CN102766399A - Gel polish, LED gel polish and LED nail polish - Google Patents
Gel polish, LED gel polish and LED nail polish Download PDFInfo
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- CN102766399A CN102766399A CN2012102704096A CN201210270409A CN102766399A CN 102766399 A CN102766399 A CN 102766399A CN 2012102704096 A CN2012102704096 A CN 2012102704096A CN 201210270409 A CN201210270409 A CN 201210270409A CN 102766399 A CN102766399 A CN 102766399A
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Abstract
The invention discloses gel polish. The gel polish is characterized by comprising, by weight, 1-10 parts of photoinitiator, 10-50 parts of acrylic monomer, 20-80 parts of acrylic polymer, and 0.1-5 parts of auxiliary. The gel polish has the advantages that nail polishing time is shortened to one sixth of that using existing products, and nail polishing efficiency is improved evidently; the nail polishing time is shortened, and accordingly UV (ultraviolet) radiation to consumers during nail beauty is reduced greatly, and damage to skin is further reduced; no heat emits in nail polishing, and accordingly the consumers feel more comfortable during nail beauty; and the gel polish is more widely applicable, and LED gel polish can be solidified to both UV lights and LED lights.
Description
Technical field
The present invention relates to a kind of light efficiency gel, LED light efficiency gel and LED light efficiency nail varnish.
Background technology
Mostly light efficiency gel on the market is UV light efficiency gel, and its supporting cure lamp source is that main crest is the high voltage mercury lamp of 365nm, i.e. UV (Ultraviolet) phototherapy lamp.The nail varnish that uses UV light efficiency gel to process, it need use the irradiation of UV phototherapy lamp to solidify when using.The nail varnish that UV light efficiency gel is processed, the weak point in its use has: 1, the running time long, the light efficiency gel is carried out single solidifies and to take 3 minutes; 2, UV (Ultraviolet) phototherapy lamp is luminous follows tangible infrared heat release, and the thermal discharge of the accumulation that works long hours continues to increase, so obvious hotness is arranged when carrying out manicure; 3, the mercury lamp tube lifetime is short, needs often to change.
LED lamp source is to be illuminating source with the photodiode, and along with the continuous development of LED lamp technology, its Application Areas is also more and more wideer.The led light source advantage is: 1, led light source is a pointolite, is more evenly distributed; 2, led light source is a cold light source, does not luminously follow heating; 3, the led light source light intensity is more concentrated, and curing efficiency is higher.
There are many advantages in relative UV lamp source, LED lamp source, but the phototherapy glue of market can only use the UV lamp to solidify, and under the effect of LED lamp source, can't be cured reaction.
Summary of the invention
The objective of the invention is in order to overcome deficiency of the prior art, provide a kind of UV lamp that both can use to solidify, can use LED lamp solidified light efficiency gel again.
For realizing above purpose, the present invention realizes through following technical scheme:
The light efficiency gel is characterized in that, comprises following component according to parts by weight:
Preferably, also comprise mill base 2-20 weight part.
Mill base is used to the light efficiency gel and mixes colours.The available mill base comprises oil pastes and water and oil applicable mill base.Its color can be confirmed according to request for utilization, include but not limited to: redness, blueness, purple, gold, silver color etc.
The available oil pastes includes but not limited to, red iron oxide, and red No. three, red No. 4, No. 57 are red, and No. 53 are red etc.; Yellow No. 11, yellow No. 5, yellow No. 6, yellow No. 7, titanium white, titanium oxide; Manganese violet, naphthols is black, iron oxide black, carbon black, ultramarine blue; Blue No. 2, blue No. 27, green No. 3, green No. 4, chromoxide green.
Preferably, also comprise pearling agent 0.1-3 weight part.
The available pearling agent includes but not limited to: diglycol stearate, covering nacreous mica pigment.Cover nacreous mica pigment another name woddnite pearly pigment, it is to be substrate with the flaky mica powder, and the surface covers the composite pigment of one deck mica or other materials formation with chemical process.The woddnite pearly pigment can be allocated as kind of color surplus gold, silver color, the purple etc. ten according to request for utilization.Adopt the pearling agent of color can also replace mill base.Above pearling agent both can have been selected a kind of, also can select several kinds to mix use.
