CN107536728A - A kind of persistently environmentally friendly ground beetle factice and preparation method thereof - Google Patents
A kind of persistently environmentally friendly ground beetle factice and preparation method thereof Download PDFInfo
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- CN107536728A CN107536728A CN201710771403.XA CN201710771403A CN107536728A CN 107536728 A CN107536728 A CN 107536728A CN 201710771403 A CN201710771403 A CN 201710771403A CN 107536728 A CN107536728 A CN 107536728A
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Abstract
An a kind of persistently environmentally friendly ground beetle factice, is made up of the following component counted in parts by weight：60 70 parts of oligomer；20 30 parts of esters of acrylic acid activated monomer；15 parts of light trigger；15 parts of auxiliary agent, it is one or two kinds of or two or more combination in polyethylene glycol/propane diols, dimethylacrylate, ethoxylated/propoxylated polyethylene glycol/propane diols of molecular weight 1000, diacrylate, the phenoxy-propyl of 2 acrylic acid, 2 hydroxyl 3 and the hydroxyl butyl methyl acrylate of molecular weight 400 that the oligomer, which is aliphatic polyurethane modified diacrylate, the pure acrylic acid ester oligomer of 2 degrees of functionality, aliphatic polyurethane is modified nine acrylate or organic silicon modified polyurethane diacrylate, esters of acrylic acid activated monomer.Raw materials of the present invention are not low to the macromolecular compound or aqueous compounds of human body fanout free region, corrosivity.
Description
Technical field
The invention belongs to chemical industry then product cosmetic technical field, more particularly to a kind of solidification of ultraviolet light is solvent-free holds
One ground beetle factice of environmental protection long, more particularly, to an a kind of persistently environmentally friendly ground beetle factice and its making of color layers applied on finger
Method.
Background technology
Manicure it is with a long history, just make nail shinny with the fur friction of chamois early in ancient Egyptian, and be coated with mignonettetree
Juice makes it that charming bright red be presented, and in China's period Tang Dynasty, the prevailing custom for contaminating first has just occurred.Material used is balsamine,
Way is that the flower for the balsamine for taking corrosivity stronger and leaf are placed in small alms bowl and smashed to pieces, adds a small amount of alum, can be to refer to for contaminating
First.Silk flosssilk wadding can also be pinched into the thin slice as nail, be put into colored juice, taken out after sucking moisture, be placed on nail surface, passed through
Cross and continuously contaminate three to five times, the several months is all without colour fading.At all times, as people are constantly lifted to nail U.S. awareness,
Skill and technique and mode are in the renewal of not section, also more health, the environmental protection of present manicure material in continuous pursue！Meet different
The beautiful demand of crowd.From after the flower juice of most original flower liquid manicure, the two generation nail-care products that occur in succession, used with Gu drawing of painting
Coloured silk oil on nail, it is such to paint the multi-purpose minal matter pigment of oil, be typically made up of the great soil group of different colours, it is pure with extracting later
Inorganic pigment, to three generations's nail-care products be exactly the oil product by manually extracting after coloring earth, organic pigment.
Then UV glue is adjoint and give birth to, and UV glue is also known as light-sensitive emulsion, ultraviolet cured adhesive, and shadowless glue is that one kind must be by ultraviolet
The curable a kind of adhesive of linear light irradiation, it can be used as bonding agent, also can be as paint, coating, ink etc.
Sizing material uses.UV is English Ultraviolet Rays abbreviation, i.e. ultraviolet light.Ultraviolet (UV) be it is invisible,
It is one section of electromagnetic radiation beyond visible ray, scope of the wavelength in 110 ~ 400nm.The shadowless glue principle of solidification is UV curing materials
In light trigger（Or sensitising agent）Living radical or cation are produced after ultraviolet light is absorbed under ultraviolet irradiation, is triggered
Monomer polymerization, cross-linking chemistry reaction, make adhesive be converted into solid-state by liquid within the several seconds.So raw applied was referring to later
In first, then there have been manicure glue, nail polish glue etc..
