CN102754650A - Desflurane bacteria amide compound bactericide - Google Patents
Desflurane bacteria amide compound bactericide Download PDFInfo
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- CN102754650A CN102754650A CN 201210272792 CN201210272792A CN102754650A CN 102754650 A CN102754650 A CN 102754650A CN 201210272792 CN201210272792 CN 201210272792 CN 201210272792 A CN201210272792 A CN 201210272792A CN 102754650 A CN102754650 A CN 102754650A
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- acid amides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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Abstract
The invention provides a desflurane bacteria amide compound bactericide which comprises active components of 1-50 percent of desflurane bacteria amide and 1-45 percent of (E,Z)-4-[3-(4-chlorphenyl)3-(3,4- dimethoxyphenyl) acryloyl]drewamine. The desflurane bacteria amide composite bactericide disclosed by the invention has the advantages of improved sterilizing effect and synergism.
Description
Technical field
The present invention relates to agricultural chemicals, is a kind of fluorine ether bacterium acid amides composite bactericide.
Background technology
Applicant's fluorine ether bacterium acid amides bactericide, clearly record has the good sterilization effect in the CN201010274196.5 file, and has the therapeutic activity height, and the ability to ward off risks is strong, and the lasting period is long, low cost and other advantages.The applicant further discovers, this bactericide and known bactericide compounded, and its bactericidal effect is better.
Summary of the invention
The purpose of this invention is to provide a kind of fluorine ether bacterium acid amides composite bactericide, make it have the advantage that improves bactericidal effect, synergy.
The present invention is for realizing above-mentioned purpose; Realize through following technical scheme: a kind of fluorine ether bacterium acid amides composite bactericide, its active ingredient be fluorine ether bacterium acid amides with (E, Z)-4-[3-(4-chlorphenyl) 3-(3; The 4-Dimethoxyphenyl) acryloyl] morpholine; Fluorine ether bacterium acid amides be 1-50%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 1-45%.
Described a kind of fluorine ether bacterium acid amides composite bactericide, its active ingredient be fluorine ether bacterium acid amides be 10-40%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 10-20%.
Described a kind of fluorine ether bacterium acid amides composite bactericide, its active ingredient be fluorine ether bacterium acid amides be 15-25%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 15-20%.
Described a kind of fluorine ether bacterium acid amides composite bactericide; The component of water dispersible granules is that fluorine ether bacterium acid amides is 10-40%, (E; Z)-4-[3-(4-chlorphenyl) 3-(3; The 4-Dimethoxyphenyl) acryloyl] morpholine is 12-20%, and dispersant is that 0.5-5%, wetting agent are that 0.5-5%, disintegrant are that 1-10%, adhesive are 0.5-5%, and surplus is a filler.
Described a kind of fluorine ether bacterium acid amides composite bactericide, the component of water dispersible granules is that fluorine ether bacterium acid amides is 20%, (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 40%, calcium lignosulfonate is 3%; Aliphatic alcohol sulfate is 5%; Ammonium sulfate is 8%, and hydroxyethylcellulose is 4%, and surplus is a kaolin.
Described a kind of fluorine ether bacterium acid amides composite bactericide, the component of water dispersible granules is that fluorine ether bacterium acid amides is 50%, (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 45%, alkyl sulfate is 0.5%; Nekal BX is 0.5%; Sodium alginate is 1%, and dextrin is 0.5%, and surplus is a bentonite.
Described a kind of fluorine ether bacterium acid amides composite bactericide, the component of water dispersible granules is that fluorine ether bacterium acid amides is 40%, (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 12%, aliphatic alcohol polyether is 5%; Aliphatic alcohol sulfate is 0.5%; Bentonite is 10%, and hydroxyethylcellulose is 0.5%, and surplus is a precipitated calcium carbonate.
Bactericidal composition of the present invention has very high biologically active to the Oomycete pathogen, and stronger permeability is arranged; Can permeate downwards from the blade upper surface, conduct to the blade tip direction, can protect blade not receive infection process after young shoot is handled from phyllopodium; Can distribute from root along the plant xylem to whole strain crop; Simultaneously, can destroy the formation of cell envelope, all there is effect in each stage of oomycetes history of life; The formation stage at sporangiophore and egg spore is particularly responsive, even under extremely low concentration, also can be suppressed.In Oomycete diseases such as control cucumber downy mildew, tomato late blight, wheat rust good effect is arranged, treatment and protection effect all can reach more than 90%, exceed about 30% than the preventive effect effect of independent use fluorine ether bacterium acid amides.