Preferably, said auxiliary agent comprises anti-settling agent 0.05-2 weight part.
The available anti-settling agent includes but not limited to: organobentonite (this BENTONE SD-1 of hamming, BENTONE 52, BENTONE 34); Aerosil (Cabot M5, Degussa R972); Polyolefin-wax (BYK CERAMAT250,258,131); Modified hydrogenated Viscotrol C (CRAYVALLAC SF, CRAYVALLAC MT, Cray Valley CVP); Polyamide wax (Taiwan moral modest 229, this chemical 6900-20 of Japanese nanmu, Japanese this chemistry of nanmu 4300) series; The modified urea N-Methyl pyrrolidone (BYK-411, BYK-420); The modified high-molecular polymkeric substance (Britain Ao Weisi Solthix250, French brother Supreme Being scholar THIXOL100, BYK-428) etc.Above anti-settling agent both can have been selected a kind of, also can select several kinds to mix use.
Preferably, said auxiliary agent comprises flow agent 0.05-2 weight part.
The available flow agent includes but not limited to: polyether siloxane copolymer, (Tego Glide482, Glide410, the Poly flowNo7 of common prosperity society, No75, BYM354); Cross-linking organosilicon propenoate (Tego Red2500,2600,2700), organically-modified siloxanes (Efka-3239; HX-3080, HX-5600, YCK-1180;), fluorine-carbon modified XPA (Irgaflow110, Efka3777; Efka3600), (BYK-UV 3510, BYK306) for organic silicon modified by polyether.Above flow agent both can have been selected a kind of, also can select several kinds to mix use.
Preferably, said auxiliary agent comprises wetting agent 0.05-2 weight part.The available wetting agent includes but not limited to: (Silok 8030,8000, BYK348, BYK246 for organic silicon modified by polyether oxygen alkane; BYK337, Tego Wet260, Wet270, Wet500) polyether-modified YSR 3286 interpolymer (BYK333); Fluorine-carbon modified polymkeric substance (Efka3777, Efka3600, FC430; BYK-340, BYK388, CYTEC ADDITOLVXM6396).Above wetting agent both can have been selected a kind of, also can select several kinds to mix use.
Preferably, also comprise essence 0.02-0.5 weight part.
Available essence includes but not limited to: daily use chemicals compound compound essence, fruit flavouring or floral type.
Preferably, the available light trigger includes but not limited to: autothermic cracking type initiator and photosensitizers.
Available cracking type initiator includes but not limited to: described light trigger is selected from one or more among light trigger 1173, light trigger 184, light trigger 907, MBF, light trigger 651, light trigger 369, TPO-L, TPO, light trigger 819 and the BP.
Light trigger 1173, i.e. 2-hydroxy-2-methyl-1-phenyl-acetone; Light trigger 184, i.e. 1-hydroxy-cyclohexyl phenyl ketone; Light trigger 907, i.e. 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone; MBF, i.e. methyl benzoylformate; Light trigger 651, i.e. benzoin dimethylether, chemical name 2,2-dimethoxy-1,2-phenylbenzyl ketone; Light trigger 369, i.e. 2-phenyl benzyl-2-dimethyl amine-1-(4-morpholine benzyl phenyl) butanone; TPO-L, promptly 2,4,6-trimethylbenzoyl phenyl-phosphonic acid ethyl ester; TPO, promptly 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide; Light trigger 819, i.e. two (2,4, the 6-trimethylbenzoyl) phosphine oxides of phenyl.
The available photoinitiator comprises but is not limited to: BP, i.e. BP UVNUL MS-40.
Above light trigger both can have been selected a kind of, also can select several kinds to mix use.
