CN108635248B - Solvent-free primer for colored drawing nails and preparation method thereof - Google Patents
Solvent-free primer for colored drawing nails and preparation method thereof Download PDFInfo
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- CN108635248B CN108635248B CN201810419327.0A CN201810419327A CN108635248B CN 108635248 B CN108635248 B CN 108635248B CN 201810419327 A CN201810419327 A CN 201810419327A CN 108635248 B CN108635248 B CN 108635248B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
- C09J163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Abstract
The invention relates to a solvent-free primer for colored drawing nails and a preparation method thereof, wherein the solvent-free primer for colored drawing nails comprises the following components: 0.5 to 1.5 portions of titanate coupling agent, 25 to 30 portions of epoxy acrylic resin, 25 to 30 portions of aliphatic polyurethane acrylic resin, 3 to 10 portions of pure acrylic resin, 25 to 35 portions of acrylate monomer, 0.5 to 1.5 portions of photoinitiator-184, 2 to 5 portions of TPO, 0.05 to 0.2 portion of flatting agent and 0.1 to 0.3 portion of defoaming agent. The durability of the primer for the solvent-free colored drawing nail can reach 3 weeks or more than 3 weeks; the elongation at break is more than 7 percent; tensile strength >500 psi; the ISO grade of the one hundred grid test is 0; the viscosity is 1000cps to 40000cps at 25 deg.C.
Description
Technical Field
The invention belongs to the technical field of products for nail beautifying, and particularly relates to a solvent-free primer for colored drawing nails and a preparation method thereof.
Background
As society develops, beauty-conscious beautification of body parts has progressed from the earliest face, skin to the eyelashes, nails. Different clothes and ornaments are matched with different nail ornaments, wherein the nail ornament is more and more valued by girls.
How to prolong the durability of nail products on the nail surface always troubles the nail industry. There are also related prior art photo-curing primers, for example, chinese patent application CN201480016595.8 discloses a primer for polyurethane sealant for construction, which is a solvent-free primer that uses only an acrylic oligomer having a glass transition temperature of-25 ℃ or less, a weight average molecular weight of 350 to 2000 or less, and a molecular weight distribution of 1.6 or less, and is manufactured using monomers of alkyl (meth) acrylate, (meth) acrylic acid, (meth) acrylate having an alkoxysilyl group, and (meth) acrylate having a hydroxyl group. For example, CN201510874038.6 discloses a 4D methyl gum, which comprises the following components in parts by weight: 38-45 parts of 11, 14-dioxa-2, 9-diazepan-16-enoic-4, 4, 6, 16-tetramethyl-10, 15-dioxo-2- [ (2-methyl-1-oxo-2-propenyl) oxo ] ethyl ester; 0.02 to 0.04 part of a compound of formula I; 25-29 parts of acrylate oligomer; 2.4-2.9 parts of 1-hydroxycyclohexyl phenyl ketone; 2.5-3.1 parts of bis-phenylphosphine oxide (2, 4, 6-trimethylbenzoyl); 11-13 parts of hydroxyethyl methacrylate; 1.1-1.4 parts of triethanolamine; 0.7-0.8 part of laureth-21; 1.5-2.8 parts of mica.
However, in the above-mentioned techniques disclosed in the prior art, the durability of the nail primer is not more than 20 days, and some of the prior art disclosed glues are not used in many cases, and are not actually dedicated to nail primers, so that the performance of the nail primer is unsatisfactory when the nail primer is used, and the durability of the nail primer is one of the most important indexes for evaluating the nail primer.
The inventor of the invention aims to research the improvement of the lasting performance of the primer for the nail, and provides a solvent-free primer for colored drawing nail and a preparation method thereof.
Disclosure of Invention
In order to solve the technical problems, the invention provides a solvent-free primer for colored drawing nails and a preparation method thereof, and the technical purpose of the invention is realized by the following technical scheme:
a solvent-free primer for color-drawing fingernails comprises the following components
Titanate coupling agent of 0.5 to 1.5 portions,
25 to 30 parts of epoxy acrylic resin,
25 to 30 portions of aliphatic polyurethane acrylic resin,
3 to 10 portions of pure acrylic resin,
acrylate monomer of 25 to 35 portions,
photoinitiator-184-0.5-1.5 parts,
TPO-2 to 5 parts,
0.05 to 0.2 portion of flatting agent,
0.1 to 0.3 portions of defoaming agent.
The photoinitiator-184 is 1-hydroxycyclohexyl phenyl ketone.