Embodiment
A kind of fluorine ether bacterium acid amides composite bactericide of the present invention; Its active ingredient is fluorine ether bacterium acid amides and (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine, fluorine ether bacterium acid amides is 1-50%, (E; Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 1-45%.
One of preferred scheme is: described a kind of fluorine ether bacterium acid amides composite bactericide, its active ingredient be fluorine ether bacterium acid amides be 10-40%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 10-20%.
Two of preferred scheme is: described a kind of fluorine ether bacterium acid amides composite bactericide, its active ingredient be fluorine ether bacterium acid amides be 15-25%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 15-20%.
Fluorine ether bacterium acid amides composite bactericide active ingredient according to the invention can have following multiple combination:
1, fluorine ether bacterium acid amides be 1%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 1%.
2, fluorine ether bacterium acid amides be 50%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 45%.
3, fluorine ether bacterium acid amides be 10%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 10%.
4, fluorine ether bacterium acid amides be 40%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 20%.
5, fluorine ether bacterium acid amides be 15%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 15%.
6, fluorine ether bacterium acid amides be 25%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 20%.
7, fluorine ether bacterium acid amides be 20%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 40%.
8, fluorine ether bacterium acid amides be 30%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 30%.
9, fluorine ether bacterium acid amides be 1%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 45%.
10, fluorine ether bacterium acid amides be 50%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 1%.
11, fluorine ether bacterium acid amides be 10%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 20%.
12, fluorine ether bacterium acid amides be 40%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 10%.
13, fluorine ether bacterium acid amides be 15%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 20%.
14, fluorine ether bacterium acid amides be 25%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 15%.
Of the present invention (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is hereinafter to be referred as dimethomorph.
Discover through the applicant; Fluorine ether bacterium acid amides in the fluorine ether bacterium acid amides composite bactericide according to the invention can also be composite with following compound: M 9834, white urea cyanogen; Cyprofuram, metalaxyl; Metalaxyl-M, fenfuram, Wakil; Aliette; Phosphorous acid or phosphorous acid disodium, carbendazim, tricyclazole, Tebuconazole, oxime bacterium ester, triazolone, phosethyl-Al, probenazole, thifluzamide, phonetic mould amine, Fluoxastrobin, nitrile bacterium azoles, thiophanate-methyl, own azoles alcohol, the mould prestige of second, procymidone, fluorine ring azoles, Flusilazole, Flutriafol, sodium dichloro cyanurate, rice blast acid amides, Isoprothiolane, kasugarnycin, propiconazole, Difenoconazole, benomyl, octicin solution, Prochloraz, prochloraz-manganese chloride complex, kresoxim-methyl, bitertanol, alkene azoles alcohol; Anilazine, difoltan, captan, tpn, Delan, Euparen, fentinacetate, come bacterium pellet, copper, Cupravit, iprodione, Kocide SD, copper acetate, asomate, network ammonia copper, sulphur, copper 8-hydroxyquinolinate, copper oxychloride (Cupravit), mancozeb, maneb, Carbatene, zineb, tmtd, ziram, two hot guanidine; Grandox fumigant, fenaminosulf 、 hymexazo, Propamocarb and hydrochloride thereof, prothiocarb, pcnb, cyanogen frost azoles.
Though the present invention is above-mentioned composite without crossing its effect of land for growing field crops evidence, discovering still has composite effect, all better than the result of use of single medicine.
Above-mentioned composite can in the scope of 1:20 to 10:1, the selection of the present invention.
Fluorine ether bacterium acid amides of the present invention can also be composite with following component: 1-(2-cyanic acid-2-methoxyimino acetyl group)-3-ethyl carbamide (white urea cyanogen); Methyl (E)-methoxyl group imido grpup-(E)-α-[1-(α, α-three fluoro-m-tolyl)-ethyleneimino oxygen base]-o-tolyl } ethyl acetate (oxime bacterium ester); Propyl group-3-(dimethylamino) propyl carbamic acid hydrochloride (propamocarb); (E)-2-{2-[6 (2-cyano-benzene oxygen) pyrimidine-4-base oxygen] phenyl }-3-methoxy acrylate (Fluoxastrobin); Methyl (N)-[[[1-(4-chlorobenzene) pyrazoles-3 base)-oxygen]-the 0-methoxyl group]-N-methoxymethyl carbamate (pyraclostrobin).
