CN108624220A - A kind of environment-friendly type photocuring crystal extension glue - Google Patents
A kind of environment-friendly type photocuring crystal extension glue Download PDFInfo
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- CN108624220A CN108624220A CN201810419328.5A CN201810419328A CN108624220A CN 108624220 A CN108624220 A CN 108624220A CN 201810419328 A CN201810419328 A CN 201810419328A CN 108624220 A CN108624220 A CN 108624220A
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- Prior art keywords
- photocuring
- environment
- friendly type
- glue
- photoinitiator
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of environment-friendly type photocuring crystals to extend glue, and formula includes following component：Photocuring performed polymer, photocuring activated monomer, photoinitiator, polymer powder, auxiliary rheological agents, pigment, thixotropic agent.The environment-friendly type photocuring crystal of the present invention extends glue and has the following advantages that：(1) it does not flow, thixotropy is good, and colloid surface viscosity is small, is conducive to being operated with pen for manicuristisn；(2) smell is low, is free of solvent and micromolecular compound, environmental-friendly；(3) heat release is low；(4) bulk strength is high, and durability is good.
Description
Technical field
The invention belongs to daily chemical product fields, mainly as nail-care products, and in particular to a kind of environment-friendly type photocuring crystal
Extend glue.
Background technology
At present do on the market it is extended there are mainly two types of, one is traditional crystal first, using in crystal liquid
Crystal powder is added, manicuristisn voluntarily adds when operating, and specific ratio is controlled by manicuristisn oneself.This mode of operation greatly according to
Rely the operation in manicuristisn, the abundant degree of manicuristisn experience impacted very big for the final experience sense of consumer.Crystal liquid
In be added to a large amount of organic solvent, operated in manicuristisn and when product curing molding can largely volatilize, for periphery
Environment has an adverse effect.And it is also unfavorable for the health of manicuristisn and customer.Traditional crystal extends glue crystal in operation
First can slowly cure, if manicuristisn operation is unskilled, there are no operations to complete to be possible to have been cured molding, thus can
Influence final molding effect.Another is that traditional photocuring extends glue, and this photocuring extension glue mobility is big, operation
When it is inconvenient, operation technique and skilled operation degree for manicuristisn require all very high.Colloid can release a large amount of when curing
The impression of heat, customer is very unfriendly.Traditional photocuring extends the hardness of glue and toughness is difficult balance, it is difficult to reach ideal shape
State, using effect are undesirable.A kind of light-cured crystal rubber of patent CN 102181012 B descriptions, is the system for craftwork
Make, the styrene used is first generation photocuring raw material, does not meet environmental requirement already, and remain containing inertia small molecule.
Other have the entitled polyester resins such as several patents such as 103102644 B of CN, but chemical system is neither photocuring, are used for nor beautiful
First field.
In existing public technology, do not find performance characteristics be it is easy to operate, do not flow, photocuring heat release it is low, environmental-friendly
Photocuring crystal extend glue.
Invention content
To solve the problems, such as above-mentioned background technology, the present invention provides a kind of photocuring crystal and extends glue, by with
Under technical solution realize：
(1) a large amount of high hardness high toughness polymer powder and thixotropic agent is added, to realize the high viscosity and height of colloid
Thixotroping, number of polymers powder also reduce the surface oxygen inhibition effect of photocuring as the presence of inert component so that colloid
Surface cure after illuminator is more abundant；
(2) colloid is made to cure using photocuring principle, raw material used are nonirritant, are free of small molecule volatile object
Matter has abandoned small molecule curing agent and small molecule acrylic that traditional polyester resin uses；
(3) a large amount of polymer powder is added as the chemistry in inert component to formula, reduced when formula system cures
Key forms density, to reduce the heat release of polymerisation；
(4) the high hardness high toughness polymer powder and matrix component such as esters of acrylic acid performed polymer and activity list being added
Body can partially compatible, and play the role of similar fiberglass reinforced to matrix component；By the technique mistake for being dispersed with stirring deaeration
Journey, obtained homogeneous colloids, product after solidification have very high hardness, and pass through the pre- of suitable ratio and appropriate mix
Aggressiveness realizes good toughness.
A kind of environment-friendly type photocuring crystal provided by the invention extends glue, and formula includes following component：
The present invention also provides the preparation methods that a kind of environment-friendly type photocuring crystal extends glue, include the following steps：
(1) photocuring performed polymer, photocuring activated monomer, photoinitiator are disperseed in vacuum dispersion machine, is formed uniform
Mixture；
(2) rheology dispersing aid is added and is gradually added polymer powder, thixotropic agent in batches, divides in vacuum dispersion machine
It dissipates, tentatively obtains paste material body；
(3) dispersion machine unlatching vacuumizes, the vacuumizing and defoaming in dispersion, to obtain uniform bubble-free material body；
(4) it when needing toning, mixes colours after the bubble that disappeared, is further continued for carrying out defoaming treatment in vacuum dispersion machine；
(5) the material body prepared is by filling to the required terminal packaging material of bottle placer.
