CN103751036A - UV (Ultraviolet) nail phototherapy gel and preparation method thereof - Google Patents
UV (Ultraviolet) nail phototherapy gel and preparation method thereof Download PDFInfo
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- CN103751036A CN103751036A CN201410016652.4A CN201410016652A CN103751036A CN 103751036 A CN103751036 A CN 103751036A CN 201410016652 A CN201410016652 A CN 201410016652A CN 103751036 A CN103751036 A CN 103751036A
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- fingernail
- phototherapy
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- phototherapy glue
- acrylic resin
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- 238000001126 phototherapy Methods 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 238000001879 gelation Methods 0.000 title 1
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 20
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 19
- 229920002635 polyurethane Polymers 0.000 claims abstract description 19
- 239000004814 polyurethane Substances 0.000 claims abstract description 19
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003292 glue Substances 0.000 claims description 40
- 210000004905 finger nail Anatomy 0.000 claims description 33
- 239000013530 defoamer Substances 0.000 claims description 14
- 125000000524 functional group Chemical group 0.000 claims description 11
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 5
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 claims description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 4
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 11
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 6
- 239000002518 antifoaming agent Substances 0.000 abstract description 2
- 238000005282 brightening Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 11
- 239000004922 lacquer Substances 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 101000720524 Gordonia sp. (strain TY-5) Acetone monooxygenase (methyl acetate-forming) Proteins 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 210000000282 nail Anatomy 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000035943 smell Effects 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 102100026735 Coagulation factor VIII Human genes 0.000 description 2
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- KEEXOYPZMIJIEP-UHFFFAOYSA-N diphenoxyphosphoryl 2,4,6-trimethylbenzoate Chemical compound CC1=CC(C)=CC(C)=C1C(=O)OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 KEEXOYPZMIJIEP-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- -1 phthalic acid ester Chemical class 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Abstract
The invention provides an UV (Ultraviolet) nail phototherapy gel and a preparation method thereof. According to the formula, the phototherapy gel comprises the following components in percentage by mass: 40 to 50% of single functional monomer, 40 to 50% of aliphatic polyurethane acrylic resin, 8 to 11% of photoinitiator, 0.2 to 0.4% of flatting agent, and 0.1 to 0.2% of defoaming agent. The UV nail phototherapy gel shows an outstanding brightening effect with a coating, and also has the characteristics of being environmentally-friendly, convenient to coat, high in transparence, high in glossiness, natural, lightweight, high in toughness, no pungent smell, difficult to yellow and break, long in holding time, etc.
Description
Technical field
The present invention relates to a kind of UV glue coating, particularly a kind of UV fingernail phototherapy glue and preparation method thereof.
Background technology
In common nial polish, contain a large amount of chemical solvents as toluene, ethyl acetate and ethanol, phthalic acid ester, formaldehyde etc., produce many harm to health, and cover with paint, lacquer, colour wash, etc. after dry easily drop, abnormal smells from the patient is large, glossiness conservation degree is low.
Publication number is that the Chinese patent application of CN103479537 discloses a kind of flash of light nial polish, and its formula contains following component: 20 grams, acetone, 15 grams of ethyl acetate, 75 grams of phthalic acid esters, 10 grams of tonyreds, 5 grams, formaldehyde, 25 grams of flashlight powders.Although this nial polish has flash effect, wherein contain formaldehyde etc., health is had to certain harm.
Summary of the invention
The object of the invention is to make up the deficiencies in the prior art, a kind of UV fingernail phototherapy glue is provided, it films this phototherapy glue and has excellent brightness effect, also has environmental protection simultaneously, covers with paint, lacquer, colour wash, etc. the features such as convenient, transparency is high, glossiness good, naturally light and handy, good toughness, nonirritant taste, inhibited from yellowing, the retention time is grown.
