CN112336647A - Nail-beautifying anti-overflow glue based on aqueous polyurethane dispersion - Google Patents
Nail-beautifying anti-overflow glue based on aqueous polyurethane dispersion Download PDFInfo
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- CN112336647A CN112336647A CN201910723469.0A CN201910723469A CN112336647A CN 112336647 A CN112336647 A CN 112336647A CN 201910723469 A CN201910723469 A CN 201910723469A CN 112336647 A CN112336647 A CN 112336647A
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- nail
- aqueous polyurethane
- polyurethane dispersion
- overflow glue
- beautifying
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
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Abstract
The invention discloses a nail-beautifying anti-overflow glue based on an aqueous polyurethane dispersion, which is prepared from the following components in percentage by weight: (a) 73.5-97.5% of an aqueous polyurethane dispersion; (b) 0-1% of a thickening agent; (c) 0-10% of a humectant; (d) 0.5-2% of silicon dioxide; (e) 2-10% of water-soluble silicone oil; (f) 0-0.5% of a preservative; (g) 0-3% of essence. Evenly film around the nail skin evenly when this anti-overflow is glued and is used, paints the operation of nail polish after the dry film forming again, and beautiful first back that finishes can relax peels off this anti-overflow is glued the film forming, and the nail polish that overflows when will painting peels off in the lump, does not have to tear and draws painful sense, and the skin feels not tight, does not have and remains, can effectively prevent the excessive of nail polish at beautiful first in-process, protects skin around the nail margin, makes the beautiful first process convenient more healthy environmental protection again.
Description
Technical Field
The invention relates to nail-beautifying anti-overflow glue, in particular to nail-beautifying anti-overflow glue based on an aqueous polyurethane dispersion.
Background
Nowadays, with the improvement of life quality and the pursuit of beauty of people, more and more women pursue nail beauty in various colors and shapes. However, in the nail art, it is inevitable to apply nail polish to the skin of the nail margin other than the nails due to the necessity of shaping or due to the level of the person who carries out nail art. In order to remove the overflowing nail polish, cotton balls soaked with nail polish remover are generally used for wiping off the nail polish, so that the nail polish which is well beautified is easily wiped, and substances such as acetone, toluene and the like in the nail polish are in long-term contact with the nail polish, so that respiratory tract health and nail-edge skin are greatly damaged.
In order to solve the problem of nail polish overflow, many technicians have provided solutions, and CN201730022216.2 discloses an anti-overflow clip, which is clipped to the edge of the nail by a plastic clip to prevent nail polish overflow, and similarly, a nail polish overflow preventing paste is used to prevent nail polish overflow. However, the clip or the sticker with the fixed shape cannot be attached to the nail margins of different shapes of everyone in percentage, and a gap is easily formed between the clip or the sticker and the skin, so that the nail polish cannot be completely prevented from overflowing.
Therefore, in the actual operation process, a product capable of effectively preventing nail polish from overflowing during nail beautifying is urgently needed to be invented, the nail beautifying operation difficulty is reduced, the nail beautifying process is simplified, the nail margin skin is protected, and the nail beautifying process is convenient and safer.
Disclosure of Invention
The invention aims to provide nail-beautifying anti-overflow glue, which is moisturizing nail-beautifying anti-overflow glue based on an aqueous polyurethane dispersion, and the anti-overflow glue takes the aqueous polyurethane dispersion as a main component and is optionally matched with a thickening agent, a humectant, silicon dioxide, water-soluble silicone oil, a preservative, essence and the like. Evenly film the skin around the nail during use, the operation of paining nail polish is carried out again after the dry film forming, and the beautiful nail finishes the back, can relax peel off this anti-overflow glue film forming, and the nail polish that overflows when will paining peels off in the lump, does not have the sense of tightness, does not have to tear and draws painful sense, and is not remained, can effectively prevent the excessive of nail polish at beautiful nail in-process, protects skin around the nail margin, makes the beautiful nail process not only convenient but also more healthy environmental protection.
