CN105901002A - Sterilization composition containing fluoride ether bacteria amide and dimethomorph and application thereof - Google Patents

Sterilization composition containing fluoride ether bacteria amide and dimethomorph and application thereof Download PDF

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Publication number
CN105901002A
CN105901002A CN201610361996.8A CN201610361996A CN105901002A CN 105901002 A CN105901002 A CN 105901002A CN 201610361996 A CN201610361996 A CN 201610361996A CN 105901002 A CN105901002 A CN 105901002A
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CN
China
Prior art keywords
dimethomorph
ether bacterium
bacterium amide
fluorine ether
bactericidal composition
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Pending
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CN201610361996.8A
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Chinese (zh)
Inventor
杨琴
白杰
高瑞花
夏小云
孙会杰
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Nanjing Huazhou Pharmaceutical Co Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Priority to CN201610361996.8A priority Critical patent/CN105901002A/en
Publication of CN105901002A publication Critical patent/CN105901002A/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Abstract

The invention discloses a sterilization composition containing fluoride ether bacteria amide and dimethomorph and application thereof. The sterilization composition takes fluoride ether bacteria amide and dimethomorph as main effective components, wherein the mass ratio of fluoride ether bacteria amide to dimethomorph is (1-70) to (1-50). The sterilization composition can be applied to prevention and treatment of diseases of cereals, fruit trees and vegetables, has relatively high synergistic effect, can be used for overcoming and delaying the drug resistance of bacteria, and has the advantages of rapid sterilization effect, long lasting period and capability of reducing the application cost; and the prevention and treatment effect is obviously better than that of a single dosage. The sterilization composition can be used for preventing and treating fungal diseases on the crops and is particularly suitable for preventing and treating the fungal diseases including grape downy mildew, phytophthora capsici, potato late blight, rice sheath blight, cotton seedling damping-off, apple powdery mildew and the like, and the effect is remarkably better than that of single dosages.

