CN105613505A - Nematicide containing fluoride ether bacterium amide - Google Patents
Nematicide containing fluoride ether bacterium amide Download PDFInfo
- Publication number
- CN105613505A CN105613505A CN201610219967.8A CN201610219967A CN105613505A CN 105613505 A CN105613505 A CN 105613505A CN 201610219967 A CN201610219967 A CN 201610219967A CN 105613505 A CN105613505 A CN 105613505A
- Authority
- CN
- China
- Prior art keywords
- acid amides
- fluorine
- bacterium acid
- parts
- ether bacterium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
The invention discloses nematicide containing fluoride ether bacterium amide. Active ingredients at least comprise the fluoride ether bacterium amide and account for 0.01%-80% of the total weight of the nematicide, and the balance is auxiliary materials; preparations of the nematicide can be soluble liquid, emulsion in water, an aqueous solution, missible oil and granules; the active ingredients further can comprise the fluoride ether bacteria amide and a component A; and the component A is abamectin, fosthiazate, metham or dazomet. The nematicide disclosed by the invention has a remarkable insecticidal effect and relatively less use amount, has no phytotoxicity on crops, does not generate pesticide residues, has no drug resistance on the crops and is safe to human and livestock; the nematicide has relatively wide preparations, can be used for carrying out soil treatment before plant seedlings are planed, and also can be used for carrying out root irrigation or furrow application at a seedling stage of the plants; and the nematicide has a long pesticide effect, can be used for inhibiting hatching of nematode ova and killing nematodes in a whole growth period of the plants, and has a relatively good nematode killing effect on the crops.
Description
Technical field
The present invention relates to technical field of pesticide, it is the nematocides of a kind of fluorine-containing ether bacterium acid amides specifically.
Background technology
Control plant parasitic nematodes is to reaching the high harvest of plant and important, because the root damage that nematode is caused can cause crop yield and quality seriously to reduce, searching for food of nematode can significantly reduce plant to the absorption of nutrition and moisture, and it is searched for food, the wound caused also can provide convenient to phytopathogen invasion. The nematicide effect of current nematocides is poor, this mostly colonizes in soil or in plant materials by nematode, affect insecticidal effect, if improving concentration or the toxicity of nematocides, poisoning can be had even to form drug residue in farm crop crop, the safety of people and animals is caused harm, and therefore the insecticidal effect of existing nematocides is poor.
Summary of the invention
For solving the problem, it is an object of the invention to provide the nematocides of a kind of fluorine-containing ether bacterium acid amides.
The present invention for achieving the above object, is achieved through the following technical solutions:
A nematocides for fluorine-containing ether bacterium acid amides, its activeconstituents is at least containing fluorine ether bacterium acid amides, and activeconstituents accounts for the 0.01 ~ 80% of nematocides gross weight, and all the other are auxiliary material; The formulation of nematocides is soluble concentrate, aqueous emulsion, aqua, missible oil and granule.
Preferably, the activeconstituents of nematocides comprises fluorine ether bacterium acid amides and composition A, described composition A is Avrmectin, fosthiazate, metamsodium or dazomet, and activeconstituents accounts for the 5 ~ 30% of nematocides gross weight, and described fluorine ether bacterium acid amides and the weight ratio of composition A are 1 ~ 25:1 ~ 25.
Preferred further, activeconstituents accounts for the 10% of nematocides gross weight, and described fluorine ether bacterium acid amides and the weight ratio of composition A are 1:1 ~ 5.
Further preferred activeconstituents is fluorine ether bacterium acid amides and Avrmectin, and described activeconstituents accounts for the 10% of nematocides gross weight, and the weight ratio of fluorine ether bacterium acid amides and dazomet is 1:3.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 5 ~ 10 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 3 part, Avrmectin 2 ~ 5 parts, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 2 part, fosthiazate 3 ~ 6 parts, castor oil polyoxyethylene ether 1 ~ 2 part, polycarboxylate sodium 1 ~ 2 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 3 part, metamsodium 2 ~ 6 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 2 part, dazomet 2 ~ 5 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferred further, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 10 parts, castor oil polyoxyethylene ether 1.5 parts, 2 parts, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1.5 parts, fatty alcohol-polyoxyethylene ether 0.5 part, xanthan gum 0.15 part, neusilin 1.5 parts, dimethyl siloxane 0.3 part, Sodium Benzoate 0.3 part, glycerol 4 parts and deionized water 78.25 parts.