It is the epoch that today's society economy is advanced by leaps and bounds, rich on material, pursue the spiritual fashion outside material enjoy into
It is the theme, therefore miscellaneous beauty fashion turns into leading battle array.Also it is unwilling to be outshone as the manicure of the spotlight of fashion one,
The style of thousand strange different expressions, magnificent mansion are played out on slight nail.Hand is second face of people, because bright a, life on nail
Taste and mastery also have natural beauty just to demonstrate heartily, because nail one is bright, many Mies are many spiritual in therefore acquirement
Encourage and self-confident, sense of loving to make up and wearing beautiful clothes is carefree and leisurely and gives birth to, and the contemporary heavy operating pressure of release, manicure is not only a special kind of skill, more
An or exquisite art..
Three relatively broad ground beetle factices are used at present：Also known as light efficiency freezing plastic, its main component are that one kind passes through purple
Outside line triggers the acrylic resin oligomer of solidification, a kind of gel for beautifying and decorating nail.
Manicure phototherapy glue is broadly divided into：Primer（Base Gel）, nail polish glue（Polish Gel）, color factice（Color
Gel）, clean sealing glue（WipeTop Coat）, exempt to clean sealing glue（No Wipe Top Coat）, three-in-one nail polish（3 in
1）, extend glue（Builder Gel）.
Operating procedure：
1. carving mill nail surface with sponge emery stick, and clean clean；
2. quarter grinds, nail of polishing, cleaning first face etc.；
Detachable primer or thin layer are detachable transparent on 3., illuminator 1 minute；Detachable primer needs to clean.（This is can skip as do not taken
One step）（This step is to be used for stiffened nail than relatively thin customer for nail, and detachable primer function is more to check product
Details page）
4. nail polish glue color (suggesting first shaking shaking flask before coating colour, to prevent there is precipitation), pays special attention to nail matrix leading edge one on
Surely bound edge, illuminator 1 ~ 2 minute, then last layer color glue, illuminator 1 ~ 2 minute are wanted；（It is recommended that according to enough 2 minutes）
5. detachable sealing needs bound edge first time on, and taken amount is more, normal to apply, and illuminator 30 seconds, second of very thin last layer, shines
Lamp 3 ~ 5 minutes；（It is recommended that 4 minutes）.Or last sealing is good, direct illuminator 4 minutes.
6. use phototherapy water（Wash hair gel）Clean surface, complete whole operation.
This three ground beetles factice, whole operation process is relatively complicated, and process is more.
The nail polish glue of environmental protection needs to carve mill nail in addition, and nail can more and more thinner.Successional smearing nail polish, can hinder
" eupnea " of nail, the horn cell of nail is destroyed, because the chronic corrosion of anoxic caused by unsmooth breath and nail polish,
Nail thins down naturally, is easily broken off and slow-growing.And need to unload first after reaching certain time, unload first water meeting
Injure skin and nail.A set of nail is done in other manicure shop needs 2-3 hours, and time cost is higher.
The content of the invention
The technical problem to be solved in the present invention is to provide one kind to have adhesive force good, and smell is low, colouring it is full, effect persistently and
Frangible lasting environmentally friendly ground beetle factice removed and preparation method thereof.
In order to solve the above-mentioned technical problem, the present invention takes following technical scheme：
An a kind of persistently environmentally friendly ground beetle factice, is made up of the following component counted in parts by weight：Oligomer 60-70 parts, acrylic acid
Esters activated monomer 20-30 parts, light trigger 1-5 parts and auxiliary agent 1-5 parts, the oligomer are that aliphatic polyurethane is modified dipropyl
Olefin(e) acid ester, the pure acrylic acid ester oligomer of 2 degrees of functionality, aliphatic polyurethane are modified nine acrylate or organic silicon modified polyurethane
Diacrylate.
The esters of acrylic acid activated monomer be polyethylene glycol/propane diols of molecular weight 400, dimethylacrylate, point
Ethoxylated/propoxylated polyethylene glycol/propane diols, diacrylate, the 2- acrylic acid -2- hydroxyl -3- phenoxy groups third of son amount 1000
One or two kinds of or two or more combination in ester and hydroxyl butyl methyl acrylate.