Preferably; The available acrylate monomer; Include but not limited to: lauryl acrylate, Isooctyl acrylate monomer, Bing Xisuandingzhi, ethyl acrylate, methylacrylic acid-2-hydroxy methacrylate (HEMA), methylacrylic acid-2-hydroxy propyl ester, TEB 3K, NSC 20956, Propenoic acid, 2-methyl, isobutyl ester, IBOA, isobornyl methacrylate, 1,3 butyleneglycol diacrylate, neopentylglycol diacrylate, (2) third oxidation neopentylglycol diacrylates, polyethylene glycol dimethacrylate, oxidation Tri Ethyleneglycol dimethacrylate, tri (propylene glycol) diacrylate, Viscoat 295, pentaerythritol triacrylate and (3) propoxylation Viscoat 295.Above Acrylic Acid Monomer both can have been selected a kind of, also can select several kinds to mix use.
Preferably, said XPA is one or more in the urethane acrylate polymkeric substance of aliphatic urethane acrylate polymkeric substance or urethane acrylate polymkeric substance or acroleic acid esterification.
Available urethane acrylate polymkeric substance includes but not limited to, Sartomer CN9893, CN929, CN965, CN971A80, CN963E80, CN9007; The special EB230 of cyanogen, EB8200, EB264, EB4858, EB9626, EB8402, EB284; Changxing 611B85,6113, DR-U300,6115J-80,6148T-85; The peaceful PHOTOMER 6008 of section, PHOTOMER 6019, and PHOTOMER 6010, and PHOTOMER 6892; DSM NeoRad U-6282, NeoRad U-20-12H, AgiSyn 230 S1-B85, A giSyn230 T1, AgiSyn230 TH, AgiSyn235; Japan is synthetic, UV-3000B, UV-2750B, UV-2000B, UV-3200B.Above urethane acrylate polymkeric substance can be selected for use one or more to mix and use.
Above light efficiency gel both can use the LED lamp to solidify, and also can use the UV lamp to solidify.
Two of the object of the invention provides a kind of LED light efficiency gel.
LED light efficiency gel is characterized in that, comprises aforesaid light efficiency gel.
Three of the object of the invention provides a kind of LED light efficiency nail varnish.
LED light efficiency nail varnish is characterized in that, comprises aforesaid light efficiency gel.
The present invention is the LED phototherapy glue of the supporting exploitation in LED lamp source, and this glue product can be accomplished film-forming in the 10s-30s scope under the effect of LED lamp source, does not have heating in the film process, and film forming is tough, and state of cure is good, and can make the product of shades of colour effect.
Product among the present invention also has following beneficial effect:
1, the manicure running time foreshortens to 1/6 of currently available products required time, obviously improves the manicure working efficiency.
2,, the nocuity of skin is further reduced because the running time shortens, and the UV radiation that the human consumer receives in the manicure process significantly reduces.
3, do not have heat release in the operating process, make the human consumer more comfortable in the manicure process.
4, flexibility is wider, LED light efficiency gel in UV lamp source, LED lamp source all can realize solidifying.
Embodiment
Below in conjunction with embodiment the present invention is carried out detailed description.
Umber in following examples is weight part.
Embodiment 1
Get 1 part of light trigger 369 and join in 15 parts of lauryl acrylates and the 5 parts of Tri Ethyleneglycol dimethacrylates, high speed dispersion is dissolved it fully; Drop into 78 parts of aliphatic urethane acrylate polymkeric substance CN965 again, be uniformly dispersed; Drop into 3239,0.2 part of wetting agent BYK348 of 0.3 part of flow agent EFKA and 0.5 part of this BENTONE SD-1 of anti-settling agent hamming more successively, fully disperse; Promptly got the LED primer light efficiency gel of bonding nature first and light efficiency gel first.