In the solvent-free primer for colored drawing nails, the titanate coupling agent is at least one of KR238S, KR12 and KR-TTS.
In the solvent-free primer for color-painted nails, the epoxy acrylic resin is at least one of CNUVE151, HL-160 and 6120G.
Preferably, in the solvent-free primer for color drawing nails, the aliphatic polyurethane acrylate is aliphatic polyurethane acrylate with a functionality of 2, and preferably at least one of HS-230, 2031 and 2752-8.
Preferably, in the solvent-free primer for color drawing nails, the acrylic resin is at least one of DR-A801, DR-A830 and DR-A840.
Preferably, in the solvent-free primer for color-painted nails, the acrylic monomer is at least one of UDMA, EOEOEA and DEGDMA.
Preferably, the leveling agent in the solvent-free primer for color drawing nails is at least one of BYK3455, BYK346 and BYK 333.
Preferably, the defoaming agent in the solvent-free color-drawing nail primer is at least one of BYK-1790, BYK-1798 and BYK-1794.
The invention also provides a preparation method of the solvent-free primer for the colored drawing nail, which comprises the following steps:
(1) mixing photoinitiator-184, TPO and acrylate monomer solution;
(2) under the condition of stirring, adding aliphatic polyurethane acrylic resin, epoxy acrylic resin, titanate coupling agent, pure acrylic resin and flatting agent, and uniformly mixing;
(3) adding a defoaming agent and stirring to prepare the solvent-free primer for the colored drawing fingernails.
In another embodiment of the present invention, the present invention further provides a method for preparing the above product:
(1) the photoinitiator-184, TPO and acrylate monomer are stirred for 15-20 min at 1000-2000 r/min, and are dissolved and mixed uniformly;
(2) under the condition of stirring, adding aliphatic polyurethane acrylate, epoxy acrylic resin, titanate coupling agent, pure acrylic resin and flatting agent, and stirring for 20-25 min at 1000-2000 r/min until the materials are uniformly mixed;
(3) adding a defoaming agent, stirring for 10min at 1000r/min, standing, filtering and discharging to obtain the solvent-free primer for the colored drawing fingernails.
According to the invention, the titanate coupling agent is selected, the epoxy acrylic resin with high curing speed, high hardness and good corrosion resistance, the pure acrylic resin with good toughness and good adhesive force and the aliphatic polyurethane acrylate with certain tensile strength and good flexibility are reasonably matched, the flexibility of the primer is improved under the condition of ensuring that the primer has enough tensile strength, so that the primer is prevented from falling off due to large brittleness and cannot abrade the front edge of the primer due to insufficient tensile strength of the primer when the fingernail performs small-amplitude manual labor.
Meanwhile, in order to meet the requirements of the product on filling of nail polish bottles and the using method of a nail chemist, a UV monomer is required to be added to adjust the viscosity of the product to 1000-40000 cps (25 ℃); the amount of UV monomer can be reduced if a higher viscosity primer is desired.
The primer disclosed by the invention has the following excellent properties:
1. the fastness is good, and the durability can reach 3 weeks or even more than 3 weeks;
2. the elongation at break is more than 7 percent; 3. tensile strength >500 psi;
3. the product of the invention has good base glue fastness and better flexibility than the prior art by a plurality of grades which are tested by a Baige method and have an ISO grade of 0, and the result is unexpected by the technical personnel in the field;
4. titanate coupling agent, pure acrylate and epoxy acrylate are compounded, and RO-bond in the titanate coupling agent is utilized to react with protein residue amino acid on the surface of the nail, so that the purpose of chemical coupling is achieved, and the adhesive force of the primer on the nail is obviously improved;
5. the other end of the titanate coupling agent is compatible with the prepolymer and the monomer; meanwhile, hydroxyl on the pure acrylic resin and an N-H bond of the primer form a hydrogen bond to promote the adhesive force of the primer on the primer; the nail body refers to the nail body, and is relative to the nail protector, the nail body is added on the nail during nail beautifying, and then the nail body can be decorated on the nail protector, the nail body of the human body, namely the nail body belongs to the connective tissue, the main component of the nail body is keratin, contains more N-H bonds, and has the characteristic of being harder than other human body tissues.