An advantage of fluorine ether bacterium acid amides composite bactericide of the present invention be synergistic effect or reduce pesticide resistance, another advantage is a broad spectrum of activity.
Fluorine ether bacterium acid amides composite bactericide of the present invention has protection concurrently, treats and roots out activity, is used for preventing and treating by the microbial disease of Oomycete cause of disease: downy mildew, late blight, white eqpidemic disease, rotten mildew, damping off, balck shank, canker, white blister, (millet) poliosis.The method that fluorine ether bacterium acid amides composite bactericide of the present invention is catched and killed fungi at the scene; Comprise with fluorine ether bacterium acid amides composite bactericide of the present invention and handle this place, the wherein on-the-spot plant of standing fungal attack, the seed of these plants or the medium of plant growing of comprising: fruit tree (apple tree, pear tree, oranges and tangerines, grape, lichee, pineapple, banana, watermelon); Cereal (wheat, barley, rye, oat, corn, paddy rice, Chinese sorghum, triticale and relevant crop); Beet (sugar beet and fodder beet); Leguminous plant (Kidney bean, kidney bean, pea, soybean); Oil crop (rape, leaf mustard, rape, sunflower, peanut); Cucumber plants (custard squash, cucumber, muskmelon); Fibre plant (cotton, flax, hemp, jute); Vegetables (spinach, lettuce, asparagus, wild cabbage, cauliflower, carrot, onion, tomato, potato, capsicum, ginger); And ornamental plants (flower, shrub, broad-leaved tree, evergreen tree such as coniferophyte).Suitable especially is cotton, corn, soybean, beet, cucumber plants and vegetables.
Control to by the microbial disease of Oomycete cause of disease such as downy mildew, late blight, white eqpidemic disease, rotten mildew, damping off, balck shank, canker, white blister, (millet) poliosis etc. has special efficacy.
Fluorine ether bacterium acid amides composite bactericide of the present invention can be mixed with granule, wetting powder, water dispersible granules, water-soluble granule, soluble concentrate, missible oil, aqueous emulsion, microemulsion, (water) but but suspending agent, microcapsule suspending agent dispersed oil suspending agent, suspension emulsion, seed treatment dispersion powder, seed treatment emulsion, suspension seed-coating agent.
The auxiliary material of said water dispersible granules is made up of dispersant, wetting agent, disintegrant, adhesive, filler; The acting in conjunction of each auxiliary material and mutual coordination not only make water dispersible granules have quick humidification property, disintegrative and good suspension property, suspension again; Have good stable property simultaneously and do not play performances such as dirt; And can also take to increase fluorine ether bacterium acid amides composite bactericide soup in the hold-up of plant surface, prolong the holdup time and improve purposes such as penetration capacity plant surface; Thereby improved the biologically active of fluorine ether bacterium acid amides composite bactericide; Reduced the using dosage of fluorine ether bacterium acid amides composite bactericide, reduced cost, alleviated pollution environment.
The dispersant kind that said water dispersible granules is commonly used mainly contains: cationic surfactants such as calcium lignosulfonate, naphthalene sulfonate, polycarboxylate, GY-D04, naphthalenesulfonic acid-formaldehyde condensate (NNO), fatty acid amide-N methyl taurine salt, alkyl sulfate, alkyl sulfo succinate, non-ionic surface active agents such as aliphatic alcohol polyether, alkyl phenol polyether; The wetting agent kind mainly contains: anionic surfactant (like aliphatic alcohol sulfate, dodecyl benzene sulfonate etc.) and nonionic (like peregal, agricultural newborn 100#, agricultural newborn 600# tween, sorbitol polyoxyethylene ether etc.), Nekal BX; The adhesive kind mainly contains: hydroxyethylcellulose, soluble starch, polyethylene glycol, methylcellulose, dextrin, polyvinyl alcohol, fructose; The principal item of disintegrant has: ammonium sulfate, urea, polyvinylpyrrolidone, sodium sulphate, starch and derivative thereof, cellulose, sodium bicarbonate, sldium lauryl sulfate, sodium alginate, bentonite, sodium chloride.Filler mainly contains: kaolin, precipitated calcium carbonate, bentonite.