Description

A kind of fluorine-containing ether bacterium amide and the bactericidal composition of dimethomorph and application thereof
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially a kind of based on fluorine ether bacterium amide and dimethomorph Want bactericidal composition and the application thereof of active component.
Background technology
Fluorine ether bacterium amide molecule formula: C15H8ClF7N2O2, chemical name: N-(3-chloro-5-(trichloromethyl) pyridine-2-first Base)-2,3,5,6-four chloro-4-methoxy benzamide.Structural formula is as follows:
Fluorine ether bacterium amide acts on the respiratory chain of fungal mitochondria, the activity of suppression succinate dehydrogenase, thus blocks electricity Son transmission, suppress fungus spore germination, germ tube extend, mycelial growth and spore mother cell formed fungus growth and breeding main In the stage, bactericidal action is directly caused by parent active agent, does not has corresponding metabolic activity, for downy mildew of garpe, Phytophthora capsici, The multiple fungal diseases such as the late blight of potato, rice sheath blight disease, cotton seedling blight all have higher preventive effect, are that one is novel extensively Spectrum antibacterial.
Dimethomorph (dimethomorph), molecular formula: C21H22ClNO4, chemical name: (E, Z)-4-[3-(4-chlorobenzene Base) 3-(3,4-Dimethoxyphenyl) acryloyl] morpholine.Structural formula:
Dimethomorph is a kind of novel interior suction therapeutic special low toxicity antibacterial, and its mechanism of action is to destroy pathogenic bacteria cell wall The formation of film, causes the decomposition of spore cyst wall, and makes pathogenic bacteria dead.To downy mildew, peronospora tabacina, late blight, phytophthora rot, rotten mould The fungal diseases such as disease are respectively provided with good prevention effect.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc. Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens；Separately On the one hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant Disease control is faced with significant challenge.
Summary of the invention:
It is an object of the invention to provide a kind of applied widely, low cost, effective fluorine-containing for above-mentioned technical problem Ether bacterium amide and the plant bactericidal composition of dimethomorph.
It is a still further object of the present invention to provide this bactericidal composition and cause answering on fungal disease at preventing and treating plant epiphyte With, especially preventing and treating downy mildew of garpe, Phytophthora capsici, the late blight of potato, rice sheath blight disease, cotton seedling blight, Oryza sativa L. rice Purposes on the fungal diseases such as pestilence.
It is an object of the invention to be achieved through the following technical solutions:
A kind of fluorine-containing ether bacterium amide and the bactericidal composition of dimethomorph, this bactericidal composition is with fluorine ether bacterium amide and alkene acyl Morpholine is principle active component, and wherein fluorine ether bacterium amide is 1～70:1～50 with the mass ratio of dimethomorph, wherein Bactericidal composite In thing, active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein fluorine ether bacterium amide is preferably 1～30:1～50 with the mass ratio of dimethomorph, enters One step is preferably 1～20:1～20.
In the compositions of the present invention, account for both fluorine ether bacterium amide and dimethomorph the weight/mass percentage composition of compositions be 2～ 80%.Preferably 10～40%, the most preferably 5～20:1～10.The preferred mass of fluorine ether bacterium amide and dimethomorph is joined Ratio can also be: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30, 1:50.
In the compositions of the present invention, account for both fluorine ether bacterium amide and dimethomorph the weight/mass percentage composition of compositions be 2～ 80%.Preferably 5～70%.
Described bactericidal composition, wherein with fluorine ether bacterium amide and dimethomorph for principle active component and known auxiliary agent Any one dosage form allowed it is re-dubbed on pesticide with excipient.Auxiliary agent known to these, excipient have dispersant, diffusant, Defoamer, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol polyoxy second Alkene ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products, aliphatic amine polyoxyethylene ether, fatty acid Ethylene oxide adduct, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphorous acid One or more combinations in salt, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc., excipient Including Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and Other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating cereal Application in terms of class, fruit tree, vegetable crop disease has significant effect.
Above-mentioned application, described fungal diseases of plants is downy mildew of garpe, Phytophthora capsici, the late blight of potato, Oryza sativa L. At least one in banded sclerotial blight, cotton seedling blight, rice blast.
The feature of bactericidal composition of the present invention:
1, the fluorine ether bacterium amide used by the present invention and dimethomorph, the mechanism of action is different, and mutual mixture will not produce low touching, Can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable, Particularly prevent and treat downy mildew of garpe, Phytophthora capsici, the late blight of potato, rice sheath blight disease, cotton seedling blight, rice blast etc. All there is significant effect.Ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease are had very well by bactericidal composition of the present invention Prevention effect；And suppress insect or fungus or the antibacterial Drug resistance to unitary agent (fluorine ether bacterium amide and dimethomorph are arbitrary) Generation.Bactericidal composition of the present invention can produce higher synergistic function, and the amount ratio of this mixture is the most active The consumption of compound is substantially reduced, and i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as The fungal diseases such as downy mildew of garpe, Phytophthora capsici, the late blight of potato, rice sheath blight disease, cotton seedling blight, rice blast have Substantially synergistic function, overcomes and has delayed Drug resistance, and expanding prevention is composed, hence it is evident that improve prevention effect；(2) preventing and treating is reduced Recruitment, drug cost；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, produce and use cost drops Low；(5) the suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is routine side Method, " % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A single dose toxicity index of proportion+B single dose in mixture of theoretical toxicity index=A single dose × B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, and CTC exists It it is summation action between 80-120.
According to effective ingredient fluorine ether bacterium amide (A): dimethomorph (B) quality proportioning is: 80:1,70:1,50:1,30:1, 20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:30,1:50,1:60,1:70 test, and survey Its common poison system to downy mildew of garpe (Plasmopara viticola (Berk.dt Curtis) Berl.Et de Toni.) fixed Number.