The environment-friendly type photocuring crystal of the present invention extends glue when in use, and Operation Key mainly has：
1, curing light source used recommends LED light source lamp, and power more high solidification is better, but exists specific to including UV lamp
Interior different solidification lamp sources, manicuristisn should be tested first in operation, to determine that can the lamp source be applicable in, and selection
Suitable hardening time.
2, about hardening time, recommend 60 seconds, specific manicuristisn can adjust according to actual needs in operation.
3, curing the extension first piece of final molding, thickness is recommended at 0.8 millimeter or more, too thin to weaken bulk strength,
Have on hand in consumer fracture in advance, split equivalent risk.
The present invention achieves beneficial technique effect：
(1) it does not flow, thixotropy is good, and colloid surface viscosity is small, is conducive to being operated with pen for manicuristisn；Existing extension glue stream
Dynamic property is too strong, is not easy plasticity and long-time operation.
(2) smell is low, is free of solvent and micromolecular compound, environmental-friendly；Existing polyester resin contains small molecule curing agent,
There is obvious irritation smell, is increasingly repelled by consumer.
(3) heat release is low, and often heat release is larger for existing extension glue, and hot sense is had when slightly thick on first face.
(4) bulk strength is high, and durability is good；Existing extension glue is not hard enough, and the extension first made is yielding.
Specific implementation mode
With reference to embodiment, the present invention is further illustrated.
A kind of environment-friendly type photocuring crystal provided by the invention extends glue, and formula includes following component：
Preferably, the photocuring performed polymer is selected from urethane acrylate, epoxy acrylate, polybutadiene acrylic acid
One or more of ester, polyether acrylate.
Preferably, the photocuring activated monomer is selected from methylacrylic acid isobornyl thiocyanoacetate, methylacrylic acid hydroxyl ethyl ester, ethoxy
Change the photocurings containing acryloyl-oxy based structures such as trimethylolpropane trimethacrylate, the third oxidation neopentylglycol diacrylate
The compounding of one or more of activated monomer
Preferably, the photoinitiator is selected from photoinitiator TPO, photoinitiator 819, photoinitiator 184, photoinitiator
One or more of 1173 compounding.
Preferably, the polymer powder is selected from polymethylmethacrylate powder, Phenolic resin powder, ABS resin
One or more of powder.
Preferably, the grain size of the polymer powder is 5 μm -80 μm.
Preferably, the auxiliary rheological agents are capable of helping to disperse, defoaming, enhance rheological property for routine in the art
Auxiliary agent.
Preferably, the thixotropic agent is white carbon.
Heretofore described pigment can be known convention pigment.
The present invention also provides the preparation methods that a kind of environment-friendly type photocuring crystal extends glue, it is characterised in that including as follows
Step：
(1) photocuring performed polymer, photocuring activated monomer, photoinitiator are disperseed in vacuum dispersion machine, is formed uniform
Mixture；
(2) rheology dispersing aid is added and is gradually added polymer powder, thixotropic agent in batches, divides in vacuum dispersion machine
It dissipates, tentatively obtains paste material body；
(3) dispersion machine unlatching vacuumizes, the vacuumizing and defoaming in dispersion, to obtain uniform bubble-free material body；
(4) it when needing toning, mixes colours after the bubble that disappeared, is further continued for disappearing in vacuum dispersion machine
Bubble processing；
(5) the material body prepared is by filling to the required terminal packaging material of bottle placer.
Embodiment 1：
Preparation method is：
(1) urethane acrylate, isobornyl acrylate IBOA, TPO are disperseed in vacuum dispersion machine, is formed uniform
Mixture；
(2) dispersant and wetting agent is added, polymethylmethacrylate powder and white carbon are added in three batches, in vacuum point
It dissipates and disperses in machine, tentatively obtain paste material body；
(3) dispersion machine unlatching vacuumizes, the vacuumizing and defoaming in dispersion, to obtain uniform bubble-free material body；
(4) pigment is added, is further continued for carrying out defoaming treatment in vacuum dispersion machine；
(5) the material body prepared is by filling to the required terminal packaging material of bottle placer.