The technical scheme that the present invention reaches its object employing is as follows: a kind of UV fingernail phototherapy glue, and its formula comprises each component of following mass percent:
Described monofunctional monomer is one or more the mixture in acryloyl morpholine (be called for short ACMO), hydroxyethyl methylacrylate (being called for short HEMA), 3.3.5-trimethyl cyclohexyl acrylate (being called for short TMCHA).Wherein, acryloyl morpholine (be called for short ACMO) can adopt the product of Japanese Xing Ren Co., Ltd., hydroxyethyl methylacrylate (being called for short HEMA) can adopt the product of MIT, and 3.3.5-trimethyl cyclohexyl acrylate (being called for short TMCHA) can adopt the EM2104 of Changxing, Taiwan company.The monomer that the present invention adopts all adopts the high curing rate monomer in the middle of simple function, wherein acryloyl morpholine is a kind of thermostability functional monomer of superior performance, zest to skin is very little, because its steam pressure is very low, so produce hardly any penetrating odor.ACMO also has the features such as low viscosity and fast setting and low cubical contraction.The zest of the adhesive force that hydroxyethyl methylacrylate has had and low skin, 3.3.5-trimethyl cyclohexyl acrylate (be called for short TMCHA) has high adhesion force high response and low cure shrinkage, can improve the internal stress that reduces coating in curing rate in system.Also can be to the effects such as hardness, adhesive force are provided of filming in the diluting effect that above monomer can play when coordinating or using in formula system of the present invention separately and fast curing rate.
Described aliphatic polyurethane acrylic resin Wei Er functional group's aliphatic polyurethane acrylic resin and composite the mixing of six functional groups aliphatic polyurethane acrylic resin.In formula system of the present invention, use this composite resin, it has in low energy condition and is issued to high curing rate, and filming after solidifying has high rigidity, the feature of high tenacity, high glaze and high richness effect.In the present invention, two functional group's aliphatic polyurethane acrylic resins and six functional groups aliphatic polyurethane acrylic resin specifically can be according to mass ratio (30-40): (5-15) composite.Concrete, described aliphatic polyurethane acrylic resin can preferably adopt two functional groups that Shenzhen Sa Bisi Science and Technology Ltd. produces exempt from clean the six functional groups aliphatic polyurethane acrylic resin 6145-100 that the special-purpose specific functionality aliphatic urethane acrylate SM-582 of UV phototherapy glue and Changxing, Taiwan company produce and mix.The resistance to xanthochromia transitivity that aliphatic urethane acrylate has had, what the present invention adopted is the composite use of 2 functional groups and 6 functional groups.The SM-582 preferably adopting be a kind of two functional groups exempt to clean the special-purpose specific functionality aliphatic urethane acrylate of UV phototherapy glue, there is low-yield high curing rate, high glaze, outstanding oil resistant and weather-proof chemical resistance, outstanding wear-resisting scratch-resisting, outstanding film forming tenacity, can be in the present invention as matrix resin, supporting resin preferably adopts 6 officials' energy aliphatic polyurethane acrylic resin 6145-100 of Changxing company, it has high curing rate, high rigidity, and high tenacity, can be used as matrix resin hardness and curing rate deficiency supplementary.
Described light trigger is 1-hydroxy cyclohexyl phenylketone (184), 2,4, the mixture of 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO), diphenyl phosphine oxide (819); Specifically can be selected from the corresponding Related product of BASF AG or Beijing Ying Li scientific & technical corporation or Tianjin Jiu scientific & technical corporation.Light trigger can absorb ultraviolet energy, produces free radical, then causes coating oligomer and monomer is realized polymerization, crosslinked, makes system be cross-linked film forming.The light trigger that the present invention preferably adopts is 1-hydroxy cyclohexyl phenylketone (184), 2, 4, 6-, trimethylbenzoyl-diphenyl phosphate oxidation (TPO) and diphenyl phosphine oxide (819) mix composite forming according to the mass ratio of 1:1:0.1, 1-hydroxy cyclohexyl phenylketone (184) belongs to skin drying mould light trigger, 2, 4, 6-trimethylbenzoyl-diphenyl phosphate oxidation (TPO) and diphenyl phosphine oxide (819) belong to long wave deep layer and solidify light trigger, light trigger after composite can absorb ultraviolet wavelength between 280-450um, just in time send wavelength correspondence with phototherapy lamp, the energy-curable effect that allows fingernail phototherapy glue reach.