Table 1: fluorine ether bacterium amide+dimethomorph different ratio indoor biometrics result to downy mildew of garpe
Field control effectiveness test:
The pesticidal preparations prepared with above-described embodiment prevents and treats downy mildew of garpe test.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine Agent is pesticide single dose 50% fluorine ether bacterium amide WP and 50% dimethomorph WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating before dispenser and preventing and treating Method is: randomization 5 point in test treatment region, carries out severity Scaling according to country's field test relevant criterion, calculates preventive effect. Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, fluorine ether bacterium amide and dimethomorph compositions have significantly association Same potentiation, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural is applied Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates two kinds with specific embodiment below The preparation that effective ingredient is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% fluorine ether bacterium amide dimethomorph wettable powder (1:2)
By fluorine ether bacterium amide 5g, dimethomorph 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, expansion Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out comminution by gas stream, prepares and has Effect Ingredient percent is 15% fluorine ether bacterium amide dimethomorph wettable powder.
Embodiment 2:15% fluorine ether bacterium amide dimethomorph wettable powder (1:4)
By fluorine ether bacterium amide 3g, dimethomorph 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, high Ridge soil adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 15% fluorine ether bacterium amide alkene acyl Quinoline wettable powder.
Embodiment 3:14% fluorine ether bacterium amide dimethomorph wettable powder (1:6)
By fluorine ether bacterium amide 2g, dimethomorph 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g, high Ridge soil adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent is 14% fluorine ether bacterium amide alkene acyl Quinoline wettable powder.
Embodiment 4:20% fluorine ether bacterium amide dimethomorph suspending agent (1:1)
Weigh 10g fluorine ether bacterium amide, 10g dimethomorph, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof 4g, xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at the work of sand mill Making effective Ingredient percent under with is 20% fluorine ether bacterium amide dimethomorph suspending agent.
Embodiment 5:55% fluorine ether bacterium amide dimethomorph aqueous emulsion (1:10)
Weigh 5g fluorine ether bacterium amide, 50g dimethomorph, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane Base phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely is thrown Entering the mixing of mixing kettle high speed, making effective Ingredient percent is 55% fluorine ether bacterium amide dimethomorph aqueous emulsion.
Embodiment 6:42% fluorine ether bacterium amide dimethomorph cream (1:20)
Weigh 2g fluorine ether bacterium amide, 40g dimethomorph, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient Mass percent is 42% fluorine ether bacterium amide dimethomorph cream.
Embodiment 7:70% fluorine ether bacterium amide dimethomorph cream (2.5:1)
Weigh 50g fluorine ether bacterium amide, 20g dimethomorph, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor oil polyoxyethylene ether 2g, 150# solvent naphtha to 100g.The method that above raw material is prepared cream routinely puts into mixing Mixing in still, making effective Ingredient percent is 70% fluorine ether bacterium amide dimethomorph cream.
Embodiment 8:18% fluorine ether bacterium amide dimethomorph water dispersion granule (5:1)
Weigh 15g fluorine ether bacterium amide, 3g dimethomorph, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, Polyvinyl alcohol 5g, Borax 2g, kieselguhr complements to 100g, is formed with imitating into sub-prime by water dispersible granular agent method by above raw material Amount percentage ratio is 17% fluorine ether bacterium amide dimethomorph water dispersion granule.
Embodiment 9:11% fluorine ether bacterium amide dimethomorph cream (10:1)
Weigh 10g fluorine ether bacterium amide, 1g dimethomorph, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient Mass percent is 11% fluorine ether bacterium amide dimethomorph cream.
Embodiment 10:31.5% fluorine ether bacterium amide micellar emulsion of dimethomorph (20:1)
Weigh 30g fluorine ether bacterium amide, 1.5g dimethomorph, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether Phosphate ester 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is joined routinely The method of microemulsion processed puts in mixing kettle and mixes, and making effective Ingredient percent is 31.5% fluorine ether bacterium amide alkene acyl Morpholine microemulsion.
Embodiment 11:31% fluorine ether bacterium amide dimethomorph cream (30:1)
Weigh 30g fluorine ether bacterium amide, 1g dimethomorph, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effective ingredient Mass percent is 31% fluorine ether bacterium amide dimethomorph cream.
Embodiment 12:51% fluorine ether bacterium amide dimethomorph suspending agent (50:1)
Weigh 50g fluorine ether bacterium amide, 1g dimethomorph, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill Making effective Ingredient percent is 51% fluorine ether bacterium amide dimethomorph suspending agent.
Embodiment 13:32% fluorine ether bacterium amide micellar emulsion of dimethomorph (1:15)
Weigh 2g fluorine ether bacterium amide, 30g dimethomorph, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared routinely The method of microemulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 32% fluorine ether bacterium amide dimethomorph Microemulsion.
Embodiment 14:6% fluorine ether bacterium amide dimethomorph aqueous emulsion (1:5)
Weigh 1g fluorine ether bacterium amide, 5g dimethomorph, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is prepared aqueous emulsion routinely puts into Mixing kettle high speed mixes, and making effective Ingredient percent is 6% fluorine ether bacterium amide dimethomorph aqueous emulsion.
Embodiment 15:62% fluorine ether bacterium amide micellar emulsion of dimethomorph (1:30)
Weigh 2g fluorine ether bacterium amide, 60g dimethomorph, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.Above raw material is prepared routinely The method of microemulsion puts in mixing kettle and mixes, and making effective Ingredient percent is 62% fluorine ether bacterium amide dimethomorph Microemulsion.
Embodiment 16:51% fluorine ether bacterium amide dimethomorph suspending agent (1:50)
Weigh 1g fluorine ether bacterium amide, 50g dimethomorph, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof, Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, under the effect of sand mill Making effective Ingredient percent is 51% fluorine ether bacterium amide dimethomorph suspending agent.
Embodiment 17:7% fluorine ether bacterium amide dimethomorph water dispersion granule (1:2.5)
Weigh 2g fluorine ether bacterium amide, 5g dimethomorph, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g, gather Vinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, are formed with by water dispersible granular agent method by above raw material Effect Ingredient percent is 7% fluorine ether bacterium amide dimethomorph water dispersion granule.