The present invention has the following advantages compared to existing technology:
The present invention adopts fluorine ether bacterium acid amides to obtain a kind of novel nematocides as activeconstituents, and the formulation of this nematocides is soluble concentrate, aqueous emulsion, aqua, missible oil and granule; Fluorine ether bacterium acid amides generally uses as sterilant in currently available products, Oomycete fungi germ there is very high biological activity, the fluorine ether bacterium acid amides of the present invention uses as nematocides, fluorine ether bacterium acid amides is low as toxic limit medium dose during nematocides, therefore the insecticidal effect of this nematocides is remarkable, consumption is less, crop can not have poisoning and produce drug residue, can not be developed immunity to drugs by crop; The formulation of the present invention is wider, namely it is used in the soil treatment before plant seedlings plantation, can carry out filling with root or ditch spread in the plant seedlings phase again, and drug effect is long, the hatching of line eggs can be suppressed whole vegetation period and kill nematode, crop is played good nematicide effect; One and fluorine ether bacterium acid amides compound in Avrmectin, fosthiazate, metamsodium and dazomet use, it is possible to greatly improve drug effect, play good synergistic function, and can delay the generation of resistance, play good nematocidal effect.
Embodiment
It is an object of the invention to provide the nematocides of a kind of fluorine-containing ether bacterium acid amides, it be achieved through the following technical solutions:
A nematocides for fluorine-containing ether bacterium acid amides, its activeconstituents is at least containing fluorine ether bacterium acid amides, and activeconstituents accounts for the 0.01 ~ 80% of nematocides gross weight, and all the other are auxiliary material; The formulation of nematocides is soluble concentrate, aqueous emulsion, aqua, missible oil and granule.
Preferably, the activeconstituents of nematocides comprises fluorine ether bacterium acid amides and composition A, described composition A is Avrmectin, fosthiazate, metamsodium or dazomet, and activeconstituents accounts for the 5 ~ 30% of nematocides gross weight, and described fluorine ether bacterium acid amides and the weight ratio of composition A are 1 ~ 25:1 ~ 25.
Preferred further, activeconstituents accounts for the 10% of nematocides gross weight, and described fluorine ether bacterium acid amides and the weight ratio of composition A are 1:1 ~ 5.
Further preferred activeconstituents is fluorine ether bacterium acid amides and Avrmectin, and described activeconstituents accounts for the 10% of nematocides gross weight, and the weight ratio of fluorine ether bacterium acid amides and dazomet is 1:3.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 5 ~ 10 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 3 part, Avrmectin 2 ~ 5 parts, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 2 part, fosthiazate 3 ~ 6 parts, castor oil polyoxyethylene ether 1 ~ 2 part, polycarboxylate sodium 1 ~ 2 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 3 part, metamsodium 2 ~ 6 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferably, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 2 part, dazomet 2 ~ 5 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
Preferred further, the nematocides of fluorine-containing ether bacterium acid amides, with parts by weight, composed of the following components: fluorine ether bacterium acid amides 10 parts, castor oil polyoxyethylene ether 1.5 parts, 2 parts, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1.5 parts, fatty alcohol-polyoxyethylene ether 0.5 part, xanthan gum 0.15 part, neusilin 1.5 parts, dimethyl siloxane 0.3 part, Sodium Benzoate 0.3 part, glycerol 4 parts and deionized water 78.25 parts.
The nematocides of fluorine-containing ether bacterium acid amides of the present invention has the hatching suppressing line eggs and the effect killing nematode; in the habitat that can act on nematode or soil; the root system of protection plant is not by the destruction of nematode; the solid dosage that can carry out liquid dosage form and the ditch spread filling with root can be processed into, such as soluble concentrate, aqueous emulsion, missible oil, aqua and granule etc.