The dimethyl polysiloxane of described levelling agent Wei Han acrylic functional group; Specifically can adopt the BYK of Bi Ke chemical company
-UV3576.Phototherapy glue needs quick levelling effect, in formulation for coating material, add appropriate levelling agent, can improve coating flow leveling, in the present invention, levelling agent adopts polyether siloxane copolymers, the preferred dimethyl polysiloxane of Yong Han acrylic functional group, more preferably adopt BYK company containing the dimethyl polysiloxane leveling auxiliary agent BYK of acrylic functional group
-UV3576, levelling is eliminated and is coated with trace fast.
Described defoamer, for not containing organosilyl polymer-type defoamer, specifically can be selected from the BYK1794 of Bi Ke chemical company.Phototherapy glue all can produce bubble in production covering with paint process, the existence of bubble can cause the generation defect of filming, need defoamer to improve, defoamer can provide good defoaming effect, prevent the generation of paint film defect, defoamer of the present invention is not for containing organosilyl polymer-type defoamer, in formula system of the present invention, add not containing organosilyl polymer-type defoamer, in the good antifoam performance of maintenance, prepared UV fingernail phototherapy glue does not have a negative impact to ply adhesion when recoat, make the effect of UV fingernail phototherapy glue of the present invention better.
Second aspect present invention provides a kind of method of preparing UV fingernail phototherapy glue as described above, comprises the steps:
Step 1, takes each component by formula: monofunctional monomer 40～50%, aliphatic polyurethane acrylic resin 40～50%, light trigger 8～11%, levelling agent 0.2～0.4%, defoamer 0.1～0.2%;
Step 2, drops into monofunctional monomer, fat adoption urethane acrylate resin to disperse, in cylinder, to use high speed dispersor high speed dispersion 10～15 minutes;
Step 3, drops into levelling agent, with high speed dispersor, disperses 10～15 minutes;
Step 4, drops into light trigger, uses high speed dispersor high speed dispersion 10～15 minutes;
Step 5, drops into defoamer, with high speed dispersor, disperses 10～15 minutes, and 300 order filter-cloth filterings, make UV fingernail phototherapy glue;
Wherein, the rotating speed of the high speed dispersor of described step 2 and step 3 is 1200～1500 revs/min; The rotating speed of the high speed dispersor of step 4 and step 5 is 800～1000 revs/min.
Phototherapy glue of the present invention can be no more than 10% shades of colour environmental protection mill base and bronze and by toning, forms the UV fingernail phototherapy glue of different colours series by adding.
Technical scheme of the present invention has following beneficial effect:
Adopt formula of the present invention, in its formula system, each component compatibility is good, by each component interaction, the prepared UV fingernail phototherapy glue of working in coordination, have environmental protection, cover with paint, lacquer, colour wash, etc. and conveniently, low-yield to solidify, to have after film forming highlighted effect, good toughness, tasteless nontoxic, inhibited from yellowing, not frangibility, loss of gloss not, the feature such as do not come off, the retention time is long.
UV fingernail phototherapy glue preparation method provided by the invention has feature simply and easily, and prepared phototherapy glue is covered with paint, lacquer, colour wash, etc. after fingernail with professional manicure instrument, and under 36W phototherapy lamp, lamp, according to 2 minutes, gets final product film forming.Phototherapy glue after film forming is filmed, and to have gloss highlighted, and richness is good, and adhesive force is good, good toughness, and the features such as good weatherability also have good leveling property simultaneously, low abnormal smells from the patient, the low-yield feature such as solidify.Manicure surface-brightening after phototherapy glue of the present invention is covered with paint, lacquer, colour wash, etc., naturally lightly, good toughness, nonirritant taste, inhibited from yellowing, frangibility, retention time do not reach one month.
The specific embodiment
Below technical scheme of the present invention is described further:
Embodiment 1～4
Embodiment 1-4 is the Preparation Example of UV fingernail phototherapy glue, the formula of embodiment 1～4 (unit: kg) as shown in table 1.
Table 1
The SM-582 that two sense aliphatic polyurethane acrylic resins described in table 1 specifically can adopt Shenzhen Sa Bisi Science and Technology Ltd. to produce; The 6145-100 that six described sense aliphatic polyurethane acrylic resins specifically can adopt Changxing, Taiwan to produce).