Claims (10)

1. a fluorine-containing ether bacterium amide and the bactericidal composition of dimethomorph, it is characterised in that this bactericidal composition is with fluorine ether bacterium acyl Amine and dimethomorph are principle active component, and wherein fluorine ether bacterium amide is 1～70:1～50 with the mass ratio of dimethomorph.
Bactericidal composition the most according to claim 1, it is characterised in that described fluorine ether bacterium amide and the quality of dimethomorph Ratio is 1～30:1～50.
Bactericidal composition the most according to claim 2, it is characterised in that described fluorine ether bacterium amide and the quality of dimethomorph Ratio is 1～20:1～20.
Bactericidal composition the most according to claim 3, it is characterised in that described fluorine ether bacterium amide and the quality of dimethomorph Ratio is 5～20:1～10.
Bactericidal composition the most according to claim 1, it is characterised in that both described fluorine ether bacterium amide and dimethomorph The weight/mass percentage composition accounting for compositions is 2-80%.
Bactericidal composition the most according to claim 5, it is characterised in that both described fluorine ether bacterium amide and dimethomorph The weight/mass percentage composition accounting for compositions is 5-70%.
Bactericidal composition the most according to claim 1, it is characterised in that with fluorine ether bacterium amide and dimethomorph for mainly having Effect composition and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 7, it is characterised in that described dosage form be cream, suspending agent, aqueous emulsion, Wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 9, it is characterised in that described fungal diseases of plants is downy mildew of garpe, Fructus Capsici At least one in phytophthora, the late blight of potato, rice sheath blight disease, cotton seedling blight, rice blast.
CN201610361996.8A 2016-05-26 2016-05-26 Sterilization composition containing fluoride ether bacteria amide and dimethomorph and application thereof Pending CN105901002A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020193251A1 (en) * 1997-04-16 2002-12-19 Agrogene Ltd. Synergistic mixtures of selected amino acids
CN102086173A (en) * 2010-09-07 2011-06-08 唐剑峰 Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing
CN102754650A (en) * 2012-07-24 2012-10-31 山东省联合农药工业有限公司 Desflurane bacteria amide compound bactericide
CN102845436A (en) * 2012-09-19 2013-01-02 山东省联合农药工业有限公司 Bactericide composition containing fluoro-ether bacterium amide and dimethomorph

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020193251A1 (en) * 1997-04-16 2002-12-19 Agrogene Ltd. Synergistic mixtures of selected amino acids
CN102086173A (en) * 2010-09-07 2011-06-08 唐剑峰 Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing
CN102754650A (en) * 2012-07-24 2012-10-31 山东省联合农药工业有限公司 Desflurane bacteria amide compound bactericide
CN102845436A (en) * 2012-09-19 2013-01-02 山东省联合农药工业有限公司 Bactericide composition containing fluoro-ether bacterium amide and dimethomorph

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