The light trigger be acyl group phosphorous oxide, styrax or one or both of benzoin ether and benzophenone or
Three kinds.
The auxiliary agent is one or both of anti-settling agent, defoamer and levelling agent or three kinds.
A kind of preparation method of a persistently environmentally friendly ground beetle factice, comprises the following steps：
Oligomer, esters of acrylic acid activated monomer, light trigger and auxiliary agent are well mixed according to setting proportion relation, are heated to
40-50 DEG C, stirring 65--80min is well mixed under 1200-2000r/min；
Then the strainer filtering of 300 mesh is used, packaging, obtains finished product.
Methods described specifically chooses 10 parts of hydroxyl butyl methyl acrylate, 10 parts of 2- acrylic acid -2- hydroxyl -3- benzene oxygen
Base propyl ester, 5 parts of polyethylene glycol/propane diols or dimethylacrylate, 5 parts of ethoxylated/propoxylated polyethylene glycol/propane diols or two
Acrylate, 3 parts of acyl group phosphorous oxides and 1 part of styrax are well mixed, and are heated to 40-50 DEG C, are stirred under 1200-2000r/min
Mix 40-45min；
Then 34 parts of aliphatic polyurethane modified diacrylates, 20 pure acrylic acid ester oligomers, 5 parts of aliphatic polyurethanes are modified
Nine acrylate, 5 parts of organic silicon modified polyurethane diacrylates and 1 portion of anti-settling agent, stir 20-30min；It is eventually adding 0.2
Part defoamer and 0.8 part of levelling agent, 10-15min is stirred, is filtrated to get finished product.
The lasting environmentally friendly ground beetle factice that the present invention makes has that smell is low, and environmental protection, heavy metal, toluene, formaldehyde, methanol contain
Measure relatively low, good attachment and brightness retention time are grown, and up to more than 30 days, can not fall side, not edging on hand, good brightness, surface without
Pin hole, full color, paint, easy removal（Removal time 3-5min）The features such as.
Embodiment
For the ease of the understanding of those skilled in the art, below the invention will be further described.
Present invention is disclosed an a kind of persistently environmentally friendly ground beetle factice, it is made up of the following component counted in parts by weight：It is oligomeric
Thing 60-70 parts；Esters of acrylic acid activated monomer 20-30 parts；Light trigger 1-5 parts；Auxiliary agent 1-5 parts, the oligomer are fat
Adoption urethane modified diacrylate, the pure acrylic acid ester oligomer of 2 degrees of functionality, aliphatic polyurethane be modified nine acrylate or
Organic silicon modified polyurethane diacrylate.The esters of acrylic acid activated monomer is polyethylene glycol/the third two of molecular weight 400
Alcohol, dimethylacrylate, ethoxylated/propoxylated polyethylene glycol/propane diols, diacrylate, the 2- propylene of molecular weight 1000
One or two kinds of or two or more combination in acid -2- hydroxyl -3- phenoxy-propyls and hydroxyl butyl methyl acrylate
It is specifically chosen as follows：Aliphatic polyurethane modified diacrylate can provide the overall curing rate of formula and not influence
The adhesive force of product, the pure acrylic acid ester oligomer of 2 degrees of functionality provide adhesive force, and aliphatic polyurethane is modified nine acrylate and changed
The curing rate of kind formula, organic silicon modified polyurethane diacrylate can provide the anti-scratch of surface while attachment is provided
Property, wearability, keep relatively good surface brightness etc.
While above monomer can provide adhesive force, curing rate is unaffected, and corrosivity is extremely low, to human body without wound
Evil；
The light trigger is one in the free radical photo-initiations such as acyl group phosphorous oxide, styrax or benzoin ether and benzophenone
Kind or two kinds or three kinds.184, TPO, TPO-L etc. can be selected
The auxiliary agent is one or both of anti-settling agent, defoamer and levelling agent or three kinds, wherein anti-settling agent-greatly subtract
Hold one's horse the subsidence velocity of toner, extended shelf-life can be caused by more than 1 year；Defoamer-elimination bubble, levelling agent-glue
Can quick levelling.