6. It is important to note that the component levels of the present invention are obtained through creative efforts and are not routine choices in the art for the following reasons: when the titanate coupling agent or the pure acrylic resin is excessive, the RO-bond of the titanate is easy to react with the N-H bond of the pure acrylic resin, the RO-bond and the N-H bond which actually occur with the nail surface are reduced, and the adhesion of the primer on the nail surface is reduced; when the titanate coupling agent or the pure acrylic resin is too little, the ideal effect cannot be achieved at all; in summary, the titanate coupling agent or the pure acrylic resin is beneficial to be attached to the surface of the present armor, if the amount of the titanate coupling agent or the pure acrylic resin is moderate, and the excessive or insufficient amount of the titanate coupling agent or the pure acrylic resin can be adverse, which is also the result of a great deal of experiments and creative work performed by the inventor.
7. Meanwhile, in order to increase the flexibility, the elongation at break and the tensile strength of the primer, the epoxy acrylate with high compound hardness and high tensile strength and the aliphatic polyurethane acrylate with good flexibility and certain tensile strength are selected, so that the flexibility and the tensile strength of the primer are improved on the premise of ensuring the adhesive force; the product of the invention has good elongation at break and tensile strength, and the viscosity is 1000 cps-40000 cps (25 ℃);
8. according to the invention, the viscosity of the primer is adjusted through the type and the dosage of the acrylate monomer, when the viscosity of the system is higher than 40000cps (25 ℃), the prepolymer in the primer is tightly wound, the primer cannot effectively wet the nail, although the tensile strength is improved, the adhesion capability is reduced, and the function of the nail primer is lost.
In addition, in the nail beautifying process, the primer is firstly adhered to the nail surface, and then the color glue is coated on the primer after curing, so that the adhesion firmness of the color glue on the nail surface is prolonged, and the color glue is adhered to the nail surface for as long as possible.
Detailed Description
The present invention will be further described with reference to the following examples.
Example 1
A preparation method of solvent-free primer for colored drawing nails comprises (1) stirring photoinitiator-184, TPO and acrylate monomer at 2000r/min for 20min, dissolving and mixing uniformly; (2) under the condition of stirring, adding aliphatic polyurethane acrylate, epoxy acrylate, titanate coupling agent, pure acrylic resin and flatting agent, and stirring at 2000r/min for 25min until the components are uniformly mixed; (3) adding a defoaming agent, stirring at 1000rpm for 10min, standing, filtering and discharging to obtain the solvent-free primer for the colored drawing nail. In the embodiment, the adopted components comprise 1 part of KR238S, 30 parts of CNUVE151, 20 parts of HS-230, 9.8 parts of DR-A801, 35 parts of UDMA, 1 part of photoinitiator-184, 3 parts of TPO, 0.1 part of BYK333 and 0.1 part of BYK-1794.
Comparative example 1A
The nail primer in this comparative example is a conventional nail primer, which may be a primer of a conventional composition in the prior art, or a primer of a common commercial product on the market, such as a nail primer of Emma Hardie, and the like, and in this comparative example, an acrylic oligomer of the nail primer, which is manufactured using monomers of an alkyl (meth) acrylate, a (meth) acrylic acid, a (meth) acrylate having an alkoxysilyl group, and a (meth) acrylate having a hydroxyl group, has a glass transition temperature of-25 ℃ or less, a weight average molecular weight of 350 to 2000 or less, and a molecular weight distribution of 1.6 or less.
Example 2
A preparation method of solvent-free primer for colored drawing nails comprises (1) stirring photoinitiator-184, TPO and acrylate monomer at 1000r/min for 15min, dissolving and mixing uniformly; (2) under the condition of stirring, adding aliphatic polyurethane acrylate, epoxy acrylate, titanate coupling agent, pure acrylic resin and flatting agent, and stirring for 20min at 1000r/min until the materials are uniformly mixed; (3) adding a defoaming agent, standing at 1000rpm for 10min, filtering, and discharging to obtain the solvent-free primer for the colored drawing nail. In this example, the adopted ingredients specifically include 1 part of KR238S, 25 parts of HL-160, 30 parts of 2031, 9.8 parts of DR-A830, 30 parts of EOEOEA, 1 part of photoinitiator-184, 3 parts of TPO, 0.1 part of BYK3455, and 0.1 part of BYK-1798.