Embodiment 2
Get 1 part of 1-hydroxy-cyclohexyl phenyl ketone and 2 part 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide joins in 20 parts of Isooctyl acrylate monomers and the 20 parts of neopentylglycol diacrylates, and high speed dispersion is dissolved it fully; Drop into 55 parts of urethane acrylate polymer P HOTOMER 6010 again, be uniformly dispersed; Drop into 410,0.2 parts of wetting agent Silok8000 of 0.3 part of flow agent TEGO GLIDE and 1.5 parts of anti-settling agent Cabot M5 more successively, fully disperse; Promptly got the LED primer light efficiency gel of bonding nature first and light efficiency gel first.
Embodiment 3
Get 2 parts of BP UVNUL MS-40 and 2 parts of light triggers 907 join in 20 parts of ethyl acrylates, high speed dispersion is dissolved it fully; Drop into 66 parts of aliphatic urethane acrylate polymkeric substance EB4858 again, be uniformly dispersed; Drop into 0.2 part of flow agent POLY FLOW NO7,0.2 part of wetting agent BYK246 and 0.3 part of this BENGEL 828 of anti-settling agent hamming more successively, fully disperse; Drop into 9.3 parts of red mill bases at last, promptly get red LED light efficiency gel.
Embodiment 4
Get 3 parts of MBF and 4 parts of TPO-L join in 25 parts of ethyl acrylates, high speed dispersion is dissolved it fully; Drop into 49 parts of urethane acrylate polymkeric substance EB9626 again, be uniformly dispersed; Drop into 3777,0.1 parts of wetting agent SlLOK 8030 of 0.2 part of flow agent EFKA and 0.4 part of anti-settling agent THIXOL 100 more successively, fully disperse; Drop into 15 parts of titanium white mill bases at last, No. 3 mill bases of 3.3 parts of redness promptly get the color glue light efficiency of the LED gel of pink effect.
Embodiment 5
Get 2 parts of light triggers 907 and 0.5 part of light trigger 819 joins in 20 parts of IBOAs, high speed dispersion is dissolved it fully; Drop into the special EB8200 of urethane acrylate polymkeric substance cyanogen of 70 parts of acroleic acid esterifications again, be uniformly dispersed; Drop into 0.1 part of flow agent BYK354,0.1 part of wetting agent and 2.3 parts of anti-settling agent R972 more successively, fully disperse; Drop into 4 parts of No. 53 red slurries, No. 27 mill bases of 1 part of blueness at last, promptly get the color glue light efficiency of the LED gel of piece redness.
Embodiment 6
Get 2 parts of light triggers 184 and 2 parts of light triggers 369 and join in 15 parts of Viscoat 295s and the 30 parts of oxidation Tri Ethyleneglycol dimethacrylates, high speed dispersion is dissolved it fully; Drop into 31 parts of aliphatic urethane acrylate polymkeric substance DSM NeoRad U-6282 again, be uniformly dispersed; Drop into 2500,0.1 parts of wetting agent BYK340 of 0.3 part of flow agent TEGO RED more successively, 3 parts of anti-settling agent BYK CERAMAT250 fully disperse; Drop into 15 parts of ultramarine blue mill bases and 1.6 parts of golden pearlescences at last, promptly get the LED light efficiency gel of blue ribbon pearl effect.
Embodiment 7
Get 2 parts of light triggers 651 and 4 parts of TPO join in 23 parts of polyethylene glycol dimethacrylates, high speed dispersion is dissolved it fully; Drop into 60 parts of aliphatic urethane acrylate polymkeric substance Changxing 6115J-80 again, be uniformly dispersed; Drop into 0.1 part of flow agent BYK354 more successively, 0.1 part of wetting agent Irgaflow110 and 2.5 parts of anti-settling agent Cabot M5 conduct fully disperse; Drop into 5 parts of stock whites, 3 parts of manganese violet mill bases and 0.3 part of blue pearlescence at last, promptly get the LED light efficiency gel of lilac band pearl effect.