The plant nematode of all kinds all can prevent and treat with the active ingredient combination of the present invention. Following nematode is had good prevention effect by the nematocides of the fluorine-containing ether bacterium acid amides of the present invention: root knot nematode, such as Meloidogyne incognita, javanese root knot nematode, M hapla, peanut root-knot nematode; Ditylenchus, such as, fuller's teasel Ditylenchus dipsaci, potato haulm nematode; Pratylenchidae belongs to, such as, and Cobb root, pseudo-Pratylenchidae, coffee pot handle, Lu Si Pratylenchidae, disability Pratylenchidae; Ball Heterodera, such as, globodera rostochiensis, pallidum golden nematode etc.; Heterodera, such as soybean cyst nematode etc.; Aphelenchoides, such as aphelenchoides besseyi, Aphelenchoides ritzema-bosi, strawberry sword nematode; Similes thorne belongs to, such as Radopholus similis Throne; Tylenchulus Semipenetrans belongs to, such as Tylenchulus Semipenetrans; Shallow bid spin line worm belongs to, such as kidney shape shallow bid spin line worm; Bursaphelenchus, such as pine wood nematode, Aphelenchoides, minute hand nematode genus, Xiphinema, burr nematode belong to.
The Dressing date of the nematocides of the fluorine-containing ether bacterium acid amides of the present invention is soil treatment or carry out filling with root or ditch spread in the plant seedlings phase before plant seedlings is transplanted, and ditches at surrounding plants and spreads fertilizer over the fields.
Missible oil (EC) or aqueous emulsion (EW) can be prepared like this: fluorine ether bacterium acid amides is dissolved in organic solvent (the optional mixture containing one or more wetting agents, one or more emulsifying agents). Suitable organic solvent for EC comprises aromatic hydrocarbon (such as alkylbenzene or alkylnaphthalene), ketone (such as pimelinketone or methylcyclohexanone) and alcohol (such as benzylalcohol, furfuryl alcohol or butanols).
Aqua can be prepared like this: is dissolved in deionized water by effective constituent, fatty alcohol-polyoxyethylene ether and alkyl glycoside to mix namely obtain aqua.
Granule (GR) can by carrying out granulating to the mixture of fluorine ether bacterium acid amides and one or more powdery solid diluent or carriers; or by making fluorine ether bacterium amide absorption enter honeycombed grain material; blank granule as preformed in float stone, attapulgite clay, Fuller's earth, diatomite or corn cob meal is formed; or by making fluorine ether bacterium acid amides (or its solution) in Suitable agents be adsorbed onto on hard core material such as sand, silicate, mineral carbonic acid salt, vitriol or phosphoric acid salt, and optionally drying is formed. It is commonly used to help the reagent absorbing or adsorbing to comprise solvent, such as aliphatic series and aromatic petroleum solvent, alcohol class, ether class, ketone class and ester class, and tackiness agent, such as polyvinyl acetate, polyvinyl alcohol, dextrin, carbohydrate and vegetables oil.
One or more other additives can also add in the formulation of nematocides of the present invention, and included formulation is as in soluble concentrate, aqueous emulsion, aqua, missible oil and granule.
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
The nematocides of a kind of fluorine-containing ether bacterium acid amides, the granule being made up of the corn cob meal of the fluorine ether bacterium acid amides of 0.1g and 1kg, concrete grammar is mix in 325 object corn cob meals for 0.1g fluorine ether bacterium acid amides is joined 1kg order number, namely obtains the nematocides of the fluorine-containing ether bacterium acid amides of particulate state.
Embodiment 2
A nematocides for fluorine-containing ether bacterium acid amides is the missible oil being mixed to get by 80g fluorine ether bacterium acid amides and 20g pimelinketone.
Embodiment 3
A nematocides for fluorine-containing ether bacterium acid amides, the soluble concentrate being made up of 10g fluorine ether bacterium acid amides, 3g castor oil polyoxyethylene ether, 4g neusilin, 1g Sodium Benzoate and 82g deionized water.
Embodiment 4
A nematocides for fluorine-containing ether bacterium acid amides, the aqueous emulsion being made up of 3g fluorine ether bacterium acid amides, 2g Avrmectin, 1g dimethyl siloxane, 4g glycerol and 90g deionized water.
Embodiment 5
A nematocides for fluorine-containing ether bacterium acid amides, the missible oil being made up of 10g fluorine ether bacterium acid amides, 20g metamsodium, 2g Sodium Benzoate, 3g polycarboxylate sodium, 1g xanthan gum and 64g deionized water.