Comparative example 2A
The nail polish gel comprises the following components in parts by weight: 38-45 parts of 11, 14-dioxa-2, 9-diazepan-16-enoic-4, 4, 6, 16-tetramethyl-10, 15-dioxo-2- [ (2-methyl-1-oxo-2-propenyl) oxo ] ethyl ester; 0.02 to 0.04 part of a compound of formula I; 25-29 parts of acrylate oligomer; 2.4-2.9 parts of 1-hydroxycyclohexyl phenyl ketone; 2.5-3.1 parts of bis-phenylphosphine oxide (2, 4, 6-trimethylbenzoyl); 11-13 parts of hydroxyethyl methacrylate; 1.1-1.4 parts of triethanolamine; 0.7-0.8 part of laureth-21; 1.5-2.8 parts of mica.
Example 3
A preparation method of solvent-free primer for colored drawing nails comprises (1) stirring photoinitiator-184, TPO and acrylate monomer at 1000r/min for 15min, dissolving and mixing uniformly; (2) under the condition of stirring, adding aliphatic polyurethane acrylate, epoxy acrylate, titanate coupling agent, pure acrylic resin and flatting agent, and stirring for 20min at 1000r/min until the materials are uniformly mixed; (3) adding a defoaming agent, standing at 1000rpm for 10min, filtering, and discharging to obtain the solvent-free primer for the colored drawing nail. In the present example, the adopted components specifically include 1 part of KR238S, 30 parts of 6120G, 30 parts of 2752-8, 9.8 parts of DR-A840, 25 parts of DEGDMA, 1 part of photoinitiator-184, 3 parts of TPO, 0.1 part of BYK346, and 0.1 part of BYK-1794.
Comparative example 3A
A common nail primer purchased in the market.
The durability of the primer for the solvent-free colored drawing nail can reach 3 weeks or more than 3 weeks; the elongation at break is more than 7 percent; tensile strength >500 psi; the ISO grade of the one hundred grid test is 0; the viscosity is 1000cps to 40000cps at 25 deg.C. The comparative data and the effect data are shown in table 1.
TABLE 1 examples of the invention and comparative examples and their technical effects
| Smell(s) | Durability | Deep layer curing (viewing cured film) | b value (color difference meter measurement) | Tensile strength | |
| Example 1 | Is substantially odorless | 28 days | The film-forming reverse side is smooth and the luster is high | 5.67 | ＞500psi |
| Comparative example 1A | Slight taste | 9 days | Has convex points and high luster | 7.74 | 200psi |
| Example 2 | Is substantially odorless | 34 days | The film-forming reverse side is smooth and the luster is high | 0.22 | ＞500psi |
| Comparative example 2A | Slight taste | 7 days | Rendering speckle | 2.27 | 180psi |
| Example 3 | Has no taste | 33 days | The film-forming reverse side is smooth and the luster is high | 0.80 | ＞500psi |
| Comparative example 3A | Slight taste | 10 days | Wrinkling, discoloration and spots | 2.17 | 210psi |
The foregoing is only a preferred embodiment of the invention. It will be understood by those skilled in the art that the above embodiments are not intended to limit the present invention and any modifications, equivalent substitutions of parts and improvements made within the spirit and principle of the present invention are included in the scope of the present invention.
Claims (10)
1. The solvent-free primer for the colored drawing fingernails is characterized by comprising the following components:
titanate coupling agent- -0.5 to 1.5 parts,
25 to 30 parts of epoxy acrylic resin,
25-30 parts of aliphatic polyurethane acrylic resin,
3 to 10 parts of pure acrylic resin,
acrylate monomer of 25 to 35 parts,
photoinitiator-184-0.5 to 1.5 parts,
TPO-2 to 5 parts,
0.05 to 0.2 parts of flatting agent,
0.1 to 0.3 parts of defoamer;
the durability of the primer is more than 3 weeks; the primer has an elongation at break of >7%, a tensile strength of >500psi, and a viscosity of 1000cps to 40000cps at 25 ℃.
2. The solvent-free colored drawing primer for fingernails as defined in claim 1,
the titanate coupling agent is at least one of KR238S, KR12 and KR-TTS; the epoxy acrylic resin is at least one of CNUVE151, HL-160 and 6120G.
3. The solvent-free colored drawing primer for fingernails as defined in claim 2,
the aliphatic polyurethane acrylic resin is resin with the functionality of 2, and the aliphatic polyurethane acrylic resin is at least one of HS-230, 2031 and 2752-8; the pure acrylic resin is at least one of DR-A801, DR-A830 and DR-A840; the acrylate monomer is at least one of UDMA, EOEOEA and DEGDMA.
4. The solvent-free colored drawing primer for fingernails as defined in claim 3,
the leveling agent is at least one of BYK3455, BYK346 and BYK 333; the defoaming agent is at least one of BYK-1790, BYK-1798 and BYK-1794.