In addition, present invention further teaches a kind of preparation method of a persistently environmentally friendly ground beetle factice, embodiment one
This method 10 parts of hydroxyl butyl methyl acrylate of specific selection, 10 parts of 2- acrylic acid -2- hydroxyl -3- phenoxy-propyls, 5 parts
Polyethylene glycol/propane diols or dimethylacrylate, 5 parts of ethoxylated/propoxylated polyethylene glycol/propane diols or diacrylate, 3
Part acyl group phosphorous oxide and 1 part of styrax are well mixed, and are heated to 40-50 DEG C, 40-45min is stirred under 1200-2000r/min.
Then 34 parts of aliphatic polyurethane modified diacrylates, 20 pure acrylic acid ester oligomers（2 officials）, 5 parts of aliphatic
Polyurethane-modified nine acrylate, 5 parts of organic silicon modified polyurethane diacrylates and 1 portion of anti-settling agent, stir 20-30min；Most
0.2 part of defoamer and 0.8 part of levelling agent are added afterwards, are stirred 10-15min, are filtrated to get finished product.
Embodiment two
This method specifically chooses 8 parts of hydroxyl butyl methyl acrylate, and 8 parts of 2- acrylic acid -2- hydroxyl -3- phenoxy-propyls, 4 parts poly-
Ethylene glycol/propylene glycol or dimethylacrylate, 4 parts of ethoxylated/propoxylated polyethylene glycol/propane diols or diacrylate, 3 parts
Acyl group phosphorous oxide and 1 part of styrax are well mixed, and are heated to 40-50 DEG C, 40-45min is stirred under 1200-2000r/min.
Then 34 parts of aliphatic polyurethane modified diacrylates, 20 pure acrylic acid ester oligomers（2 officials）, 5 parts of aliphatic
Polyurethane-modified nine acrylate, 5 parts of organic silicon modified polyurethane diacrylates and 1 portion of anti-settling agent, stir 20-30min；Most
0.2 part of defoamer and 0.8 part of levelling agent are added afterwards, are stirred 10-15min, are filtrated to get finished product.
Manufactured end properties are excellent, and major parameter is as shown in following table one
Table one：
| Parameters necessary | Basic standard | The standard reached |
| 1st, real colour code It is accurate | Paint twice | The thickness of a secondary persistently environmentally friendly ground beetle factice is brushed, most real color is once can reach with real coloring agent Effect, it is wrinkle resistant. |
| 2nd, contracting glue, Shrinkage cavity standard | Part has | Before solidification with this it is solid after, tip portion must not have cured layer or no glue.Shrinkage cavity standard refers to Surface requirements are smooth, round and smooth, glossy after solidification, without crafters, shrinkage cavity. |
| 3rd, solidified bars Part standard | 36W UV：120 seconds 12W led:90 seconds | UV or LED are curable, the thickness of the secondary persistently environmentally friendly ground beetle factice of thickness, with 36WUV lamps 90 Second solidification, solidified 60 seconds with 12WLED lamps and solidified. |
| 4th, viscosity mark It is accurate | 4000-8000cps（25 DEG C, 3#12） | Viscosity is adjustable |
| 5th, corrugation mark It is accurate | Twice of colouring is thick without corrugation Spend 0.1-0.3mm | Colloid is when once brushing solidification, it is impossible to has corrugated any phenomenon（Thickness is 0.1- 0.3mm）. |
| 6th, outward appearance mark It is accurate | It is amber translucent | It is amber translucent |
| 7th, anti-settling mark It is accurate | 3 months or more | When adding shimmering powder paillette, do not sink in 6 months, color and the mixing of base-material substantially uniformity, anti-settling agent It is non-rising. |
| 8th, adhesive force | 15 days or so | More than 30 days |
| 9th, detachable mark It is accurate | First bag 5-10min is unloaded, with unloading First is to can random removal | First bag 3-5min is unloaded, with unloading first to can random removal |
| 10th, mix colours Standard | Meet part colours | Meet all colours |
It should be noted that described above is not the restriction to technical solution of the present invention, the creation structure of the present invention is not being departed from
It is any obviously to replace within protection scope of the present invention on the premise of think of.