Embodiment 2
Embodiment 3
Embodiment 4
The environment-friendly type photocuring of the present invention extends glue and the existing comparison for extending glue class product, has the following advantages that：
1 environment-friendly type photocuring crystal of table extends glue and traditional crystal extends the comparison of glue
2 environment-friendly type photocuring crystal of table extends glue and traditional photocuring extends the comparison of glue
The above is only presently preferred embodiments of the present invention.It will be appreciated by those skilled in the art that the present invention is not limited to here
The specific embodiment, can carry out for a person skilled in the art it is various it is apparent variation, readjust and substitute and
Without departing from the scope of protection of the present invention.Therefore, although being described in further detail to the present invention by above example,
But the present invention is not limited only to above example, can also include more other without departing from the inventive concept
Equivalent embodiment, and the scope of the present invention is determined by scope of the appended claims.
Claims (8)
1. a kind of environment-friendly type photocuring crystal extends glue, which is characterized in that the environment-friendly type photocuring crystal extends the formula of glue
Including following component：
2. environment-friendly type photocuring crystal according to claim 1 extends glue, which is characterized in that preferred, the photocuring
One kind in urethane acrylate, epoxy acrylate, polybutadiene acrylic acid ester, polyether acrylate of performed polymer or
It is several.
3. environment-friendly type photocuring crystal according to claim 1 extends glue, which is characterized in that the photocuring activated monomer
Selected from isobornyl acrylate, isobornyl methacrylate, hydroxyethyl methacrylate, ethoxyquin trimethylolpropane tris third
Olefin(e) acid ester, one kind in the third photocuring activated monomer of the oxidation neopentylglycol diacrylate etc. containing acryloyl-oxy based structures or
Several compoundings.
4. environment-friendly type photocuring crystal according to claim 1 extends glue, which is characterized in that the photoinitiator is selected from
The compounding of one or more of photoinitiator TPO, photoinitiator 819, photoinitiator 184, photoinitiator 1173.
5. environment-friendly type photocuring crystal according to claim 1 extends glue, which is characterized in that the polymer powder choosing
From one or more of polymethylmethacrylate powder, Phenolic resin powder, ABS resin powder.
6. environment-friendly type photocuring crystal according to claim 5 extends glue, which is characterized in that the polymer powder
5 μm -80 μm of grain size.
7. environment-friendly type photocuring crystal according to claim 1 extends glue, which is characterized in that the thixotropic agent is hard charcoal
It is black.
8. extending the preparation method of glue according to claim 1-7 any one of them environment-friendly type photocuring crystals, it is characterised in that
Include the following steps：
(1) photocuring performed polymer, photocuring activated monomer, photoinitiator are disperseed in vacuum dispersion machine, forms uniformly mixing
Object；
(2) rheology or dispersing aid is added and is gradually added polymer powder, thixotropic agent in batches, divides in vacuum dispersion machine
It dissipates, tentatively obtains paste material body；
(3) dispersion machine unlatching vacuumizes, the vacuumizing and defoaming in dispersion, to obtain uniform bubble-free material body；
(4) it when needing toning, mixes colours after the bubble that disappeared, is further continued for carrying out defoaming treatment in vacuum dispersion machine；
(5) the material body prepared is by filling to the required terminal packaging material of bottle placer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419328.5A CN108624220A (en) | 2018-05-04 | 2018-05-04 | A kind of environment-friendly type photocuring crystal extension glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810419328.5A CN108624220A (en) | 2018-05-04 | 2018-05-04 | A kind of environment-friendly type photocuring crystal extension glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108624220A true CN108624220A (en) | 2018-10-09 |
Family
ID=63695406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810419328.5A Pending CN108624220A (en) | 2018-05-04 | 2018-05-04 | A kind of environment-friendly type photocuring crystal extension glue |
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| Country | Link |
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| CN (1) | CN108624220A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109528553A (en) * | 2018-11-08 | 2019-03-29 | 安徽省明睿合成材料有限公司 | Nail lengthening glue and preparation method thereof and solidification demoulding application |
| CN110731913A (en) * | 2019-08-19 | 2020-01-31 | 金华市科维思日化有限公司 | novel carving glue for nail beauty |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
| US20180092827A1 (en) * | 2016-06-15 | 2018-04-05 | Mycone Dental Supply Co., Inc. | One part acrylic nail formulation with discontinuous phase |
-
2018
- 2018-05-04 CN CN201810419328.5A patent/CN108624220A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
| US20180092827A1 (en) * | 2016-06-15 | 2018-04-05 | Mycone Dental Supply Co., Inc. | One part acrylic nail formulation with discontinuous phase |
Non-Patent Citations (1)
| Title |
|---|
| 涂料工艺编委会: "《涂料工艺 （第三版） 下册》", 31 December 1997, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109528553A (en) * | 2018-11-08 | 2019-03-29 | 安徽省明睿合成材料有限公司 | Nail lengthening glue and preparation method thereof and solidification demoulding application |
| CN110731913A (en) * | 2019-08-19 | 2020-01-31 | 金华市科维思日化有限公司 | novel carving glue for nail beauty |
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Application publication date: 20181009 |
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