In order to achieve the above purpose, the technical scheme of the invention is as follows:
a nail-beautifying anti-overflow glue based on an aqueous polyurethane dispersion is prepared from the following components in percentage by weight:
(a) 73.5-97.5% of an aqueous polyurethane dispersion;
(b) 0-1% of a thickening agent;
(c) 0-10% of a humectant;
(d) 0.5-2% of silicon dioxide;
(e) 2-10% of water-soluble silicone oil;
(f) 0-0.5% of a preservative;
(g) 0-3% of essence.
The nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion disclosed by the invention is characterized in that (a) the aqueous polyurethane dispersion is an aqueous polyurethane dispersion synthesized by HMDI, the aqueous polyurethane dispersion is an aliphatic aqueous polyurethane dispersion with the effective component content (solid content) of 20-60 wt% and the particle diameter of 10-200 nm, the mixture of polyurethane-35 and polyurethane-11 is preferably selected under the cosmetic raw material name (INCI name), and more preferably is selected under the cosmetic raw material name
ST11(INCI name: polyurethane-35 (and) polyurethane-11, Vanhua chemical group, Inc.). It has been found that the aqueous polyurethane dispersions synthesized by HMDI have excellent ductility and elasticity, and the preferred polyurethane dispersions are used for nail-beautifying anti-spill glue, and the formed film has good elasticity and is not easy to break when peeled off.
The nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion comprises (b) a thickening agent, wherein the thickening agent is one or more of HEUR thickening agents, acrylic acid thickening agents, cellulose, diatomite, carbomer, starch, gelatin, sodium alginate, guar gum, gum arabic, xanthan gum, soy protein gum and agar, and preferably comprises 0-0.1 wt% of xanthan gum and 0.1-0.3 wt% of HEUR thickening agents (the HEUR thickening agents are preferably selected from HEUR thickening agents)
9240NP, Vanhua chemical group Co., Ltd.) based on the total mass of the raw materials. The thickening agent with the optimal proportion can adjust the viscosity of the nail-beautifying anti-overflow glue, can be uniformly and thinly applied to the skin at the nail margin when in use, and is not easy to drip.
The nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion is characterized in that the humectant (c) is a water-soluble humectant commonly used in the cosmetic field such as glycerin, urea, propylene glycol, 1, 3-butanediol and the like, and preferably 0.5-3 wt% of 1, 3-butanediol and 0.5-2.0 wt% of glycerin are compounded for use, based on the total mass of raw materials. The humectant with the optimal proportion has good compatibility with the aqueous polyurethane dispersoid and low cost.
According to the nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion, the silicon dioxide (d) is hydrophilic silicon dioxide with the particle size of less than 100nm, and the preferable addition amount is 0.7-1.5 wt%. The optimized silicon dioxide has low cost, plays a role of a pigment and a filler in a formula, and is interpenetrated among polymer particles during film forming, so that the crosslinking during the film forming of the polymer can be reduced, the tight feeling after the film forming is reduced, and the skin feeling after the film forming is more comfortable.
The moisturizing nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion is characterized in that (e) water-soluble silicone oil is polydimethylsiloxane, polymethylphenylsiloxane, polydimethylsiloxane, aminosilicone oil and the like, and the polydimethylsiloxane is preferred; the amount of the water-soluble silicone oil is preferably 3-8 wt%. The water-soluble silicone oil with the optimal proportion has good compatibility with the formula, and plays a role of a 'mold release agent' in the formula, so that the anti-overflow nail polish glue is easier to tear.
The moisture-preserving nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion is characterized in that the preservative (f) is preferably a broad-spectrum preservative.
The moisturizing nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion is characterized in that the essence (g) is water-soluble essence.
The preparation method of the moisturizing nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion comprises the following steps: according to the component proportion in the formula, the water-based polyurethane dispersion is taken as a main component, and other components such as thickening agent, humectant, silicon dioxide, water-soluble silicon oil and the like are added to be stirred and mixed uniformly to obtain the water-based polyurethane water-based paint.
The specific operation method of the nail-beautifying anti-overflow glue of the invention is as follows: the nail polish preventing glue is evenly smeared on skin around a nail before the nail polish is smeared, after the nail polish is smeared after the nail polish is dried and formed into a film for about 30-60 seconds, the nail polish is smeared again, after the nail polish is finished, the nail polish preventing glue can be easily stripped into the film, the nail polish overflowing during smearing is stripped, no tearing pain and no residue are caused, and the nail polish can be effectively prevented from overflowing in the nail polish process.
The method is convenient and rapid, the waterborne polyurethane dispersion does not cause damage to the skin around the nail, the components such as the humectant, the silicon dioxide, the water-soluble silicone oil and the like are added into the formula, so that the nail can be beautified, the anti-overflow effect can be realized, the moisturizing and skin-care effects can be realized, the tightness and the viscosity of the anti-overflow glue are reduced, the nail can be torn off easily, multiple purposes are realized, and the nail beautifying process is convenient, healthy and environment-friendly.
Compared with the prior art, the nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion has the following advantages:
the aqueous polyurethane dispersion has the characteristics of good film-forming elasticity, good toughness, non-sticky hand feeling and good tearing property, is different from the defects that the film-forming agent PVA \ PVP and the like used for the traditional cosmetics are difficult to peel when forming a film on skin, can be coated on the nail margin skin in a smearing mode when being applied to nail-beautifying anti-overflow glue, can completely fit the nail margins of different shapes of everyone compared with clips and stickers with fixed shapes,
convenient to use is swift, can laminate everyone's different natures the nail reason completely, does not have to tear and draws painful sense, and is not tight, and is not remained, and is healthy environmental protection, can effectively prevent the excessive of nail polish at first beautiful in-process.
Detailed Description
The following further illustrates the invention by way of specific examples, which should not be construed as limiting the invention.
The raw materials used in the examples:
Polyvinyl alcohol (INCI name: polyvinyl alcohol PVA, Beijing Entrepaneur Science & tracing Co., Ltd.)
xanthan gum (thickener, Zhengzhou Hongyutai chemical industry);
glycerol (humectant, Shanghai flower king)
1, 3-butanediol (humectant, Japan empire chemical)
Silicon dioxide (pigment and filler, German Wake)
Polydimethylsiloxane (Silicone oil, dao kang Ning)
TCW2890404 (essence, lihua essence ltd);
dmdmdmh (preservative, dow chemical).
The nail-beautifying spill-proof glue of the examples and the comparative examples is prepared by the following method: according to the proportion, the aqueous polyurethane dispersion and other components such as thickening agent, humectant, silicon dioxide, water-soluble silicon oil and the like are stirred and mixed uniformly.
Table 1 example each raw material part by mass of nail-beautifying anti-overflow glue
Table 2: raw material parts by mass of comparative example nail-beautifying anti-overflow glue
Test method
A. Drying speed
The prepared nail-beautifying anti-overflow glue is dipped by a small nail polish brush in an environment with the temperature of 25 ℃ and the humidity of 50 percent, is smeared on the skin, and the drying time is tested and recorded by a finger touch method. Preferably, the inner surface is dried for 60 seconds.
B. Spreadability
The prepared nail-beautifying anti-overflow glue is dipped by a small nail polish brush in an environment with the temperature of 25 ℃ and the humidity of 50 percent, and is smeared on the skin at the nail margin, and the smearing uniformity is scored by 10 testers.
C. Peelability of
The prepared nail polish anti-overflow glue is dipped by a small nail polish brush in an environment with the temperature of 25 ℃ and the humidity of 50 percent and is smeared on the skin at the nail margin, and 10 testers score the stripping performance of the nail polish anti-overflow glue after drying and film forming.
D. Skin feel
The prepared nail polish anti-overflow glue is dipped by a small nail polish brush in an environment with the temperature of 25 ℃ and the humidity of 50 percent and is smeared on the skin of the nail margin, and the skin feel of the nail polish anti-overflow glue after being dried and formed into a film is scored by 10 testers.
TABLE 3 sensory evaluation index and score table
Table 4: EXAMPLES evaluation results
Table 5: comparative example evaluation results
From the above results, it can be seen that: the moisturizing nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion disclosed by the invention is uniformly coated on the skin at the edge of a nail when in use, is high in drying speed and good in smearing property, can be easily stripped into a film after the nail is beautified, can strip off the nail polish overflowing during nail beautifying, has no tearing pain, has no tight skin feeling and no residue, can effectively prevent the nail polish from overflowing during nail beautifying, protects the skin around the nail edge, and enables the nail beautifying process to be convenient and more healthy and environment-friendly.
Claims (7)
1. A nail-beautifying anti-overflow glue based on an aqueous polyurethane dispersion is characterized by comprising the following components in percentage by weight:
(a) 73.5-97.5% of an aqueous polyurethane dispersion;
(b) 0-1% of a thickening agent;
(c) 0-10% of a humectant;
(d) 0.5-2% of silicon dioxide;
(e) 2-10% of water-soluble silicone oil;
(f) 0-0.5% of a preservative;
(g) 0-3% of essence.
2. The aqueous-based composition of claim 1The nail-beautifying anti-overflow glue of polyurethane dispersoid is characterized in that the (a) aqueous polyurethane dispersoid is an aqueous polyurethane dispersoid synthesized by HMDI, the content of the effective component is 20-60 wt%, the particle diameter is 10-200 nm, the mixture of the cosmetic raw materials named as polyurethane-35 and polyurethane-11 is preferred, and the mixture of Wanhua chemical group company Limited is more preferred
ST11。
3. The nail polish-based anti-overflow glue based on the aqueous polyurethane dispersion according to claim 1 or 2, wherein the thickener (b) is one or more of HEUR thickeners, acrylic acid thickeners, cellulose, diatomite, carbomer, starch, gelatin, sodium alginate, guar gum, gum arabic, xanthan gum, soy protein gum and agar, preferably xanthan gum with the mass percentage of 0-0.1 wt% and HEUR thickeners with the mass percentage of 0.1-0.3 wt% based on the total mass of raw materials.
4. The nail polish anti-overflow glue based on the aqueous polyurethane dispersion according to any one of claims 1 to 3, wherein the humectant (c) is one or more of glycerin, urea, propylene glycol and 1, 3-butanediol, preferably 0.5 to 3 wt% of 1, 3-butanediol and 0.5 to 2.0 wt% of glycerin are compounded based on the total mass of raw materials.
5. The nail-beautifying anti-overflow glue based on the aqueous polyurethane dispersion according to any one of claims 1 to 4, characterized in that the silicon dioxide (d) is hydrophilic silicon dioxide with the particle size of less than 100nm, and the addition amount is 0.7-1.5 wt%.
6. The nail polish remover according to any one of claims 1 to 5, wherein the water-soluble silicone oil (e) is one or more of polydimethylsiloxane, polymethylphenylsiloxane, polydimethylsiloxane and aminosilicone, preferably polydimethylsiloxane; the amount of the water-soluble silicone oil is preferably 3-8 wt%.
7. A process for preparing the aqueous polyurethane dispersion-based nail-care flash gum of any one of claims 1 to 6, comprising: the components are uniformly mixed to obtain the product.
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| CN201910723469.0A CN112336647B (en) | 2019-08-07 | 2019-08-07 | Nail-beautifying anti-overflow glue based on aqueous polyurethane dispersion |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113616554A (en) * | 2021-07-07 | 2021-11-09 | 河源魅思新材料有限公司 | Nail polish gel nail polish removing cream and preparation method thereof |
| CN113682033A (en) * | 2021-09-06 | 2021-11-23 | 越达光电科技(浙江)有限公司 | Display screen full-lamination method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113616554A (en) * | 2021-07-07 | 2021-11-09 | 河源魅思新材料有限公司 | Nail polish gel nail polish removing cream and preparation method thereof |
| CN113616554B (en) * | 2021-07-07 | 2024-03-15 | 河源魅思新材料有限公司 | Nail polish gel nail polish remover paste and preparation method thereof |
| CN113682033A (en) * | 2021-09-06 | 2021-11-23 | 越达光电科技(浙江)有限公司 | Display screen full-lamination method |
| CN113682033B (en) * | 2021-09-06 | 2023-06-16 | 越达光电科技(浙江)有限公司 | Full-lamination method for display screen |
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| CN112336647B (en) | 2023-01-13 |
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