agent |
| CN102767097A (en) * | 2012-08-01 | 2012-11-07 | 劲霸男装（上海）有限公司 | Processing method of three-proofing easy-care clothing fabric |
| CN102965817A (en) * | 2012-11-26 | 2013-03-13 | 江苏申利实业股份有限公司 | Waterproof monomer-resisting fabric and production method thereof |
-
2013
- 2013-12-19 CN CN201310705299.6A patent/CN104727147A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000129573A (en) * | 1998-10-23 | 2000-05-09 | Unitika Ltd | Waterproof cellulosic fiber cloth and its production |
| JP2009102463A (en) * | 2007-10-22 | 2009-05-14 | Yunimatekku Kk | Water-repellent and oil-repellent agent |
| CN102767097A (en) * | 2012-08-01 | 2012-11-07 | 劲霸男装（上海）有限公司 | Processing method of three-proofing easy-care clothing fabric |
| CN102965817A (en) * | 2012-11-26 | 2013-03-13 | 江苏申利实业股份有限公司 | Waterproof monomer-resisting fabric and production method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019065443A (en) * | 2017-10-02 | 2019-04-25 | ダイワボウホールディングス株式会社 | Water repellent recycled cellulose fiber, manufacturing method therefor and fiber structure containing the same |
| JP7064083B2 (en) | 2017-10-02 | 2022-05-10 | ダイワボウレーヨン株式会社 | Water-repellent regenerated cellulose fiber, its manufacturing method and fiber structure containing it |
| CN109957968A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | A kind of fire-entry suit finishing agent and its preparation method and application used under room temperature |
| CN111286982A (en) * | 2020-04-14 | 2020-06-16 | 北京邦维高科特种纺织品有限责任公司 | Water-repellent and oil-repellent finishing agent, preparation method and application thereof, and water-repellent and oil-repellent treatment method |
| CN115538165A (en) * | 2022-11-01 | 2022-12-30 | 陕西元丰纺织技术研究有限公司 | Antifouling and soil-release finishing process for aramid fabric |
| CN115538165B (en) * | 2022-11-01 | 2023-09-08 | 陕西元丰纺织技术研究有限公司 | Antifouling and soil-release finishing process for aramid fabrics |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150624 |
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| WD01 | Invention patent application deemed withdrawn after publication |