Claims (6)
1. an a kind of persistently environmentally friendly ground beetle factice, is made up of the following component counted in parts by weight：Oligomer 60-70 parts, propylene
Esters of gallic acid activated monomer 20-30 parts, light trigger 1-5 parts and auxiliary agent 1-5 parts, the oligomer are that aliphatic polyurethane is modified two
Acrylate, the pure acrylic acid ester oligomer of 2 degrees of functionality, aliphatic polyurethane are modified nine acrylate or organic-silicon-modified poly- ammonia
Ester diacrylate.
A 2. persistently environmentally friendly ground beetle factice according to claim 1, it is characterised in that the esters of acrylic acid activated monomer
It is the polyethylene glycol/propane diols, dimethylacrylate, the ethoxylated/propoxylated poly- second two of molecular weight 1000 of molecular weight 400
One kind in alcohol/propane diols, diacrylate, 2- acrylic acid -2- hydroxyl -3- phenoxy-propyls and hydroxyl butyl methyl acrylate
Either two kinds or two or more combinations.
A 3. persistently environmentally friendly ground beetle factice according to claim 2, it is characterised in that the light trigger aoxidizes for acyl group
Phosphorus, styrax or one or both of benzoin ether and benzophenone or three kinds.
A 4. persistently environmentally friendly ground beetle factice according to claim 3, it is characterised in that the auxiliary agent is anti-settling agent, defoaming
One or both of agent and levelling agent or three kinds.
5. a kind of preparation method of lasting environmentally friendly ground beetle factice according to any one of claim 1-4, including it is following
Step：
Oligomer, esters of acrylic acid activated monomer, light trigger and auxiliary agent are well mixed according to setting proportion relation, are heated to
40-50 DEG C, stirring 65--80min is well mixed under 1200-2000r/min；
Then the strainer filtering of 300 mesh is used, packaging, obtains finished product.
6. the preparation method of a persistently environmentally friendly ground beetle factice according to claim 5, it is characterised in that methods described is specific
Choose 10 parts of hydroxyl butyl methyl acrylate, 10 parts of 2- acrylic acid -2- hydroxyl -3- phenoxy-propyls, 5 parts of polyethylene glycol/the third two
Alcohol or dimethylacrylate, 5 parts of ethoxylated/propoxylated polyethylene glycol/propane diols or diacrylate, 3 parts of acyl group phosphorous oxides
It is well mixed with 1 part of styrax, is heated to 40-50 DEG C, 40-45min is stirred under 1200-2000r/min；
Then 34 parts of aliphatic polyurethane modified diacrylates, 20 pure acrylic acid ester oligomers, 5 parts of aliphatic polyurethanes are modified
Nine acrylate, 5 parts of organic silicon modified polyurethane diacrylates and 1 portion of anti-settling agent, stir 20-30min；It is eventually adding 0.2
Part defoamer and 0.8 part of levelling agent, 10-15min is stirred, is filtrated to get finished product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115991948A (en) * | 2022-12-09 | 2023-04-21 | 南雄市沃太化工有限公司 | UV-LED cured additive base adhesive and preparation method thereof |
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|---|---|---|---|---|
| CN102286230A (en) * | 2011-09-15 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Ultraviolet curable ink and preparation method thereof |
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
| CN106928870A (en) * | 2017-02-09 | 2017-07-07 | 河源然生新材料有限公司 | A kind of Liquid optical clear adhesive and preparation method thereof |
-
2017
- 2017-08-31 CN CN201710771403.XA patent/CN107536728A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102286230A (en) * | 2011-09-15 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Ultraviolet curable ink and preparation method thereof |
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
| CN106928870A (en) * | 2017-02-09 | 2017-07-07 | 河源然生新材料有限公司 | A kind of Liquid optical clear adhesive and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115991948A (en) * | 2022-12-09 | 2023-04-21 | 南雄市沃太化工有限公司 | UV-LED cured additive base adhesive and preparation method thereof |
| CN115991948B (en) * | 2022-12-09 | 2024-03-08 | 南雄市沃太化工有限公司 | UV-LED cured additive base adhesive and preparation method thereof |
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Application publication date: 20180105 |
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