5. The solvent-free colored drawing primer for fingernails as defined in claim 4,
KR238S- -1 part,
CNUVE151- -25 parts,
HS-230-25 parts,
DR-A801-9.8 parts,
UDMA- -35 parts,
photoinitiator-184-1 part,
TPO- -3 parts,
BYK 333-0.1 part,
BYK-1794-0.1 part.
6. The method for preparing the solvent-free colored drawing primer for fingernails as defined in any one of claims 1 to 4,
(1) mixing photoinitiator-184, TPO and acrylate monomer solution;
(2) under the condition of stirring, adding aliphatic polyurethane acrylic resin, epoxy acrylic resin, titanate coupling agent, pure acrylic resin and flatting agent, and uniformly mixing;
(3) adding a defoaming agent and stirring to prepare the solvent-free primer for the colored drawing fingernails.
7. The method for preparing a solvent-free colored drawing primer for fingernails as defined in claim 6,
(1) selecting photoinitiator-184, TPO and acrylate monomers, stirring at 1000-2000 r/min, and dissolving and mixing uniformly;
(2) under the condition of stirring, adding aliphatic polyurethane acrylic resin, epoxy acrylic resin, titanate coupling agent, pure acrylic resin and flatting agent, and stirring and mixing uniformly at 1000 r/min-2000 r/min;
(3) adding a defoaming agent, controlling the stirring speed at 1000r/min, standing, discharging and obtaining the solvent-free primer for the colored drawing fingernails.
8. The method for preparing a solvent-free colored drawing primer for fingernails as defined in claim 7,
(1) selecting photoinitiator-184, TPO and acrylate monomers, stirring for 15-20 min at 1000-2000 r/min, and dissolving and mixing uniformly;
(2) under the condition of stirring, adding aliphatic polyurethane acrylic resin, epoxy acrylic resin, titanate coupling, pure acrylic resin and a flatting agent, and stirring for 20-25 min at 1000-2000 r/min until the materials are uniformly mixed;
(3) adding a defoaming agent, controlling the stirring speed at 1000r/min, stirring for 10min, standing, filtering and discharging to obtain the solvent-free primer for the colored drawing fingernails.
9. The method for preparing the solvent-free type primer for color-drawing nails according to claim 7, wherein the durability of the prepared solvent-free type primer for color-drawing nails is 3 weeks or more; elongation at break > 7%; tensile strength >500 psi; the ISO grade of the one hundred grid test is 0; the viscosity is 1000cps to 40000cps at 25 deg.C.
10. Use of the solvent-free type colored drawing primer for fingernails according to any one of claims 1 to 5 or the solvent-free type colored drawing primer for fingernails prepared by the preparation method according to any one of claims 6 to 9 as a nail primer for colored drawing.
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| CN110540807A (en) * | 2019-09-23 | 2019-12-06 | 浙江新空气工艺品有限公司 | glue for nail paster |
| CN110547978A (en) * | 2019-10-18 | 2019-12-10 | 广东昊辉新材料有限公司 | primer for nail beautification and preparation method thereof |
| CN111265428A (en) * | 2020-01-21 | 2020-06-12 | 浙江风尚化妆品有限公司 | Carved glue and synthesis process thereof |
| CN113304070A (en) * | 2021-06-16 | 2021-08-27 | 广州蓝之天化工科技发展有限公司 | High-gloss low-yellowing wash-free sealing layer and preparation method thereof |
| CN114891436A (en) * | 2022-05-31 | 2022-08-12 | 河源魅思新材料有限公司 | LED-UV bonding agent and preparation method and application thereof |
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| CN1694678A (en) * | 2002-10-02 | 2005-11-09 | 奥里尔股份有限公司 | Composition for application to the skin and skin covering |
| CN103751036A (en) * | 2014-01-14 | 2014-04-30 | 广东美涂士建材股份有限公司 | UV (Ultraviolet) nail phototherapy gel and preparation method thereof |
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| US20050065297A1 (en) * | 2003-09-22 | 2005-03-24 | American International Industries | Radiation curable nail polish |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1694678A (en) * | 2002-10-02 | 2005-11-09 | 奥里尔股份有限公司 | Composition for application to the skin and skin covering |
| CN103751036A (en) * | 2014-01-14 | 2014-04-30 | 广东美涂士建材股份有限公司 | UV (Ultraviolet) nail phototherapy gel and preparation method thereof |
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