Embodiment 6
A nematocides for fluorine-containing ether bacterium acid amides, the aqua being made up of 5g fluorine ether bacterium acid amides, 8g fatty alcohol-polyoxyethylene ether, 3g alkyl glycoside and 84g deionized water.
Embodiment 7
The nematocides of a kind of fluorine-containing ether bacterium acid amides, aqueous emulsion composed of the following components: fluorine ether bacterium acid amides 5g, castor oil polyoxyethylene ether 1g, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium 3g, polycarboxylate sodium 1g, fatty alcohol-polyoxyethylene ether 0.6g, xanthan gum 0.1g, neusilin 1.5g, dimethyl siloxane 0.4g, Sodium Benzoate 0.2g, glycerol 4g and deionized water 72g.
Embodiment 8
The nematocides of a kind of fluorine-containing ether bacterium acid amides, aqueous emulsion composed of the following components: fluorine ether bacterium acid amides 1g, Avrmectin 5g, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium 1g, polycarboxylate sodium 1g, fatty alcohol-polyoxyethylene ether 1g, xanthan gum 0.1g, neusilin 1g, dimethyl siloxane 0.1g, glycerol 1g and deionized water 70g.
Embodiment 9
The nematocides of a kind of fluorine-containing ether bacterium acid amides, aqueous emulsion composed of the following components: fluorine ether bacterium acid amides 2g, fosthiazate 6g, castor oil polyoxyethylene ether 2g, polycarboxylate sodium 1g, xanthan gum 0.1g, neusilin 2g, dimethyl siloxane 0.5g, Sodium Benzoate 0.1g, glycerol 4g and deionized water 80g.
Embodiment 10
The nematocides of a kind of fluorine-containing ether bacterium acid amides, aqueous emulsion composed of the following components: fluorine ether bacterium acid amides 2g, metamsodium 4g, castor oil polyoxyethylene ether 1g, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium 3g, polycarboxylate sodium 1g, fatty alcohol-polyoxyethylene ether 0.4g, xanthan gum 0.1g, neusilin 1.2g, Sodium Benzoate 0.3g, glycerol 3g and deionized water 74g.
Embodiment 11
The nematocides of a kind of fluorine-containing ether bacterium acid amides, aqueous emulsion composed of the following components: fluorine ether bacterium acid amides 1.4g, dazomet 4g, castor oil polyoxyethylene ether 1.2g, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium 1.5g, fatty alcohol-polyoxyethylene ether 0.6g, xanthan gum 0.15g, neusilin 1.8g, dimethyl siloxane 0.4g, Sodium Benzoate 0.2g, glycerol 3g and deionized water 75g.
Embodiment 12
The nematocides of a kind of fluorine-containing ether bacterium acid amides, aqueous emulsion composed of the following components: fluorine ether bacterium acid amides 10g, castor oil polyoxyethylene ether 1.5g, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium 2g, polycarboxylate sodium 1.5g, fatty alcohol-polyoxyethylene ether 0.5g, xanthan gum 0.15g, neusilin 1.5g, dimethyl siloxane 0.3g, Sodium Benzoate 0.3g, glycerol 4g and deionized water 78.25g.
1. pair fluorine ether bacterium acid amides is according to NY/T1833.1-2009 " farm-chemical indoor determination test rule nematocides " the 1st part: suppress plant pathogeny line insect test dip method to detect, and calculates fluorine ether bacterium acid amides to the regression equation of line eggs and nematode, LC50, that relation conefficient and 95% fiducial interval obtain table 1 result is as follows.
Table 1 fluorine ether bacterium acid amides is to the nematicide ovum of line eggs and nematode and nematicide effect table
| Regression equation | LC50(�� g/ml) | Relation conefficient (r) | 95% fiducial interval | |
| Line eggs | y=4.2202+0.8064x | 9.2672 | 0.9773 | 6.1477~13.9696 |
| Nematode | y=1.0288x+3.9643 | 10.1550 | 0.9806 | 6.7105~15.3676 |
As can be seen from Table 1, fluorine ether bacterium acid amides is lower to the toxic limit medium dose of line eggs and nematode, illustrates that fluorine ether bacterium acid amides has and well suppresses line eggs hatching, and can effectively kill nematode.