The present invention is used for the water dispersible granules of control by the fluorine ether bacterium acid amides composite bactericide of the microbial disease of Oomycete cause of disease such as downy mildew, late blight, white eqpidemic disease, rotten mildew, damping off, balck shank, canker, white blister, (millet) poliosis, and it is to form (% by mass percentage) with following material combination:
1, fluorine ether bacterium acid amides: 1-50%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 1-45%
Dispersant: 0.5-5%
Wetting agent: 0.5-5%
Disintegrant: 1-10%
Adhesive: 0.5-5%
Surplus is a filler.
2, fluorine ether bacterium acid amides: 10-40%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 12-20%
Dispersant: 0.5-5%
Wetting agent: 0.5-5%
Disintegrant: 1-10%
Adhesive: 0.5-5%
Surplus is a filler.
3, fluorine ether bacterium acid amides: 20%,
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 40%
Calcium lignosulfonate: 3%
Aliphatic alcohol sulfate: 5%
Ammonium sulfate: 8%
Hydroxyethylcellulose: 4%
Surplus is a kaolin.
4, fluorine ether bacterium acid amides: 1%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 45%
Naphthalene sulfonate: 0.5%
Dodecyl benzene sulfonate: 0.5%
Urea: 1%
Soluble starch: 0.5%
Surplus is a precipitated calcium carbonate.
5, fluorine ether bacterium acid amides: 50%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 1%
Polycarboxylate: 5%
Peregal: 5%
Polyvinylpyrrolidone: 10%
Polyethylene glycol: 5%
Surplus is a bentonite.
6, fluorine ether bacterium acid amides: 1%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 45%
GY-D04:0.5%
The newborn 100#:5% of farming
Sodium sulphate: 1%
Methylcellulose: 5%
Surplus is a precipitated calcium carbonate.
7, fluorine ether bacterium acid amides: 50%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 1%
Naphthalenesulfonic acid-formaldehyde condensate: 5%
The newborn 600# tween of farming: 0.5%
Cellulose: 10%
Dextrin: 0.5%
Surplus is a kaolin.
8, fluorine ether bacterium acid amides: 10%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 12%
Naphthalenesulfonic acid-formaldehyde condensate: 0.5%
The newborn 600# tween of farming: 0.5%
Sodium bicarbonate: 1%
Polyvinyl alcohol: 0.5%
Surplus is a bentonite.
9, fluorine ether bacterium acid amides: 40%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 20%
Fatty acid amide-N methyl taurine salt: 5%
Sorbitol polyoxyethylene ether: 5%
Sldium lauryl sulfate: 10%
Fructose: 5%
Surplus is a precipitated calcium carbonate.
10, fluorine ether bacterium acid amides: 10%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 20%
Alkyl sulfate: 5%
Nekal BX: 0.5%
Sodium alginate: 10%
Dextrin: 0.5%
Surplus is a kaolin.
11, fluorine ether bacterium acid amides: 40%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 12%
Aliphatic alcohol polyether: 5%
Aliphatic alcohol sulfate: 0.5%
Bentonite: 10%
Hydroxyethylcellulose: 0.5%
Surplus is a precipitated calcium carbonate.
12, fluorine ether bacterium acid amides: 50%
(E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine: 45%
Alkyl sulfate: 0.5%
Nekal BX: 0.5%
Sodium alginate: 1%
Dextrin: 0.5%
Surplus is a bentonite.
Fluorine ether bacterium acid amides composite bactericide of the present invention also can contain other component, and for example other has the compound of weeding, desinsection or bactericidal property.Also can mix with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Fluorine ether bacterium acid amides composite bactericide of the present invention can improve the active duration of protection.Use a kind of carrier that can shift to the also slow release Fungicidal compounds of being protected of plant, the preparation of this slow release can be put near the soil the trailing plant root, or comprises a kind of adhesion component, so that can be applied directly on the stem of trailing plant.
Fluorine ether bacterium acid amides composite bactericide of the present invention can be used by common method, like blade face, dipping, cast, injection, spray, be fuming, distribution or dusting, select according to destination object and main environment.
The test of fluorine ether bacterium acid amides composite bactericide according to the invention is following:
Test 1: protection and therapeutic activity test (laboratory test)
At room temperature fluorine ether bacterium acid amides and other bactericide are tested their effect to bacterium of downy mildew of cucumber separately and jointly.