Embodiment 8
Get 2 parts of light triggers 1173 and 3 parts of TPO-L join in 10 parts of 1,3 butyleneglycol diacrylates, high speed dispersion is dissolved it fully; Drop into 20 parts of aliphatic urethane acrylate polymkeric substance CN9893 and 56 parts of aliphatic urethane acrylate polymkeric substance Changxing 6113 again, be uniformly dispersed; Drop into 0.3 part of flow agent BYK306 more successively, 0.1 part of wetting agent BYK-340 and 0.3 part of anti-settling agent Solthix250 fully disperse; Drop into 5 parts of titanium white mill bases, 3 parts of No. 57 red slurries and 0.3 white part pearlescence at last, promptly get the LED light efficiency gel of pink colour band pearl effect.
Embodiment 9
Get 4.3 part 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide joins in 23 parts of Propenoic acid, 2-methyl, isobutyl esters, and high speed dispersion is dissolved it fully; Drop into 72 parts of aliphatic urethane acrylate polymer A giSyn 230 S1-B85 again, be uniformly dispersed; Drop into 0.3 part of flow agent YCK-1180 more successively, 0.1 part of wetting agent BYK348,0.3 part of anti-settling agent BYK411 fully disperses, and promptly gets the LED seal light efficiency gel that shields and high gloss effect is provided.
Embodiment 10
Get 184,3.3 parts of light triggers 651 of 3 parts of light triggers and 4 parts of light trigger TPO-L and join in 30 parts of Tri Ethyleneglycol dimethacrylates and the 20 parts of methylacrylic acid-2-hydroxy propyl esters, high speed dispersion is dissolved it fully; Drop into 39 parts of aliphatic urethane acrylate polymkeric substance Changxing 6113 again, be uniformly dispersed; Drop into 0.3 part of flow agent HX5600 more successively, 0.1 part of wetting agent BYK348,0.3 part of this chemistry of anti-settling agent nanmu 4300 fully disperses; Promptly get the LED seal light efficiency gel that shields and high gloss effect is provided.
Embodiment 11
Get 4 parts of light triggers 1173 and 3 parts of light triggers 907 join in 25 parts of 1,3 butyleneglycol diacrylates, high speed dispersion is dissolved it fully; Drop into 24 parts of polyurethane acrylic resin PHOTOMER 6892 and 32 parts of polyurethane acrylic resin AgiSyn230 TH again, be uniformly dispersed; Drop into 1.5 parts of flow agent BYK306 more successively, 1 part of wetting agent BYK-340 and 0.8 part of anti-settling agent Solthix250 fully disperse; Drop into 5.4 parts of titanium white mill bases, 3 parts of No. 57 red slurries and 0.3 white part pearlescence at last, promptly get the LED light efficiency gel of pink colour band pearl effect.
Embodiment 12
Get 907,1 parts of light trigger TPO of 1 part of light trigger, 0.5 part of light trigger 184 joins in 15 parts of polyethylene glycol dimethacrylates, and high speed dispersion is dissolved it fully; Drop into 71 parts of aliphatic urethane acrylate polymkeric substance EB230 again, be uniformly dispersed; Drop into 3510,1.6 parts of wetting agent BYK-246 of 1.8 parts of flow agent BYK-UV and 1.9 parts of anti-settling agent BYK-428 more successively, fully disperse; Drop into 1.7 yellow No. 7 mill bases, 4.5 parts of titanium white mill bases at last, promptly get the LED light efficiency gel of yellow effect.
Embodiment 13
Get 1 part of light trigger 819 and 2.25 parts of light triggers 369 join in 15 parts of methylacrylic acids-2-hydroxy propyl ester, high speed dispersion is dissolved it fully; Drop into 78.5 parts of synthetic UV-2750B of urethane acrylate polymkeric substance Japan again, be uniformly dispersed; 0.15 part of wetting agent EFKA3777 and 0.1 part of anti-settling agent Japan this chemical 6900-20 of nanmu successively fully disperse again; Drop into 3 parts of carbon black looks at last, promptly get the LED light efficiency gel of black effect.