2. pair fluorine ether bacterium amide content be 10% nematocides detect, step and result are as follows:
Detecting step: according to GB/T17980.38-2000 " field control effectiveness test criterion (one) nematocides control root oxyuriasis ", choose root knot nematode and serious plot occurs throughout the year, dispenser before cucumber field planting, the liquid dosage form of fluorine ether bacterium acid amides adopts filling root mode to carry out dispenser, solid dosage adopts mode dispenser of spreading manuer in holes, the dispenser depth wants consistent, and medicine amount is even. Within after medicine 60 days, carrying out the inspection of pharmacodynamic results, result is as shown in table 2.
Table 2 fluorine ether bacterium amide content be the nematocides of 10% medicine after 60d prevention effect table
| Medicament title | Effective ingredient consumption (gram/acre) | 60d prevention effect (%) after medicine |
| 10% fluorine ether bacterium acid amides aqueous emulsion | 50 | 90% |
| 10% fluorine ether bacterium acid amides missible oil | 50 | 93% |
| 10% fluorine ether bacterium acid amides soluble concentrate | 50 | 95% |
| 10% fluorine ether bacterium acid amides granule | 50 | 91% |
| 10% fluorine ether bacterium acid amides aqua | 50 | 90% |
3. by fluorine ether bacterium acid amides and Avrmectin, fosthiazate, metamsodium or the composite use of dazomet product, and its co-toxicity is detected, measuring method is with reference to NY/T1833.1-2009 " farm-chemical indoor determination test rule nematocides " the 1st part: suppressing plant pathogeny line insect test dip method to carry out, result is as shown in table 3.
The co-toxicity result table of table 3 fluorine ether bacterium acid amides and Avrmectin, fosthiazate, metamsodium or the composite use of dazomet product
| Medicament title | LC50(mg/L) | Cotoxicity coefficient (CTC) |
| Fluorine ether bacterium acid amides: Avrmectin (1:3) | 0.32 | 280.6 |
| Fluorine ether bacterium acid amides: fosthiazate (1:5) | 0.65 | 220.3 |
| Fluorine ether bacterium acid amides: metamsodium (2:3) | 1.21 | 202.0 |
| Fluorine ether bacterium acid amides: dazomet (1:1) | 0.90 | 230.8 |
As shown in Table 3, fluorine ether bacterium acid amides and the composite use of Avrmectin, fosthiazate, metamsodium or dazomet, can greatly improve the nematicide effect of nematocides, can play good synergistic function.
4. the nematocides of pair embodiment 7 ~ 12 detects, and step and result are as follows:
Detecting step: according to GB/T17980.38-2000 " field control effectiveness test criterion (one) nematocides control root oxyuriasis ", choose root knot nematode and serious plot occurs throughout the year, dispenser before cucumber field planting, the liquid dosage form of fluorine ether bacterium acid amides adopts filling root mode to carry out dispenser, solid dosage adopts mode dispenser of spreading manuer in holes, the dispenser depth wants consistent, and medicine amount is even. Within after medicine 60 days, carrying out the inspection of pharmacodynamic results, result is as shown in table 4.
60 days prevention effect tables after the nematocides medicine of table 4 embodiment 7 ~ 12 gained
| Medicament title | Effective ingredient consumption (gram/acre) | 60 days prevention effect (%) after medicine |
| Embodiment 7 | 50 | 85% |
| Embodiment 8 | 50 | 91% |
| Embodiment 9 | 50 | 90% |
| Embodiment 10 | 50 | 91% |
| Embodiment 11 | 50 | 93% |
| Embodiment 12 | 50 | 97% |
As can be seen from the result of table 4, the nematocides consumption of the present invention is little, nematicide effect is remarkable, and especially fluorine ether bacterium acid amides and the composite use nematicide effect of Avrmectin, fosthiazate, metamsodium or dazomet product are remarkable, meets in current agricultural chemicals the action that the decrement advocated uses.
Claims (10)
1. the nematocides of a fluorine-containing ether bacterium acid amides, it is characterised in that: its activeconstituents is at least containing fluorine ether bacterium acid amides, and activeconstituents accounts for the 0.01 ~ 80% of nematocides gross weight, and all the other are auxiliary material; The formulation of nematocides is soluble concentrate, aqueous emulsion, aqua, missible oil and granule.
2. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 1, it is characterized in that: the activeconstituents of nematocides comprises fluorine ether bacterium acid amides and composition A, described composition A is Avrmectin, fosthiazate, metamsodium or dazomet, activeconstituents accounts for the 5 ~ 30% of nematocides gross weight, and described fluorine ether bacterium acid amides and the weight ratio of composition A are 1 ~ 25:1 ~ 25.
3. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 2, it is characterised in that: activeconstituents accounts for the 10% of nematocides gross weight, and described fluorine ether bacterium acid amides and the weight ratio of composition A are 1:1 ~ 5.
4. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 2, it is characterized in that: described activeconstituents is fluorine ether bacterium acid amides and Avrmectin, described activeconstituents accounts for the 10% of nematocides gross weight, and the weight ratio of fluorine ether bacterium acid amides and dazomet is 1:3.
5. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 1, it is characterized in that: with parts by weight, composed of the following components: fluorine ether bacterium acid amides 5 ~ 10 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
6. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 1, it is characterized in that: with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 3 part, Avrmectin 2 ~ 5 parts, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
7. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 1, it is characterized in that: with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 2 part, fosthiazate 3 ~ 6 parts, castor oil polyoxyethylene ether 1 ~ 2 part, polycarboxylate sodium 1 ~ 2 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
8. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 1, it is characterized in that: with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 3 part, metamsodium 2 ~ 6 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1 ~ 2 part, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
9. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 1, it is characterized in that: with parts by weight, composed of the following components: fluorine ether bacterium acid amides 1 ~ 2 part, dazomet 2 ~ 5 parts, castor oil polyoxyethylene ether 1 ~ 2 part, 1 ~ 3 part, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, fatty alcohol-polyoxyethylene ether 0.1 ~ 1 part, xanthan gum 0.1 ~ 0.2 part, neusilin 1 ~ 2 part, dimethyl siloxane 0.1 ~ 0.5 part, Sodium Benzoate 0.1 ~ 0.5 part, glycerol 1 ~ 5 part and deionized water 70 ~ 80 parts.
10. the nematocides of a kind of fluorine-containing ether bacterium acid amides according to claim 5, it is characterized in that: with parts by weight, composed of the following components: fluorine ether bacterium acid amides 10 parts, castor oil polyoxyethylene ether 1.5 parts, 2 parts, ethoxylated dodecyl alcohol sulfosuccinic ester two sodium, polycarboxylate sodium 1.5 parts, fatty alcohol-polyoxyethylene ether 0.5 part, xanthan gum 0.15 part, neusilin 1.5 parts, dimethyl siloxane 0.3 part, Sodium Benzoate 0.3 part, glycerol 4 parts and deionized water 78.25 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610219967.8A CN105613505B (en) | 2016-02-02 | 2016-04-11 | A kind of nematicide of fluorine-containing ether bacterium acid amides |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2016201041906 | 2016-02-02 | ||
| CN201620104190 | 2016-02-02 | ||
| CN201610219967.8A CN105613505B (en) | 2016-02-02 | 2016-04-11 | A kind of nematicide of fluorine-containing ether bacterium acid amides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105613505A true CN105613505A (en) | 2016-06-01 |
| CN105613505B CN105613505B (en) | 2017-12-19 |
Family
ID=56029214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610219967.8A Active CN105613505B (en) | 2016-02-02 | 2016-04-11 | A kind of nematicide of fluorine-containing ether bacterium acid amides |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105613505B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106342882A (en) * | 2016-08-25 | 2017-01-25 | 山东省联合农药工业有限公司 | Nematicidal composition and application thereof |
| CN106857659A (en) * | 2017-04-01 | 2017-06-20 | 江西凝盛生物科技有限公司 | A kind of thing table thimerosal of asepsis environment-protecting and preparation method thereof |