Method: the cucumber seedling pot-culture method is adopted in test, and cucumber grows to two leaves, one heart stage crop sprayer foliar spray handles, and chemicals treatment was carried out in therapeutic test inoculation in back 24 hours, and the inoculation back was investigated in 7-8 days.
The therapeutic activity test:
Test 2: protection and therapeutic activity test (laboratory test)
At room temperature fluorine ether bacterium acid amides and other bactericide are tested their effect to the tomato late blight bacterium separately and jointly.
Method: the tomato seedling pot-culture method is adopted in test, and tomato seedling grows to two leaves, one heart stage crop sprayer foliar spray to be handled, and chemicals treatment was carried out in therapeutic test inoculation in back 24 hours, and the inoculation back was investigated in 7-8 days.The therapeutic activity test:
Test 3: protection and therapeutic activity test (outdoor test)
At room temperature fluorine ether bacterium acid amides and other bactericide are tested their effect to wheat rust separately and jointly.
Method: at the wheat jointing or convert water spray booting stage and use, once sprayed two weeks " Invest, Then Investigate " result again at a distance from 7-10 days;
Claims (7)
1. fluorine ether bacterium acid amides composite bactericide; It is characterized in that: its active ingredient is fluorine ether bacterium acid amides and (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine, fluorine ether bacterium acid amides is 1-50%, (E; Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 1-45%.
2. a kind of fluorine ether bacterium acid amides composite bactericide according to claim 1 is characterized in that: its active ingredient be fluorine ether bacterium acid amides be 10-40%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 10-20%.
3. a kind of fluorine ether bacterium acid amides composite bactericide according to claim 1 is characterized in that: its active ingredient be fluorine ether bacterium acid amides be 15-25%, (E, Z)-4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 15-20%.
4. a kind of fluorine ether bacterium acid amides composite bactericide according to claim 1; It is characterized in that: the component of water dispersible granules is that fluorine ether bacterium acid amides is 10-40%, (E; Z)-4-[3-(4-chlorphenyl) 3-(3; The 4-Dimethoxyphenyl) acryloyl] morpholine is 12-20%, and dispersant is that 0.5-5%, wetting agent are that 0.5-5%, disintegrant are that 1-10%, adhesive are 0.5-5%, and surplus is a filler.
5. a kind of fluorine ether bacterium acid amides composite bactericide according to claim 1, it is characterized in that: the component of water dispersible granules is that fluorine ether bacterium acid amides is 20%, (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 40%, calcium lignosulfonate is 3%; Aliphatic alcohol sulfate is 5%; Ammonium sulfate is 8%, and hydroxyethylcellulose is 4%, and surplus is a kaolin.
6. a kind of fluorine ether bacterium acid amides composite bactericide according to claim 1, it is characterized in that: the component of water dispersible granules is that fluorine ether bacterium acid amides is 50%, (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 45%, alkyl sulfate is 0.5%; Nekal BX is 0.5%; Sodium alginate is 1%, and dextrin is 0.5%, and surplus is a bentonite.
7. a kind of fluorine ether bacterium acid amides composite bactericide according to claim 1, it is characterized in that: the component of water dispersible granules is that fluorine ether bacterium acid amides is 40%, (E; Z)-and 4-[3-(4-chlorphenyl) 3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine is 12%, aliphatic alcohol polyether is 5%; Aliphatic alcohol sulfate is 0.5%; Bentonite is 10%, and hydroxyethylcellulose is 0.5%, and surplus is a precipitated calcium carbonate.
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CN201310297334.5A CN103348984B (en) | 2012-07-24 | 2013-07-16 | Desflurane bacteria amide compound bactericide |
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Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102845436A (en) * | 2012-09-19 | 2013-01-02 | 山东省联合农药工业有限公司 | Bactericide composition containing fluoro-ether bacterium amide and dimethomorph |
WO2014015538A1 (en) * | 2012-07-24 | 2014-01-30 | 山东省联合农药工业有限公司 | Fluorine kresoxim amide compound bactericide |
CN104413031A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Compound pesticide composition containing fluoride ether bacteria amide |
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2012
- 2012-08-02 CN CN 201210272792 patent/CN102754650A/en active Pending
- 2012-08-07 WO PCT/CN2012/079764 patent/WO2014015538A1/en active Application Filing
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CN103348984B (en) | 2015-01-07 |
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