Embodiment 14
Get 3.5 parts of light triggers 369 and join in 38 parts of 1,3 butyleneglycol diacrylates, high speed dispersion is dissolved it fully; Drop into 52.5 parts of urethane acrylate polymkeric substance Sartomer CN9007 again, be uniformly dispersed; It is modest 229 to drop into 0.3 part of Poly flow No7 of flow agent common prosperity society and 0.7 part of anti-settling agent Taiwan moral more successively, fully disperses; Drop into No. three mill bases of 5 parts of greens at last, promptly get the LED light efficiency gel of green effect.
Embodiment 1-14, finished product use the UV lamp to be 2-4min set time, use the LED lamp to be 20-40S set time; No matter which kind of curing mode uses the working order of this product according to primer, color glue, seal glue, and guarantees set time, in hold-time of normal first face all more than 1 month, and keep persistent color and glittering gloss.
LED light efficiency gel of the present invention, simple operation is prone to brushing, strong coloring force, can form the coating of shades of colour and effect, and after the curing, luminance brightness is high, and the hold-time is of a specified duration, and is incrust damaged.When removing, add cleaning cotton coating 10 minutes, removal easily with unloading first liquid like need.
Embodiment among the present invention only is used for that the present invention will be described, does not constitute the restriction to the claim scope, and other substituting of being equal in fact that those skilled in that art can expect are all in protection domain of the present invention.
Claims (12)
1. the light efficiency gel is characterized in that, comprises following component according to parts by weight:
2. light efficiency gel according to claim 1 is characterized in that, also comprises mill base 2-20 weight part.
3. light efficiency gel according to claim 1 is characterized in that, also comprises pearling agent 0.1-5 weight part.
4. light efficiency gel according to claim 1 is characterized in that, said auxiliary agent comprises anti-settling agent 0.05-3 weight part.
5. light efficiency gel according to claim 1 is characterized in that, said auxiliary agent comprises flow agent 0.05-2 weight part.
6. light efficiency gel according to claim 1 is characterized in that, said auxiliary agent comprises wetting agent 0.05-2 weight part.
7. light efficiency gel according to claim 1 is characterized in that, also comprises essence 0.02-0.5 weight part.
8. light efficiency gel according to claim 1; It is characterized in that described light trigger is selected from one or more among light trigger 1173, light trigger 184, light trigger 907, MBF, light trigger 651, light trigger 369, TPO-L, TPO, light trigger 819 and the BP.
9. light efficiency gel according to claim 1; It is characterized in that; Said Acrylic Acid Monomer be selected from lauryl acrylate, Isooctyl acrylate monomer, Bing Xisuandingzhi, ethyl acrylate, methylacrylic acid-2-hydroxy methacrylate (HEMA), methylacrylic acid-2-hydroxy propyl ester, TEB 3K, NSC 20956, Propenoic acid, 2-methyl, isobutyl ester, IBOA, isobornyl methacrylate, 1,3 butyleneglycol diacrylate, neopentylglycol diacrylate, (2) third oxidation neopentylglycol diacrylates, polyethylene glycol dimethacrylate, oxidation Tri Ethyleneglycol dimethacrylate, tri (propylene glycol) diacrylate, Viscoat 295, pentaerythritol triacrylate and (3) propoxylation Viscoat 295 one or more.
10. light efficiency gel according to claim 1 is characterized in that, said XPA is one or more in aliphatic urethane acrylate polymkeric substance and the aliphatic polyurethane methacrylate polymers.
11.LED the light efficiency gel is characterized in that, comprises the described light efficiency gel of the arbitrary claim of claim 1-10.
12.LED the light efficiency nail varnish is characterized in that, comprises the described light efficiency gel of the arbitrary claim of claim 1-10.
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| CN2012102704096A CN102766399A (en) | 2012-07-31 | 2012-07-31 | Gel polish, LED gel polish and LED nail polish |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012102704096A CN102766399A (en) | 2012-07-31 | 2012-07-31 | Gel polish, LED gel polish and LED nail polish |
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| CN102766399A true CN102766399A (en) | 2012-11-07 |
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| CN2012102704096A Pending CN102766399A (en) | 2012-07-31 | 2012-07-31 | Gel polish, LED gel polish and LED nail polish |
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