The preparation method of the UV fingernail phototherapy glue of embodiment 1-4, all in accordance with the following steps:
Step 1, takes each component by the formula of upper table 1;
Step 2, drops into monofunctional monomer, aliphatic polyurethane acrylic resin to disperse, in cylinder, to use high speed dispersor high speed dispersion 10～15 minutes;
Step 3, drops into levelling agent, with high speed dispersor, disperses 10～15 minutes;
Step 4, drops into light trigger, with high speed dispersor, disperses high speed dispersion 10～15 minutes,
Step 5, drops into defoamer, with high speed dispersor, disperses 10～15 minutes, and 300 order filter-cloth filterings, make UV fingernail phototherapy glue.
Wherein, the rotating speed of the high speed dispersor of described step 2 and step 3 is 1200～1500 revs/min; The rotating speed of the high speed dispersor of step 4 and step 5 is 800～1000 revs/min.
After testing, the UV fingernail phototherapy glue of embodiment 1～4 preparation, color outward appearance is that colourless transparent liquid, solid content are 98～99%, viscosity is 800～1000mpa.s (25 ℃).After embodiment 1-4 processes by color paste toning separately, all adopt following coating method to cover with paint, lacquer, colour wash, etc.: 1. with professional manicure instrument polishing fingernail, 2. with professional nail brush, evenly cover with paint, lacquer, colour wash, etc. first color UV fingernail phototherapy glue after fingernail, under 36W phototherapy lamp, lamp was according to 2 minutes, 3. with professional nail brush, evenly cover with paint, lacquer, colour wash, etc. the 2nd road color UV fingernail phototherapy glue on fingernail, under 36W phototherapy lamp, lamp was according to 2 minutes, 4. with professional nail brush, evenly cover with paint, lacquer, colour wash, etc. the colourless UV fingernail of light phototherapy glue on fingernail, under 36W phototherapy lamp, lamp, according to 2 minutes, obtains the lasting beautiful phototherapy glue of color and films.After the phototherapy glue film forming of embodiment 1-4, it is filmed and all has difficult drop-off, easily smears, and solidify drying time short, and hold period is permanent, there is no bad smell, easy fracture not, high resilience, the feature such as color is lasting beautiful.
The above, it is only preferred embodiment of the present invention, not the present invention is done to any pro forma restriction, the content that does not depart from technical solution of the present invention therefore all, according to technical spirit of the present invention, to any simple modification made for any of the above embodiments, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (8)
1. a UV fingernail phototherapy glue, is characterized in that, its formula comprises each component of following mass percent:
2. UV fingernail phototherapy glue according to claim 1, is characterized in that, monofunctional monomer is one or more the mixture in acryloyl morpholine, hydroxyethyl methylacrylate, 3.3.5-trimethyl cyclohexyl acrylate.
3. UV fingernail phototherapy glue according to claim 1, is characterized in that, described aliphatic polyurethane acrylic resin Wei Er functional group's aliphatic polyurethane acrylic resin and composite the mixing of six functional groups aliphatic polyurethane acrylic resin.
4. UV fingernail phototherapy glue according to claim 3, is characterized in that, described aliphatic polyurethane acrylic resin is the SM-582 of Shenzhen Sa Bisi Science and Technology Ltd. production and composite the mixing of 6145-100 that Changxing, Taiwan company produces.
5. UV fingernail phototherapy glue according to claim 1, is characterized in that, described light trigger is 1-hydroxy cyclohexyl phenylketone, 2,4, the mixture of 6-trimethylbenzoyl-diphenyl phosphate oxidation, diphenyl phosphine oxide.
6. UV fingernail phototherapy glue according to claim 1, is characterized in that, the dimethyl polysiloxane of described levelling agent Wei Han acrylic functional group.
7. UV fingernail phototherapy glue according to claim 1, is characterized in that, described defoamer is not for containing organosilyl polymer-type defoamer.
8. a method of preparing the UV fingernail phototherapy glue as described in claim 1-7 any one, is characterized in that, comprises the steps:
Step 1, takes each component by formula: monofunctional monomer 40～50%, aliphatic polyurethane acrylic resin 40～50%, light trigger 8～11%, levelling agent 0.2～0.4%, defoamer 0.1～0.2%;
Step 2, drops into monofunctional monomer, aliphatic polyurethane acrylic resin to disperse, in cylinder, to use high speed dispersor high speed dispersion 10～15 minutes;
Step 3, drops into levelling agent, with high speed dispersor, disperses 10～15 minutes;
Step 4, drops into light trigger, uses high speed dispersor high speed dispersion 10～15 minutes;
Step 5, drops into defoamer, with high speed dispersor, disperses 10～15 minutes, and 300 order filter-cloth filterings, make UV fingernail phototherapy glue.