| CN107410298A (en) * | 2017-05-27 | 2017-12-01 | 石家庄市兴柏生物工程有限公司 | A kind of composition pesticide containing Avermectin B2 and its application |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086173A (en) * | 2010-09-07 | 2011-06-08 | 唐剑峰 | Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing |
| CN102754650A (en) * | 2012-07-24 | 2012-10-31 | 山东省联合农药工业有限公司 | Desflurane bacteria amide compound bactericide |
| CN103298341A (en) * | 2010-09-22 | 2013-09-11 | 拜耳知识产权有限责任公司 | Use of active ingredients for controlling nematodes in nematode-resistant crops |
| CN104585230A (en) * | 2014-12-30 | 2015-05-06 | 海利尔药业集团股份有限公司 | Nematicidal composition containing fosthiazate and fluopyram |
| CN104585190A (en) * | 2014-12-30 | 2015-05-06 | 海利尔药业集团股份有限公司 | Nematicide composition containing abamectin and fluopyram |
-
2016
- 2016-04-11 CN CN201610219967.8A patent/CN105613505B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086173A (en) * | 2010-09-07 | 2011-06-08 | 唐剑峰 | Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing |
| CN103298341A (en) * | 2010-09-22 | 2013-09-11 | 拜耳知识产权有限责任公司 | Use of active ingredients for controlling nematodes in nematode-resistant crops |
| CN102754650A (en) * | 2012-07-24 | 2012-10-31 | 山东省联合农药工业有限公司 | Desflurane bacteria amide compound bactericide |
| CN104585230A (en) * | 2014-12-30 | 2015-05-06 | 海利尔药业集团股份有限公司 | Nematicidal composition containing fosthiazate and fluopyram |
| CN104585190A (en) * | 2014-12-30 | 2015-05-06 | 海利尔药业集团股份有限公司 | Nematicide composition containing abamectin and fluopyram |
Non-Patent Citations (2)
| Title |
|---|
| 华乃震: "安全和环保型的农药水乳剂", 《现代农药》 * |
| 王连起 等: "50%氟醚菌酰胺水分散粒剂防治葡萄霜霉病田间药效试验", 《中外葡萄与葡萄酒》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106342882A (en) * | 2016-08-25 | 2017-01-25 | 山东省联合农药工业有限公司 | Nematicidal composition and application thereof |
| CN106342882B (en) * | 2016-08-25 | 2019-05-21 | 山东省联合农药工业有限公司 | A kind of nematicidal composition and application thereof |
| CN106857659A (en) * | 2017-04-01 | 2017-06-20 | 江西凝盛生物科技有限公司 | A kind of thing table thimerosal of asepsis environment-protecting and preparation method thereof |
| CN107410298A (en) * | 2017-05-27 | 2017-12-01 | 石家庄市兴柏生物工程有限公司 | A kind of composition pesticide containing Avermectin B2 and its application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105613505B (en) | 2017-12-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9848542B2 (en) | Compositions and methods for the treatment of soil | |
| CN106342882B (en) | A kind of nematicidal composition and application thereof | |
| CN102349506B (en) | Ultralow-volume solvent containing Flusilazole | |
| CN105613505A (en) | Nematicide containing fluoride ether bacterium amide | |
| EP2242369A1 (en) | Use of bio-derived surfactants for mitigating damage to plants from pests | |
| US20080166437A1 (en) | Methods of reducing pests and treating gastrointestinal nematode infections | |
| CN107509734A (en) | A kind of nematicidal composition | |
| BG66218B1 (en) | Fungicide compositions | |
| CN103814934B (en) | A kind of nematicidal composition | |
| BG107509A (en) | Fungicidal composition comprising in particular an oil of vegetable origin with high drying power | |
| JP4055021B2 (en) | Insecticides and acaricides | |
| CN115067341B (en) | Nematicidal composition | |
| CA2769988C (en) | Compositions and methods for the treatment of soil | |
| CN106577718A (en) | Weeding composition including furan sulcotrione and pyriftalid | |
| CN103271081B (en) | Etoxazole-triazophospesticide pesticide composition | |
| RU2638044C1 (en) | Composition for treating agricultural crop seeds | |
| CN104839226A (en) | Combined nematicide | |
| CN103704258B (en) | A kind of Fungicidal insecticidal composition containing abietic acid ketone | |
| CN107683854A (en) | A kind of nematicide of containing fluopyram and methyl jasmonate | |
| CN106973914A (en) | A kind of Herbicidal combinations and its application | |
| CN116369322A (en) | Pesticide composition of trifloxystrobin and application thereof | |
| CN103734182B (en) | A kind of Fungicidal insecticidal composition containing mancozeb | |
| CN115067343A (en) | Nematicidal composition | |
| CN113455512A (en) | Nematicidal composition containing allyl isothiocyanate and fluensulfone and application thereof | |
| JPH08198710A (en) | Controller for soil disease damage |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |