CN106137790A - Three-in-one ultraviolet light efficiency gel for finger paint and preparation method thereof - Google Patents
Three-in-one ultraviolet light efficiency gel for finger paint and preparation method thereof Download PDFInfo
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- CN106137790A CN106137790A CN201510158556.8A CN201510158556A CN106137790A CN 106137790 A CN106137790 A CN 106137790A CN 201510158556 A CN201510158556 A CN 201510158556A CN 106137790 A CN106137790 A CN 106137790A
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- light efficiency
- ultraviolet light
- efficiency gel
- acrylate
- finger paint
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Abstract
The invention discloses a kind of three-in-one ultraviolet light efficiency gel for finger paint, the component formula mass ratio of described three-in-one ultraviolet light efficiency gel is: low functional polyurethanes acrylate: 10～70%, low functionalized propylene's acid monomers: 15～55%, polyfunctional acrylic monomer: 5～25%, high official energy urethane acrylate: 10～20%, light trigger: 0.5～10%, anti-settling thixotropic agent: 0.2～3%, granule surface contral auxiliary agent: 0.05～5%.The invention also discloses the preparation method of a kind of above-mentioned three-in-one ultraviolet light efficiency gel.The present invention has that preparation technology is simple, product environmental protection, use advantage simple to operate, that adhesive force is excellent, color saturation is high, brightness persistency is good.
Description
Technical field
The present invention relates to finger paint technical field, be especially a kind of three-in-one ultraviolet light efficiency gel for finger paint and preparation method thereof.
Background technology
Nial polish is the one of color make-up, is coated on fingernail and can make henna gorgeous moist and the most colour-fast, is liked by people；The thin film that nial polish is formed after being applied to fingernail, strong and have appropriateness coloring gloss, fingernail can be protected, again give fingernail one aesthetic feeling.
At present, traditional nial polish contains substantial amounts of solvent, and such as ethyl acetate, toluene, acetone etc., these are harmful substance, not only pollutes the environment, endangers health, and curing rate is slow, and attachment persistency is poor, easily comes off.The advantages such as then, someone have developed ultraviolet light efficiency gel products, overcomes disadvantages mentioned above, has environment friendly and pollution-free, and curing rate is fast, and attachment persistency is good, difficult drop-off, high brightness.
But, ultraviolet light efficiency gel products emerged in an endless stream in recent years, but was mostly " three step nial polishs ", i.e. comprised the bonding primer of fingernail, the color glue played role in decoration and the auxiliary products such as gloss varnish for the protection of first face, the complex steps when of operation.And can have the ultraviolet light efficiency gel of three-in-one function in the market simultaneously, all have that poor adhesive force, color saturation be poor, easy to fall off, the shortcoming of brightness persistency difference.
Summary of the invention
In view of the defect of above-mentioned prior art, it is an object of the invention to: a kind of simple to operate, adhesive force is excellent, color saturation is high, brightness persistency is good three-in-one ultraviolet light efficiency gel for finger paint is provided.
The technical solution of the present invention is: for the three-in-one ultraviolet light efficiency gel of finger paint, the component formula mass ratio of described three-in-one ultraviolet light efficiency gel is: low functional polyurethanes acrylate: 10～70%, low functionalized propylene's acid monomers: 15～55%, polyfunctional acrylic monomer: 5～25%, high official energy urethane acrylate: 10～20%, light trigger: 0.5～10%, anti-settling thixotropic agent: 0.2～3%, granule surface contral auxiliary agent: 0.05～5%.
Further, low functional polyurethanes acrylate contains 2～3 acrylic-functionals.
Further, low functionalized propylene's acid monomers contains 1～2 acrylic acid or unsaturated double-bond functional group, including one or more in hydroxyethyl methylacrylate, isobornyl acrylate, isobornyl methacrylate, tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, acryloyl morpholine, trimethylcyclohexyl acrylate, propylene glycol diacrylate, tripropylene glycol diacrylate, neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate, ethoxylated bisphenol a diacrylate, Tricyclodecane Dimethanol diacrylate.
Further, polyfunctional acrylic monomer contains 3 or more than 3 acrylic acid or unsaturated double-bond functional group, including one or more in pentaerythritol triacrylate, dipentaerythritol acrylate, trimethylolpropane trimethacrylate and ethoxyquin and the third oxidized derivatives, tetramethylol methane tetraacrylate and ethoxyquin and the third oxidized derivatives.
Further, high official can contain 4～9 acrylic-functionals by urethane acrylate.
Further; light trigger is cracking type free radical photo-initiation; derivant and acyl group phosphorous oxides including alpha-alcohol ketone: 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenylacetone, triethyl phosphate, 2,4,6-trimethylbenzoy-dipheny phosphine oxides.
Further, one or more during anti-settling thixotropic agent is polyamide wax, aerosil, modified urea.
Further, described granule surface contral auxiliary agent is one or more in substrate wetting agents, defoamer, levelling agent, essence, mill base, pearl essence.
It is a further object of the present invention to provide the preparation method of a kind of three-in-one ultraviolet light efficiency gel for finger paint, comprise the following steps:
(1) weigh each material by proportioning raw materials, add in vacuum stirring pot；
(2) stirring throwing raw material under the rotating speed of 800～9000 revs/min, the temperature in vacuum stirring pot is 35～75 DEG C, and pressure is-0.08MPa～-0.1MPa；
(3) sampling inspection, filters discharging after the assay was approved, is mixed colours by base material, packs after having mixed colours.
The invention has the beneficial effects as follows: preparation technology is simple, product environmental protection, use simple to operate, adhesive force is excellent, color saturation is high, brightness persistency is good.
Detailed description of the invention
For comparing intuitively, being fully understood by technical scheme, now carry out nonrestrictive feature description as follows:
Three-in-one ultraviolet light efficiency gel for finger paint, the component formula mass ratio of described three-in-one ultraviolet light efficiency gel is: low functional polyurethanes acrylate: 10～70%, hydroxyethyl meth acrylate: 15～55%, isobornyl acrylate: 5～25%, high official energy urethane acrylate: 10～20%, light trigger: 0.5～10%, anti-settling thixotropic agent: 0.2～3%, granule surface contral auxiliary agent: 0.05～5%.
Low functional polyurethanes acrylate contains 2～3 acrylic-functionals.
nullLow functionalized propylene's acid monomers contains 1～2 acrylic acid or unsaturated double-bond functional group，Including hydroxyethyl methylacrylate (HEMA)、Isobornyl acrylate (IBOA)、Isobornyl methacrylate (IBOMA)、Tetrahydrofurfuryl acrylate (THFA)、Tetrahydrofurfuryl methacrylate (THFMA)、Acryloyl morpholine (ACMO)、Trimethylcyclohexyl acrylate (TMCHA)、Propylene glycol diacrylate (DPGDA)、Tripropylene glycol diacrylate (TPGDA)、Neopentylglycol diacrylate (NPGDA)、Third oxidation neopentylglycol diacrylate (NPG2PODA)、Ethoxylated bisphenol a diacrylate (BPA3EODA)、One or more in Tricyclodecane Dimethanol diacrylate (DCPDA).
Polyfunctional acrylic monomer contains 3 or more than 3 acrylic acid or unsaturated double-bond functional group, including one or more in pentaerythritol triacrylate (PET3A), dipentaerythritol acrylate (DPHA), trimethylolpropane trimethacrylate (TMPTA) and ethoxyquin and the third oxidized derivatives, tetramethylol methane tetraacrylate (PET4A) and ethoxyquin and the third oxidized derivatives.
High official can contain 4～9 acrylic-functionals by urethane acrylate.
Light trigger is cracking type free radical photo-initiation; derivant and acyl group phosphorous oxides including being not limited to alpha-alcohol ketone: 184 (1-hydroxycyclohexyl phenyl ketone), 1173 (2-hydroxy-2-methyl-1-phenylacetones), TEPO (triethyl phosphate), TPO (2; 4,6-trimethylbenzoy-dipheny phosphine oxides).
Anti-settling thixotropic agent include being not limited to polyamide wax, aerosil, modified urea (BYK-410, LK-150) one or more, there is the resist sagging ability of excellence and anti-degradation capability, there is splendid result of prevention, the thixotropy of the present invention can be improved.
Granule surface contral auxiliary agent include be not limited to substrate wetting agents (BYK-348, TEGO-270), defoamer (TEGO-900, BYK-555), levelling agent (BYK-333, TEGO2100), essence, mill base, pearl essence, including one or more, there is ground lubrication and the flow leveling of excellence, there is good water solublity and oil-soluble, moreover it is possible to prevent the generation of the defect such as shrinkage cavity, Pericarpium Citri tangerinae.
It is a further object of the present invention to provide the preparation method of a kind of three-in-one ultraviolet light efficiency gel for finger paint, comprise the following steps:
(1) weigh each material by proportioning raw materials, add in vacuum stirring pot；
(2) stirring throwing raw material under the rotating speed of 800～9000 revs/min, the temperature in vacuum stirring pot is 35～75 DEG C, and pressure is-0.08MPa～-0.1MPa；
(3) sampling inspection, filters discharging after the assay was approved, is mixed colours by base material as required, pack, be finished product three-in-one ultraviolet light efficiency gel after having packed after having mixed colours.
The invention has the beneficial effects as follows: preparation technology is simple, product environmental protection, use simple to operate, adhesive force is excellent, color saturation is high, brightness persistency is good.
Certainly, these are only presently preferred embodiments of the present invention, non-the scope of the claims the most i.e. limiting to the present invention, all utilization description of the invention contents institute is simple for it modifies and equivalent structure change, within all should being in like manner contained in the scope of patent protection of the present invention.