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| CN201410016652.4A CN103751036B (en) | 2014-01-14 | 2014-01-14 | A kind of UV fingernail phototherapy glue and preparation method thereof |
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| CN201410016652.4A CN103751036B (en) | 2014-01-14 | 2014-01-14 | A kind of UV fingernail phototherapy glue and preparation method thereof |
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| CN105030566A (en) * | 2015-06-23 | 2015-11-11 | 上海零玖科技有限公司 | Ultraviolet curing fingernail pigment and preparation method thereof |
| CN105506768A (en) * | 2015-11-27 | 2016-04-20 | 青岛大学 | UV-curable electrospun colored micro-nanofiber stranded wire and preparation method thereof |
| JP2017066042A (en) * | 2015-09-28 | 2017-04-06 | 株式会社サクラクレパス | Photocurable artificial nail composition |
| CN106667834A (en) * | 2016-12-09 | 2017-05-17 | 陈忠燕 | Environment-friendly watermelon seed quick-dry nail-care oil |
| CN107997990A (en) * | 2018-01-03 | 2018-05-08 | 洛阳科迪艺思树脂有限公司 | A kind of UV-LED nails adhesive and preparation method thereof |
| CN108434019A (en) * | 2018-03-29 | 2018-08-24 | 刘晓宁 | A kind of alternative solvent flashing phototherapy nail polish and preparation method thereof |
| CN108635248A (en) * | 2018-05-04 | 2018-10-12 | 上海万化科技有限公司 | A kind of no-solvent type colored drawing nail primer and preparation method thereof |
| CN110339094A (en) * | 2019-07-31 | 2019-10-18 | 詹云如 | A kind of preparation method of phototherapy glue first piece |
| CN110585063A (en) * | 2019-08-05 | 2019-12-20 | 金华市科维思日化有限公司 | UV adhesive for nail-painting base coat |
| CN110731913A (en) * | 2019-08-19 | 2020-01-31 | 金华市科维思日化有限公司 | novel carving glue for nail beauty |
| CN111944230A (en) * | 2020-08-21 | 2020-11-17 | 江南大学 | Wear-resistant starch-EVA (ethylene vinyl acetate) foamed shoe material and preparation method thereof |
| CN113304070A (en) * | 2021-06-16 | 2021-08-27 | 广州蓝之天化工科技发展有限公司 | High-gloss low-yellowing wash-free sealing layer and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101164516A (en) * | 2007-09-06 | 2008-04-23 | 湖南阳光新材料有限公司 | Weak ultraviolet curing composition |
| CN102552071A (en) * | 2011-12-27 | 2012-07-11 | 温州粼粼漆科技有限公司 | Environment-friendly water-based fingernail paint |
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
| CN103450722A (en) * | 2013-08-14 | 2013-12-18 | 湖南邦弗特新材料技术有限公司 | Method for preparing UV (Ultraviolet) oily adhesion primer acting on bamboo-wood base materials |
-
2014
- 2014-01-14 CN CN201410016652.4A patent/CN103751036B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101164516A (en) * | 2007-09-06 | 2008-04-23 | 湖南阳光新材料有限公司 | Weak ultraviolet curing composition |
| CN102552071A (en) * | 2011-12-27 | 2012-07-11 | 温州粼粼漆科技有限公司 | Environment-friendly water-based fingernail paint |
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
| CN103450722A (en) * | 2013-08-14 | 2013-12-18 | 湖南邦弗特新材料技术有限公司 | Method for preparing UV (Ultraviolet) oily adhesion primer acting on bamboo-wood base materials |
Non-Patent Citations (2)
| Title |
|---|
| 张志成等编: "《高分子辐射化学》", 31 July 2000, 中国科学技术大学出版社 * |
| 邓舜扬等主编: "《精细化工配方集锦》", 31 March 2000, 化学工业出版社 * |
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