Claims (9)
1. for the three-in-one ultraviolet light efficiency gel of finger paint, it is characterised in that: described three-in-one ultraviolet
The component formula mass ratio of light efficiency gel is: low functional polyurethanes acrylate: 10～70%, low functionalized propylene
Acid monomers: 15～55%, polyfunctional acrylic monomer: 5～25%, high official energy urethane acrylate: 10～20%,
Light trigger: 0.5～10%, anti-settling thixotropic agent: 0.2～3%, granule surface contral auxiliary agent: 0.05～5%.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
In: low functional polyurethanes acrylate contains 2～3 acrylic-functionals.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
In: low functionalized propylene's acid monomers contains 1～2 acrylic acid or unsaturated double-bond functional group, including metering system
Acid hydroxyl ethyl ester, isobornyl acrylate, isobornyl methacrylate, tetrahydrofurfuryl acrylate, four
Hydrogenation furfuryl group methacrylate, acryloyl morpholine, trimethylcyclohexyl acrylate, dipropylene glycol dipropyl
Olefin(e) acid ester, tripropylene glycol diacrylate, neopentylglycol diacrylate, the third oxidation neopentyl glycol two propylene
One or many in acid esters, ethoxylated bisphenol a diacrylate, Tricyclodecane Dimethanol diacrylate
Kind.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
3 or more than 3 acrylic acid or unsaturated double-bond functional group are contained in: polyfunctional acrylic monomer, including
Pentaerythritol triacrylate, dipentaerythritol acrylate, trimethylolpropane trimethacrylate and second
Oxidation and the one in the third oxidized derivatives, tetramethylol methane tetraacrylate and ethoxyquin and the third oxidized derivatives
Or it is multiple.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
In: high official can contain 4～9 acrylic-functionals by urethane acrylate.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
In: light trigger is cracking type free radical photo-initiation, including derivant and the acyl group phosphorus oxidation of alpha-alcohol ketone
Thing: 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenylacetone, triethyl phosphate, 2,4,6-
Trimethylbenzoy-dipheny phosphine oxide.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
In: anti-settling thixotropic agent is one or more in polyamide wax, aerosil, modified urea.
Three-in-one ultraviolet light efficiency gel for finger paint the most according to claim 1, its feature exists
In: described granule surface contral auxiliary agent be substrate wetting agents, defoamer, levelling agent, essence, mill base, pearl essence,
In one or more.
9. it is used for the preparation method of the three-in-one ultraviolet light efficiency gel of finger paint, it is characterised in that include following
Step:
(1) weigh each material by proportioning raw materials, add in vacuum stirring pot；
(2) stir throwing raw material under the rotating speed of 800～9000 revs/min, the temperature in vacuum stirring pot
Degree is 35～75 DEG C, and pressure is-0.08MPa～-0.1MPa；
(3) sampling inspection, filters discharging after the assay was approved, is mixed colours by base material, packs after having mixed colours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510158556.8A CN106137790A (en) | 2015-04-02 | 2015-04-02 | Three-in-one ultraviolet light efficiency gel for finger paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510158556.8A CN106137790A (en) | 2015-04-02 | 2015-04-02 | Three-in-one ultraviolet light efficiency gel for finger paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106137790A true CN106137790A (en) | 2016-11-23 |
Family
ID=57337541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510158556.8A Pending CN106137790A (en) | 2015-04-02 | 2015-04-02 | Three-in-one ultraviolet light efficiency gel for finger paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106137790A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107569403A (en) * | 2017-08-02 | 2018-01-12 | 珠海市傲博化妆品有限公司 | It is a kind of can alcohol removal nail polish glue and preparation method thereof |
| CN114224783A (en) * | 2021-12-27 | 2022-03-25 | 东阳市柯芮生物科技有限公司 | Novel nail polish gel and preparation method thereof |
| CN115991948A (en) * | 2022-12-09 | 2023-04-21 | 南雄市沃太化工有限公司 | UV-LED cured additive base adhesive and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101164516A (en) * | 2007-09-06 | 2008-04-23 | 湖南阳光新材料有限公司 | Weak ultraviolet curing composition |
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
-
2015
- 2015-04-02 CN CN201510158556.8A patent/CN106137790A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101164516A (en) * | 2007-09-06 | 2008-04-23 | 湖南阳光新材料有限公司 | Weak ultraviolet curing composition |
| CN102766399A (en) * | 2012-07-31 | 2012-11-07 | 上海零玖科技有限公司 | Gel polish, LED gel polish and LED nail polish |
Non-Patent Citations (1)
| Title |
|---|
| 吕延晓: "UV光固化在指甲美容中的应用-"光疗美甲"", 《精细与专用化学品》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107569403A (en) * | 2017-08-02 | 2018-01-12 | 珠海市傲博化妆品有限公司 | It is a kind of can alcohol removal nail polish glue and preparation method thereof |
| CN107569403B (en) * | 2017-08-02 | 2020-05-22 | 珠海市傲博化妆品有限公司 | Nail polish gel capable of being removed by alcohol and preparation method thereof |
| CN114224783A (en) * | 2021-12-27 | 2022-03-25 | 东阳市柯芮生物科技有限公司 | Novel nail polish gel and preparation method thereof |
| CN115991948A (en) * | 2022-12-09 | 2023-04-21 | 南雄市沃太化工有限公司 | UV-LED cured additive base adhesive and preparation method thereof |
| CN115991948B (en) * | 2022-12-09 | 2024-03-08 | 南雄市沃太化工有限公司 | UV-LED cured additive base adhesive and preparation method thereof |
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Application publication date: 20161123 |
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